CA2390353A1 - Procede d'utilisation de polymeres associatifs rendus hydrophobes dans la preparation de compositions de fibres cellulosiques et compositions de fibres cellulosiques contenant lespolymeres associatifs rendus hydrophobes - Google Patents
Procede d'utilisation de polymeres associatifs rendus hydrophobes dans la preparation de compositions de fibres cellulosiques et compositions de fibres cellulosiques contenant lespolymeres associatifs rendus hydrophobes Download PDFInfo
- Publication number
- CA2390353A1 CA2390353A1 CA002390353A CA2390353A CA2390353A1 CA 2390353 A1 CA2390353 A1 CA 2390353A1 CA 002390353 A CA002390353 A CA 002390353A CA 2390353 A CA2390353 A CA 2390353A CA 2390353 A1 CA2390353 A1 CA 2390353A1
- Authority
- CA
- Canada
- Prior art keywords
- ethylenically unsaturated
- unsaturated monomer
- cellulosic fiber
- hydrophobic
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 222
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 62
- 239000000835 fiber Substances 0.000 title claims description 54
- 239000000178 monomer Substances 0.000 claims abstract description 213
- 125000002091 cationic group Chemical group 0.000 claims abstract description 81
- 125000000129 anionic group Chemical group 0.000 claims abstract description 71
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 68
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 62
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 62
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 claims description 36
- 150000003839 salts Chemical class 0.000 claims description 34
- 125000000217 alkyl group Chemical group 0.000 claims description 26
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 24
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 21
- 239000002002 slurry Substances 0.000 claims description 20
- 125000001165 hydrophobic group Chemical group 0.000 claims description 18
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 16
- -1 hydrocarbon esters Chemical class 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 15
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 12
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 claims description 11
- 239000013055 pulp slurry Substances 0.000 claims description 11
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 8
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 8
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 8
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 8
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 claims description 8
- OFESGEKAXKKFQT-UHFFFAOYSA-N n-ethenyl-n-methylformamide Chemical compound C=CN(C)C=O OFESGEKAXKKFQT-UHFFFAOYSA-N 0.000 claims description 8
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 150000003863 ammonium salts Chemical class 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims description 5
- 150000001735 carboxylic acids Chemical class 0.000 claims description 5
- 125000001188 haloalkyl group Chemical group 0.000 claims description 5
- YPHQUSNPXDGUHL-UHFFFAOYSA-N n-methylprop-2-enamide Chemical group CNC(=O)C=C YPHQUSNPXDGUHL-UHFFFAOYSA-N 0.000 claims description 5
- 229920005547 polycyclic aromatic hydrocarbon Polymers 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 229920006318 anionic polymer Polymers 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 3
- 239000011976 maleic acid Substances 0.000 claims 3
- 229920001577 copolymer Polymers 0.000 abstract description 24
- 229920002472 Starch Polymers 0.000 description 53
- 235000019698 starch Nutrition 0.000 description 53
- 230000014759 maintenance of location Effects 0.000 description 50
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- 239000000463 material Substances 0.000 description 33
- 208000023445 Congenital pulmonary airway malformation Diseases 0.000 description 30
- 239000000123 paper Substances 0.000 description 28
- 244000061456 Solanum tuberosum Species 0.000 description 27
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- 238000012360 testing method Methods 0.000 description 26
- 230000000694 effects Effects 0.000 description 23
- 229920001592 potato starch Polymers 0.000 description 23
- 239000000243 solution Substances 0.000 description 22
- 229910052739 hydrogen Inorganic materials 0.000 description 21
- 239000001257 hydrogen Substances 0.000 description 18
- 239000007787 solid Substances 0.000 description 17
- 239000000440 bentonite Substances 0.000 description 12
- 229910000278 bentonite Inorganic materials 0.000 description 12
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 12
- 239000004927 clay Substances 0.000 description 12
- 239000000701 coagulant Substances 0.000 description 12
- 239000000945 filler Substances 0.000 description 12
- 230000004044 response Effects 0.000 description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- 229920002401 polyacrylamide Polymers 0.000 description 11
- 238000003860 storage Methods 0.000 description 11
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 10
- 125000004985 dialkyl amino alkyl group Chemical group 0.000 description 10
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 10
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 9
- 230000001965 increasing effect Effects 0.000 description 9
- 230000010355 oscillation Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 229940048053 acrylate Drugs 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical class NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 8
- 239000008394 flocculating agent Substances 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 239000011087 paperboard Substances 0.000 description 8
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 7
- 239000000654 additive Substances 0.000 description 7
- 125000001931 aliphatic group Chemical group 0.000 description 7
- 125000002947 alkylene group Chemical group 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- 239000000706 filtrate Substances 0.000 description 7
- 150000002431 hydrogen Chemical class 0.000 description 7
- 150000003926 acrylamides Chemical class 0.000 description 6
- 238000012512 characterization method Methods 0.000 description 6
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 6
- 229920000847 nonoxynol Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000006467 substitution reaction Methods 0.000 description 6
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 5
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- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 229920003169 water-soluble polymer Polymers 0.000 description 5
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 4
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 4
- 125000005907 alkyl ester group Chemical group 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 4
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- CRSBERNSMYQZNG-UHFFFAOYSA-N 1 -dodecene Natural products CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
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- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
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- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 239000005862 Whey Substances 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 229920002522 Wood fibre Polymers 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- AMVQGJHFDJVOOB-UHFFFAOYSA-H aluminium sulfate octadecahydrate Chemical group O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O AMVQGJHFDJVOOB-UHFFFAOYSA-H 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- NHIXZFCJMICYJZ-UHFFFAOYSA-N benzene;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.C1=CC=CC=C1 NHIXZFCJMICYJZ-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- WQHCGPGATAYRLN-UHFFFAOYSA-N chloromethane;2-(dimethylamino)ethyl prop-2-enoate Chemical compound ClC.CN(C)CCOC(=O)C=C WQHCGPGATAYRLN-UHFFFAOYSA-N 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000001246 colloidal dispersion Methods 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 231100000673 dose–response relationship Toxicity 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000005670 ethenylalkyl group Chemical group 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- DFENKTCEEGOWLB-UHFFFAOYSA-N n,n-bis(methylamino)-2-methylidenepentanamide Chemical compound CCCC(=C)C(=O)N(NC)NC DFENKTCEEGOWLB-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- ATZHWSYYKQKSSY-UHFFFAOYSA-N tetradecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)=C ATZHWSYYKQKSSY-UHFFFAOYSA-N 0.000 description 1
- XZHNPVKXBNDGJD-UHFFFAOYSA-N tetradecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C=C XZHNPVKXBNDGJD-UHFFFAOYSA-N 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical group FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- KEROTHRUZYBWCY-UHFFFAOYSA-N tridecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C(C)=C KEROTHRUZYBWCY-UHFFFAOYSA-N 0.000 description 1
- XOALFFJGWSCQEO-UHFFFAOYSA-N tridecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C=C XOALFFJGWSCQEO-UHFFFAOYSA-N 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- 239000003190 viscoelastic substance Substances 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002025 wood fiber Substances 0.000 description 1
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/10—Retention agents or drainage improvers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/37—Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
- D21H17/375—Poly(meth)acrylamide
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/42—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups anionic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
Landscapes
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
On décrit un procédé de fabrication de papier et une composition qui renferme, en tant qu'adjuvant d'égouttage, un polymère associatif soluble dans l'eau modifié de manière hydrophobe qui est un copolymère préparé à partir de monomères comprenant un monomère hydrophobe non saturé par l'éthylène et au moins un monomère non ionique non saturé par l'éthylène, un monomère cationique non saturé par l'éthylène et un monomère anionique non saturé par l'éthylène.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US45502799A | 1999-12-06 | 1999-12-06 | |
| US09/455,027 | 1999-12-06 | ||
| PCT/US2000/032820 WO2001040578A1 (fr) | 1999-12-06 | 2000-11-30 | Procede d'utilisation de polymeres associatifs rendus hydrophobes dans la preparation de compositions de fibres cellulosiques et compositions de fibres cellulosiques contenant les polymeres associatifs rendus hydrophobes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2390353A1 true CA2390353A1 (fr) | 2001-06-07 |
Family
ID=23807073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002390353A Abandoned CA2390353A1 (fr) | 1999-12-06 | 2000-11-30 | Procede d'utilisation de polymeres associatifs rendus hydrophobes dans la preparation de compositions de fibres cellulosiques et compositions de fibres cellulosiques contenant lespolymeres associatifs rendus hydrophobes |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20020053413A1 (fr) |
| EP (1) | EP1257709A1 (fr) |
| JP (1) | JP2003517104A (fr) |
| KR (1) | KR20020058086A (fr) |
| CN (1) | CN1408039A (fr) |
| AR (1) | AR026734A1 (fr) |
| AU (1) | AU1813801A (fr) |
| BR (1) | BR0016160A (fr) |
| CA (1) | CA2390353A1 (fr) |
| MX (1) | MXPA02005108A (fr) |
| PL (1) | PL366291A1 (fr) |
| RU (1) | RU2002114071A (fr) |
| WO (1) | WO2001040578A1 (fr) |
| ZA (1) | ZA200205443B (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8241462B2 (en) | 2007-07-26 | 2012-08-14 | Harima Chemicals, Inc. | Papermaking internal sizing agent and use thereof |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE60235268D1 (de) * | 2001-12-07 | 2010-03-18 | Hercules Inc | Anionische Copolymere erhältlich in inverser Emulsion sowie deren Verwendung zur Herstellung von Cellulosefaser-Mischungen |
| US20040204535A1 (en) * | 2002-05-20 | 2004-10-14 | Philip Confalone | Cationic coating for printable surfaces |
| DE10223279A1 (de) | 2002-05-24 | 2003-12-04 | Basf Ag | Hydrophob modifizierte Vinylamin- oder Ethylenimineinheiten enthaltende Polymere, Verfahren zur ihrer Herstellung und ihre Verwendung als Retentionsmittel |
| WO2004020736A1 (fr) * | 2002-08-27 | 2004-03-11 | Kao Corporation | Additif ameliorant la qualite du papier |
| DE60202869T2 (de) * | 2002-09-11 | 2006-04-27 | Gkss-Forschungszentrum Geesthacht Gmbh | Polymermasse, Materialien hieraus und deren Anwendungen |
| FI20030490A7 (fi) * | 2003-04-01 | 2004-10-02 | M Real Oyj | Menetelmä kuitukoostumuksen valmistamiseksi |
| US7041197B2 (en) * | 2003-04-15 | 2006-05-09 | Fort James Corporation | Wet strength and softness enhancement of paper products |
| DE10334133A1 (de) | 2003-07-25 | 2005-02-24 | Basf Ag | Wässrige Zusammensetzung und deren Verwendung zur Papierherstellung |
| DE102004044379B4 (de) * | 2004-09-10 | 2008-01-10 | Basf Ag | Verfahren zur Herstellung von Papier, Pappe und Karton und Verwendung einer Retentionsmittelkombination |
| RU2363678C2 (ru) * | 2004-09-21 | 2009-08-10 | Лафарж | Композиция для нейтрализации примесей |
| DE102004056551A1 (de) * | 2004-11-23 | 2006-05-24 | Basf Ag | Verfahren zur Herstellung von Papier, Pappe und Karton mit hoher Trockenfestigkeit |
| US20060142431A1 (en) * | 2004-12-29 | 2006-06-29 | Sutman Frank J | Retention and drainage in the manufacture of paper |
| US20060142432A1 (en) * | 2004-12-29 | 2006-06-29 | Harrington John C | Retention and drainage in the manufacture of paper |
| US20060266488A1 (en) * | 2005-05-26 | 2006-11-30 | Doherty Erin A S | Hydrophobic polymers and their use in preparing cellulosic fiber compositions |
| RU2329297C1 (ru) * | 2007-02-16 | 2008-07-20 | Открытое акционерное общество "Нэфис Косметикс"-Казанский химический комбинат им. М. Вахитова | ГРАНУЛИРОВАННОЕ СИНТЕТИЧЕСКОЕ МОЮЩЕЕ СРЕДСТВО Bi 10 (ВАРИАНТЫ) |
| KR100877788B1 (ko) * | 2007-06-25 | 2009-01-08 | 양병선 | 음이온성 올리고머 수지를 함유한 벽지 |
| CN101935960B (zh) * | 2010-08-11 | 2012-08-22 | 淄博欧木特种纸业有限公司 | 人造板饰面喷涂专用纸及其制作方法 |
| CN101974122B (zh) * | 2010-09-29 | 2012-07-04 | 太原理工大学 | 一种固体丙烯酸共聚物的制备方法 |
| BR112013010261A2 (pt) | 2010-10-29 | 2016-09-13 | Buckman Lab Int Inc | método para preparar papel ou papelão, sistema de fabricação de papel, produto e produto de papel |
| EP2743383A1 (fr) * | 2012-12-13 | 2014-06-18 | Kelheim Fibres GmbH | Fibre de cellulose régénérée |
| JP6115768B2 (ja) * | 2013-04-10 | 2017-04-19 | 荒川化学工業株式会社 | 板紙用表面紙力増強剤 |
| CN103665262B (zh) * | 2013-12-13 | 2016-05-11 | 山东大学 | 一种含氟改性n-乙烯基吡咯烷酮的水溶性共聚物及其制备方法 |
| CN103866635B (zh) * | 2014-02-28 | 2016-03-09 | 苏州恒康新材料有限公司 | 一种甲基丙烯酸月桂酯湿强剂及其制备方法 |
| TW201739983A (zh) | 2016-01-14 | 2017-11-16 | 亞齊羅馬Ip公司 | 丙烯酸酯共聚物之用途、使用其之具有纖維素纖維之基材之製造方法及其基板 |
| US11708481B2 (en) * | 2017-12-13 | 2023-07-25 | Ecolab Usa Inc. | Solution comprising an associative polymer and a cyclodextrin polymer |
| AU2019337989B2 (en) | 2018-09-14 | 2025-02-27 | Solenis Technologies Cayman, L.P. | Method for producing paper or cardboard |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59120233A (ja) * | 1982-12-25 | 1984-07-11 | Nippon Oil & Fats Co Ltd | 石炭−水スラリ−用添加剤 |
| EP0172723B2 (fr) * | 1984-08-15 | 1997-11-05 | Ciba Specialty Chemicals Water Treatments Limited | Polymères solubles dans l'eau |
| CA2004495A1 (fr) * | 1988-12-29 | 1990-06-29 | Jan Bock | Association hydrophobe de polymeres renfermant la fonction dimethylacrylamide |
-
2000
- 2000-11-30 JP JP2001542639A patent/JP2003517104A/ja active Pending
- 2000-11-30 KR KR1020027007220A patent/KR20020058086A/ko not_active Withdrawn
- 2000-11-30 EP EP00980943A patent/EP1257709A1/fr active Pending
- 2000-11-30 BR BR0016160-8A patent/BR0016160A/pt not_active Application Discontinuation
- 2000-11-30 WO PCT/US2000/032820 patent/WO2001040578A1/fr not_active Ceased
- 2000-11-30 AU AU18138/01A patent/AU1813801A/en not_active Abandoned
- 2000-11-30 MX MXPA02005108A patent/MXPA02005108A/es unknown
- 2000-11-30 CN CN00816785A patent/CN1408039A/zh active Pending
- 2000-11-30 CA CA002390353A patent/CA2390353A1/fr not_active Abandoned
- 2000-11-30 PL PL00366291A patent/PL366291A1/xx unknown
- 2000-11-30 RU RU2002114071/12A patent/RU2002114071A/ru not_active Application Discontinuation
- 2000-12-06 AR ARP000106457A patent/AR026734A1/es unknown
- 2000-12-06 US US09/731,254 patent/US20020053413A1/en not_active Abandoned
-
2002
- 2002-07-08 ZA ZA200205443A patent/ZA200205443B/xx unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8241462B2 (en) | 2007-07-26 | 2012-08-14 | Harima Chemicals, Inc. | Papermaking internal sizing agent and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1813801A (en) | 2001-06-12 |
| CN1408039A (zh) | 2003-04-02 |
| JP2003517104A (ja) | 2003-05-20 |
| KR20020058086A (ko) | 2002-07-12 |
| AR026734A1 (es) | 2003-02-26 |
| RU2002114071A (ru) | 2004-03-27 |
| PL366291A1 (en) | 2005-01-24 |
| WO2001040578A1 (fr) | 2001-06-07 |
| ZA200205443B (en) | 2003-12-31 |
| MXPA02005108A (es) | 2002-12-09 |
| EP1257709A1 (fr) | 2002-11-20 |
| BR0016160A (pt) | 2002-12-24 |
| US20020053413A1 (en) | 2002-05-09 |
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