CA2038322A1 - Hair treatment composition and method - Google Patents

Abstract

COMPOSITION AND METHOD FOR COLORING AND CONDITIONING HAIR
Abstract A method for non-permanently or semi-permanently coloring hair with an aqueous clay-based composition that involves applying the composition to hair and exposing the hair to heat for a period of time sufficient to dry the composition to a hard and flaky state. The hair coloring composition also can include effective amounts of a reconstruction component (protein), a moisturizer component having sodium hyaluronate, and a shine imparting component having henna extract.

Description

rROM qEP~:HRt`lT 5~ U_C
1~, 13. 1 ~1 16: 2~1 Nû. ' ~03832Z

CO~POSITION AND ~E~OD POR CO~ORING ~D CO~ITION~NG ~AIR

Pield of the Invention 1~ This inv~ntion r~lates to aqueouq cl y-based hair treatmen~ co~positions includiog ~ :~construction com~onen~, a shir.e ~p2rtl'ng com~onent and a moisturizing C~mDoner.~ tha~
can be used in a singla a~lication to condition h~ir. The in~ention a'so relates ~o single application, aqueous clay-based hair color~ng comoosi~ions incoroorating non-pe~mar.ent or semi-per~anent. agents for colorin~ hair, as well as r~onstruction, s~i~e i~p~rting ald moisturizing co~onents for conditioning hair.

Backoround of the Invention A Yariety of chemical preparations are a~ailabl~
and commonly used to change the nat~ral characteristics of hair. Color and style are typically chan~ed usirg dyes, bleaches and permanent-waving prepa~ations. E~or example, hair color ~ay be non-permanently (i.e. tempora-ily), se~i-permanently or penmanently changed depending on the particular coloring co~positions employed. These chemical prepasations can damage hair.
In general, hair has a fila~entous struceure ~ith an inner component referred to as the cor~ex and an oute-flaD~ e component referred to as the cuticle. In the natural state, the cu~icle is closed pro~idlng natural elas~ici~y. When the cu~icle is open, t~is na~usal elasticity is los~. ~.air damaged by chemical prepa-ations, in many cases, exhibits open cuti~les. For exam~le, us~ of - I~ U ~ ! ' h' ~ Ll - Z0~8322 dye mix-ure~ can dry hair rasul~ing in a loss of elastiei~y an~ body.
To _es.ore des~red elasticity an~ body to hai~
~ollowing usa of chemical p eparctio~s, ha7`r conditioning treatmen~ ara commoniy e.~loy~d TypiC~1 hair conditio~ g treat~ents lnvo~e tha ~s~ of a ~u.~ber of componer.~s to rastore hal_ ~uaLities lost du-i~.q che~ical t~eat~ent. ~o r2c3ns-~lc. the hair and brl~g bac~ alas~ic~ty a protein pac.~
is commonly employed. ~lso~ a co~.ponent such as henna can be applied to the ha r to ~7~arl shine or luster. Anocher typi~~al post-~rea~mer~t condlt~ oning com~onent i3 . mo sturiz~r which i9 used to 2r~ance the ~ody of halr.
~ hile ha~r ~rea~men~s tha~ rscon~truct, add shine, ana 5:0' sturize :~a r a-~'~no~n, thes~ t~eatments a_e ~oth tin7e 15 const~ing and labo~ in~ensive. S?eci~ic~11y, each component in th~ hair con~itioni.qg ?roces3 mlst ~e separa'ely a~?lied and removed. The application Ot a protein pac~ t~pica11y ~equires 10 to ~0 min~tes and must then be removed prior to ap~lyins further condition n~ components. Treatment of hair with a shine im~ar~ing co~penent such 2s henn~ can invol~re ~p to one hour. ~e shir.e i.-.~a ~ ng component must als~ ~e re.~oved before anoth~ condi~ioning preparation, such as a moisturlz2r is used. In t~e ~asa of a three par hai~
conditioning treatment, to reconstruct, im~ar. shine and 2S moisturize hair, sep2rate ap?'ication and re~o~a' of each component requires a ;otal traatment time of 2bout 1 to 1-1/2 hours. It is to be unce-stood that this 1 to ~ 2 hour process i9 in addit_on ~o w~.ate~er ~ima is involved _n ;ha par~icu1ar dye o~ ~er~.anent-waviny trea~er.~ ~hich prec~dos ~ha hai~ conditionin~ o-ocedsre. For ex1mple, non-~er~anen~
or se~i-per~,anent colori~iy of ha~-, w~.ich typically re~ul_es S to 30 ~inuta3 of ~P?'`-~ '~ in conjunc~ion with hai_ r R C~ E ~' C H f~ T '~ i Cl u L `
0~, 13. 19~1 li,:22 ~u; ' ~. 6 ~03~332~
.. - 3 -conditioning couid require a total t_eatment time o about 1 t:o ~ hours.
Accordingly, a substantial need exi,cs for a h~ir condltioning co~.pos~'tion containin~ a r9constru~tion S component, a shin2 L~parting comoonent and z moistux~zing component that can be employed in a single application p-ocedure of short dur2tion. A substantial need also exits for d singla ap~l~cation co~position for col~ring hair, which in addition ~o non-permAnent or ~emi-permaner,t colori~g a~ents, c~ntains recons~ructive, shir.e imparti~g and moisturizin~ ~omponents for conditioning hair.

Summary of th~ Invention Tn~ pr~sen~ inver.tion pro~ides a hair treatme~t lS comp~sition in rh~ form of an aqueous clay-based paste wnich includes effective dmounls of a reconstruction co~pon~nt, a shinæ i~parting c~mponent and a moisturizing comoonert. It ha~ be~n fcund that the composition i9 useful in a ~ethod to condition hai~ in~olving: applying th~ prepa~a~ion to hair;
and ex2osing the prepared hair to heat until the Dreparat~ on drles to a hard flaXy state, The d-ied pack is t~.en solu~ilized ar.d removed with a com~erciall~ avz~lable cleansing shampoo.
T;~e pr~sent invent~on also provides a hair colo~ing ccmposition in the f~r~ of an aqueous clay-based pas~e which include~ effect~ve amounts of non-per~anent or semi-permanent coloring asents for coloring h~ir, a~ well as ~fective amounts of reconst-uctiYe, shine imparting and moisturi2ins componen~s for conditionLng hair. As ~ith the conditioning compcsition described ab~ve, the coloring composition is applie~ to the hair, exposed to heat until dry and then removed with a com~r~ially available shampoo. In this instance, non-per~ane:lt ha_r coloring agents a~e de~ined a3 C i; o i1 ~' ~ R ~ H H I`~ / L~ ~ L' " I Y ~ h U . I ' r, ` 20;~8322 ~hose colo~in~ pre~aratlons wh ch give a colo. that ~s completely removable in o~e sh~m~os, while se~i-per~nen~
colorin~ agents a~s defined as those which will last th~ough a~ least four c. more washin~s of the hair.
S In a ~eferred e~bcd~men_, the method of use o_ the hair ~reatment co~position ~..Jo ~ ves a two Sre~ he~
trea~ment. In the fi~s~ ste3, _ha ore~ared hai_ is enclosed in a co~er ~eans s~_:h as a cap. In the second he~t ste2, which is of shor~ar du-~tio~ than h~ first, the prepared hair is uncovere~ a~d ex~osed dire-tly t3 the heat.
In a second ~reter_ed e~od~ent, the mechod of use . c the hai- colorin~ co~ces.tiGn of the present inven~ion ir.~olves a three step p~ocass, ir.ctudir.~ a two ~te? heat tr~atment. In _he fl-st ~tep, the hair prepa~ed with the compos.tion ig enclose~ in 2 cov~r means such as a c~p, a~
is e~osed to heat for a prede~eL3ined duration. In the second s~ep, which is shor.er in duration tha~ the first ste?, the prepared hair is uncovara~ and exposed directly to the he3t t~eat~ent. In tha thir~, and final step, the dxied ha r coloring composition i~ ~ashsd fro~ the hair using a c~mercially availakle cleansir.s s~.ampoo, to yield non-permanently or semi-per~2nently col~red and condilio~ed hair.
'.~ addition, the method of use of .he presen_ nvention may em~loy ~ sir.gle heat treat~ent sr3~, whe~ein ths hair coated 2S with the comDosition is ~i.ectly exposed t.o he~t treatmen~
until i~ d-ies upon th~ hair. In this instance, a diminished, and ~herefore, ~.ore su~tle, coloring ef~ect i8 ~moa-~ed ~o the hai_ w~en co~pa-ed to the two-step heat tr3atment des~ e~ above.
3C The hai~ t~eatmer.t co~cos ~Lon arLd ~ethcd of us~ ~t ~he pres2n~ inve~rior. e~h bits a nu~ber of advantages.
.~irst, the present in~en~Lon eiim1:sàtas the need for ~.ultip~e step condi~i.oning ~a~nt~ which invo1ve sepa~te -PUrl i':~.CH~T ~ u L
. I 9 91 l G: 2 5 N ~ , 3 ; 2038322 appl1cation _.~d re~oJal of condi~ioning com.ponent3. The present inV2n~ion pr^vi~es a com~osition that c3n be us~d in a singl~ apolica~ion to condition hair by _ec3ns~ruc;ing d~Aaed hair to~at~er -~ith add~ng shine and body. Second, s in contrast to the exist~ ng ~ul~iple step condit~oning t_~at~ents, which ~2y require ~rom about 1 hour to l-l/2 ho~rs, ~he Det.~cd of the present requi~es only a~out 20 tO
40 ~inures. Thi~d, rhe pr~sent invention is labor saving in ~hat one ap?licacion st~p is re~ui-ed, thereby enabl ng mo~e 13 er.~icient us~ cr beauty salon personnel.
~ he mcis~urizer hyaluronic acid pene;-ates deepiy;
while clay locks ln moisture an~ protein, natllral'y sealir.g the c~tic1e laye~. ~ha presen~ CompoSit~Gn cor.ditions, seals and ~nhar.ces na~ur21 sheen and a Light but full app~aranc~
o.~ hal~
The hair color~ng composi~i~na and metnod o the presen~ in~ention provides the ad~a~tages of a or.e-step non-per~a~ent or semi-p~r~anent color~ng and conditioning treatment. ~ccord~ngly, as with t~e above-described 2~ conditi~ning c~mposition, the coloring co~position of the p_es~nt invention save3 tim~ and labor allocation. Thus, in contrast to a multiple-step colo~ing and condi~iohing proces~
re~uiring 1 to 2 ~ours, the met:~od and com?osi~i~ns or t~e ~resent invention c~n accompliah the same result with a on9-25 S~2p process ~equi_ing 20 to 40 minutes.

Detailed ~escription of the Invention T~e presen~ ~.air conditioning compositions aspreferably fo~lulated include a sufSicient amount o~ a clay 3~ component to fcnm a malleable pasts having a~ oil phase and water, together ~ith effective amounts of a ~econs~ruction component~ a sh~ne impa~ing component and a ~oisturizing compon~nt. Tha ~es~red paste consistency of ~he composition r f~ U Il ~l ~ R C H l~l h l~ ' D
3, 1 9 ~ I 1 6: ~ b 11 ~ . ' 2 ~ . '?

o 2038322 ~s achieved and ~aint~ined with ~he aid of oationic, non~on c and anionic poly~er3, surf~c_an~s and emulsi~ie-s.
~ ha prrsent ~aste ~s an a~ueous clay-based ~o~osi~ion. Acueous clay-based co~position refe~s to a paste lncorporating wat~r and ~lay ~n amounts suf~cient t~
~3~m a dry and f'aky coat~g on hai- whan sub~ected to heac as describe~ herein. P~e~erab!y, the paste ha~ ~he consistency of a iig~ cdelin~ clay. In a ?reîerrad em~odi~en~, fro~ abo~t 1;-25~ of ~he co~.posit~on L3 -~2y (th's ~ercentage and a l follo-~lng per^ents bein~ waigh~
?e_cent3 relative to th~ -~tal ~eigh~ of t~.e composi~or.).
In ge~eral, clay refe_s tc a c~o~ition of extre~ely fine c~ystals o- particles of r~c'.c whic;~ i~ mar.y cases ha3 the charact~ristic of pl~s~icity. The ve~ fir.e par-icl~s yield ~ ve~y lar~e s~ecific su_face tha~ ~s physically so~?~ive and rhe~ically sur~ace-raact~ve.
~ he presen~ c3~posirions can empioy a n~mber of ~lays elth~r alone o~ in combinat_on. ~or ex,~ple, ~aelin, fuller's earth, mont~orillonita, geor~ia or calcine clays 2Q can be used. Prefer_ed composi~ions employ a co~bi~ation Or kaolin and fullerl~ ea-th. Mors orefera~ly, the clay of the p-esent composit$on is rom about 13-20~ kaolLn av~ilable ~-om Georqian Raolin a~ ~ydride Fla~ D and about 2-12 uller~s earth. While -~.e _ombir.ation o kaolin and fuller~
earth is preferrrd, one of s~ill in the arl will be able to ~ o other -ypes o~ clays ~ased on an e~aluaticn of the hydration, emul~ion 12;tice filling characterl~tics, and thixotropic and r~2closlc p-oper~ies o' _he preferred co~osltions described here n.
'~he present ~3 ~a ~ill incor?or~ce an effecti~e ~mount o~ recons~ructi3r. compcnen~ in the form o~ p.otein.
Preferakly, the cor.?csi~_on ;iil include _rom abou~ 0 substa~t~e pro eir.. ~.os ?ree~ably, ~he composition wi,~

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include a' least 10~ prot~in ha~ing average molecular wei~r,~s -angi~g fro~ !,000 to 5,000. Praferred ~ources of pro-e~n include hydrolyzed a~i~al protein such as availa~le from Inol~x as Lexein X250 an_ cocodimoniu~ hydro;yzed anlmal protein available f~om Croda a3 C_o~ua~ ~. O~her prota~n sources that can be ~sPd include oat flour available f-om Quaker Oats as Oat Pro or S~ero Pro.
The presant co~.position can be used ~o deliv~r an amount of moisturizer to ~he hair ef-ec~ive to pro~ide bo~y lC without addi~g a ~-eig:~ty oil coat to the hair. The mois.urizing component is oreferably from about 0.1-;.3% of the composition. While the present composit~on may incorporate a nl~ber of co~mcn ~oisturizers such as vlyce_~'n, Acetamide ~EA o~ honey, the preferred mois~1rize- is hyaluronic a~id ~now known as sodium hyaluronat2)~ available fro~ ~iaqnostics as Hyaluro TN. It is beliaved that hyaluronic a-id peretrates dee~ly ~nto the hair and ca~ be used i~ very sma~l amounts. The present composition utilizes fro~ about 0.~00001-1% hyal~ronic acid. ~hile hyaluronic ac~d functions as a natural moisturizer, it may also bind to and carry the protein in t~.e composition through the c~iticle tO the co~tex G~ the hair to aid in recons~ruc'tion of the h3ir.
The present co~position also incorporaees a s~'ne or sheen i.~pa~ting com~or.en~. Useful shine i~p2r~in~
co~,ponents incLude her.na extract, PVM/~A Copolyme~, a~ailable from ~A~ Cor~oration as Gan~_az AN169, PPG-5 Lanolin in ether avai~b1e from A~archol as Solulan P8-5 and Amodiomethicone a~ail~le fr~ Dow Cornin~ as a componen~ o~ Dow Corning 929 Emulsion. ~hese shi~e i~pa~ting components may be used ~lone or in cc~ination as is ~nown by those of sXill 'n ~he art.
Prefe~red co~ sitions include from about 0.5-2C~ of the shi.~a i~par~ing c~or.ent. ~ost preferably, the s`r.~ne ' F 0 ~ R C i11~ O ~: ~. C~
, I 9 ~ 1 1 6: ' 9 X0~313322 i.~.par~ing com2on~nt inclu~es frcm ~out 5-L53 her.~a extract and O.5-5~ PVM/~ copolymer.
The ~rescn~ composi~ior~ in~ludes an oil phase that serves as a lubrlc~ting ~ehicle to en~ance appli^ation.
Use~ul oil phase compound3 inc`uda fatty ~lcohols. ~h3 prer~-rred oil p~.~s~ c~mponen.ts are fat.y alcohols such as stea~yl ~lcohol, and cetrl alc^hol. The oil phase ir. tne 2resent com~osition praf2ra~1v r~nges from a~ou~ ore pre~arably, the oil phasa is f~o.~ abou~ 3-7~ fa~y alcohol.
1~ ~he a~laous phase cr t~ ~rasent _o~position is pref2rably 'ro~ about ~a-~o~ ~ate~. ~Or2 ~referably, ~rom a~out 20-4C% waTe- and ~.os~ ~-efe=ably fro~ abou- ~0-3~
~a~er. To eLimlnate _he p~es3n_e ol un~e_lred mine-al i~pu_itias, deiGni-ed w~ter ~s mcs- pr~fe~-ed.
~; Nonion'c e~ulsif'~rs ar~ con~only added to ~he 2r~s~r.t compos''ion to e~hance -elubilL2ation of oi' sclubl~
components and fragran~e. Prefarably a ~ombi~ation ~f catio~ic and ~nionic emulsif~ers is used, Use~ul nonionic emulsiiers include n~noxyn~l surf~ctan~s such as ava lable ~rom hir~esot~ SolYen~s as Surroni~ N-g5. Prere~red cationic e~ lsifie-s include ~2llcwtrimG~ chloride, avAi' ~le from Dow Corning 92S Emulsionr ~at~rr~i~m 2~, a~Tzila~ rom V2!1 Dy3ce a~ Ceraphyl 60. In praferred co~positior,s ~he cation~c emulsifier cornpon~nt ran~es frcm abou~ 0, ~5-5% .
2S The preser.~ c~mpcsi~_ons ^~n also i:~clude m~r~or ~ut e- ective amountO af varLous ad j~rant s~.atar~ als ~n-.luding ~risco~it~I ~odifiars, preservat_ves and fragrances.
Ir. the inanu4acture ~t the cl~y-~ased com~ositions, t~ a~o~a~descr bad c~>m~or.an~ g ~re i~ixe~ tog~ther in phasas 3C and in order ~onsister.r wit!~ av~ilabla manufa. tu_ing equi~mer.~ until a 1 i~-~.; mode1i.~., clay consistency is cchia~re~. In c-ie_ to a~.-o~ ss of m~` 12 ~ y, the ~_;sp~s~tion ~ust b~ .a~2i~.1y c_arsfer~e~ to 3 S~,Or~5e G r~ r1 E R C: H ~ ~ T '; ~
q ~ 1 6: 3 1~ P, ~ _ - 9 - Z~:)38322 container, such as a jar, berore ~he compositior. far~her set~
or gels.
The present c~ay-~a~ad composi~ions for coloring h~Lr as pr~raDly formulated are pre~red b~ Le same 5 ~erhods and con~ain t~.e sa~e co~ponents as the conditionins compositiOnS described above. Xowever, the colorinq comDosi~ions als~ concain effective amounts of non-permanen_ or semî-permanent coloring a~ents ror coloring hair.
In con'rast to the aDove-desc~ibed condi loning composit~ons, the coloring com~ositions preferably con~ain from abou~ 5-25~ clay, and ~n ~ parti_ularly preferred e~bodiment cont~n ~rom a~out 2-129s ~;aolin ar~d about 0.5-7~
fuller~s earth. ~he colorinq composit!ons also prefe-ab~y contain 2-2~ pr~tein with at leas~ 5~ of .he protein ha~Jing 15 averase molecular weights rang~ ng from 1, '`C0 to 5, 000, henr.a excract as a shina impart_ng com?onent f~o~n about l-1596, and an ac~ueous phas~ ~rom about 20-7û~6, and mora praferably frorn a~out S0-~0~. In addition, hyaluronic acid is provided rrom about 0.0000'-1.0~ ~n its salt for~ as sodi~lm hyalursnate 20 from ~i~ecore.
The colo~ing com2csitions deliver effect~ve amou~s of non-permanent or semi-pex~anent coloring agents to ~he hair, while rataini~g the benef ~ ts imQarted tO the hair by the rec:onstrucr ive, shir.e imparting and moisturizing 25 co.~nponents described above. The non-pe~nar.enc or sami-permanan~ colc~ing agen~s are provlded from about 0.00001- !
5.0~, pre~erably fro~ about 0.1-5.0~, and ~ore ~re~erably from a~out ~.5-5.0~ o~ the composition.
T~e hair coloring compositions accordlng to the present invention ~ay incorpor~te anv of a n~er of non-permanen~ and semi-permanent c~loring agents such as F~uC
(Food, Drug ~ Cosrne~ic) ~ D&C (~rug ~ cosmetic) and :~IC (Xair Color) dyes and their Lrt~rm~d~ates, including var_o~ls F ~ O r1 ~, E ~ C ~ C~

, . - 1 0 - X0;.3~3322 pyrazolone, monoazo, xant~2n~, r_i2he~yi.~e.~.ane and dia~o co~.?ou~ds, metal-~omplex dyes i~c}uding azo complexes o.
cobal. or chro~ium and oxi~ation dye inra=mediates including m t~pheny!enedi~ines such as o-ni~ro-p-phenylenediamine S and ~-nit~o-o-p:~enyl2r.edi~1^.a.
I~ will be ap~rec .a_e thac the c~ay-'e2sed color,n~
CQm?Osi~iO~s of the ?_esent inv~tion c~n incor?orat~ any combin~t,on of the mo~st~rizir,g, ~econstructing and shi~s i~rarting compo~2n~.s previously desc-i~ed, Thus, the coloring comaositior.3 ~ay ~ont~in ~e colo-ing agen~ 9 alone, ar in com~inatio~s containi~g or~e, t-~o or all three of ~he ~o~urizing, reconst~uct~r.s ,nd shine i~a-ting co~ponent,.
_t will ~e rurThe_ a~prec~.ated that strongly cationic comp~nents, such as ~icetyl di~onium chlorlde can be incorporated into tha o1ay-based color ng com?ositions of ~he ~r3sent ~n~rention. Howe~er, care ~us~ be tak~n with t~e propcrtio~ of s~ch camponen~a to be ~dded, as a~ excess ~Otl~t ~ill com~lex with t.he an~onlc colo-ing com~onents of t~.a prQsent ~n~ention, the~aby r2ducing t.~e ef~ec~ eness of the clay-based co~?osftions ~o color hai-.
In use th~ com~ositions o. the ~rPsant in-~antion are preferab~y a?oli~d to hair after appli~ation of a chemical pre?aratien such as a d~e, ~leach or pe~ma;ler.~-wa~ring prepa~ation. An a~di~ion, th.e co;~positions for 25 coloring hai~ are applie-' tO ~he hair in a one-s~ep ~oloring ar~d conditionin~, process. Prior to applicacio~ o~ the composi~.ion the hair is shampooed and ex-ess water squee~ed ou~. The co~,positi~n is dispens2d from its c~ntainer and r~bbed be~ween the hands ~o ennance the li~idity 3nd ~preadability of t'ne ~o~positlorl pr~or to applicat1on, thereby facilit~tir.3 dic~ri~u~ion e~ the co~positlon in the hair. A libe~al as~ou:l- c~ -ha ~o~oc2ition is ap~lied to and ~or~ed in~o the h-~L- ar.~ sc~l?. ~he treated hair is -.~en r R ~ C H R ~ T ~ U ~ ' ~l~i. I ,, 19~1 :6: 3~ llCl. 1. ~.

1 } - ~038322 exposed to heat fo~ a period of ti.~e suffisien~ to dry the composition to a hard and fla~y stace. This is accompli~hed by ex?osing the h2ir to ;~mperatures from about R0 F-120 F
for a pe~iod of time bet-~en about 15-45 ~inute~.
Prefera~ly, ~he treated haLx is sub jected to a t~o-step heat process. In the first step, th~ hair i3 enclos2d in cove- means such as a plastic cap or ~he like. The co~Jered halr is hea~ed for a period of time bet-~een about 13-3~ minutes at a temper~ure from abou~ gO F-120 ~ under a prehaated sa~on d~yer o~ the type known in the art. Most prefer~bly, the co~er2d hai~ is heated for a ~e_iod of _~e between about 20-30 ~.inutss at a tempe_ature of f~om about 90 F-110 ~. It is to be understood that by co~ering the h2~_ with a cap t:~e _lay-based composition retains ~.oistur2 for an extended pa-iod o time allowing the ~rotein Ln the comp~si~lon to bake into the hai- there~y enhancing reconst~ction o damaged hair. If hair dries too ~uickly, incorporation of prota~n into the hair i9 l~ss complete. By co~ering t~e hair, protein incorporation is maxim~2ed.
~he seeond step of the preferred heat treatment involves ~e~av~n~ the cap and exposing the hair directly to ~eAt at a te~,pera~ure from about 80 F-120 F for a period ~r ti~e between ~out 2-15 ~ir.utes. Most preferably, the second step or the hea~ treat~ent involves sep2rati.ng the hair with finqers and exposing the unco~ered hair to a temperature of from about 90 F-llO F for a period of tL~,e between about 3-8 minutes. mhe head is then ailowed to cool for several minutes. The applicat~on of heat to the exposed hair co~.ple es ~he dryir,g o~ the co~pcsition, ther~y polishing 30 the hai~ and saaling the cuticle.
After the composition has dried to the desired hard and ~laXy sta~ is re~oved by wetti~g t~e head ~ith wat~r rROrl ~IERI~H~ T ~ I;OIJ-[~
'. 1991 16: 3~ NO. :~ - . 15 --Z~3832Z

and app'ying a cleanslng sham?oG of a type ~ell ~nown ~n the ar~.
The a~cve-des~ribed ~e~hod of use may ~lso be emoloyed wit~ the hair coloring compositlons of the p~esent ~nv~nticn. ~_ordingl~, as dasc~Lbed above, tha hair ~s ~irst sh~m2ooel and tne excess water is ,queezed out. The ~-lay-~asad com~o~i~ion, in~uding the incc-porated non-per~ane~t dyelng agent, is applied and hea~ traa~ed acc3rding to the above-described me~hod. ~nally, the clay-base~
colo~ing ccmp^sitlon i3 removed by cleansing t~.3 hai~ w~th a sham300 of :he ty~e w~ll kno~-n in the art.
In wll' b~ ap?reciated th t t~.e cc~oo3itions for color~ng hair 2~cl~rding to the prese~t inver.~ion can ba o~cionally su~j~cted to a cr.e-~tep he~t 2rocess. In this instance, the hair coa~2d wit~ thC comoosition i 5 dirac-l~
exposed to temperl~ure fro~ out 80F-120~ f~r a period of time between 2-15 min~tes. ~os~ prer~raDly, the heat treatment involves separat_ng ~he hair ~ith the fingers and exposi~,~ the uncove_-d hair to a temperature of f~om about 90~F-llC~ for a pe_iod of t~.~e bQtween 3-3 minutes. ~he hair is then a'..lo~ed to cool fo~ saveral minu;es. When utilized in t~.is .~ar~er, the coloring co~posi~io~s acco~di~g to the pr3sent ~nvention impar~ a diminished, and therefore, ~ore subtl~, coloring effect ~o ~he hair bein~ trzated.
~5 It ~ill be further a~prsciated that the aompositi^ns fo_ s~'ori.n~ ir a~cordin~ _o the preser.t inven~ian may ba u~ilized as a cor-ecti~e coloring agents for eliminatins ~nna~ral co10r ;cnzs in prz r' ously d~ed o~ ~rea~ed hai- .
Far e.~ample, hair which has been dyed to a brunet-te _0 coioracion frequentl~f dis~lays ~ re~ tone arter the passaye of tL~e andjor ex~sur~ _~ the sun. By utili~ing a slate-bl~e hair colorir~g :o~.?os_tisn according to the p,esent inven~ion, s~ch re -cone~ :rSir can be ret~ne~ to a natural F~ E~:Ci'P'~T ~ OUL~
1 6: 3 ~ ~ 0 . 1 ~ r, 1 - 13 - ~ X0383X2 brsne~ta coloration, and at the Sam2 t~me, can be condit~oned. In addition, it will be appreciated ~y tho~e s~illed in the zr~ that th~ particular dye colorat~on emplo~;ed in th~ cl3~-based coloring composit~ons o~ the present inventL~n do not necessarily correspond to the colora~ion impartad to the hair, For exa~.ple, utili~a~ion of certaln green dye~ will in fact im~ar~ a qolden coloration to the hair to b~ dyed.
It will alsG be appreciated that both the clay~based condi~ioning and c~ay-~ased coloring and cond_~ioning c_mpositi~ns accordi.ng to the p-esen~ in~ention can be utilizsd in eirr.er a beauty salon ~r at home. An individual may h2ve the co~.positions o~ the present invent_on appiie~
~y a hair ~~eat~ent professional at a beauty salon or shcp, or may optio~ally purcnase the pres~nt composition~ a~ a salon o~ other appropriate retail outlet, and apoly the contpos,t ons themsel~ at home.
~ he present comoosi~on will be further descri~ed by reference to th2 follcwing detailed Examples, and it is ur.derstood t~at the in~ention i~ no~ ited thereto. All parts ar2 by weig.it unless otier~ise indicated.

EXAM~E 1 The cor.srituent3 below are blended in the ~eight percencages indi~2~ed tO yield a pas~e ~mposition.

FF~01`1 MEF~CHP:~T C< J~ILG
~ 3 . i ~,: ~ 9 1. b: ~ li H O . I ~, ~ 7 CT~'A Cesiqnat~on ~ade Name~ bY ~eiqht Delonized Water ~eionized Wa~er Q.S to 100 S Kaolin ~ydride 18.13 Hy~ro'yzed Animal Pro~elnLexein X250 10.00 Henna Ex~ract ~enna SxtractlO.0C
Amodimethicone (and) Dow Corning 929 8.00 Nonoxyn~1-10 (and) E~ulsion Tallow~rimonium Chloric-15 S~earyl Alcohol Stea~l Alcohol 2.52 Fu~le~ls Ear~h Fuilar~s Ear~4.41 PV~ ~ Copol~mer Gantraz AN165S.00 Glyc2~in Glycerin 3.C0 Magnesiu.~ Aluminu-~ Veegum :~V2.64 silicate Nonoxynol-10 Sur_snic N-950 . 25 Oa~ Flour Oat P~o 1. 72 30 A~2~amide ~EA A^e~a~lde ~.E~1.50 Quaternium-22 Ceraphyl 60 0.25 Sodium Hyaluronate Sodiul~ Hy~luronate ~0.01 C~codimonium Hydro'yzed Cro~at ~ 0.25 Animal Protein PPG-5 Lanolin Eche~ Sol~lan P3-5 0,50 Dimethyl ~auramlne Oleate Necen ~o 1.50 Honey Ho~ey 0.25 45 C.~ionic Collagen C~tionic Collagen 2.00 Polypeptidcs Poly?eptides Cetearyl Alcohol (an~1`, C"c lo~o~ iCS 3.19 PrG-40 Cas~or Oil ~a-~
Stearalkonium C~lcci~e FF~I llEl~l Hi~t~r ~ ;~UI r~
~ . 1 3, I g ~t I 1 6 ~ O, I . G, I ~:

- 15- ~03832'~:

Cetyl Alcohol Cetyl Alcohol 0.21 Glyceryl Stearate (and; Arlacel 16i 1.00 PEG-100 Stearate .ethvlparab2n Methylparaben 0.30 Propylparaben Propylparaben 0.08 }O
DM~ Xydantoin GLydant 0.35 Gluteral Ucarcide 225 0.20 ~S Fr~ance ~ragrance Q.S

The cons~it~entq below are blended in the ~eight percentages indicated to yie}d a pa~te ccmposition whic~ can te~orariiy aiter the color of hai~ through ~he use o ~on-per~allent or semi-eerman~nt coloring compositions, as ~ell as condition ~he treated hair.

E~SPLE 2 The const~t~ents listed below result in a lavender coiored clay pac~ for coloring and conditicning whi~ or grey hair.

~R011 '~lERCh~!~T ~ L~ ~33. 13. 1991 1~ , 12 P. `~

C.~A De jiqnatio~ Trade Na~e ~ bY '~eiqht De~onized ~a~er D~ior.ized ~ater Q.S. ~o 100 Henn~ Extract Hen~^ Extract 7.00 .~thyipara~en MathYl?ar~en 0.30 ~agnesi~m Aluminum Veequm ~V 1.00 Silicate Sodium ~l~aluronate Lif2c~re Sodiu~ >~.01 Hy~:uronata Glycerin Glyc2rin 0.35 ~oney Honey Blend ~3 0.10 ~cetamide ~EA Ace~mida ~EA 0.01 20 Ga~ Flour Stero Pro 1.34 PV~ ~ Copolymer Ga~t-9z AN 15~ ~ol . ) 4 . 0~
Quaternium-22 Cera~hyl 60 0.01 Xydrolyzed Animal Prorein Lexein 250 6. ao Cationic Collagen Ca lonic Colla~en 1.50 Polypeptides ~lypeptides (Lmerchol) Cocodimoni~m Hyd~olyze~ Croquat ~ 1.50 Animai Protei~
~snthenoi DL P~ enol 0.50 Stearyl Alcohol - St~aryl Alcoh~l 0.01 Cetyl Alcohol Cer.yl Alcohol 4.09 51yceryl Stea-a~e (and) ~r'ac21 165 ~.14 PEG-;00 Ste~rate Ce~aaryl Alcohol (and) Cy~lo~on SCS 2.1 PEG-40 castor Oil (and) Stearalkonlu.~ Chloride Ceeearvl Alcchol ~And! .~'aze_~ax 1631.33 Ste~ralkoniu~ Chlorlde ~an~) ~olysorbate 60 -RC;1 r1ERl~r;i~lT 8 fii~

.. - 17 - Z03~33ZZ

Dimethyl Lauramine Necon Lo 2 . 01 Oleate Dicetyl dimonium Chloride Adogen q 32 CG 0 . 53 Propylparabe}~ Propylparaben 0.10 PPG-; I.anoli.n Ether Solulan PB-S 0.21 ~0 Disperse Violet 2~o .1 Dispersa Violet No . 1 0 . Oo D~C '~iolet No . 2 D&C Vio l et No . 2 0 . 02 External :)&C External D&C 0 . C
Violet No. 2 Violet No. 2 C~clorr.ethicorle l:ow Corning 345 0 . 25 Dimethicone 30w Cornins C0 0 . 25 P~ymethoxy b~cyclic Nuosept C O.50 Cxa~o 1 idlne Kaclin Huber 35/~ydrite 6 . 5~
Fullars Earth Fullers ~arth 100 2 . 70 Amodimethico~e (and) Dow Corning 92g 3 . 00 Nonoxynol-10 ~and) Emulsion ~a 1 low tr imo:~i usn Chlori de ~onoxynoi-10 Surronic N-95 0 . 01 3 5 Fragrance Fragrance Q . S .

While ~.e above example has been de cribe~ with particul2rity, it is to b~a understood that the dye loads ~0 incorpor~ted lnto th~ c!~y-based compositions of the presen~
invention cin occur a~ anywhere bet~een about 0 . 00001 to 5 . 00 Fercent by weight, dependir.g upon the tone and inten~ity of coloratior. sol~ght. In addition, the other listed colriponents can occ--r ~i.hin any ran~e of ~alues which render e~ective 45 cl~y-~ased color.ng and cor.ditioning co;npo~ ons ls~
accor~ance ~ith the p~esent invention. For e.~ampl~, the F ~< 0 '~ t ' G O U L C~
~ 5 1 r ` c~ 9 1 ~ 10, ! ~ P

X03832;~

~7a~er component can occur at an~ .era between about 20-7096 by welght, the cla~ componer~t3 ~et~een ~bout 5-25% by weight, the mois~u_izir.g cornponents bet,teen abou~ 0 .10-5 . 00% by weigh~, the hanna co~ponent b~-ween about 1-1596 by weight, 5 the protein compon~nts be-ween abou~ 2-2056 by wf3ight, ~ha sodium hyalurona~? bet"een dl'OU; O . 00001-1 . 00% by weight and 4he em~llsifying compG~ents b2tween a~out 0.25-1~.00% by we ~' ght .

1 0 ~ 5pT,F' ,3 The conscitu~nts fo~ ExamE,l~- 3 re~ul- in a Li~h~
viole~ c~lor~d clay~ p2C~C fo~ colcring and conditioning 310nd~, whi~e and gre~f !lair. The constituents are the same as li~t2d in E:~ample ~, witr~ th~ llowing variations:
1;

;RO~l ~C~CHF~NT & ~OU~ Q ~. 13, J 991 16: 41 ~lC, . ' ~. ,~

- 1 9 - -203~322 CTFA Desiqnation Trade Name ~ by Wei~ht Disperse Vlolet No. 1 ~isperse Violet No. 1 0.0~
D~C Violet No. 2 ~&C Violet ~o. 2 0.00 ~xte~nal D~C Ext~rnal D~C 9~00 Violet NG. 2 Yiol~t No- 2 Polymethoxy Bicycl~c Nuosept C O.00 Oxazolidlr~e Glut2ral Uc arc ide 2 ~ 5 0 . 15 DMDM Xydantoin Glydant 0. 3;

EXAYPI,E 4 ~he cons:ituents ~or Examele 4 result in 2n c~aque lavender colored clzy pack for coloring and condit.o:-ir.g white or grey hair, The constituents ara the same as lis~d in Example 2, with the fcllowing variations:

CTFA Desi~nation Trade Name % by Weiq:.-Disperse Yiolet No. 1 Disperse Violet No. ' 0.0 ~&C Violet No. 2 D~C Violet No. 2 0.39 External D&C Exter~l D~C o.oo Viole~ No. 2 Violat No. 2 The constituen~ for Example 5 result in a opaqua lavender colored clay pac`.~ for colorinq and conditionlnq white or grey hair. The constituencs are the sa~ne as listed in Example 2, with the follo~ing variations:

CTFA Desianation Trade Name % bv Welqht Disperse Violet No. 1 :)~ s~>erse Violet No. 1 0.03 D&C Vicle~ No . 2 DhC Violet No . 2 0 . 00 F l~ 11' (1 E I~ C H ~ T & 1; l3 ~ L t) ~ c '~ l I D 4 ! N O, I ~

` 203~332Z

External D~C Ex~ernal DSC 0.00 Violet No. 2 Violet No. 2 S
~PLB 6 The consti~uents for Example 6 rasult in an opaqus lavendar co1ored clay pack for c~loring and conditioni~g blonde hair. The constitue~ts are the same as l isted in ~xa~ple 2, with the following variations:

C~A ~esicnalion Tr~de ~ame ~ bY Weiqht Henna Extract Henr.a Extra~t 2.00 c Disperse Vic!et No. 1 ~sperse Violet No. 1 0.02 ~&C Violet No. 2 D&~ Yiolat No. 2 0.00 External D&C ~xte-nal D6C 0.00 Yiolet No. 2 Vi~let ~lo. 2 Polymethcxy bicyclic Nuosept C O.00 Oxazolidine 25 Te~rasodillm EDTA ~ampene }00 0.2i Glu~eral Uca~cide 225 0.15 D~M Hydantcin Glydan~ 0.35 EXAMP~E 7 Tha consti~uenrs for E.Yample 7 result in an ooaque lavender coiored clay pack f~r coiorir.g and conditioning ~lor.de hair. The consti~een~s ara the same a~ listed in Example 2, wi~h the folle~ing ~ariations:

CTF~ &es iqnation Tra~e Name % by ~ei~ht H~nna Extract Henna Ex~act 2.00 Dis?ers2 violet ~o. 1 GlsF3rse Viole~ No, 1 0.0!

FF:0i1 ~1ER~HRhT & GOUL~ 3. 19gl 16:4~ NO, 1~ 4 . - 21 - ZC)3832~

HC Blue No ~ 2 HC 31ue No . 2 0 . 03 D&C Violet No . 2 D~C Violst No . 2 0 . 00 S External D&C External D&C ~ . 00 Violat No. 2 Violet ~o. 2 ~olym.ethoxy bicyclic Nuosep~ C O . 00 Oxa~olldine Tetrasodium EDTA Hams~ne 100 . O . 25 Gluteral Ucarcide 225 0.15 D~lD~q Hyda~toin Glydant ~ . 35 E~AMPLE 8 2~ The constituer.ts for Exa~e 8 resu~ t in a golden wheat colorad clay pac}c for coloring and conditionir.g blonde hal_. The constit-lents are ~he sar~e a~ liated in Exam~le 2, with the following variation~:

FR011 ~tC~,H~ 30~lL~ ~_. 13, 1~91 !D: 43 I~C, ' :~ ' . .,5 - ~2 - ~03~322 CTFA ~esiqn3tion T_~de ~ame~ bY Wei~ht H~nna Extrac~ Xenn~ Extract 2.00 ~ntersperse Pink B2 rnt~rs~erse Pink 32 C.06 HC Black ~o, 9 HC Black ~o. 30.08 Dispers~ Violet No. 1 Disperse Violee No. } 0.00 10 D~C V~olet No. 2 D~C Violet No. 2 0.C0 External D~C External C&C 0.C0 Viole~ ~o. 2 Vioiet No. 2 lS Poly~.ethoxy bicyc'ic ~u_sapt C O.00 Oxazolidine Tetrasodi1m E~TA Hamp~ne 100 0.25 Gluterai Uclrcide 225 0.1;
DMD~ Hydantoin ~lyda~t O, 35 E~AMP~Z ~
The cons~it~ents for E~a~?lz 9 result in a golden whe~t colored clay pacX. fo_ ~o~oring and conditionir~g blonde hair. The constitu~nts ar~ the sa~.e as listed in E~ample 2, with the followir.g variat on~:

R ~ h R ~ T c ;I U L D
91 1 ~.: 4 4 r! ~l, 1 2 P . - 5 C1'FA Desisnation Tra~e Na~e % b~ r~eiqht ~e:nna ~tract Henna Extract 2.00 Interspers2 Pink B2 Intarsperse Pink B2 0.12 H_ Black No. 9 HC 81acX No. 9 0. lo Dispe~se Violet No. 1 Cisperse Vio}et No. 1 0,00 10 7&C Viole~ No. 2 D&C ~iGlet No. 2 0.00 External D~C External D&C 0.00 ~oLet No. 2 Viclet No. 2 l; Poly~e~hoxy bicyclic Nuosept C O.C3 ~xa~oiiàine Te~rasodium EDmA ~am~ene 100 0.25 20 Glu~eral Ucarcide 225 O.i5 M Hydantoin Gly~ant 0.3S

EXAMPLE lQ
The constit~ent~ for Example 1~ result in a blue colored clay pack for colorin~ and conditioning brunette hair. The ccns~i~uents are the sa~e as listed in ~xample 2, ~0 ~ the fol;owing variations:

F F~ ~I M rl E R C l; P ~ U U L ~ , N U . I ' - 2 4 - Z03832;~

CTFA ~esi~na~,ion Tr~de Na~e % b~r ~eicht Henna Extract ~Ianna Extract 2 . Qû
HC Blue ~o . 1 HC Blua No . 1 0 . 08 HC Blue No . 2 HC BlLe No. 2 0 . 52 o-nitro-p- o-nLtro-p- 0.01 pnenyisnediamine ~henylenedi~Eni ne p-nitro-o- p-r.itro-o~~0 ~ o }
phenylanediarr ir.e phar:ylenedia.~lne HC Yel low No. 5HC Yello~ No. S ~0 . 01 ~5 Disperse Violet No . 1Dis?erse Violet No. 1 0 . 00 D&C Viole~ No . 2D~C ~iole~ No . ~ 0 . 00 External D~C Ex er~.al D&C 0 . 00 Violet No. 2 'Ji313t ~o. '' ~olynethoxy bicycl ~ c~_osept C O . 00 Oxa201 idine Tet-asodiu.n EDTA H~ er.e 100 0 . 2~
Gluteral Ucarcide 225 0 . ' 5 D~DM Hydanto~ n Glydant 0, 35 E~.PI,E 1 1 $he constituent~ for Exampla 11 resul_ in an or~ns2 colored clay pack for coloring and conditioning b_unette hair. The cor~stlt~er.ts are ~he same a list2d i n Exa~p' 2 2, with the following varia~lon3:

F R ~ M ~ c F~ N `~ U L [~ ~ 3 . 1 5 . l 9 Y 1 ' 6: 4 5 ~i O . I 2 - 25 Z038;~Z

CT A De3ianation Trade Name~ bv Weiaht Henna Extract ~enna ~xtract 2.00 o-ni~ro-o- o-nitro-p- 0.07 phenylenediamine phenylenediamine Inter~perse Pink ~2 Intersparse Pink 82 0.06 HC Y211OW NO . 5 HC YP11OW NO . 5 0 . 06 HC Yellow No. 4 HC Yellow No. 40.09 Disperse Violet No. 1 ~isperse Violet No. 1 0.00 D&C Violet No. 2 D&C Violet No. 2 0.00 External D~C External D&C O . 00 Violet No. 2 Violer No. 2 20 Po~ymethoxy bicyclic Nuosept C ~.00 Oxa2clidine Tetrasodium EDTA ~am?ene 100 O. 25 25 Glute~al Vcarcide 225 0. lS
D~.D~ Hydantoin Glydant 0.3S

~XAMPLE 12 The constituents for Example 12 result in a red-orange colored clay pacX 'or c310ring and conditioning brunette halr. ~he const_tuents ar~ the same as listed in ~ample 2, with the following varia~ions:

~RUI'l llFRCh~ iOULU ~3. 13, !C~ ' b: 46 1~0, 12 P, ~'j - 25 - Z0383Zz Cl'~A Desianation Trade Na~e % bY '~ei~h~
Henna Extrac~ Henna Extract 2.0~
~C Blue No. 1 ~C Bl~e No. 1 0.32 o-nitro-p- o-nitro-p- 0.10 ph~nylenedia~ine phenyleD~diamine HC Yello~ No. 5 ~C Yellow No. 5 0.15 Disperse Violet No. ' Dispers. Violet No. 1 0.00 D~C Violet No. 2 D&C Violet No. 2 0.00 lS Ex~ernal D~C Ex ernal D~C 0.00 Violet No. 2 Viol~t No. 2 Polymethcxy bicyclic NUos~?r C O.00 Oxazolidine Tetrasodium E~TA H~pene 100 C.2~
Gluteral Ucar~ice 225 0.15 25 ~M3M Hydantoln Glydant - 0.3s ~AMPLE 13 The constit~er.~s for Ex~mple 13 re3ulr in a ~ahogany colored clay pack for coloring and conditioning ~rown, dark ~r~n or black hair. The cons~i~uen~s a-e the 52.~ as list~d 1.~ Example 2, with the following variations:

K ~ J U L V
03 . 1 3 . 1 991 I b: 4 r.~ P, 30 - 27 - ~ Z~3~3Z2 CT~ Desianation T~ade Name ~ by ~eiaht HC Blue Nc. 2 XC 81ue No. 2 3.GS
o-nitro-~- o-nitro-p- ~.50 phenylenediamir.a pher~ylenediamine Dispexse Violet No. i Di3l?erse Vioiet No . 1 G . 00 D~C Violet No . 2 D&C Violet No . 2 0 . 00 1~
Extarnal D~C Ex err.al D&C 0.00 Violet No. 2 Violet No. 2 Polymethoxy bic~fclic Ni~osept C O.00 Oxazolidine Gl~eral U~rc de 225 0.15 D~M Hydantoin Glydant 0.~5 E~P~ 14 The constituents for Exa~ple 14 result in a brigh~
red colored clay pack for coloring and conditioning golden blonde hdir. The constituents ar~ the same as listPd in Example 2, with the roliowing varlations:

~ u rl l7 t ~ r~ l ~ C ~J U ~ ~' . 1 7 `. ~ ~ D; '~ U, I ' r ~ I

28 - ~ 2~;~832 CTFA Desi~nation Tr~de ~a~.e % by ~e}~h~
Int:ersoerse Pink ~2 Intersperse Pink B2 0.~0 Dispersed BlacX No. 9 Dispersed Blac~ No. ~ 0.30 HC Y~llow No. 4 ~C Y~llow No. 4 0.10 Disperse Violet No. 1 DLsperse Violet No. 1 0.00 10 D~C Violet No. 2 O ~ Violet No. 2 0.00 External D&C External D~C a . oo ViolQt No. 2 Viol_t No. 2 15 Polymet'noxy bi~yclic Nuosept C O.0 Oxazolidine 51uteral Ucarcide 225 0.li 20 D~CM Hydantoin Glycant 0,35 E~XPLE 1S
The constituents for Example 15 result in a crange-brown colored clay pack îor coloring and con~i~ionir.g da~
blonde, li~ht brown an~ dark brown nair. The constituents are the same as l,sted i~ ~xa~ple 2 ~ with the following ~ariation~:
3a FRur~ Yc~:CH~- r .~ ~ULi`
S .: ~ Y l ~ u . 1 - 29 - -20:3832Z

CTFA Desianation Trade Na~e ~ by Wei~h~
o-~ni~ro~p- o-nitr~-p- O.iS
phenylenediamine phenylened~amine 5 ~C ~lue No. l HC 31ue No. l 0.02 XC Yellow No. 4 HC Yellaw No. 4 0.18 Dis~erse Violet ~o. l Disperse Violet No. l 0.00 D~C Violet No. 2 D6C Violec No. 2 0.00 ExternaL D~C External D&C 0.00 Violet No. 2 Violet No. 2 Polymethoxy bicyclic Nuosapt C O,00 O~azolid~ne Gluteral Uca~cide 225 O.lS
D~ ydantoin Glydant 0.35 2S E~A~LE 16 ~he constituents for Example 1~ result in a opaque deep bur~undy colored clay pac~ for coloring and conditioning medium ~rown, dark brown, and black hair. The cons~ituents ar~ the same as ~ist2d in Example 2, with the following ~ariatl~n~:

FPOM ,~lcPl`H~ lT ~ ~o I r 3 . 1 3 . 1~ 9 1 16: 4 ~ ;U _~ 3 --203~332 _FA Desi~nation ,Trade Name ~ b~ eiqht o-nit~o-p-o-n~ tro-p- 0 . S0 phenylen~dia~ine phe:~ylenediamine S HC Blue No . 2 HC Blue ~o . 2 0 . 05 Dispe~se Violet No . 1 Disperse t~iolet No . 1 0 . 00 D~C Violet No . 2 D6C Violet No. 2 0 . 00 ~xternal D&C Externai D~C 0 . 00 yiOl e~ No. 2 Viole~ No . 2 ~ he consti~.uerts for Ex~mple 17 result in a opaque dee? burgundy colored clay ~ack for coloring and conditioning ~.,ediu~ ~rown, dark bro~n, and biac:c hai~. The constituents 20 ar~ che same as liste~ in Exa~r.ple 2, with the following variatior.s:

CTFA Desi~nati~n Trade ~ame% b~ '~ei~ht o-nitro-p- o-nitro-p- 0.~3 2 5 phenyienedia~ine phonylenediamine HC ~lu~ ~o . 2 .~C 31ue No. 20 . 06 Disperse ~Jiolet No. 1 Disperse Violet No . 1 ~ . Oi~
D&C Viol~t ~lo . 2 D~C Yiolec Uo . ~ O . 00 External D~C External 3&C 0 . 00 Violet No. 2 Vlole~ No. 2 The con~tituents for Example 18 result in a opaque 40 dee~ burgundy colc~ed clay pack for coloring and c~ndi tionin~, me~ium brown, dar~; b-own, and black hair. The constituents a~2 the same as listed ir. Example 2, ,lith the follo~ing variations:

FROI~ '1EkCHI;~ 5;1ULP ~.. . 1 3, ' ~ 6: 5~ NO . I ~ 4 2~ Z2 Cl-FA Desi~naticn Tr-~ce Name % by ~eiqht a-nit~c-2- c-nitro-p- 0.7S
phenylenediamine phenyle~ediam~ne .C Blu~ No. 2 HC Bl~e No. 2 0.08 ~isperse Viole~ ~o. 1 ~isperse Viole-~ No. ; 0. no 3&C Viole~ No. 2 D~C YioleC ~o. 2 0.00 Extarnal D&C ~xtarnal D&C 0.00 Viclet No. 2 Violet No. 2 E~PL~ 1g ,he cons~it~lents for _xampl3 :9 ~asult in an opaque deep bursundy colored clay ~ack for coloring -nd conditiGni~g medium brown, dar~ brown, and D}3C~ hair. The constituents are t~.e sa~.~ as lis;ed in xa.~ple 2, ~ith the following variations:

C~FA ~esiqnatlon Trade Name~ by '~ei~t 25 o-ni~ro-p- o-nit-o-?- 1.5C
phanylenedi~mine phenyl enedia~ina HC 31ue No. 2 HC Biue ~lo. ~ 0.15 Disperse Violet No . 1 Dispe.se Violet ~o, 1 0 . 00 ~C V~oler No. 2 ~C Jioiet No. 2 0.00 Ext~rnal D~C E~.err.al ~&C 0.00 ~5 Viol~t No. 2 Violet No. 2 E~YPI.E 20 The constituents for Exampl2 10 result in a opaque brs-~n colorea cl~r pack for coloring an~ condicioning light ~-own, ~edium brcwn and iar~ ~rown halr. Th2 cansti~uents FkClr ':~:RCHFI`.~ & S~lJi D ~)~, 13, 1~1 16:51 NO. 1. c,35 20383~2 are the same as listed in Example 2, with the foilowing ~ariations:

C~ Desiqnation ~rade Name~ b~ '~eiqht S o-nitro-p- o-nitro-p- O.S0 phenylenedi~mir.e phenylenediamine HC Blue No. 2 HC ~lue No. 2 O.lS
10 2-nitro-o- p-nit-o-c- 0.05 phenylenediamine p'nenylenediamine DispersR Violet No. 1 Disperse Violet No. 1 O.C0 15 D~C Violet No. 2 DSC Vlolet ~o. 2 0.00 2xternal D~C Ex~er~al DsC O.O0 Vioiet No. 2 Viole~ ~o. 2 E~PLE 21 The constituents for Example 21 result in a brown colored clay pack for colorlng and conditioning light brown, mediu~ ~rown an~ d~rk brown hair. The constituents arP the sa.~.e as listed in Exam~le 2, with the following va-ia~ions:

F R O M ~l E R C H ~ l l T ~ 5 tl 'J ~ 9 9 1 ~ 5 '` 110, 1 "

~0383~2 C~A ~esiqnation _~ade ~ame % bv Weiqht o-nitrc-p- o-nitrc-p- 0.50 pheny~ened~2~in~ p~.enylened~&~ine 5 HC Bl~e No. 2 HC Blue NG . 2 0.15 p-nit~ p-nitr9-o- 0.10 pr.enylened.ia~ine phenylene~iamine Dispe-so Viol~t No. l ~iq?ers~ Violet No. 1 O.OQ
D~C violet No. 2 DSC Violet No. 2 0.0 Extarnal ~C r xtern2l. D&C 0.00 lS V_ole~ No. 2 Violet No. 2 E~U~L~ 22 The cons~i~uer.ts for ~ pie 22 res~lr in ~n opaque ~rownlsh-bur~ndy colorad cl~y pack for ~oioring and cohdition~ng li~hr brown, ~edlum brown ~nd darl.c bro~.~ hair.
The cons~i~uents ara the sa~,e ~s listed in Ex~le 2, with t~.e rollouing variation~:
C~FA Desl~nz~ion Tra~e ~ame~ by '~eicth~
o-nitro-~- o-nitro-p- 0.50 phenylenediamine pherylenedi~ine ~0 HC Blue ~Jo. 2 ~C 31ue No. 2~.15 Dls~erse Violet No. l - D~s~erse Violet~ No. l 0.00 ~&C Viclec No. 2 ~C Violet No. ~ C.00 ~S
~xrernal D&C E,c~ernal D&C0.00 Violet No. 2 Vlole~ No. 2 4~

rl~lrl ~1~1. t1HI~ ' Y~ I~LI~ L `
, I . . I '19 1 1 ~; 5 3 ~ '` P, 3 7 - 34 - 203832;2 EXA~LE 2 3 The consci~uents lis~ed below resul~ in a bright vio'et color~d clay pack for coloring and conditioning white or ~rey h2ir.
C~FA ~esiqnation Trade Name ~ by Wei~ht Deionized Water Deionized Wa~er Q.S. to 100 Henna Extracc ~enna ~xtract ~.00 ~ethyl~araben Methylpara~en 0.30 Magnesium Aluminu~ Veegum HV 1.00 Silicate Sodiu~ ~yaluronate Lifecore S~di~m ~0.01 Hyalu-onate Gl~cerin Glycerin 0.30 Honey ~oney Blend ~3 0.i0 Acetamide ME~ Acetamide ME~ 0.01 25 Oat Flour Stero Pro 1.34 P~/MA Copolymer Gantre2 AN 169 (sol.) 4.^0 Qu~terniu.~-2~ Ceraphyl 60 0 . 01 Hydrolyzed Anim~l Protein ~exein 250 6.03 Cationic Collagen Cationic Collagen 1. 50 Po~ypeptide~ Polypeptides ~Amerchol) C3codimonium Hy~rolyzed Croquat M 1.50 Animal Protein Stearyl Alcohol Stearyl Alco~ol 0.10 Pant~enol DL Panthenol o.50 Catyl ~lcohol Cetyl Alcohol 3.06 4i Glyceryl St~arate (and) Arlacel 165 1 6 PEG- 100 Steara~e =P~i1 'lERCH~NT :'~ G~ 03. 13. 19~1 16:53 h~, 12 -,~>8 - . 2038;~2Z

Cet:earyl Alcohol ~and) Cycloton SCS 1.00 PEG-40 Cast~r 0~'1 (an~
Stearalkonium Chloride S Cetearyl Alcohol (and) ~azer~ax 163 1.80 Polysorbate 60 (and) St~aralkonium Chloride Dim~thyl Lau~amir.e Necon Lo 2.00 Olea~e Dicetyldi~onium Chlorid2 Adogen 432 CE 0.~3 P opylpara~en ~ropyl~araben 0.10 PP~-5 Lano'in Ether Sol~ r PB-5 0.15 Dispers2 Viole~ No. 1 Disperse Jiole- No. 1 0.03 2Q Cyclome~hic3ne Dow Cc~nin~ 3~; ~.23 Di~ethi~on~ Dow ~orning 203 0.23 Tetrasodiu~ E3~A Hampene 130 0.50 ~5 P~-15 Tallow Poiya~ina Polyquart H 0.50 D~D~ ~ycantoin ~lydant 0.35 30 ~aolin Hu~er 35!Hydrite 6.50 Fullers Ear~h Fu'lers Earth 130 2.70 A~.odime~hicone ~and) ~ow C~rning 329 3,00 Nonox~nol 10 /and) E~lq~on Tallowt-imonium Chlorid~
Nonoxynol-10 Surfonic N-9S O.Ql 40 Fragrance Frag~ance Q.S.

Whila the aboYe ex~m~l~ has be~n ~es~ribed with particularity, it is to be un~ers~ood that the dya ~oads 4; incorporate;~ ~nto the clav-~ase~ compositions of the pre~ant ir.v~n~ion can oc~lr ac ar.-~-~her2 ~e~2en about 0.0~001 to 5.00 2arcent by w~igr.~, ~e~r.din~ upon t~.e tone ar,d in~2nsity of CRUIl !`1Ei:C:HRl T ~ GOU ~
9 1 1 6: 5 ~ 1`1 0,: 2 P . ~ 9 ., - 36 - ;~0383Zz coloration sought. In addition, the othe~ listed componen~s can occur w.~thin hny r~nge of values whic~ render ef ~ective clay-based coloring and conditioning compos~tions in accordance with the present invention. For example, the S water component can occur a~ anywhere be~ween about 20-~0 by weignt, the clay components between about 5-25~ by weigh~, the moisturizin~ components bet~een about 0.10-5.00% by w~gh~, the henna component between about 1-15~ by weight, the proteir. components between about 2-20~ by .ieight, t~.e lC sodium ~.y~luronate between about 0.00001-l.00~ by weigh~ ar.d t~.e emul~ifying componen~s between about 0.25-10.00~ by weight.

E~MPL~ 24 T~.e cons~ituents for Example 24 result in ~ gol~en wheat colored clay pack for colori~g and conditioning blonde h3ir. The cons~ituents are the same as lis~ed in ~xample 23, with the ~ollowing variations:

20 ~TFA Desicr.ation Trade Name % by Wei~ht Intersperse Pink B2 Intersperse Pink B2 0.07 HC Black ~o. 9 HC ~lack No. 9 0.10 Disperse Viole~ No. l Disperse Violet No. 1 0.00 The constituents for Example 25 result in a navy blue colorad clay pack for coloring and conditioning brunette hai.r. The constituents are the same as listed in Example 23, with the fol~owing variations:

FROM 11FRCHRNT ~ ~iO!!L~ ~, 17, 1991 lD: 55 ~10, i2 P. 4~

_ 31 - - 2038322 C~F~ Cesiqnation Trad~ Na~.e ~ bv Ueiqht HC Blue N3. i HC 3l~e ~o. l O.L6 HC ~lue No. 2 HC Bl~e No. 2 O.l9 3isperse Yiolet No. l Dis~ersa Violet ~o. l 0.00 E~MPLE 25 The cons~it~uents for Example 26 in an orange colored clay pGck for coLoring and cond~tioning b~unett~ hair. ~he constituents are t~2 s2r~e a~ listed Ln Exa~pla 23, with the following variations~
CT~A Desi~na_icn TLade ~a~e ~ by '~eiqhc o-nit~o-p- o-ni~ro-p- 0.07 phenylenedi~mLne phanylenedia~ine 20 Interspersa Pin'~ B2 In~ersperse Pink B2 0.06 ~C Yellow No. 4 HC Vellow No. 40.09 ~C Yellc~ No. 5 HC Yel1ow No. S0.06 Disperse Violet No. 1 Dis?e~se ViGlet No. l 0.00 It is to be understood, however, that e~Jen though nu~erous characteris~ics and a~vantages of the in1~ention ha~e been set fortn in the for~go'ng àescription, th~ disclosure is illustrat~'ve only, and changes may be ~ade in datail within the principle of the invent~on, to the full extent indicated by tha broad general meaning o~ the ter~s in which the append~d claims are ex~ressa~..

Claims (25)

1. A composition for coloring hair comprising:
water;
an amount of clay sufficient to produce a paste; and an effective amount of a coloring component, wherein said coloring component is selected from the group consisting of a non-permanent coloring agent and a semi-permanent coloring agent.

2. A composition of claim 1 further comprising an effective amount of a moisturizer component, a reconstruction component, a shine imparting component or any combination thereof.

3. A composition of claim 2 wherein the combination is effective amounts of a reconstruction component, a moisturizer component and a shine imparting component.

4. A composition of claim 2 wherein the moisturizer component is sodium hyaluronate.

5. A composition of claim 3 wherein the moisturizer component is sodium hyaluronate.

6. A composition for coloring and conditioning hair comprising:
about 20-7% water;
about 5 25% clay;
about 0.00001-5.0% of an effective amount of a coloring component, wherein said coloring component is selected from the group consisting of a non-permanent and a semi-permanent coloring agent; and an effective amount of a moisturizing component, a reconstruction component, a shine imparting component or any combination thereof.

7. A composition of claim 6 wherein the coloring component is a non-permanent coloring agent selected from the group consisting of FD&C colors and dyes, D&C colors and dyes, H&C colors and dyes and oxidation dye intermediates.

8. A composition of claim 6 wherein the coloring component is a semi-permanent coloring agent selected from the group consisting of pyrazolone compounds, monoazo compounds, xanthene compounds, triphenylmethane compounds, diazo compounds, metal-complex dyes and oxidation dye intermediates.

9. A composition of claim 8 wherein the semi-permanent coloring agent is a metal-complex dye selected from the group consisting of cobalt azo complexes and chromium azo complexes.

10. A composition of claim 8 wherein the oxidation dye intermediate is a nitrophenylenediamine.

11. A composition of claim 10 wherein the nitrophenylenediamine is selected from the group consisting of o-nitro-p-phenylenediamine and p-nitro-o-phenylenediamine.

12. A composition of claim 6 wherein said reconstruction component is protein.

13. A composition of claim 12 wherein said protein is from about 2-20% of said composition.

14. A composition of claim 6 wherein said moisturizer component comprises sodium hyaluronate.

15. A composition of claim 14 wherein the sodium hyaluronate is from about 0.00001-1.0% of said composition.

16. A composition of claim 6 wherein said shine imparting component comprises henna.

17. A composition of claim 13 wherein said henna is from about 1-15% of said composition.

18. A composition of claim 6 further comprising from about 0.25-10% of an emulsifier component.

19. A composition of claim 18 wherein said emulsifier component comprises a nonionic emulsifier and a cationic emulsifier.

20. A composition of claim 6 wherein said clay comprises kaolin and fuller's earth.

21. A composition of claim 20 wherein said kaolin is from about 2-12% of said composition and said fuller's earth is from about 0.5-7% of said composition.

22. A composition of claim 6 wherein said moisturizing component is from about 0.1-5% of said composition.

23. A composition of claim 6 further comprising a fatty alcohol component.

24. A method for coloring hair comprising the steps of:
(a) applying to hair an aqueous clay-based composition incorporating a coloring component, wherein said coloring component is selected from the group consisting of a non-permanent coloring agent and a semi-permanent coloring agent; and (b) exposing the hair to heat for a period of time sufficient to dry the composition to a hard and flaky state.

25. A method according to claim 24 wherein the hair is exposed to heat for a period of time between 15-45 minutes at a temperature of from about 80°F-120°F.

25. A method according to claim 24 wherein said clay-based coloring composition includes an effective amount of a moisturizer component, a reconstruction component, a shine imparting component or any combination thereof.

27. A method or coloring hair comprising the steps of:
(a) applying an aqueous clay-based paste incorporating a coloring component to hair on an individual's head, wherein said coloring component is selected from the group consisting of a non-permanent coloring agent and a semi-permanent coloring agent;
(b) enclosing the hair in cover means;
(c) exposing he hair to a temperature of from about 80°F-120°F for a period of time between about 15-45 minutes;

(d) removing the cover means; and (e) exposing the hair to a temperature of from about 80°F-120°F for a period of time between about 2-15 minutes.

28. A method according to claim 27 wherein the hair in step (c) is exposed to a temperature of from about 90°F-110°F for a period of time between about 20-30 minutes and the hair in step (e) is exposed to a temperature of from about 90°F-110°F for a period of time between 3-8 minutes.

29. A method according to claim 27 wherein said clay-based paste includes an effective amount of a moisturizer component, a reconstruction component, a shine imparting component or any combination thereof.

30. A method according to claim 27 wherein said aqueous clay-based paste includes from about 5-25% clay and from about 20-70% water.

31. A method according to claim 30 wherein said clay is a mixture of kaolin and fuller's earth.

32. A method according to claim 27 wherein the coloring component is a non-permanent coloring agent selected from the group consisting of FD&C colors and dyes, D&C colors and dyes, H&C colors and dyes and oxidation dye intermediates.

33. A method according to claim 27 wherein the coloring component is a semi-permanent coloring agent selected from the group consisting of pyrazolone compounds, monoazo compounds, xanthene compounds, triphenylmethane compounds, diazo compounds, metal-complex dyes and oxidation dye intermediates.

34. A method according to claim 33 wherein the semi-permanent coloring agent is a metal-complex dye selected from the group consisting of cobalt azo complexes and chromium azo complexes.

35. A method according to claim 33 wherein the oxidation dye intermediate is a nitrophenylenediamine.

36. A method according to claim 35 wherein the nitrophenylenediamine is selected from the group consisting of o-nitro-p-phenylenediamine and p-nitro-o-phenylenediamine.

37. A method according to claim 29 wherein said reconstruction component is protein.

38. A method according to claim 37 wherein said protein is from about 2-20% of said composition.

39. A method according to claim 29 wherein said moisturizer component comprises sodium hyaluronate.

40. A method according to claim 39 wherein the sodium hyaluronate is from about 0.000001-1.0% of said composition.

41. A method according to claim 29 wherein said shine imparting component comprises henna.

42. A method according to claim 41 wherein said henna is from about 1-15% of said composition.

43. A method according to claim 27 further comprising from about 0.25-10% of an emulsifier component.

44. A method according to claim 43 wherein said emulsifier component comprises a nonionic emulsifier and a cationic emulsifier.