CA2263497A1 - Procede d'oxydation par micro-onde d'un minerai sulfure dans un lit fluidise, sans emission de dioxyde de soufre - Google Patents
Procede d'oxydation par micro-onde d'un minerai sulfure dans un lit fluidise, sans emission de dioxyde de soufre Download PDFInfo
- Publication number
- CA2263497A1 CA2263497A1 CA002263497A CA2263497A CA2263497A1 CA 2263497 A1 CA2263497 A1 CA 2263497A1 CA 002263497 A CA002263497 A CA 002263497A CA 2263497 A CA2263497 A CA 2263497A CA 2263497 A1 CA2263497 A1 CA 2263497A1
- Authority
- CA
- Canada
- Prior art keywords
- reaction
- bed
- fluidizing
- gas
- microwave energy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- 238000007254 oxidation reaction Methods 0.000 title claims description 13
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 title description 43
- 239000000463 material Substances 0.000 title description 11
- 235000010269 sulphur dioxide Nutrition 0.000 title description 9
- 239000004291 sulphur dioxide Substances 0.000 title description 9
- 230000003647 oxidation Effects 0.000 title description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000005864 Sulphur Substances 0.000 claims abstract description 17
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052683 pyrite Inorganic materials 0.000 claims abstract description 16
- 239000011028 pyrite Substances 0.000 claims abstract description 15
- 239000007795 chemical reaction product Substances 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 229910052595 hematite Inorganic materials 0.000 claims abstract description 7
- 239000011019 hematite Substances 0.000 claims abstract description 7
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000003134 recirculating effect Effects 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 65
- 239000007789 gas Substances 0.000 claims description 37
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 230000001590 oxidative effect Effects 0.000 claims description 4
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims 2
- 239000011261 inert gas Substances 0.000 claims 1
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 6
- 239000011707 mineral Substances 0.000 abstract description 6
- 238000011084 recovery Methods 0.000 description 7
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 4
- 239000011343 solid material Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 229910052952 pyrrhotite Inorganic materials 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 101150075433 SSO2 gene Proteins 0.000 description 1
- 230000003190 augmentative effect Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- NFMAZVUSKIJEIH-UHFFFAOYSA-N bis(sulfanylidene)iron Chemical compound S=[Fe]=S NFMAZVUSKIJEIH-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000012932 thermodynamic analysis Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
- C22B1/10—Roasting processes in fluidised form
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/02—Obtaining noble metals by dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0002—Preliminary treatment
- C22B15/001—Preliminary treatment with modification of the copper constituent
- C22B15/0013—Preliminary treatment with modification of the copper constituent by roasting
- C22B15/0015—Oxidizing roasting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00026—Controlling or regulating the heat exchange system
- B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
- B01J2208/00044—Temperature measurement
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
La présente invention concerne un procédé de traitement de minéraux de pyrite par l'utilisation d'un réacteur de fluidisation alimenté par énergie micro-onde, à des conditions de température qui permettent d'obtenir des produits de réaction relativement exempts d'émissions de SO¿2?. Les conditions de température contrôlées auxquelles les produits de réaction deviennent hématite ou soufre élémentaire peuvent être obtenues par recyclage et refroidissement d'une partie du gaz de fluidisation sortant et par régulation de l'énergie micro-onde qui alimente le lit fluidisé.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US70370396A | 1996-08-27 | 1996-08-27 | |
| US08/703,703 | 1996-08-27 | ||
| US89710397A | 1997-07-18 | 1997-07-18 | |
| US08/897,103 | 1997-07-18 | ||
| PCT/CA1997/000561 WO1998008989A1 (fr) | 1996-08-27 | 1997-08-08 | Procede d'oxydation par micro-onde d'un minerai sulfure dans un lit fluidise, sans emission de dioxyde de soufre |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2263497A1 true CA2263497A1 (fr) | 1998-03-05 |
Family
ID=27107190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002263497A Abandoned CA2263497A1 (fr) | 1996-08-27 | 1997-08-08 | Procede d'oxydation par micro-onde d'un minerai sulfure dans un lit fluidise, sans emission de dioxyde de soufre |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0950122A1 (fr) |
| AU (1) | AU721221B2 (fr) |
| CA (1) | CA2263497A1 (fr) |
| WO (1) | WO1998008989A1 (fr) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5972302A (en) * | 1996-08-27 | 1999-10-26 | Emr Microwave Technology Corporation | Method for the microwave induced oxidation of pyritic ores without the production of sulphur dioxide |
| AT408992B (de) * | 2000-06-28 | 2002-04-25 | Voest Alpine Ind Anlagen | Verfahren zur direktreduktion von feinerz sowie anlage zur durchführung des verfahrens |
| RU2224805C1 (ru) * | 2002-06-20 | 2004-02-27 | Швецов Владимир Алексеевич | Способ предварительного обжига сульфидных руд и продуктов их переработки, содержащих золото и серебро, в пробирном анализе |
| DE10260742A1 (de) * | 2002-12-23 | 2004-07-08 | Outokumpu Oyj | Verfahren und Anlage zum thermischen Behandeln von körnigen Feststoffen in einem Wirbelbett |
| DE10260731B4 (de) | 2002-12-23 | 2005-04-14 | Outokumpu Oyj | Verfahren und Anlage zur Wärmebehandlung von eisenoxidhaltigen Feststoffen |
| DE10260733B4 (de) | 2002-12-23 | 2010-08-12 | Outokumpu Oyj | Verfahren und Anlage zur Wärmebehandlung von eisenoxidhaltigen Feststoffen |
| DE10260744A1 (de) * | 2002-12-23 | 2004-07-01 | Outokumpu Oyj | Verfahren und Anlage zum thermischen Behandeln von körnigen Feststoffen |
| DE102010022400B4 (de) * | 2010-06-01 | 2013-04-25 | Outotec Oyj | Verfahren und Anlage zur Absenkung des Rest-Kohlenstoffgehaltes von Asche |
| FR3136541B1 (fr) * | 2022-06-14 | 2024-06-21 | Innovation & Dev Company | four de calcination par micro-ondes et à lit fluidisé |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2209331A (en) * | 1936-11-12 | 1940-07-30 | Haglund Ture Robert | Roasting process |
| US4324582A (en) * | 1980-06-11 | 1982-04-13 | Kruesi Paul R | Process for the recovery of copper from its ores |
| US4678478A (en) * | 1986-04-14 | 1987-07-07 | Massachusetts Institute Of Technology | Method for desulfurization of coal |
| JPH0711594B2 (ja) * | 1987-05-21 | 1995-02-08 | 動力炉・核燃料開発事業団 | 流動床システム |
| US5123956A (en) * | 1991-04-12 | 1992-06-23 | Newmont Mining Corporation | Process for treating ore having recoverable gold values and including arsenic-, carbon- and sulfur-containing components by roasting in an oxygen-enriched gaseous atmosphere |
| JP2766586B2 (ja) * | 1992-06-23 | 1998-06-18 | 大阪ガスエンジニアリング株式会社 | 粒状処理物の焙煎方法とその装置 |
| DE4329417C1 (de) * | 1993-09-01 | 1994-08-18 | Metallgesellschaft Ag | Verfahren zum Rösten refraktärer Golderze |
-
1997
- 1997-08-08 EP EP97935397A patent/EP0950122A1/fr not_active Withdrawn
- 1997-08-08 WO PCT/CA1997/000561 patent/WO1998008989A1/fr not_active Ceased
- 1997-08-08 AU AU38439/97A patent/AU721221B2/en not_active Ceased
- 1997-08-08 CA CA002263497A patent/CA2263497A1/fr not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| AU721221B2 (en) | 2000-06-29 |
| WO1998008989A1 (fr) | 1998-03-05 |
| EP0950122A1 (fr) | 1999-10-20 |
| AU3843997A (en) | 1998-03-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |