CA2024593A1 - Catalyseur et porteur pour la polymerisation de l'ethylene - Google Patents
Catalyseur et porteur pour la polymerisation de l'ethyleneInfo
- Publication number
- CA2024593A1 CA2024593A1 CA2024593A CA2024593A CA2024593A1 CA 2024593 A1 CA2024593 A1 CA 2024593A1 CA 2024593 A CA2024593 A CA 2024593A CA 2024593 A CA2024593 A CA 2024593A CA 2024593 A1 CA2024593 A1 CA 2024593A1
- Authority
- CA
- Canada
- Prior art keywords
- polymerization
- ethylene
- titanium compound
- new carrier
- carrier catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title 1
- 239000005977 Ethylene Substances 0.000 title 1
- 150000003609 titanium compounds Chemical class 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- 239000002685 polymerization catalyst Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- AENCLWKVWIIOQH-UHFFFAOYSA-K cyclopentane;trichlorotitanium Chemical compound Cl[Ti](Cl)Cl.[CH]1C=CC=C1 AENCLWKVWIIOQH-UHFFFAOYSA-K 0.000 abstract 1
- 150000002681 magnesium compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Fittings On The Vehicle Exterior For Carrying Loads, And Devices For Holding Or Mounting Articles (AREA)
- Nonmetallic Welding Materials (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI894216 | 1989-09-06 | ||
| FI894216A FI85151C (fi) | 1989-09-06 | 1989-09-06 | Ny baerarkatalysator foer polymerisation av eten. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2024593A1 true CA2024593A1 (fr) | 1992-03-05 |
| CA2024593C CA2024593C (fr) | 1998-11-24 |
Family
ID=8528953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002024593A Expired - Fee Related CA2024593C (fr) | 1989-09-06 | 1990-09-04 | Catalyseur et porteur pour la polymerisation de l'ethylene |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5324698A (fr) |
| EP (1) | EP0416928B1 (fr) |
| AT (1) | ATE120213T1 (fr) |
| CA (1) | CA2024593C (fr) |
| DE (1) | DE69017987T2 (fr) |
| FI (1) | FI85151C (fr) |
| NO (1) | NO175314C (fr) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0598609B1 (fr) * | 1992-11-18 | 1997-04-23 | Mitsui Petrochemical Industries, Ltd. | Catalyseur de polymérisation d'oléfines et procédé de polymérisation d'oléfines l'utilisant |
| WO1994021691A1 (fr) * | 1993-03-25 | 1994-09-29 | Mobil Oil Corporation | Procede de formation d'une resine granulaire |
| JP2882241B2 (ja) * | 1993-06-07 | 1999-04-12 | 東ソー株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
| WO1996006117A1 (fr) * | 1994-08-18 | 1996-02-29 | Asahi Kasei Kogyo Kabushiki Kaisha | Polymere ethylenique a haute densite et son procede de production |
| AU3894395A (en) * | 1994-10-31 | 1996-05-23 | W.R. Grace & Co.-Conn. | Preparation of modified polyolefin catalysts and in situ preparation of supported metallocene and ziegler-natta/metallocene polyolefin catalysts |
| ATE245665T1 (de) * | 1995-09-28 | 2003-08-15 | Basell Polyolefine Gmbh | Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen |
| CA2163681C (fr) * | 1995-11-24 | 2007-02-13 | Daryll G. Harrison | Catalyseur a base de monocyclopentadienylzirconium |
| US5965477A (en) * | 1997-02-21 | 1999-10-12 | Council Of Scientific & Industrial Research | Process for the preparation of supported metallocene catalyst |
| EP0878483B1 (fr) * | 1997-03-27 | 2008-03-12 | Council of Scientific and Industrial Research | Procédé pour la polymérisation et copolymérisation des oléfines |
| EP0878484B1 (fr) * | 1997-03-27 | 2004-12-15 | Council of Scientific and Industrial Research | Procédé de préparation d'un catalyseur métallocène supporté sur un halogénure de magnésium |
| DE69735755T2 (de) * | 1997-05-14 | 2007-04-12 | Council Of Scientific And Industrial Research | Verfahren zur Polymerisation von Olefinen |
| GB9722447D0 (en) | 1997-10-23 | 1997-12-24 | Borealis As | Process |
| US6300271B1 (en) | 1998-05-18 | 2001-10-09 | Phillips Petroleum Company | Compositions that can produce polymers |
| BR9910611B1 (pt) | 1998-05-18 | 2009-05-05 | processo para produção de uma composição de catalisador. | |
| US6323148B1 (en) * | 1998-12-04 | 2001-11-27 | Equistar Chemicals, Lp | Ethylene polymerization catalyst and catalyst system |
| US6355594B1 (en) | 1999-09-27 | 2002-03-12 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6395666B1 (en) | 1999-09-29 | 2002-05-28 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6391816B1 (en) | 1999-10-27 | 2002-05-21 | Phillips Petroleum | Organometal compound catalyst |
| US6548442B1 (en) | 1999-12-03 | 2003-04-15 | Phillips Petroleum Company | Organometal compound catalyst |
| AU4716301A (en) | 1999-12-16 | 2001-06-25 | Phillips Petroleum Company | Organometal compound catalyst |
| US6750302B1 (en) | 1999-12-16 | 2004-06-15 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6524987B1 (en) | 1999-12-22 | 2003-02-25 | Phillips Petroleum Company | Organometal catalyst compositions |
| EP1572756B1 (fr) * | 2002-12-18 | 2013-04-10 | Basell Poliolefine Italia S.r.l. | Composants catalytiques pour la polymérisation d'oléfines |
| US7217676B2 (en) * | 2004-01-16 | 2007-05-15 | Exxon Mobil Chemical Patents Inc. | Hydrophobization and silica for supported catalyst |
| US7456021B2 (en) * | 2004-01-16 | 2008-11-25 | Exxonmobil Chemical Patents Inc. | Analysis method |
| BRPI0703586B1 (pt) | 2007-10-19 | 2018-02-06 | Braskem S.A | Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular |
| CA2760264C (fr) | 2011-12-05 | 2018-08-21 | Nova Chemicals Corporation | Supports passives pour utilisation avec catalyseurs de polymerisation d'olefine |
| US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
| US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| CN116693729A (zh) * | 2023-08-02 | 2023-09-05 | 研峰科技(北京)有限公司 | 茂金属催化剂环戊二烯三氯化钛的合成方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL162664B (nl) * | 1969-06-20 | 1980-01-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1. |
| GB1348655A (en) * | 1970-05-22 | 1974-03-20 | Montedison Spa | Catalysts for the polymerization of olefins |
| NL163523C (nl) * | 1970-07-31 | 1983-11-16 | Montedison Spa | Werkwijze om een polymerisatiekatalysator te bereiden. |
| US4107414A (en) * | 1971-06-25 | 1978-08-15 | Montecatini Edison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
| US4107413A (en) * | 1971-06-25 | 1978-08-15 | Montedison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
| DE2543181C2 (de) * | 1975-09-27 | 1986-08-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Polymerisation von Äthylen oder zu dessen Copolymerisation mit C↓3↓- bis C↓1↓↓0↓-α-Monoolefinen |
| DE2835944A1 (de) * | 1978-08-17 | 1980-03-13 | Heyl & Co | Metallhaltige loesliche polymere katalysatoren fuer polymerisationen, verfahren zur herstellung derselben und ihre verwendung in polymerisationsverfahren |
| US4383095A (en) * | 1979-02-16 | 1983-05-10 | Union Carbide Corporation | Process for the preparation of high density ethylene polymers in fluid bed reactor |
| US4684703A (en) * | 1979-02-27 | 1987-08-04 | Union Carbide Corporation | Polymerization catalyst for ethylene homopolymerization |
| ATE91691T1 (de) * | 1987-06-17 | 1993-08-15 | Dow Chemical Co | Katalysator und verfahren zur herstellung syndiotaktischer polystyrene. |
-
1989
- 1989-09-06 FI FI894216A patent/FI85151C/fi not_active IP Right Cessation
-
1990
- 1990-09-04 CA CA002024593A patent/CA2024593C/fr not_active Expired - Fee Related
- 1990-09-05 NO NO903866A patent/NO175314C/no unknown
- 1990-09-06 EP EP90309782A patent/EP0416928B1/fr not_active Expired - Lifetime
- 1990-09-06 AT AT90309782T patent/ATE120213T1/de not_active IP Right Cessation
- 1990-09-06 DE DE69017987T patent/DE69017987T2/de not_active Expired - Fee Related
-
1992
- 1992-09-21 US US07/947,967 patent/US5324698A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5324698A (en) | 1994-06-28 |
| FI85151C (fi) | 1992-03-10 |
| NO903866D0 (no) | 1990-09-05 |
| CA2024593C (fr) | 1998-11-24 |
| EP0416928B1 (fr) | 1995-03-22 |
| EP0416928A3 (en) | 1991-11-21 |
| NO175314C (no) | 1994-09-28 |
| DE69017987T2 (de) | 1995-11-02 |
| FI894216L (fi) | 1991-03-07 |
| NO175314B (no) | 1994-06-20 |
| FI85151B (fi) | 1991-11-29 |
| EP0416928A2 (fr) | 1991-03-13 |
| FI894216A0 (fi) | 1989-09-06 |
| DE69017987D1 (de) | 1995-04-27 |
| ATE120213T1 (de) | 1995-04-15 |
| NO903866L (no) | 1991-03-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |