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CA2350507A1 - Method and apparatus for discharging polymerization reactors - Google Patents

Method and apparatus for discharging polymerization reactors Download PDF

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Publication number
CA2350507A1
CA2350507A1 CA002350507A CA2350507A CA2350507A1 CA 2350507 A1 CA2350507 A1 CA 2350507A1 CA 002350507 A CA002350507 A CA 002350507A CA 2350507 A CA2350507 A CA 2350507A CA 2350507 A1 CA2350507 A1 CA 2350507A1
Authority
CA
Canada
Prior art keywords
reactor
polymer
polymer powder
gas
valve
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002350507A
Other languages
French (fr)
Other versions
CA2350507C (en
Inventor
Jouni Kivela
Klaus Nyfors
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Borealis Technology Oy
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Individual
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Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8552903&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2350507(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CA2350507A1 publication Critical patent/CA2350507A1/en
Application granted granted Critical
Publication of CA2350507C publication Critical patent/CA2350507C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
    • B01J8/003—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005—Separating solid material from the gas/liquid stream
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00654—Controlling the process by measures relating to the particulate material
    • B01J2208/00681—Agglomeration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00247—Fouling of the reactor or the process equipment

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A method and an apparatus of discharging polymer from a continuously operated gas phase reactor, wherein at least one monomer is polymerized in a bed containing active catalyst formed by catalyst and polymer particles suspended in a fluid, the bed defining a fluidized bed level in said reactor. The invention comprises continuously withdrawing polymer powder from the reactor; and adjusting the discharge rate of the polymer powder so as to maintain a constant bed level during polymerization. By means of the invention the discharge of the polymer can be made truly continuous without any disturbance of the polymerization. The rate of withdrawn polymer can be flexibly adjusted depending on the progress of the polymerization and it can also easily be scaled up if the capacity of the reactor is increased.

Claims (28)

1. A method of producing a polymer in a continuously operated gas phase reactor, comprising polymerizing at least one monomer in a bed containing active catalyst formed by catalyst and polymer particles suspended in a fluid, said bed defining a fluidized bed level in said reactor, - continuously withdrawing polymer powder from the reactor;
- adjusting the discharge rate of the polymer powder so as to maintain a constant bed level during polymerization; and - withdrawing and separately recovering particle agglomerates from the reactor.
2. The method according to claim 1, wherein the discharge rate of the polymer powder is adjusted by using a continuously operated control valve.
3. The method according to claim 2, wherein the continuously operated valve is a ball valve, a V-ball valve or a hose valve.
4. The method according to claim 2 or 3, wherein the polymer powder is withdrawn via an outlet nozzle connected to the control valve, and said nozzle is provided with a grid flush mounted at the reactor wall to prevent lumps from entering the pipe.
5. The method according to any of claims 2 to 3, wherein the operation of the control valve is adjusted by using a control signal obtained from a bed level controller.
6. The method according to any of claims 2 to 5, wherein the control valve is adjusted to provide for pulsating operation to prevent clogging of the valve.
7. The method according to any of the preceding claims, wherein polymer powder is continuously withdrawn from a point above a fluidization plate.
8. The method according to any of the preceding claims, wherein polymer powder is continuously withdrawn from a point below the bed level.
9. The method according to any of the preceding claims, wherein the discharge line and the control valve are discontinuously backflushed with a flushing gas flow.
10. The method according to any of the preceding claims, comprising - using a gas phase reactor having a mechanically mixed zone of the fluidized bed, and - continuously withdrawing polymer powder from said mixed zone.
11. The method according to any of the preceding claims, wherein polymer powder is also separately withdrawn from the reactor using a discontinuous discharge device.
12. The method according to any of the preceding claims, wherein the polymer powder is withdrawn together with gas from the reactor, the gas is separated from the polymer powder, and the separated gas is recycled into the reactor.
13. The method according to any of the preceding claims, wherein polymer agglomerates are withdrawn from the reactor using a discharge line with a discontinuously operated discharge valve.
14. A method of discharging polymer from a continuously operated gas phase reactor, wherein at least one monomer is polymerized in a bed containing active catalyst formed by catalyst and polymer particles suspended in a fluid, said bed defining a fluidized bed level in said reactor, comprising - continuously withdrawing polymer powder from the reactor;
- feeding the withdrawn polymer powder into a collecting vessel, wherein lumps are separated from finely-divided polymer powder and at least a part of the gas is separated from the solid material;
- recovering the lumps, and - adjusting the discharge rate of the polymer powder so as to maintain a constant bed level during polymerization.
15. The method according to claim 14, wherein the separated gas is recycled into the reactor, said collecting vessel being provided with a return valve for adjusting the gas flow recycled to the reactor.
16. The method according to claim 15, wherein the return valve is controlled by the fluidized bed level of the reactor.
17. The method according to claim 16, wherein the polymer level in the vessel is controlled by using a continuously operating control valve.
18. The method according to any of claims 14 to 17, wherein the collecting vessel is provided with a screen for separating lumps.
19. The method according to any of the preceding claims, wherein the catalyst is fed into the gas phase reactor as a stream comprising polymer and active catalyst together with reaction medium.
20. The method according to claim 19, wherein the catalyst is fed into the gas phase reactor from a slurry reactor.
21. The method according to claim 20, wherein the slurry reactor is a loop reactor.
22. The method according to any of the preceding claims, wherein the monomers are selected from the group of C2 to C16 olefins and mixtures thereof.
23. The method according to any of the preceding claims, wherein the monomer is selected from the group of ethylene, propylene, 1-butene, 4-methyl-1-pentene, 1-hexene, dienes, and cyclic olefins, and mixtures thereof.
24. The method according to any of the preceding claims, wherein the polymer that is continuously withdrawn is either directly or indirectly fed into another gas phase reactor.
25. The method according to any of claims 14 to 24, wherein the collecting vessel is connected to a gas separator, said polymer powder being pneumatically conducted from the collecting vessel to the gas separator.
26. An apparatus for discharging polymer from a continuously operated gas phase reactor, wherein at least one monomer is polymerized in a bed captaining active catalyst formed by catalyst and polymer particles suspended in a fluid, said bed defining a fluidized bed level in said reactor, said apparatus comprising - an outlet nozzle communicating with the fluidized bed of the gas phase reactor, - a collecting vessel placed in communication with the outlet nozzle for separating gas from solid material, with a screen for collecting the lumps and a separate discharge nozzle for the lumps;

- a continuously operating valve for adjusting the amount of polymer powder withdrawn from the reactor via the outlet nozzle; and - means for controlling the operation of the valve for adjusting the discharge rate of the polymer powder so as to maintain a constant bed level during polymerization.
27. The apparatus according to claim 26, wherein the continuously operating valve is connected to the collecting vessel.
28. The apparatus according to claim 26 or 27, wherein the collecting vessel comprises a gas space which is connected to the gas phase reactor via a gas conduit.
CA2350507A 1998-11-12 1999-11-12 Method and apparatus for discharging polymerization reactors Expired - Lifetime CA2350507C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI982456A FI111953B (en) 1998-11-12 1998-11-12 Process and apparatus for emptying polymerization reactors
FI982456 1998-11-12
PCT/FI1999/000941 WO2000029452A1 (en) 1998-11-12 1999-11-12 Method and apparatus for discharging polymerization reactors

Publications (2)

Publication Number Publication Date
CA2350507A1 true CA2350507A1 (en) 2000-05-25
CA2350507C CA2350507C (en) 2010-03-30

Family

ID=8552903

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2350507A Expired - Lifetime CA2350507C (en) 1998-11-12 1999-11-12 Method and apparatus for discharging polymerization reactors

Country Status (16)

Country Link
US (2) US7812102B2 (en)
EP (1) EP1159305B1 (en)
JP (1) JP4558941B2 (en)
KR (1) KR100561797B1 (en)
CN (1) CN1155623C (en)
AR (1) AR021251A1 (en)
AT (1) ATE265471T1 (en)
AU (1) AU755948B2 (en)
BR (1) BR9915279B1 (en)
CA (1) CA2350507C (en)
DE (1) DE69916895T2 (en)
ES (1) ES2219114T3 (en)
FI (1) FI111953B (en)
TW (1) TW518342B (en)
WO (1) WO2000029452A1 (en)
ZA (1) ZA200103316B (en)

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