CA2137007A1 - Method for removing alkaline sulfate scale - Google Patents
Method for removing alkaline sulfate scaleInfo
- Publication number
- CA2137007A1 CA2137007A1 CA002137007A CA2137007A CA2137007A1 CA 2137007 A1 CA2137007 A1 CA 2137007A1 CA 002137007 A CA002137007 A CA 002137007A CA 2137007 A CA2137007 A CA 2137007A CA 2137007 A1 CA2137007 A1 CA 2137007A1
- Authority
- CA
- Canada
- Prior art keywords
- scale
- sonic
- solvent
- khz
- frequency
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 title 1
- 239000002904 solvent Substances 0.000 abstract 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004090 dissolution Methods 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- -1 oxalate anion Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/52—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning
- C09K8/528—Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning inorganic depositions, e.g. sulfates or carbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F21/00—Dissolving
- B01F21/02—Methods
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F31/00—Mixers with shaking, oscillating, or vibrating mechanisms
- B01F31/80—Mixing by means of high-frequency vibrations above one kHz, e.g. ultrasonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
- B08B3/04—Cleaning involving contact with liquid
- B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
- B08B3/12—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration by sonic or ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/20—Obtaining alkaline earth metals or magnesium
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B37/00—Methods or apparatus for cleaning boreholes or wells
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/003—Vibrating earth formations
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Fluid Mechanics (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Saccharide Compounds (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to the use of low frequency sonic energy in the sonic frequency range for enhancing the disso-lution of alkaline earth metal scales using a scale-removing solvent comprising an aqueous alkaline solution having a pH of about 8 to about 14 and containing EDTA or DTPA and a catalyst or synergist, preferably an oxalate anion. When the scale-rem-oving solvent is contacted with a surface containing a scale deposit while simultaneously transmitting low frequency sonic energy through the solvent, substantially more scale is dissolved at a faster rate than previously possible. The frequency of the sonic ener-gy is within the range of 1.5 to 6.5 kHz and preferably 1.5 kHz.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US89287692A | 1992-06-03 | 1992-06-03 | |
| US07/892,876 | 1992-06-03 | ||
| PCT/US1993/005317 WO1993024199A1 (en) | 1992-06-03 | 1993-06-02 | Method for removing alkaline sulfate scale |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2137007A1 true CA2137007A1 (en) | 1993-12-09 |
| CA2137007C CA2137007C (en) | 2003-09-16 |
Family
ID=25400649
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002137007A Expired - Lifetime CA2137007C (en) | 1992-06-03 | 1993-06-02 | Method for removing alkaline sulfate scale |
Country Status (6)
| Country | Link |
|---|---|
| CA (1) | CA2137007C (en) |
| GB (1) | GB2282619B (en) |
| NL (1) | NL9320035A (en) |
| NO (1) | NO312438B1 (en) |
| RU (1) | RU2110489C1 (en) |
| WO (1) | WO1993024199A1 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0733779B1 (en) * | 1995-03-24 | 2002-12-18 | Norbert Dipl.-Ing. Dipl.-Wirtsch.-Ing. Patzner | Method and apparatus for cleaning wells by means of ultrasound |
| GB2338254B (en) | 1998-06-12 | 2002-10-16 | Sofitech Nv | Well completion clean-up fluids and method for cleaning up drilling and completion filtercakes |
| US6140277A (en) * | 1998-12-31 | 2000-10-31 | Schlumberger Technology Corporation | Fluids and techniques for hydrocarbon well completion |
| GB9914398D0 (en) | 1999-06-22 | 1999-08-18 | Bp Exploration Operating | Reduction in solids deposition |
| GB9925373D0 (en) | 1999-10-27 | 1999-12-29 | Schlumberger Ltd | Downhole instrumentation and cleaning system |
| US6631764B2 (en) | 2000-02-17 | 2003-10-14 | Schlumberger Technology Corporation | Filter cake cleanup and gravel pack methods for oil based or water based drilling fluids |
| RU2286204C1 (en) * | 2005-04-20 | 2006-10-27 | Общество с ограниченной ответственностью "Астор-С" | Method of preparation of the water solutions of electrolytes under action of the ultrasonic cavitation |
| RU2490430C1 (en) * | 2012-10-04 | 2013-08-20 | Открытое акционерное общество "Татнефть" им. В.Д. Шашина | Procedure for oilfield pipeline operation |
| RU2552434C1 (en) * | 2014-04-17 | 2015-06-10 | Федеральное государственное бюджетное учреждение науки Институт химии нефти Сибирского отделения Российской академии наук | Composition for sediment removal from oil wells and reservoir bottomhole zone |
| DE102017011116A1 (en) * | 2017-11-30 | 2019-06-06 | Alfred Pohlen | Online cleaner for water-bearing or water-contacting systems |
| CA3038556A1 (en) | 2019-04-01 | 2020-10-01 | Fluid Energy Group Ltd. | Composition useful in sulfate scale removal |
| CA3049343A1 (en) | 2019-07-11 | 2021-01-11 | Fluid Energy Group Ltd. | Composition useful in sulfate scale removal |
| CA3114487A1 (en) | 2021-04-09 | 2022-10-09 | Fluid Energy Group Ltd | Composition useful in sulfate scale removal |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3648769A (en) * | 1970-09-04 | 1972-03-14 | Beehler Vernon D | Well cleaner |
| US3956164A (en) * | 1974-09-23 | 1976-05-11 | Calgon Corporation | Chelating agents |
| US4320528A (en) * | 1980-01-23 | 1982-03-16 | Anco Engineers, Inc. | Ultrasonic cleaner |
| US4980077A (en) * | 1989-06-22 | 1990-12-25 | Mobil Oil Corporation | Method for removing alkaline sulfate scale |
-
1993
- 1993-06-02 RU RU94046196A patent/RU2110489C1/en active
- 1993-06-02 GB GB9423576A patent/GB2282619B/en not_active Expired - Lifetime
- 1993-06-02 NL NL9320035A patent/NL9320035A/en active Search and Examination
- 1993-06-02 WO PCT/US1993/005317 patent/WO1993024199A1/en not_active Ceased
- 1993-06-02 CA CA002137007A patent/CA2137007C/en not_active Expired - Lifetime
-
1994
- 1994-12-02 NO NO19944660A patent/NO312438B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NL9320035A (en) | 1995-05-01 |
| GB2282619B (en) | 1996-06-05 |
| NO944660D0 (en) | 1994-12-02 |
| GB2282619A (en) | 1995-04-12 |
| NO312438B1 (en) | 2002-05-13 |
| RU2110489C1 (en) | 1998-05-10 |
| CA2137007C (en) | 2003-09-16 |
| WO1993024199A1 (en) | 1993-12-09 |
| RU94046196A (en) | 1996-10-20 |
| GB9423576D0 (en) | 1995-01-11 |
| NO944660L (en) | 1994-12-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |