CA2265901A1 - Composition detergente a base d'amines cationiques et d'enzymes cellulases - Google Patents
Composition detergente a base d'amines cationiques et d'enzymes cellulases Download PDFInfo
- Publication number
- CA2265901A1 CA2265901A1 CA002265901A CA2265901A CA2265901A1 CA 2265901 A1 CA2265901 A1 CA 2265901A1 CA 002265901 A CA002265901 A CA 002265901A CA 2265901 A CA2265901 A CA 2265901A CA 2265901 A1 CA2265901 A1 CA 2265901A1
- Authority
- CA
- Canada
- Prior art keywords
- cationic
- detergent composition
- group
- alkyl
- granular detergent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 152
- 239000003599 detergent Substances 0.000 title claims abstract description 98
- -1 cationic amines Chemical class 0.000 title claims abstract description 86
- 108010059892 Cellulase Proteins 0.000 title description 20
- 102000004190 Enzymes Human genes 0.000 claims abstract description 50
- 108090000790 Enzymes Proteins 0.000 claims abstract description 50
- 125000002091 cationic group Chemical group 0.000 claims abstract description 44
- 230000001461 cytolytic effect Effects 0.000 claims abstract description 30
- 239000002689 soil Substances 0.000 claims abstract description 29
- 150000001767 cationic compounds Chemical class 0.000 claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims description 44
- 229920000642 polymer Polymers 0.000 claims description 42
- 239000004094 surface-active agent Substances 0.000 claims description 30
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 27
- 239000002243 precursor Substances 0.000 claims description 27
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 26
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 24
- 229920000768 polyamine Polymers 0.000 claims description 23
- 239000007844 bleaching agent Substances 0.000 claims description 21
- 125000002947 alkylene group Chemical group 0.000 claims description 18
- 125000005702 oxyalkylene group Chemical group 0.000 claims description 15
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- 125000004450 alkenylene group Chemical group 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 13
- 150000004967 organic peroxy acids Chemical class 0.000 claims description 13
- 238000005406 washing Methods 0.000 claims description 13
- 125000003118 aryl group Chemical group 0.000 claims description 12
- 125000000732 arylene group Chemical group 0.000 claims description 12
- 229920006317 cationic polymer Polymers 0.000 claims description 12
- 239000004927 clay Substances 0.000 claims description 12
- 239000003352 sequestering agent Substances 0.000 claims description 9
- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- 125000000129 anionic group Chemical group 0.000 claims description 8
- 229910001385 heavy metal Inorganic materials 0.000 claims description 8
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 238000004061 bleaching Methods 0.000 claims description 7
- 125000001033 ether group Chemical group 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 239000002563 ionic surfactant Substances 0.000 claims description 2
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 1
- 239000004642 Polyimide Substances 0.000 claims 1
- 235000019256 formaldehyde Nutrition 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- 229920001721 polyimide Polymers 0.000 claims 1
- 230000000750 progressive effect Effects 0.000 claims 1
- 229940088598 enzyme Drugs 0.000 description 46
- 239000002253 acid Substances 0.000 description 36
- 125000000217 alkyl group Chemical group 0.000 description 36
- 125000004432 carbon atom Chemical group C* 0.000 description 29
- 150000003839 salts Chemical class 0.000 description 27
- 239000002518 antifoaming agent Substances 0.000 description 23
- 239000011734 sodium Substances 0.000 description 23
- 229910052708 sodium Inorganic materials 0.000 description 23
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 22
- 239000000047 product Substances 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 16
- 239000010457 zeolite Substances 0.000 description 16
- 150000002148 esters Chemical class 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 229910021536 Zeolite Inorganic materials 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000004744 fabric Substances 0.000 description 13
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000002245 particle Substances 0.000 description 13
- 229920001296 polysiloxane Polymers 0.000 description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 101710166469 Endoglucanase Proteins 0.000 description 11
- 150000001204 N-oxides Chemical class 0.000 description 11
- 229920002873 Polyethylenimine Polymers 0.000 description 11
- 229910052783 alkali metal Inorganic materials 0.000 description 11
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 10
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 10
- 150000007513 acids Chemical class 0.000 description 10
- 150000008051 alkyl sulfates Chemical group 0.000 description 10
- 150000001768 cations Chemical class 0.000 description 10
- 238000009472 formulation Methods 0.000 description 10
- 150000004965 peroxy acids Chemical class 0.000 description 10
- 229920001601 polyetherimide Polymers 0.000 description 10
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 9
- 229920005646 polycarboxylate Polymers 0.000 description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
- 241000194110 Bacillus sp. (in: Bacteria) Species 0.000 description 8
- 235000010582 Pisum sativum Nutrition 0.000 description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 8
- 229910052700 potassium Inorganic materials 0.000 description 8
- 239000011591 potassium Substances 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 108090001060 Lipase Proteins 0.000 description 7
- 239000004367 Lipase Substances 0.000 description 7
- 102000004882 Lipase Human genes 0.000 description 7
- 150000001340 alkali metals Chemical class 0.000 description 7
- 150000001450 anions Chemical class 0.000 description 7
- 229940106157 cellulase Drugs 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 238000007046 ethoxylation reaction Methods 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- 235000019421 lipase Nutrition 0.000 description 7
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 7
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 7
- 108010065511 Amylases Proteins 0.000 description 6
- 102000013142 Amylases Human genes 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 108091028043 Nucleic acid sequence Proteins 0.000 description 6
- 125000001539 acetonyl group Chemical group [H]C([H])([H])C(=O)C([H])([H])* 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- 125000004429 atom Chemical group 0.000 description 6
- 229920002678 cellulose Polymers 0.000 description 6
- 235000010980 cellulose Nutrition 0.000 description 6
- 125000000623 heterocyclic group Chemical group 0.000 description 6
- 125000001183 hydrocarbyl group Chemical group 0.000 description 6
- 229960002163 hydrogen peroxide Drugs 0.000 description 6
- 244000005700 microbiome Species 0.000 description 6
- 229920000620 organic polymer Polymers 0.000 description 6
- 229920000120 polyethyl acrylate Polymers 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 5
- 229910000323 aluminium silicate Inorganic materials 0.000 description 5
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- 239000000975 dye Substances 0.000 description 5
- 230000002401 inhibitory effect Effects 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 125000006850 spacer group Chemical group 0.000 description 5
- 241000894007 species Species 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 241000219843 Pisum Species 0.000 description 4
- 240000004713 Pisum sativum Species 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 150000001413 amino acids Chemical group 0.000 description 4
- 229940025131 amylases Drugs 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 4
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 4
- 150000007942 carboxylates Chemical class 0.000 description 4
- 239000012876 carrier material Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
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- 229910052906 cristobalite Inorganic materials 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
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- 229910052682 stishovite Inorganic materials 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
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- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 3
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 3
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- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
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- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
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- IGBSXRIJNMDLFB-UHFFFAOYSA-N ethane-1,2-diamine;pentanedioic acid Chemical compound NCCN.OC(=O)CCCC(O)=O.OC(=O)CCCC(O)=O IGBSXRIJNMDLFB-UHFFFAOYSA-N 0.000 description 1
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- 235000010299 hexamethylene tetramine Nutrition 0.000 description 1
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- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- JEGIFBGJZPYMJS-UHFFFAOYSA-N imidazol-1-yl(phenyl)methanone Chemical compound C1=CN=CN1C(=O)C1=CC=CC=C1 JEGIFBGJZPYMJS-UHFFFAOYSA-N 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000000356 indirect laser absorption spectroscopy Methods 0.000 description 1
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- 230000000977 initiatory effect Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
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- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical group COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-M oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC([O-])=O ZQPPMHVWECSIRJ-KTKRTIGZSA-M 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
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- 235000010603 pastilles Nutrition 0.000 description 1
- XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical class OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 150000004885 piperazines Chemical class 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
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- 229920002717 polyvinylpyridine Polymers 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 150000004023 quaternary phosphonium compounds Chemical class 0.000 description 1
- 238000006268 reductive amination reaction Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229940071089 sarcosinate Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960000999 sodium citrate dihydrate Drugs 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- RPQSWSMNPBZEHT-UHFFFAOYSA-M sodium;2-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=CC=C1S([O-])(=O)=O RPQSWSMNPBZEHT-UHFFFAOYSA-M 0.000 description 1
- KQHKITXZJDOIOD-UHFFFAOYSA-M sodium;3-sulfobenzoate Chemical compound [Na+].OS(=O)(=O)C1=CC=CC(C([O-])=O)=C1 KQHKITXZJDOIOD-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 229940032330 sulfuric acid Drugs 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 210000001364 upper extremity Anatomy 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 229910009112 xH2O Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Compositions détergentes granuleuses, ou leurs éléments, renfermant une enzyme cellulolityque et un ou plusieurs composés cationiques, qui sont des composés (poly)amines éthoxylés cationiques (partiellement) quaternarisés ayant les propriétés suivantes: élimination de salissure argileuse/antiredéposition.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9619929.4 | 1996-09-24 | ||
| GB9619929A GB2317395A (en) | 1996-09-24 | 1996-09-24 | Detergent compositions |
| PCT/US1997/017076 WO1998013464A1 (fr) | 1996-09-24 | 1997-09-22 | Composition detergente a base d'amines cationiques et d'enzymes cellulases |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2265901A1 true CA2265901A1 (fr) | 1998-04-02 |
Family
ID=10800428
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002265901A Abandoned CA2265901A1 (fr) | 1996-09-24 | 1997-09-22 | Composition detergente a base d'amines cationiques et d'enzymes cellulases |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0929643A4 (fr) |
| JP (1) | JP2000503064A (fr) |
| CN (1) | CN1238803A (fr) |
| AR (1) | AR010476A1 (fr) |
| AU (1) | AU4497897A (fr) |
| CA (1) | CA2265901A1 (fr) |
| CZ (1) | CZ102299A3 (fr) |
| GB (1) | GB2317395A (fr) |
| HU (1) | HUP9904670A3 (fr) |
| TR (1) | TR199900657T2 (fr) |
| WO (1) | WO1998013464A1 (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1187898A1 (fr) * | 1999-05-19 | 2002-03-20 | Colgate-Palmolive Company | Compositions detergentes de lessive a forte teneur en protease |
| EP1876227B2 (fr) * | 2006-07-07 | 2020-08-12 | The Procter and Gamble Company | Compositions de lavage |
| CN103797104A (zh) * | 2011-07-12 | 2014-05-14 | 诺维信公司 | 储存稳定的酶颗粒 |
| WO2022063697A1 (fr) * | 2020-09-28 | 2022-03-31 | Basf Se | Composition anti-grisaille pour le linge |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4659802A (en) * | 1982-12-23 | 1987-04-21 | The Procter & Gamble Company | Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions |
| DE3380259D1 (en) * | 1982-12-23 | 1989-08-31 | Procter & Gamble | Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties |
| US4664848A (en) * | 1982-12-23 | 1987-05-12 | The Procter & Gamble Company | Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties |
| JPS6147800A (ja) * | 1984-08-13 | 1986-03-08 | 花王株式会社 | 洗浄剤組成物 |
| US4861512A (en) * | 1984-12-21 | 1989-08-29 | The Procter & Gamble Company | Sulfonated block polyesters useful as soil release agents in detergent compositions |
| US4711730A (en) * | 1986-04-15 | 1987-12-08 | The Procter & Gamble Company | Capped 1,2-propylene terephthalate-polyoxyethylene terephthalate polyesters useful as soil release agents |
| US4713194A (en) * | 1986-04-15 | 1987-12-15 | The Procter & Gamble Company | Block polyester and like compounds having branched hydrophilic capping groups useful as soil release agents in detergent compositions |
| US4822516A (en) * | 1986-12-08 | 1989-04-18 | Kao Corporation | Detergent composition for clothing incorporating a cellulase |
| US4861502A (en) * | 1988-02-08 | 1989-08-29 | The Procter & Gamble Company | Conditioning agent containing amine ion-pair complexes and composiitons thereof |
| WO1993016158A1 (fr) * | 1992-02-18 | 1993-08-19 | The Procter & Gamble Company | Compositions detersives contenant de la cellulase a activite elevee et des composes d'ammonium quaternaire |
| PE6995A1 (es) * | 1994-05-25 | 1995-03-20 | Procter & Gamble | Composicion que comprende un polimero de polialquilenoamina etoxilado propoxilado como agente de separacion de sucio |
| EP0763089A1 (fr) * | 1994-06-01 | 1997-03-19 | The Procter & Gamble Company | Composition de detergent contenant du sarcosinate d'oleolyle et des tensioactifs anioniques dans des rapports optimaux |
| EP0906382A4 (fr) * | 1996-05-17 | 1999-11-24 | Procter & Gamble | Composition detergente |
-
1996
- 1996-09-24 GB GB9619929A patent/GB2317395A/en not_active Withdrawn
-
1997
- 1997-09-22 WO PCT/US1997/017076 patent/WO1998013464A1/fr not_active Ceased
- 1997-09-22 JP JP10515859A patent/JP2000503064A/ja not_active Withdrawn
- 1997-09-22 CZ CZ991022A patent/CZ102299A3/cs unknown
- 1997-09-22 TR TR1999/00657T patent/TR199900657T2/xx unknown
- 1997-09-22 AU AU44978/97A patent/AU4497897A/en not_active Abandoned
- 1997-09-22 EP EP97943527A patent/EP0929643A4/fr not_active Withdrawn
- 1997-09-22 CN CN97199995A patent/CN1238803A/zh active Pending
- 1997-09-22 CA CA002265901A patent/CA2265901A1/fr not_active Abandoned
- 1997-09-22 HU HU9904670A patent/HUP9904670A3/hu unknown
- 1997-09-24 AR ARP970104403A patent/AR010476A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| HUP9904670A3 (en) | 2001-02-28 |
| CN1238803A (zh) | 1999-12-15 |
| EP0929643A1 (fr) | 1999-07-21 |
| JP2000503064A (ja) | 2000-03-14 |
| WO1998013464A1 (fr) | 1998-04-02 |
| HUP9904670A2 (hu) | 2000-05-28 |
| AR010476A1 (es) | 2000-06-28 |
| CZ102299A3 (cs) | 1999-08-11 |
| GB9619929D0 (en) | 1996-11-06 |
| EP0929643A4 (fr) | 2000-01-05 |
| AU4497897A (en) | 1998-04-17 |
| TR199900657T2 (xx) | 1999-06-21 |
| GB2317395A (en) | 1998-03-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |