CA2090975A1 - Cellulosic pulp bonded by polyhydroxy acid resins - Google Patents

Abstract

Cellulosic pulp products bonded by a resin containing polyhydroxy acid with improved wet and dry strengths, and their preparation.

Description

WO~2t~$311 ~ U J 9 7 ~ PCT/US91/0~81 TITLE
CELLULOSIC PULP BONDED BY POLYHYDROXY ACID RESINS

IELD OF THE I~JVE~'TION

5This invention relates to novel resin bonded cellulosic pulp products which have improved dry strength and wet strength and are degradable and their ; preparation.
PRIOR ART
Most conventional paper, when wet, will lose as much as 95% or more of the original dry tensile strength. To improve wet and/or dry strength of paper, it is known in the art to add certain water soluble resins and/or thermoplastic polymers to paper, usually during the papermaking process. There are many resins known in the art which impart a long lasting wet strength, and others which impart only temporary wet strength. The latter is discussed in U.S. Pat. 4,035,229 by Espy and discloses that temporary wet strength is useful for tissue and certain other applications. Temporary wet strength polymers are produced by reacting glyoxal with vinylamide polymers (U.S. Pat. 3,556,g32, Coscia et al.).
These resins have a short shelf life when stored in aqueous solukions at concentrations useful in commercial papermaking processes. Espy (4,035,229) discloses the importance of high solids concentration and a long shelf life as being commercially useful and 30 teaches the use of a resin based on a branched water-soluble polyalanine reacted with glyoxal.
Resins that a_e commercially useful for imparting dry strength and a longer lasting wet strength are of the cationic, water-soluble, 35 polyamide-apichlorohydrin (PAE) resin type. Numerous . I

: . wn~2/0s3~ 9 ~ PCT/US~1/0~81 ~-PAE resins are known to the art. See U.S. Patent 3,332,901 to Keim.
One preferred PAE is made by the conden~ation polymerization of dimethyl glutarate and 5 diethylenetriamine ~ollowed by reaction with epichlorohydrin. Details of this polymerization are described in Chan, U.S. Patent 3,887,510 assigned to - Borden, Inc.
There are many disadvantages to the PAE type 10 resins. First, toxic by-products from the PAE
manufacture remain in the product and must be further processed to minimize their concentration. These toxic by-products include residual epichlorohydrin, a suspect carcinogen; l-chloro-2,3-propanediol which 15 reconverts to epichlorohydrin under hot alkaline conditions; and finally, cyclopentanone contamination which can be detected in adipic acid-based PAE resins.
The second disadvantage is that PAE resins continue to hydrolyze in solution and have a limited shel~ life.
20 Another disadvantage is t:hat most PAE resins commercially available today have a maximum of 30% to 35% solids due to commercial processing and shelf life constraints. This limits the commercial shipping distance of these aqueous solutions. PAE resins added 25 to the wet end o~ the paper manufacture are not all retained on the fiber. Efficiency o~ the PAE re~in in papermaking is limited to naar neutral to alkaline pH
and is strongly influenced by the presence of COOH
groups in the cellulose paper matrix.
It has been long known that thermoplastic polyolefin particles or fibers will thermally bond cèllulose fibers. These polymers provide much higher dry and wet strengths, which are dependent on the amount of polymer in the cellulose matrix.
Aroi et al., Japanese Kokai Patent 74 25,226 (March 6, 1974), describe a process to produce ' ... ,:., , u~ ~; a WOl~2/~)$311 PCT/US91/0~81 10-50 mm. diar ter x l-lO mm fi~ers (I) from a high-pressure ~ lyethylene (PE) solution. The ~ibers were beaten in water containing a small amount of surfactant to give a pulped mixture7 A 50:50 blend of (I) pulp and natural cellulosic pulp was made into a uniform paper with good wet strength.
- Absorbent wood fluff cellulosic pulp materials bonded with spurted fibrillated polyolefin pulp treated with a wetting agent is disclosed in Espy U.S. Pat. ~,4S8,042. Thesa products have good absorbency, but they are not readily degrada~le when discarded.
Badr~an, German ~tent 2,063,933 (Julv l, 1971), describes the use of denier lO synthetic ~ibers made from polypropylene (PP) filled with calcium carbonate. Filaments were cut into staple fibers and mixed with pulp to improve wet strength of paper.
Inorganic filled PP ~ilaments ~ixed more easily with the pulp than pure polypropylene fihers.
Barton and Matsuda (Proc IUPAC/EULEPA June 1972: 133.50) describe useful paper products based on polypropylene and polyethylene thermoplastics (with or without wood pulp blends). Advantages claimed include water resistance, dimensional stability, wet strength, decorative effects and special functional properties.
Bogomol ~ Luchinkina (Bumazh, Prom (l):lO-ll (1975); Russian) reports that beating of wood pulp increases the speci~ic ~urface area (S) and length~diameter (l/d). The increase of S and l/d also improves bonding between the acrylic fibers.
Hydroly~ed nylon, (FMC British Patent l,229,806, April 28, 1971) has aLso been used to improve wet strength.
Although olefinic polymers provide superior wet and dry s~rength via thermal ~onding, they are not .

WV~2/~531l ~ UJ ~ 9 7 j PCTtUS9l/0~81 ~^

readily biodegradable and are non-hydrolyzable. Thus their disposal poses a problem.
Bohmer (Norsk Skogind, 28(11):301-~) (November, 1974) discussea the resulta OL a study on the natural decomposition rates of paper versus plastic-based materials. Paper and plastic wastes first degrade photochemically, followed by relatively slower biolog.ical degradation. The presence of wet-strength resins retards the degradation of paper.
- 10Cellophane and polyethylene (PE) decompose relatively faster than polystyrene (PS) and polyvinylchloride (PVC). After 15 months of exposure, the structure of paper and polyethylene may still be intact, but the strength properties will have approached zero.
15Gottsching described the future of synthetic pulp as bleak based on the resistance to degradation.
(Future o~ Syn~hetic Paper From Plastic Films, Papier 26(10A):720-32(0ct., 1972): Ger.; ABIPC 43:A10360.) The author reviews the cost development of raw materials and synthetic papers, and concludes that, apart from certain special applications, there will be no breakthrough for such synthetic pulp papers within the next 15-20 years.
Most conventional wet strength resins rely on chemical bonding, reacting with the paper fiber carboxylate surface to p~ovide dry and wet strength.
These bonding mechanisms are not particularly effective when papermakers use Bleached Chemi-Thermal Mechanical Pulp (BCTMP). Most such mechanical pulps have a reduced number of bonding sites compared to bleached kraft pulps. This is due to the non-reactive lignin sheath on the surface of the BCTMP fiber. The paper producers report that they would like to use more of the less expensive BCTMP fiber, but that they would like to improve the fiber's ability to bond in the sheet. In addition, the rigidity of BCTMP pulp .

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WO~/05311 f~'J~ PCT/US91/0~81 fibers provide limited fiber-to~-fiber contact for chemical bonding.
The prior art discloses tha use of long lasting and temporary cellulosic bonding resins which chemically bond to the cellulosic surface. In contrast, the paper product of this invention is made using a degradable polyhydroxy acid (PHA) resin which uses a thermal plastic bonding mechanism. The PHA
resin bonds cellulosic and inorganic substrates independent of the substrates' chemical reactivity.
The prior art also discloses useful polyacrylic bonding agents which bond cellulosic and inorganic substrates via thermal plastic bonding.
These bonding agents are not completely degradable by microorganisms to by-products of respiration (CO2, H2O, etc.) and are not hydrolyzable. Furthermore, these thermoplastic bonding agents cannot be separated from the cellulosic substrate during conventional repulping conditions.
SUMMARY OF INVENTION
In accordance with this invention there is provided polymeric resin-bonded cellulosic pulp products that are totally repulpable under conventional repulping c:onditions. Also, under certain controlled repulp,ng conditions the resin can be retained in the pulp as a reusable resin bonding agent. Alternatively under other conditions and selection of resin properties, the resin can be completely removed from the cellulosic pulp during repulping.
Specifically, it has been found that certain degradable polyhydroxy acid (PHA) resins are effective dry strength and wet strength resins for paper. The resins are stable in aqueous solution under paper-making conditions. The PHA polymer has the advantage .. . . .
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WO')2/053ll '~ ~ ~ o 9 r~ rj PCT/US91/0~81 of being relatively inexpensive and can be provided as lOo% solids that have a long shelf life.

DETAILED DESCRIPTION OF THE I~JVENTION
The present invention relates to high wet strength papers and other pulp products, and their preparation. The products of this invention can be in`
the form of uniform sheets (both hard and tissue), composite laminates, or shaped articles. By appropriate selection of the resin properties, suitable containers can be made for hot liquids, such as paper coffee cups, and also ~or mildly basic or acidic materials. Also liquid absorbing hydrophilic batting materials, such as used in disposable diapers, sanitary napkins and medical pads having high absorption capacity, can be made. PHA f ilaments can also be incorporated into non-woven cellulosic fiber or pulp disposable garments.
The compositions of this invention have a wide variety of uses due to the polymeric resin's ability to thermally bon~ chemically dissimllar sur~aces such as BCTMP, b:Leached L/C kra~t, synthetic organic or inorganic fibers and particulates under a wide pH range. A major advantage is that he polymeric resin of this invention provides superior thermal bonding whila retaining the capability to repulp, recycle, hydrolyze and biodegrade.
The products of this invention comprise cellulosic pulp fibers bonded by c~rtain degradable polyhydroxy acid resins ~onding agents. The bonding agent comprises 5-50% by weight of the product. If the pulp fiber and the PHA resins are to be wet blended, it is desirable to use a wetting agent to facilitate blending. A wetting agent is also 3s desirable as a component in pr~ducts that are used to absor~ wa~er, such as ~owels and diapers. Preferably "

wo )2,n531 1 a ~ ~ 9 ~ ~ PCr/VS91/06481 the wetting agent is an anionic or nonionic wetting agent of less than 10000 M.W.
Polyhydroxy acids used in this invention as resin bonding agents or polymers contain at least one hydroxy acid unit selected from among:
(i) (OCR'R"COOCR'R"CO) q (ii) {O(CR'R")nCO]p (iii) (OC~'R~CR'R''OcR'R''cO)r (iV) (OCR'R'tCR'RnZCR~R"CR'R"CC))S
(v) copolymers of (i)-(iv) with non-hydroxy acid comonomers wherein n is 2, 4 or 5;
p, q, r and s are integers, the total of which may range from about 350 to 5,000; R' and R" are hydrogen, hydrocarbyl containing 1 to 12 carbon atoms, or substituted hydrocarbyl containing 1 to 12 carbon atoms:
and Z is 0, S, NH or PH..
Examples of suitable non-hydroxy acid co-monomers include those capable of condensation polymerization with lactide or lactic acid, i.e., lactones such as epsilon-caprolactone, beta-propio-lactone, alpha, alpha-dimethyl-beta-propiolactone and dodecanolactone; lactams; other hydroxy acids such as ` 25 glycolic acid: and amino acids. For a more complete list see U.S. 4,800,219 at column 9, line 27. The values of p, q, r and s are selected to impart degrees of crystallinity and crystallization rates appropriate to oriented film production. The preferred PHA is polylactic acid, either as a homopolymer or as a copolymer containing over 50~, and preferably over 70%, of lactide units. For certain uses, particularly for food containers, the L form of lactide is preferred since it is naturally present in the human body and in certain foods such as milk.
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Polyhydroxy acids may be synthesized by polymerization directly from hydroxy acid precursors, or by polymerization of the cyclic monomeric or cyclic dimeric lactone cf hydroxy acid precursors. When produced from lactones, choice of cyclic monomeric or cyclic dimeric species as polymerization monomer will depend upon the hydroxy acid type. Polymerization from cyclic lactone is preferred for producing high molecular weight polyhydroxy acids because equilibrium reactions with the intermediate, cyclic dimer and low molecular weight species place practical limits on the molecular weight of polymers produced directly from hydroxy acids.
Polyhydroxy acids of this invention have molecular weights at least high enough to provide su~ficient viscosity and strenyth to form sustainable films and fibers ~rom the polymer melt, when such shaped structures are used. Weight of averaye molecular weights ~rom about 50,000 to about 600,000, and preferably from about 150,000 to about 450,000 are effective in these forms of this invention. If the molecular weight is too high, excessive degradation occurs at the temperatures required to melt process the compositions. Lower molecular weight polymers, including those containing small amounts of unreacted monomers and oligomers, may also be used when the polymer is introduced into the pulp in a partioulate form. ~owever, the polymer must be sufficiently polymerized to be substantially non-hydrolized in the paper manufacture, storage and use and it must not soften and stick to the dryer drums.
The PHA resins normally will be used alone as bonding resins. However, to enhance certain properties such as wet or dry strength, impact strength or tear strength, ~or some products it is desirable to blend the PHA with another material such ~' ., , .

WO ~2/0531 I h U J 3 ~ 7 ~ PCT~US91/0~81 _g_ as a P~E, polyolefin, polyvinyl alcohol, starch, ~ormaldehyde polymers and others. If a non-compatible poly~er is to be blended with the PHA, a compatabil-~er will be included to produce a microhomogeneQ~s blend. Preferably the PHA content of the bondingresin is at least 50%.
The term "degrada~le", as used here with respect to the polyhydroxy acids, means that the polyhydroxy acid portion o~ the degradable material is biodegradable and, more importantly, degradable by hydrolysis. The degradation rate is consistent with its intended usage, i.e., the product does not degrade significantly in normal storage and usage, but will - degrade in a reasonable time, after discarding. For hydrolysis degradation, slightly acidic or basic conditions may be used advantageously. Rate of hyclrolysis degradation is affected by degree of polymer crystallinity and amount of water exposure.
; By hydrolysis degradation, monomer units can be recovered if desired for reconversion to useful polyhydroxy acid, or can be discarded as an environmentally benign waste material.
In papermaking, it is useful to incorporate in the PHA resin paper chemical additives that will be mechanically entrapped in the paper matrix. Such chemical additives include dyes, fluorescent whitening agents, organic and inorganic fillers, electroconduc-tive chemicals, biocides, ~ungicides, sizing agents, crepe paper-making agents, defoamers, retention aids, drainage aids, cross-linkers, anti~stick release agents, anti-corrosion chemicals, deinking solvents, hydrophilic or oleophobic chemicais and chelating agents.
In manufactùre of the products of this 3 5 invention the PHA resin is introduced directly into the pulp in any desired form such as particulate, :

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' ~vo1)2~0s3~ 9 7~ PCTtUS9l/0~81 s~-fibers, spurted fibers, or sheet material. Fibers may be short length or continuous filament and may be fibrillated. Sheet material may be in the form of film, or woven or non-woven sheet material. The resin may be introduced into the pulp by dry mixing or at any stage in the wet processing of the pulp, such as onto the screen or directly into the pulp beater.
Introduction into the beater is preferred becau~e of the resultant intimate mixing o~ the pulp and resin.
The paper is then prepared by conventional techniques.
If a wetting agent is to be used, it can be introduced onto the dry cellulosic pulp, added during dry blending of the pulp and PHA resin, or during the wet processing steps.
To achieve the strength and other desirable properties of the products of this invention it is necessary to heat soften the PLA polymer to bond the cellulosic fiber or to melt the polymer to impregnate and coat the cellulosic pulp fibers. Thus the preparation of the products includes the step of haat treating at a temperature above the polymer softening point.
A major advantage of these bonded cellulosic pulp products is that they not only have superior dry and wet strengths, but also they can be repulped and recycled: and the resins are hydrolyzable and ' biodegradable. Additionally, if the resin is "`` essentially L-polylactide, which is present in many foods such as milk and other dairy products, the products o~ this invention have high utility as food wrapping material.

;~ EXAMPLE 1 This example illustra~es a paper composition containing polylactide filament and its use as a dry and wet strength resin for paper.

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WO92/~11 PCT/US91/0~81 Part A
Medical gxade polylactide filament 6 mil diameter was used as the resin bonding agent.
Part B
High yield, Bleach Chemi-Thermal Mechanical pulp tBCTMP), northern soft wood, Tembec Company, 4000 breaking length pulp was prepared following TAPPI
standard hand sheet procedure T-205, with the exception that the pulp was disintegrated using a Waring blender for 5 minutes on high speed to a Canadian Standard Freeness (CSF) of 670 ml. Hand sheets were prepared and allowed to air dry for 24 hours at 50% relative humidity, 73 F. The sheets had 79 GE brightness and a thickness of 0.006".
Part C
on one hand sheet of BCTMP, twenty polylactide fibers (4-inch lengths) were cut and aligned side by side with a l mm spacing between the fibers over about a l" x 4" area in the center of the hand sheet. The fiber alignment was held in place ~sing 3M Scotch brand tap~ nother BCTMP hand sheet was placed on top of the base sheet so that the polylactide fibers were sandwiched between the sheets, referred to as a composite sheet.
The composite sheet was placed on a hot plate with a retalning screen on top. The composite sheet was quickly heated to 250 C to assure compl~te melting of the polylactide fibers inside the sandwiched layer. A thermocouple measured the heat rise which took l.5 minutes to reach 250-C
temperature. The composite sheet after the thermal bonding was 0.0l4" thick ver6us the control, 0.l2n taken from another section of the composite which contained no polylactide in between layers.

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W0~2/~5311 PCT/~S9ttO~81 ~-Part D
The composite sheet was cut into a l" wide by 4" long tensile specimen in such a way that the polylactide fibers were aligned in the direction of tension. A Model lOll Instron Co. tensile tester in a 50% relative humidity, 73F conditioning room was used to test l/4" spans at a crosshead speed 5~/min. Wet strength testing was conducted after allowing the test samples to soak in distilled water for 5 minutes at room temperature.
The polylactide filament described in Part A
of this example is evaluated as a dry and wet strength resin using the procedure described in Example l.
Results are shown in Table l.
TABLE l Po~cone PLA ~ddod, Dr~ S~n~llo U-t ~-n~lle ~ d on Pulp Str-n~th Sc~-n~eh De~crlp~lon _ (Dr~Ib/l- vldth) ~Ib/l~ ~Id~h) 2 BCTMP ~h~et~ 0 11 ~ 0 2 ~CTMP Jhô-~-~tor hn~tln~
t~ 250~C 0 18 2 11 9 Co~po~ltel22 0 26 ~ 20 1 hellt~d eo 2S0C
1 Polyl~ctld~ ~ndYlched betY~en 2 BCTHP ~h~2t~

Table l shows improved wet and dry strengths imparted to these BCTMP composite products containin~
PLA.
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; This example illustrates a paper composition containing polylactide film sandwiched between 2 BCTMP

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wo ~2/0531 1 h U J ~ 9 7 ~ PCT/US91/0~81 papers and its use as a dry and wet strength resin for paper.
Part A
Polylactic acid polymer containing about 15%
dipropylene glycol methyl ether acetate plasticizer and 2% Tio2 pigment was compounded and put through a twin screw extruder having 6n wide die maintained at 140-150'C. The film was then annealed. The resultant film was 3 mil thick. BCTMP hand sheets were prepared using the procedure outlined in Example 1, Part B.
Part B
Polylactide film was inserted between two TAPPI standard BCTMP handsheets and heated at various temperatures in order to melt the polymer on the surface of the BCTMP fiber. The control sheets had no polylactide sandwiched in between and were heat treated at the same temperature as the BCTMP sheets that had the polylactide sheet sandwiched in between.
Table 2 shows that BCTMP with polylactide in the middle (33% Polylactide on an Oven Dried pulp basis) has a dry strength which is dependent on the lamination temperature. Realistic l~minating temperatures are more in the 100 to 150-C range, however, the polylactide melting characteristics can be adjusted to the paper mills temperature operating range. Dry strength doubled when heat treated to 200~C to melt the PHL.
Table 3 shows the wet tensile strength of the control BCTMP sheets increased as the temparature increased indicating that the BCTMP might have had some bonding due its own lignin content which bonds ` the fibers. At room temperature the polylactid~ film does not bond to the BCTMP sheets and the tensile - strength is due to the strength of the polylactide film. As the temperature is increased ~he polylactide `; bonded at 100C and improved the wet strength. Still ~`' .

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W0~2/05~ J~9 7 ~ PCT/US91/0~81 ~-further improvements are shown in Fig GRE-2 as the temperature is increased. The BCTMP pulp discolors significantly as temperatures greater than 200 C.
Part C
The tensile testing procedure is described in Example 1, Part D.
Table 2. Effect of heat treatment of Polylactide film sandwiched between two BCTMP handsheets on Dry tensile strength.

Dry Tensile Strenqth (lb./in. width) Heat Treatment Control Polylactide Temperature roC) (2 8CTMP sheets) Composite PaPer _ 100 22.5 39.5 150 22.5 43.1 200 23.5 48.7 Table 3. Effect of heat treatment of Polylactide film sandwiched between two BCTMP handsheets on ~et tensile strength.

Wet Tensile Strenqth (lb./in.width) Heat Treatment Control Polylactide Temperature f-C~ (2 BCTMP sheets) Composite Paper 100 0 6.2 150 1.3 7.2 200 6.1 12.2 W~)~2/0531l ,~ V~3~ 7 ~ PCT/US9l/0~8~

r~A~pLE 3 Part A
The following example demonstrates the effect of polylactide filaments (~ 200,000~ diamater 5 13 microns) bl2nded with bleached kraft pulp.
Part B
TAPPI standard 205 procedures were used to prepare 3 sets of bleached kraft handsheets containing 0% synthetic fibers, 20 weight percent polylactide 10 ~ilaments and 20% wt % polyethylene pulp (Du Pont Company PUlplusTM Qp 3800).
Quarter inch lengths of extruded polylactide filaments (20 wt % oven dried pulp basis) were blended with bleach kraft pulp (70% northern softwood/30~
lS northern hardwood), 345 ml. CSF, and formed into TAPPI
standard hands~ Its. An equivalent amount of Du Pont PulplusTM QP380~ now called PlexafilTM, polyethylene pulp, was used for comparison for the TAPPI hands~eet tensile testing. The control was bleached kraft th~t 20 contained no synthetic fibers.
Table 4. Effect on dry strength of heat treatment temperature on PE and PLA-containing bleached kraft composites of 20 wt. ~ (oven dried pulp basis) of PE
and PLA.

;, Dry Te,nsile Strenqth tlb-/in. width) ,, 3 0 ~ e T~raem:!ne Conerol Polyaehyl-ne Polyl~ctlda TemDçraeure ~DaR C) ComPo?lte P,~e~ ComDo~le~ P~Der 100 31.0 19.2 2LI.S
~` 150 31.~ . 22.2 23.6 200 3~ . o 2~ . o 2s . 3 ~ ` ~

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W~2/05311 2~a9~ PCT/US91/0~81 ~

Table 5. Effect on wet strength of heat treatment temperature on the same PE and PLA-bleached kraft paper composites.

Wet Tensile Strenqth (lb./in. width) H~-t Ir~t0-n~ Conert>l PolyA~hyleno Polyl~ctld~
TomP~tura (Del~ C~ CCmDO-IeO P--De~ COmPO~I~e P--Der Room ~emp~r-t~ 0 0 0,4 ~00 0 0 1.0 lS0 0 2.~ 3.6 200 1.8 7.3 7~8 Table 4 shows that the dry strength of the PE and PLA-bleached kraft composites decreased as compared to the control. The composite containing polylactide filaments outperi-ormed the polyethylene 20 filament composite. It is hypothesized that the synthetic fibers interfere w:Lth hydrogen bonding of the cellulose fibers. The bleached kraft paper composite was heat treated al: lO0, 150 and 200'C to thermally bond the synthetic fibers to the cellulose.
25 The lOo to 150-C range represènts a realistic , temperature range for commercial papermaking processes.
Table 5 shows that the paper containing polylactide provided better wet strength as compared 30 to the paper containing polyethylene pulp and the control which contained no synthetic fibers. The polylactide has the added advantage of being repulpable and fully biodegradable.
Prior to making the hand sheets containing 35 polylactide, the polylactide filaments had to be dispersed in water with O.Ol wt. % Zonyl~ FSO

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h U.~'~ J~ )?j WO'J2/~531l PCT/VS91/0~8t (Du Pont Company) poly oxyethylene perfluoro alkyl ethanol surfactant in order to wet-out and disperse the filaments uniformly in the hand sheet.
Dispersants are also used on polyethylene pulps to 5 improve the wetting and dispersion.

This example illustrates a batting product containing cellulosic fibers, a wetting agent and a lO PHA resin bonding agent.
PHA spurted (fibrillated) fibers (bonding resin) are prepared by conventional spurting into water containing 0.01% -Zonyl~ FS0 wetting agent.
The PHA spurted fibers containing wetting agent are 15 dry mixed with bleached softwood kraft fluff pulp by pre-mixing and then passing through a blending mill~
The blend contains 25% PHA spurted fibers and 75~
kraft ~`luff pulp. This dry blend is then air laid to form a batting, which is heated to 175C to effect 20 bonding. The resultant batti.ng is used to make diaper lining. These diapers have excellent absorption ability. When discarded in a land fill, this batting material is readily degradab:le. Also, becausa of its biodegradability, it can be discarded via toilet 25 flushing into septic systems.
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This example shows the ability of PHA bonded paper to be repulped. Polylactide film was laminated 30 between two TAPPI standard BCTMP sheets at lOO~C. The laminated composite was cut into 9 one-inch wide tensile specimens and soaked in water at 60-C and tested for tensile strength in lO minute intervals for a total of 90 minutes. The tensile strength of the 35 composite did not change appreciably during this time.

w~ /n~ 9 7 5 PCT/US91/0~81 ~`

In contrast, soaking composite tensile specimens in 2~ sodium hydroxide solution resulted in a dramatic decrease in wet tensile strength and good repulpability of the composite. Tensile strength 5 decrease is a measure to determine degradation and repulpability of the polylactide BCTMP matrix. After 20 minutes soaking time at 60 C the polylactide began to delaminate from the BCTMP hand sheet. After 30 minutes soaking the film stretched before breaking, lO but after 40 minutes soaking the film fell apart immediately when put under tension.
After a 60 minute time frame (more than adequate for most repulping conditions encountered in the paper industry) the laminate had no significant 15 wet strength and was readily repulpable.
Laminated composite samples were soaked for 40 minutes in 2% caustic at 60-C and then were put in a Waring blender for l minute on high. The polylactide film separated from the BCTMP sheets and 20 some very small film particulates could be seen after blending. After 90-C soaking for 40 minutes in 2 caustic, no film particulate!3 were visible after Waring blender treatment for l minute on high.
The fact that the polylactide separates from 25 the BCTMP~when treated with caustic shows that the PLA
fibers could be reused in the paper making operation, which ls n~t ~o~lblg with Qthe~ wet ~en~th ~in~, Table 6 shows the effect of time, temperature and water vs. 2% caustic in water on the 30 degradation of a polylactide film wet tensile strength. Polylactide film prepared as in Example 2, Part A, was sandwiched between two Tembec 4000 BL, BCTMP TAPPI standard T-205 handsheets.

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W~2t05~1l PCT/US9lt~81 Soak TimeWet Tensile Wet Tensile tMinutes)in Water in 2% Caustic (lb/in. width) tl~/in. width) 6.9 1.7 10.2 0 7.~ 0 8.6 0 7.1 0 60 10.2 0 70 10.2 4.9 80 13.3 2.0 7.7 0 : 25 ~`:

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Claims (14)

CLAIMS:

1. A paper product comprising cellulosic fibers bonded by a polymeric resin containing a polymer comprising hydroxy acid units selected from the group consisting of:
(i) (OCR'R''COOCR'R''CO)q (ii) [O(CR'R")nCO]p (iii) (OCR'R''CR'R''OCR'R''CO)r (iv) (OCR'R''CR'R''ZCR'R''CR'R''CO)s (v) copolymers of (i)-(iv) with non-hydroxy acid comonomers wherein n is 2, 4 or 5; p, q, r and s are integers, the total of which is from about 350 to 5,000; R' and R'' are selected from hydrogen, hydrocarbyl containing l to 12 carbon atoms, and substituted hydrocarbyl containing 1 to 12 carbon atoms; and Z is selected from O, S, NH or PH.

2. The product of Claim l wherein the polymer contains at least 50% of polylactic acid.

3. The product of Claim l wherein the polymer contains at least 70% of polylactic acid.

4. The products of Claims 2 and 3 wherein the polymer contains at least 50% of polylactic acid with a preponderance of L-lactic units.

5. The product of Claim 1 wherein the polymeric resin contains at least 50% of said polymer.

6. The product of Claims 1-5 comprising 5-50% of the polymeric resin.

7. The product of Claims 1-6 wherein the cellulosic fibers are kraft pulp.

8. The product of Claims 1-6 wherein the cellulosic fibers are BCTMP pulp.

9. The product of Claims 1-8 containing a wetting agent.

10. The product of Claims 1-9 wherein the polymer resin is a blend containing another polymer.

11. The product of Claims 1-10 in the form of sheet material.

12. The product of Claims 1-10 in the form of a food container.

13. The product of Claim 9 in the form of a liquid-absorbing hydrophilic batting material.

14. The process for preparing a bonded cellulosic pulp product comprising admixing cellulosic pulp fibers with a polymeric resin containing polymer comprising hydroxy acid units selected from the group consisting of:
(i) (OCR'R''COOCR'R"CO)q (ii) [O(CR'R")nCO]p (iii) (OCR'R''CR'R''OCR'R''CO)r (iv) (OCR'R''CR'R''ZCR'R''CR'R''CO)s (v) copolymers of (i)-(iv) with non-hydroxy acid comonomers wherein n is 2, 4 or 5; p, g, r and s are integers, the total of which is from about 350 to 5,000, R' and R'' are selected from hydrogen, hydrocarbyl containing 1 to 12 carbon atoms, and substituted hydrocarbyl containing 1 to 12 carbon atoms; and Z is selected from O, S, NH or PH shaping the mixture of fibers and resin; and heating the shaped mixture in the dry state to a temperature above the softening point of the resin.