CA2383596A1 - Composition et procede de blanchiment d'un substrat - Google Patents
Composition et procede de blanchiment d'un substrat Download PDFInfo
- Publication number
- CA2383596A1 CA2383596A1 CA002383596A CA2383596A CA2383596A1 CA 2383596 A1 CA2383596 A1 CA 2383596A1 CA 002383596 A CA002383596 A CA 002383596A CA 2383596 A CA2383596 A CA 2383596A CA 2383596 A1 CA2383596 A1 CA 2383596A1
- Authority
- CA
- Canada
- Prior art keywords
- bleaching
- alkyl
- pyridin
- optionally substituted
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 221
- 238000004061 bleaching Methods 0.000 title claims abstract description 156
- 239000000758 substrate Substances 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 45
- 239000007788 liquid Substances 0.000 claims abstract description 128
- 239000007844 bleaching agent Substances 0.000 claims abstract description 62
- 239000000126 substance Substances 0.000 claims abstract description 49
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000001301 oxygen Substances 0.000 claims abstract description 41
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 41
- 150000003624 transition metals Chemical class 0.000 claims abstract description 31
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 30
- 239000004753 textile Substances 0.000 claims abstract description 29
- 125000000864 peroxy group Chemical group O(O*)* 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 239000003446 ligand Substances 0.000 claims description 131
- -1 alkylene ether Chemical compound 0.000 claims description 78
- 229910052739 hydrogen Inorganic materials 0.000 claims description 67
- 239000001257 hydrogen Substances 0.000 claims description 65
- 125000001072 heteroaryl group Chemical group 0.000 claims description 47
- 125000000217 alkyl group Chemical group 0.000 claims description 39
- 125000003118 aryl group Chemical group 0.000 claims description 37
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 30
- 125000002947 alkylene group Chemical group 0.000 claims description 21
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 19
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 19
- 125000000524 functional group Chemical group 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 16
- 125000003342 alkenyl group Chemical group 0.000 claims description 14
- 229910052736 halogen Inorganic materials 0.000 claims description 12
- 150000002367 halogens Chemical class 0.000 claims description 12
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- IZWKOTBNIORNES-UHFFFAOYSA-N 1,1-dipyridin-2-yl-n,n-bis(pyridin-2-ylmethyl)ethanamine Chemical compound C=1C=CC=NC=1C(C=1N=CC=CC=1)(C)N(CC=1N=CC=CC=1)CC1=CC=CC=N1 IZWKOTBNIORNES-UHFFFAOYSA-N 0.000 claims description 9
- 125000005549 heteroarylene group Chemical group 0.000 claims description 9
- 239000002609 medium Substances 0.000 claims description 9
- 150000001299 aldehydes Chemical class 0.000 claims description 8
- 239000012736 aqueous medium Substances 0.000 claims description 8
- 125000000732 arylene group Chemical group 0.000 claims description 8
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 claims description 6
- 125000006588 heterocycloalkylene group Chemical group 0.000 claims description 6
- 125000002883 imidazolyl group Chemical group 0.000 claims description 6
- 125000003226 pyrazolyl group Chemical group 0.000 claims description 6
- 125000004076 pyridyl group Chemical group 0.000 claims description 6
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 125000001425 triazolyl group Chemical group 0.000 claims description 6
- 150000001408 amides Chemical class 0.000 claims description 5
- 125000004103 aminoalkyl group Chemical class 0.000 claims description 5
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 claims description 5
- 125000003373 pyrazinyl group Chemical group 0.000 claims description 5
- 125000000168 pyrrolyl group Chemical group 0.000 claims description 5
- 239000003352 sequestering agent Substances 0.000 claims description 5
- 125000000335 thiazolyl group Chemical group 0.000 claims description 5
- 125000004450 alkenylene group Chemical group 0.000 claims description 4
- 125000006294 amino alkylene group Chemical group 0.000 claims description 4
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 4
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 3
- 150000004698 iron complex Chemical class 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 4
- 239000004744 fabric Substances 0.000 abstract description 22
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 39
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 31
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 31
- 239000007983 Tris buffer Substances 0.000 description 30
- 229910052757 nitrogen Inorganic materials 0.000 description 30
- 239000003599 detergent Substances 0.000 description 29
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 27
- 238000005406 washing Methods 0.000 description 27
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 26
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 26
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 26
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 26
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 26
- 230000000694 effects Effects 0.000 description 26
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 26
- XSCHRSMBECNVNS-UHFFFAOYSA-N quinoxaline Chemical compound N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 26
- MLCJWRIUYXIWNU-OWOJBTEDSA-N (e)-ethene-1,2-diamine Chemical compound N\C=C\N MLCJWRIUYXIWNU-OWOJBTEDSA-N 0.000 description 24
- 125000000623 heterocyclic group Chemical group 0.000 description 23
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 description 22
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 21
- 239000011734 sodium Substances 0.000 description 20
- 239000000243 solution Substances 0.000 description 19
- 238000003860 storage Methods 0.000 description 19
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 17
- 241000894007 species Species 0.000 description 17
- 239000003054 catalyst Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 16
- 239000012669 liquid formulation Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 16
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 15
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 15
- 238000001035 drying Methods 0.000 description 14
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 13
- VHMICKWLTGFITH-UHFFFAOYSA-N 2H-isoindole Chemical compound C1=CC=CC2=CNC=C21 VHMICKWLTGFITH-UHFFFAOYSA-N 0.000 description 13
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 13
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 13
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical compound C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 13
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 description 13
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 13
- 239000011575 calcium Substances 0.000 description 13
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 13
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 13
- 150000003852 triazoles Chemical class 0.000 description 13
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 150000007942 carboxylates Chemical class 0.000 description 12
- 125000005842 heteroatom Chemical group 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 150000001412 amines Chemical class 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 11
- 238000009472 formulation Methods 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 239000002243 precursor Substances 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- 229910052708 sodium Inorganic materials 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 125000003368 amide group Chemical group 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000004140 cleaning Methods 0.000 description 9
- 229940093499 ethyl acetate Drugs 0.000 description 9
- 235000019439 ethyl acetate Nutrition 0.000 description 9
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 9
- 150000002500 ions Chemical class 0.000 description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 125000004353 pyrazol-1-yl group Chemical group [H]C1=NN(*)C([H])=C1[H] 0.000 description 9
- 125000004159 quinolin-2-yl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C([H])C(*)=NC2=C1[H] 0.000 description 9
- 241000227653 Lycopersicon Species 0.000 description 8
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 125000003037 imidazol-2-yl group Chemical group [H]N1C([*])=NC([H])=C1[H] 0.000 description 8
- 125000002140 imidazol-4-yl group Chemical group [H]N1C([H])=NC([*])=C1[H] 0.000 description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- 229910021536 Zeolite Inorganic materials 0.000 description 7
- 230000003750 conditioning effect Effects 0.000 description 7
- 229940012017 ethylenediamine Drugs 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- 101150041968 CDC13 gene Proteins 0.000 description 6
- HEDRZPFGACZZDS-MICDWDOJSA-N Trichloro(2H)methane Chemical compound [2H]C(Cl)(Cl)Cl HEDRZPFGACZZDS-MICDWDOJSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 125000003545 alkoxy group Chemical group 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 102000004190 Enzymes Human genes 0.000 description 5
- 108090000790 Enzymes Proteins 0.000 description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- 229940088598 enzyme Drugs 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 150000002989 phenols Chemical class 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- PRICLFAUAJHZLI-UHFFFAOYSA-N 1,1-dipyridin-2-yl-n,n-bis(pyridin-2-ylmethyl)methanamine Chemical compound C=1C=CC=NC=1CN(C(C=1N=CC=CC=1)C=1N=CC=CC=1)CC1=CC=CC=N1 PRICLFAUAJHZLI-UHFFFAOYSA-N 0.000 description 4
- CSDSSGBPEUDDEE-UHFFFAOYSA-N 2-formylpyridine Chemical compound O=CC1=CC=CC=N1 CSDSSGBPEUDDEE-UHFFFAOYSA-N 0.000 description 4
- YKCVYVYCIXFHMD-UHFFFAOYSA-N 2-phenyl-1,1-dipyridin-2-yl-n,n-bis(pyridin-2-ylmethyl)ethanamine Chemical compound C=1C=CC=NC=1CN(C(CC=1C=CC=CC=1)(C=1N=CC=CC=1)C=1N=CC=CC=1)CC1=CC=CC=N1 YKCVYVYCIXFHMD-UHFFFAOYSA-N 0.000 description 4
- BWRRWBIBNBVHQF-UHFFFAOYSA-N 4-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)butanoic acid Chemical compound O1C(CCCC(=O)O)=NC(C=2N=CC=CC=2)=N1 BWRRWBIBNBVHQF-UHFFFAOYSA-N 0.000 description 4
- ROMPPAWVATWIKR-UHFFFAOYSA-N 4-[3-(4-chlorophenyl)-1,2,4-oxadiazol-5-yl]butanoic acid Chemical compound O1C(CCCC(=O)O)=NC(C=2C=CC(Cl)=CC=2)=N1 ROMPPAWVATWIKR-UHFFFAOYSA-N 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 125000001475 halogen functional group Chemical group 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000011149 active material Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000004696 coordination complex Chemical class 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- OUUQCZGPVNCOIJ-UHFFFAOYSA-N hydroperoxyl Chemical group O[O] OUUQCZGPVNCOIJ-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 3
- 239000004530 micro-emulsion Substances 0.000 description 3
- 239000003094 microcapsule Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 125000000160 oxazolidinyl group Chemical group 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 125000005415 substituted alkoxy group Chemical group 0.000 description 3
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 2
- PFACYSIXVKSRCE-UHFFFAOYSA-N 1-n,1-n',1-n'-tris(pyridin-2-ylmethyl)ethane-1,1-diamine Chemical compound C=1C=CC=NC=1CN(CC=1N=CC=CC=1)C(C)NCC1=CC=CC=N1 PFACYSIXVKSRCE-UHFFFAOYSA-N 0.000 description 2
- VGUWFGWZSVLROP-UHFFFAOYSA-N 1-pyridin-2-yl-n,n-bis(pyridin-2-ylmethyl)methanamine Chemical compound C=1C=CC=NC=1CN(CC=1N=CC=CC=1)CC1=CC=CC=N1 VGUWFGWZSVLROP-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- QNGNSVIICDLXHT-UHFFFAOYSA-N 4-Ethylbenzaldehyde Chemical group CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229910021135 KPF6 Inorganic materials 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 229920002873 Polyethylenimine Polymers 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
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- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- MRNZSTMRDWRNNR-UHFFFAOYSA-N bis(hexamethylene)triamine Chemical compound NCCCCCCNCCCCCCN MRNZSTMRDWRNNR-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000003857 carboxamides Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 238000010952 in-situ formation Methods 0.000 description 1
- 125000001041 indolyl group Chemical group 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 229940045996 isethionic acid Drugs 0.000 description 1
- 125000000904 isoindolyl group Chemical group C=1(NC=C2C=CC=CC12)* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
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- 235000019421 lipase Nutrition 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011565 manganese chloride Substances 0.000 description 1
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- 238000004949 mass spectrometry Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- QUEIOYSLAIWQPJ-UHFFFAOYSA-N n'-(furan-2-yl)-n,n,n'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound CC1=CC=CN=C1CN(CC=1C(=CC=CN=1)C)CCN(C=1OC=CC=1)CC1=NC=CC=C1C QUEIOYSLAIWQPJ-UHFFFAOYSA-N 0.000 description 1
- RJTPPAKVEZAPHT-UHFFFAOYSA-N n,n',n'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound CC1=CC=CN=C1CNCCN(CC=1C(=CC=CN=1)C)CC1=NC=CC=C1C RJTPPAKVEZAPHT-UHFFFAOYSA-N 0.000 description 1
- IFWXWCMXLKGUOC-UHFFFAOYSA-N n,n',n'-tris[(5-ethylpyridin-2-yl)methyl]-n-methylethane-1,2-diamine Chemical compound N1=CC(CC)=CC=C1CN(C)CCN(CC=1N=CC(CC)=CC=1)CC1=CC=C(CC)C=N1 IFWXWCMXLKGUOC-UHFFFAOYSA-N 0.000 description 1
- RKSLDIUKXNUQID-UHFFFAOYSA-N n,n,n',n'-tetrakis[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound CC1=CC=CN=C1CN(CC=1C(=CC=CN=1)C)CCN(CC=1C(=CC=CN=1)C)CC1=NC=CC=C1C RKSLDIUKXNUQID-UHFFFAOYSA-N 0.000 description 1
- YRIMJGKNHJOEFO-UHFFFAOYSA-N n,n-bis(1h-imidazol-2-ylmethyl)-1,1-dipyridin-2-ylethanamine Chemical compound C=1C=CC=NC=1C(C=1N=CC=CC=1)(C)N(CC=1NC=CN=1)CC1=NC=CN1 YRIMJGKNHJOEFO-UHFFFAOYSA-N 0.000 description 1
- GYTHUITWHUOYRG-UHFFFAOYSA-N n,n-bis(1h-imidazol-2-ylmethyl)-1,1-dipyridin-2-ylmethanamine Chemical compound N=1C=CNC=1CN(C(C=1N=CC=CC=1)C=1N=CC=CC=1)CC1=NC=CN1 GYTHUITWHUOYRG-UHFFFAOYSA-N 0.000 description 1
- SOCWPCWSEIVSKB-UHFFFAOYSA-N n,n-bis(1h-imidazol-2-ylmethyl)-2-phenyl-1,1-dipyridin-2-ylethanamine Chemical compound N=1C=CNC=1CN(C(CC=1C=CC=CC=1)(C=1N=CC=CC=1)C=1N=CC=CC=1)CC1=NC=CN1 SOCWPCWSEIVSKB-UHFFFAOYSA-N 0.000 description 1
- PJQKKTCJVOUVLQ-UHFFFAOYSA-N n,n-bis(pyrazol-1-ylmethyl)-1,1-dipyridin-2-ylethanamine Chemical compound C=1C=CC=NC=1C(C=1N=CC=CC=1)(C)N(CN1N=CC=C1)CN1C=CC=N1 PJQKKTCJVOUVLQ-UHFFFAOYSA-N 0.000 description 1
- PXVNJYVVCKFFGF-UHFFFAOYSA-N n,n-bis(pyrazol-1-ylmethyl)-1,1-dipyridin-2-ylmethanamine Chemical compound C1=CC=NN1CN(C(C=1N=CC=CC=1)C=1N=CC=CC=1)CN1C=CC=N1 PXVNJYVVCKFFGF-UHFFFAOYSA-N 0.000 description 1
- HCHJZFCNKMINLV-UHFFFAOYSA-N n,n-bis(pyridin-2-ylmethyl)-1,1-bis(1,2,4-triazol-1-yl)ethanamine Chemical compound C1=NC=NN1C(N1N=CN=C1)(C)N(CC=1N=CC=CC=1)CC1=CC=CC=N1 HCHJZFCNKMINLV-UHFFFAOYSA-N 0.000 description 1
- QGZYRQOEBLMWLO-UHFFFAOYSA-N n,n-bis(pyridin-2-ylmethyl)-1,1-bis(1,2,4-triazol-1-yl)methanamine Chemical compound C=1C=CC=NC=1CN(C(N1N=CN=C1)N1N=CN=C1)CC1=CC=CC=N1 QGZYRQOEBLMWLO-UHFFFAOYSA-N 0.000 description 1
- QNPHFVFBJIYVAX-UHFFFAOYSA-N n,n-bis[(6-methylpyridin-2-yl)methyl]-1,1-dipyridin-2-ylmethanamine Chemical compound CC1=CC=CC(CN(CC=2N=C(C)C=CC=2)C(C=2N=CC=CC=2)C=2N=CC=CC=2)=N1 QNPHFVFBJIYVAX-UHFFFAOYSA-N 0.000 description 1
- AQWLQPOKOMKMPI-UHFFFAOYSA-N n-benzyl-n,n',n'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound CC1=CC=CN=C1CN(CC=1C=CC=CC=1)CCN(CC=1C(=CC=CN=1)C)CC1=NC=CC=C1C AQWLQPOKOMKMPI-UHFFFAOYSA-N 0.000 description 1
- HNTOXKSOQQSTOX-UHFFFAOYSA-N n-ethyl-n,n',n'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound N=1C=CC=C(C)C=1CN(CC)CCN(CC=1C(=CC=CN=1)C)CC1=NC=CC=C1C HNTOXKSOQQSTOX-UHFFFAOYSA-N 0.000 description 1
- SHODXMYKLLGZQP-UHFFFAOYSA-N n-methyl-1,1-dipyridin-2-yl-n-(pyridin-2-ylmethyl)methanamine Chemical compound C=1C=CC=NC=1C(C=1N=CC=CC=1)N(C)CC1=CC=CC=N1 SHODXMYKLLGZQP-UHFFFAOYSA-N 0.000 description 1
- PEAFAHCIDIRMCA-UHFFFAOYSA-N n-methyl-n,n',n'-tris(1-methylbenzimidazol-2-yl)ethane-1,2-diamine Chemical compound C1=CC=C2N(C)C(N(CCN(C=3N(C4=CC=CC=C4N=3)C)C=3N(C4=CC=CC=C4N=3)C)C)=NC2=C1 PEAFAHCIDIRMCA-UHFFFAOYSA-N 0.000 description 1
- FDEBUWXFKPLTAA-UHFFFAOYSA-N n-methyl-n,n',n'-tris(pyridin-2-ylmethyl)ethane-1,2-diamine Chemical compound C=1C=CC=NC=1CN(C)CCN(CC=1N=CC=CC=1)CC1=CC=CC=N1 FDEBUWXFKPLTAA-UHFFFAOYSA-N 0.000 description 1
- SIMWFHSFDKZLCB-UHFFFAOYSA-N n-methyl-n,n',n'-tris[(3-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound N=1C=CC=C(C)C=1CN(C)CCN(CC=1C(=CC=CN=1)C)CC1=NC=CC=C1C SIMWFHSFDKZLCB-UHFFFAOYSA-N 0.000 description 1
- UHEQYVPNQJFCEA-UHFFFAOYSA-N n-methyl-n,n',n'-tris[(5-methylpyridin-2-yl)methyl]ethane-1,2-diamine Chemical compound C=1C=C(C)C=NC=1CN(C)CCN(CC=1N=CC(C)=CC=1)CC1=CC=C(C)C=N1 UHEQYVPNQJFCEA-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 238000009896 oxidative bleaching Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 229940097156 peroxyl Drugs 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 description 1
- QIIPQYDSKRYMFG-UHFFFAOYSA-N phenyl hydrogen carbonate Chemical compound OC(=O)OC1=CC=CC=C1 QIIPQYDSKRYMFG-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 125000004289 pyrazol-3-yl group Chemical group [H]N1N=C(*)C([H])=C1[H] 0.000 description 1
- 125000002098 pyridazinyl group Chemical group 0.000 description 1
- 125000001422 pyrrolinyl group Chemical group 0.000 description 1
- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/36—Radicals substituted by singly-bound nitrogen atoms
- C07D213/38—Radicals substituted by singly-bound nitrogen atoms having only hydrogen or hydrocarbon radicals attached to the substituent nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/55—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/13—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using inorganic agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/15—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen using organic agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
Abstract
L'invention concerne une composition blanchissante liquide permettant de blanchir des substrats par catalyse, notamment des tissus de buanderie, à l'aide d'oxygène de l'atmosphère ou d'air. Ladite composition de l'invention renferme, d'une part, une substance organique qui forme un complexe avec un métal de transition, le complexe catalysant le blanchiment d'un substrat au moyen de l'oxygène de l'air, et, d'autre part, un solvant ou porteur liquide. Cette composition est pratiquement exempte d'agent de blanchiment au peroxygène ou d'un système de blanchiment à base de péroxy ou générant ce dernier. Ladite invention a également trait à un procédé de blanchiment d'un substrat consistant à appliquer la composition de blanchiment liquide au substrat, ainsi qu'à un procédé de traitement d'un textile par mise en contact dudit textile avec ladite composition, le complexe catalysant le blanchiment du textile au moyen de l'oxygène de l'air après traitement.
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBPCT/GB99/02878 | 1999-09-01 | ||
| PCT/GB1999/002878 WO2000012808A1 (fr) | 1998-09-01 | 1999-09-01 | Procede de traitement d'un textile |
| GBPCT/GB99/02876 | 1999-09-01 | ||
| PCT/GB1999/002876 WO2000012667A1 (fr) | 1998-09-01 | 1999-09-01 | Composition et procede de blanchiment d'un substrat |
| GBGB0004990.8A GB0004990D0 (en) | 2000-03-01 | 2000-03-01 | Composition and method for bleaching a substrate |
| GB0004990.8 | 2000-03-01 | ||
| PCT/EP2000/008076 WO2001016271A1 (fr) | 1999-09-01 | 2000-08-16 | Composition et procede de blanchiment d'un substrat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2383596A1 true CA2383596A1 (fr) | 2001-03-08 |
Family
ID=27255572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002383596A Abandoned CA2383596A1 (fr) | 1999-09-01 | 2000-08-16 | Composition et procede de blanchiment d'un substrat |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP1208188A1 (fr) |
| CA (1) | CA2383596A1 (fr) |
| PH (1) | PH12000002323B1 (fr) |
| WO (1) | WO2001016271A1 (fr) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0005090D0 (en) | 2000-03-01 | 2000-04-26 | Unilever Plc | Bleaching and dye transfer inhibiting composition and method for laundry fabrics |
| GB0030877D0 (en) | 2000-12-18 | 2001-01-31 | Unilever Plc | Enhancement of air bleaching catalysts |
| GB0104980D0 (en) * | 2001-02-28 | 2001-04-18 | Unilever Plc | Liquid cleaning compositions and their use |
| GB0108737D0 (en) * | 2001-04-06 | 2001-05-30 | Unilever Plc | Composition and method for bleaching a substrate |
| EP1326074A1 (fr) * | 2002-01-07 | 2003-07-09 | Unilever N.V. | Dispositif pour analyser la qualité d'huile comestible |
| US7086110B2 (en) | 2002-02-13 | 2006-08-08 | The Procter & Gamble Company | Selective dispensing of laundry additives during automatic machine laundering of fabric |
| EP1474556A1 (fr) | 2002-02-13 | 2004-11-10 | The Procter & Gamble Company | Distribution d'additifs de rin age dans le cycle de rin age pendant le lavage automatique de tissus dans un lave-linge |
| US7340790B2 (en) | 2002-02-13 | 2008-03-11 | Procter & Gamble Company | Universal dispenser for dispensing of laundry additives during automatic machine laundering of fabrics |
| US7168273B2 (en) | 2002-11-07 | 2007-01-30 | The Procter & Gamble Company | Selective dispensing apparatus |
| US7036176B2 (en) | 2002-02-13 | 2006-05-02 | The Procter & Gamble Company | Sequential dispensing of laundry additives during automatic machine laundering of fabrics |
| US7716956B2 (en) | 2002-12-20 | 2010-05-18 | The Procter & Gamble Company | Attachment means |
| GB0313253D0 (en) * | 2003-06-09 | 2003-07-16 | Unilever Plc | Bleaching composition |
| GB0313249D0 (en) * | 2003-06-09 | 2003-07-16 | Unilever Plc | Bleaching composition |
| EP1699912A1 (fr) | 2003-12-03 | 2006-09-13 | The Procter and Gamble Company | Lavage automatique de textiles |
| DE502006002829D1 (de) * | 2005-06-01 | 2009-03-26 | Clariant Produkte Deutschland | -methyl)-1,1-bis(pyridin-2-yl)-1-aminoalkan-verbindungen und diese verbindungen enthaltende metallkomplex-salze |
| WO2009079797A1 (fr) | 2007-12-26 | 2009-07-02 | Critical Outcome Technologies, Inc. | Composés et procédé pour le traitement du cancer |
| EP3023426A1 (fr) | 2008-07-17 | 2016-05-25 | Critical Outcome Technologies, Inc. | Composés inhibiteurs à base de thiosemicarbazone et procédés de traitement du cancer |
| DE102010007059A1 (de) * | 2010-02-06 | 2011-08-11 | Clariant International Limited | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplexen |
| DE102010007058A1 (de) | 2010-02-06 | 2011-08-11 | Clariant International Limited | Verfahren zur Herstellung von 3,7-Diaza-bicyclo[3.3.1]nonan-Metallkomplex-Lösungen |
| WO2011120153A1 (fr) | 2010-04-01 | 2011-10-06 | Critical Outcome Technologies Inc. | Composés et méthodes pour le traitement du vih |
| MY160959A (en) | 2010-06-16 | 2017-03-31 | Akzo Nobel Chemicals Int Bv | Accelerator solution and process for curing curable resins |
| EP2723718A1 (fr) | 2011-06-24 | 2014-04-30 | Amgen Inc. | Antagonistes de trpm8 et leur utilisation dans le cadre thérapeutique |
| WO2012177893A2 (fr) | 2011-06-24 | 2012-12-27 | Amgen Inc. | Antagonistes de trpm8 et leur utilisation dans des traitements |
| US8952009B2 (en) | 2012-08-06 | 2015-02-10 | Amgen Inc. | Chroman derivatives as TRPM8 inhibitors |
| EP3620504A1 (fr) * | 2018-09-07 | 2020-03-11 | Henkel AG & Co. KGaA | Colloïdes platiniques comme agents de renforcement de blanchiment |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1075405A (fr) * | 1977-03-28 | 1980-04-15 | John F. Goodman | Agent de blanchiment photosensible, composition et procede connexes |
| WO1997038074A1 (fr) * | 1996-04-10 | 1997-10-16 | Unilever N.V. | Procede de nettoyage |
| DE19721886A1 (de) * | 1997-05-26 | 1998-12-03 | Henkel Kgaa | Bleichsystem |
| CA2248476A1 (fr) * | 1997-10-01 | 1999-04-01 | Unilever Plc | Activation du blanchiment |
| ES2196878T3 (es) * | 1998-06-15 | 2003-12-16 | Unilever Nv | Catalizadores de blanqueo y formulaciones que los contienen. |
| PH11999002190B1 (en) * | 1998-09-01 | 2007-08-06 | Unilever Nv | Composition and method for bleaching a substrate |
| WO2000029537A1 (fr) * | 1998-11-13 | 2000-05-25 | The Procter & Gamble Company | Compositions de blanchiment |
-
2000
- 2000-08-16 EP EP00962335A patent/EP1208188A1/fr not_active Withdrawn
- 2000-08-16 CA CA002383596A patent/CA2383596A1/fr not_active Abandoned
- 2000-08-16 WO PCT/EP2000/008076 patent/WO2001016271A1/fr not_active Ceased
- 2000-08-25 PH PH12000002323A patent/PH12000002323B1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PH12000002323B1 (en) | 2005-05-26 |
| EP1208188A1 (fr) | 2002-05-29 |
| WO2001016271A1 (fr) | 2001-03-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued | ||
| FZDE | Discontinued |
Effective date: 20100527 |