[go: up one dir, main page]

CA2085582A1 - Procede d'absorption au moyen d'un absorbant regenerable d'especes sulfureuses provenant de propylene/propane - Google Patents

Procede d'absorption au moyen d'un absorbant regenerable d'especes sulfureuses provenant de propylene/propane

Info

Publication number
CA2085582A1
CA2085582A1 CA2085582A CA2085582A CA2085582A1 CA 2085582 A1 CA2085582 A1 CA 2085582A1 CA 2085582 A CA2085582 A CA 2085582A CA 2085582 A CA2085582 A CA 2085582A CA 2085582 A1 CA2085582 A1 CA 2085582A1
Authority
CA
Canada
Prior art keywords
sulfur species
hydrocarbon stream
propane
propylene
adsorbing sulfur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2085582A
Other languages
English (en)
Other versions
CA2085582C (fr
Inventor
Donald James Norris
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=24163149&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2085582(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CA2085582A1 publication Critical patent/CA2085582A1/fr
Application granted granted Critical
Publication of CA2085582C publication Critical patent/CA2085582C/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G70/00—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
    • C10G70/04—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes
    • C10G70/046—Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00 by physical processes by adsorption, i.e. with the use of solids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Procédé permettant d'éliminer des constituants à base de soufre d'un flux d'hydrocarbures, comprenant les étapes suivantes: on effectue la mise en contact d'un flux d'hydrocarbures comprenant une quantité initiale d'au moins une espèce de soufre sélectionnée parmi le groupe comprenant les mercaptans, les sulfures organiques ainsi que les disulfures avec un catalyseur capable d'adsorber l'espèce à base de soufre en l'absence d'hydrogène ajouté depuis l'extérieur et dans des conditions propices à l'élimination d'au moins une espèce de soufre du flux d'hydrocarbures à l'aide du catalyseur de façon à obtenir un flux d'hydrocarbures renfermant une quantité réduite d'au moins une espèce de soufre.
CA002085582A 1990-06-22 1991-06-11 Procede d'absorption au moyen d'un absorbant regenerable d'especes sulfureuses provenant de propylene/propane Expired - Lifetime CA2085582C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/542,289 US5157201A (en) 1990-06-22 1990-06-22 Process for adsorbing sulfur species from propylene/propane using regenerable adsorbent
US542,289 1990-06-22
PCT/US1991/004106 WO1992000261A1 (fr) 1990-06-22 1991-06-11 Procede permettant l'adsorption d'especes de soufre a partir de propylene/propane a l'aide d'un adsorbant pouvant être regenere

Publications (2)

Publication Number Publication Date
CA2085582A1 true CA2085582A1 (fr) 1991-12-23
CA2085582C CA2085582C (fr) 1999-05-18

Family

ID=24163149

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002085582A Expired - Lifetime CA2085582C (fr) 1990-06-22 1991-06-11 Procede d'absorption au moyen d'un absorbant regenerable d'especes sulfureuses provenant de propylene/propane

Country Status (7)

Country Link
US (1) US5157201A (fr)
EP (1) EP0539433B2 (fr)
JP (1) JP2684120B2 (fr)
CA (1) CA2085582C (fr)
DE (1) DE69120951T3 (fr)
ES (1) ES2091934T5 (fr)
WO (1) WO1992000261A1 (fr)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1037778C (zh) * 1992-11-28 1998-03-18 大阪瓦斯株式会社 烃的脱硫方法
US5360536A (en) * 1993-08-09 1994-11-01 Uop Removal of sulfur compounds from liquid organic feedstreams
US5439867A (en) * 1994-03-04 1995-08-08 Phillips Petroleum Company Fluidizable sulfur sorbent and fluidized sorption process
US5914292A (en) * 1994-03-04 1999-06-22 Phillips Petroleum Company Transport desulfurization process utilizing a sulfur sorbent that is both fluidizable and circulatable and a method of making such sulfur sorbent
US5837131A (en) * 1996-04-05 1998-11-17 University Technologies International Inc. Desulfurization process
DE19710762A1 (de) * 1997-03-14 1998-09-17 Basf Ag Verfahren zur Reinigung von Stoffströmen
JP4096128B2 (ja) * 1997-08-21 2008-06-04 大阪瓦斯株式会社 脱硫剤の製造方法および炭化水素の脱硫方法
US5990372A (en) * 1998-01-12 1999-11-23 United Catalysts Inc. Adsorbent for the removal of trace quantities from a hydrocarbon stream and process for its use
GB9908752D0 (en) * 1999-04-16 1999-06-09 Bp Oil Int Purification process
US6383981B1 (en) 1999-07-20 2002-05-07 Süd-Chemie Inc. Adsorbent for the removal of trace quantities from a hydrocarbon stream and process for its use
US6884916B1 (en) * 1999-10-28 2005-04-26 Exxon Mobil Chemical Patents Inc. Conversion of unsaturated chemicals to oligomers
JP4609961B2 (ja) * 2000-01-28 2011-01-12 Ｊｘ日鉱日石エネルギー株式会社 硫黄化合物の除去方法
US20040140244A1 (en) * 2000-05-30 2004-07-22 Sughrue Edward L. Desulfurization and sorbents for same
US6579444B2 (en) 2000-12-28 2003-06-17 Exxonmobil Research And Engineering Company Removal of sulfur compounds from hydrocarbon feedstreams using cobalt containing adsorbents in the substantial absence of hydrogen
AR036902A1 (es) * 2001-10-24 2004-10-13 Exxonmobil Chem Patents Inc Un proceso para la oligomerizacion de un material de alimentacion olefinico, usos de un limite en el nivel de azufre en el material de alimentacion, una mezcla oligomerica olefinica, y un ester o una composicion polimerica plastificada
EP1438275B1 (fr) * 2001-10-24 2016-05-18 ExxonMobil Chemical Patents Inc. Procede d'oligomerisation d'olefines
US7105140B2 (en) 2002-03-04 2006-09-12 Conocophillips Company Desulfurization compositions
US6736879B2 (en) 2002-05-01 2004-05-18 Chevron Phillips Chemical Company Lp Process to prepare low carbon disulfide containing dimethyl sulfide
US7074324B2 (en) * 2002-06-05 2006-07-11 Exxonmobil Research And Engineering Company Process to remove sulfur contaminants from hydrocarbon streams
US7253330B2 (en) * 2003-04-29 2007-08-07 Exxonmobil Chemical Patents Inc. Oligomerization process
US7341977B2 (en) * 2003-06-20 2008-03-11 Nanoscale Corporation Method of sorbing sulfur compounds using nanocrystalline mesoporous metal oxides
US7309416B2 (en) * 2003-07-11 2007-12-18 Aspen Products Group, Inc. Methods and compositions for desulfurization of hydrocarbon fuels
GB0412151D0 (en) * 2004-06-01 2004-06-30 Exxonmobil Chem Patents Inc Olefin oligomerization process
GB0412139D0 (en) * 2004-06-01 2004-06-30 Exxonmobil Chem Patents Inc Olefin oligomerization process
US8323603B2 (en) * 2004-09-01 2012-12-04 Sud-Chemie Inc. Desulfurization system and method for desulfurizing a fuel stream
US7780846B2 (en) * 2004-09-01 2010-08-24 Sud-Chemie Inc. Sulfur adsorbent, desulfurization system and method for desulfurizing
US20060283780A1 (en) * 2004-09-01 2006-12-21 Sud-Chemie Inc., Desulfurization system and method for desulfurizing a fuel stream
US20060043001A1 (en) * 2004-09-01 2006-03-02 Sud-Chemie Inc. Desulfurization system and method for desulfurizing afuel stream
US7749376B2 (en) * 2005-08-15 2010-07-06 Sud-Chemie Inc. Process for sulfur adsorption using copper-containing catalyst
WO2008055591A2 (fr) * 2006-11-09 2008-05-15 Paul Scherrer Institut Procédé et installation pour convertir de la biomasse solide en électricité
US7745675B2 (en) * 2006-12-20 2010-06-29 Saudi Basic Industries Corporation Regeneration of platinum-germanium zeolite catalyst
CN101678303B (zh) * 2007-05-18 2013-10-23 国际壳牌研究有限公司 用于使原料反应的反应器系统和方法
JP5507446B2 (ja) 2007-05-18 2014-05-28 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 反応器システム並びにオレフィンオキシド、１，２−ジオール、１，２−ジオールエーテル、１，２−カーボネートおよびアルカノールアミンの調製方法
AU2008267113B2 (en) * 2007-06-14 2012-11-22 Exxonmobil Upstream Research Company Process for purification of hydrocarbons
BRPI0912718B1 (pt) 2008-05-15 2017-12-26 Shell Internationale Research Maataschappij B.V Method for producing an alkylene carbonate and / or an alkylene glycol
US8273912B2 (en) 2008-05-15 2012-09-25 Shell Oil Company Process for the preparation of an alkylene carbonate and an alkylene glycol
JP5587310B2 (ja) * 2008-07-15 2014-09-10 ビーエーエスエフ ソシエタス・ヨーロピア ジアルキルスルフィドの精製方法
EP2199269A1 (fr) * 2008-12-22 2010-06-23 Total Petrochemicals Research Feluy Procédé pour la purification de produits hydrocarbonés contenant de l'oléfine
JP5547423B2 (ja) * 2009-04-10 2014-07-16 出光興産株式会社 低硫黄ガソリン基材の製造装置及び低硫黄ガソリン基材の製造方法
JP5643529B2 (ja) * 2010-03-25 2014-12-17 大陽日酸株式会社 アセチレンの製造方法
US8597501B2 (en) * 2010-06-30 2013-12-03 Uop Llc Process for removing one or more sulfur compounds from a stream
US9446384B2 (en) 2011-02-02 2016-09-20 Reliance Industries Limited Adiabatic regeneration of sulfur capturing adsorbents
US9068128B2 (en) * 2011-10-18 2015-06-30 Baker Hughes Incorporated Method for reducing hydrogen sulfide evolution from asphalt and heavy fuel oils
DE102013225724A1 (de) * 2013-12-12 2015-06-18 Evonik Industries Ag Reinigung flüssiger Kohlenwasserstoffströme mittels kupferhaltiger Sorptionsmittel
RU2682670C1 (ru) 2013-12-20 2019-03-20 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Регулирование уровня серы дегидрогенизацией пропана
CN107406347A (zh) * 2015-03-27 2017-11-28 环球油品公司 具有额外再生步骤的组合床设计
US9517447B1 (en) 2015-06-01 2016-12-13 Uop Llc Processes for removing contaminants from a dehydrogenation effluent
AU2016428083B2 (en) * 2016-10-27 2020-04-09 Totalenergies Onetech Catalytic conversion of DSO in presence of water
US10507435B1 (en) * 2018-06-28 2019-12-17 Uop Llc Membrane process for olefin separation
US11590485B2 (en) * 2021-01-13 2023-02-28 Saudi Arabian Oil Company Process for modifying a hydroprocessing catalyst
FR3135458B1 (fr) * 2022-05-10 2025-08-01 Arkema France Procede ameliore de deshydrogenation d’hydrocarbures

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2291581A (en) * 1939-03-20 1942-07-28 Phillips Petroleum Co Process for treatment of hydrocarbons
US2362296A (en) * 1941-06-21 1944-11-07 Standard Oil Dev Co Method for removing sulphur from sulphur-bearing hydrocarbons
US2401334A (en) * 1942-12-12 1946-06-04 Standard Oil Co Process of aromatizing sulphurcontaining hydrocarbons
US2618586A (en) * 1950-11-03 1952-11-18 Wigton Abbott Corp Process for desulfurizing petroleum products in the liquid phase
US2771465A (en) * 1951-10-09 1956-11-20 Phillips Petroleum Co Adsorption process for separating elementary sulfur from sulfurized diaryl alkanes
US2760908A (en) * 1951-11-02 1956-08-28 Phillips Petroleum Co Process for removing alkyl sulfides from hydrocarbon fluids with adsorbent impregnated with cuprous chloride
BE562617A (fr) * 1956-11-27
US2971824A (en) * 1958-08-11 1961-02-14 Socony Mobil Oil Co Inc Process for recovering sulfur from hydrogen sulfide-containing gases
FR78229E (fr) * 1960-08-05 1962-06-22 Azote Office Nat Ind Procédé de préparation de certains oxydes métalliques, en particulier d'oxyde de zinc, à degré de dispersion très élevé
US3051646A (en) * 1961-03-13 1962-08-28 Phillips Petroleum Co Removal of sulfur materials from hydrocarbons
DE1142339B (de) * 1961-07-14 1963-01-17 Basf Ag Verfahren zur UEberfuehrung von 3, 4, 9, 10-Perylentetracarbonsaeure-diimid in eine zum Einfaerben von organischen Massen, wie Lacken, Firnissen, Gummi und Kunststoffen,geeignete Pigmentform
US3188293A (en) * 1962-03-21 1965-06-08 Gulf Research Development Co Process for regenerating molecular sieves
US3233003A (en) * 1962-09-12 1966-02-01 Exxon Research Engineering Co Purification of n-paraffins by adsorption
NL126960C (fr) * 1964-04-06
DE1913885B2 (de) * 1968-03-21 1974-06-20 The Gas Council, London Verfahren zur Entschwefelung von KohlenwasserstofFdestillatölen
US3778486A (en) * 1972-04-19 1973-12-11 Scm Corp Turpentine fraction purification
FR2295782A1 (fr) * 1974-12-27 1976-07-23 Inst Francais Du Petrole Procede d'epuration d'un gaz contenant du sulfure d'hydrogene et masses de contact utilisables a cet effet
US4098684A (en) * 1976-11-29 1978-07-04 Gulf Research & Development Company Purification of liquid n-paraffins containing carbonyl sulfide and other sulfur compounds
GB2043675B (en) * 1979-03-08 1983-02-23 British Gas Corp Gas oil purification
US4313820A (en) * 1980-02-28 1982-02-02 Phillips Petroleum Co. Hydrodesulfurization of organic sulfur compounds and hydrogen sulfide removal with incompletely sulfided zinc titanate materials
US4533529A (en) * 1983-10-21 1985-08-06 Standard Oil Company Sulfur recovery process
US4540842A (en) * 1984-01-16 1985-09-10 El Paso Products Company Removal of sulfur compounds from pentane
US4571445A (en) * 1984-12-24 1986-02-18 Shell Oil Company Process for removal of sulfur compounds from conjugated diolefins
US4835338A (en) * 1987-08-31 1989-05-30 Aluminum Company Of America Process for removal of carbonyl sulfide from organic liquid by adsorption using alumina adsorbent capable of regeneration
US4795545A (en) * 1987-09-17 1989-01-03 Uop Inc. Process for pretreatment of light hydrocarbons to remove sulfur, water, and oxygen-containing compounds
JP2654515B2 (ja) * 1987-11-05 1997-09-17 大阪瓦斯株式会社 脱硫剤の製造方法
JP2688749B2 (ja) * 1987-11-05 1997-12-10 大阪瓦斯株式会社 耐高温高次脱硫剤の製造方法
JPH02160728A (ja) * 1988-12-15 1990-06-20 Kawasaki Steel Corp 炭化水素中の微量硫黄化合物の除去法

Also Published As

Publication number Publication date
US5157201A (en) 1992-10-20
JP2684120B2 (ja) 1997-12-03
ES2091934T5 (es) 2008-02-16
CA2085582C (fr) 1999-05-18
DE69120951T2 (de) 1996-11-28
EP0539433A1 (fr) 1993-05-05
EP0539433B2 (fr) 2007-07-25
DE69120951D1 (de) 1996-08-22
DE69120951T3 (de) 2008-02-07
ES2091934T4 (es) 1998-03-16
WO1992000261A1 (fr) 1992-01-09
ES2091934T3 (es) 1996-11-16
JPH05508432A (ja) 1993-11-25
EP0539433B1 (fr) 1996-07-17

Similar Documents

Publication Publication Date Title
CA2085582A1 (fr) Procede d'absorption au moyen d'un absorbant regenerable d'especes sulfureuses provenant de propylene/propane
AU652600B2 (en) Desulphurisation of hydrocarbon feedstreams with N-halogeno compounds
CA2005946A1 (fr) Compose et methode pour l'adoucissement des hydrocarbures
DE68923793D1 (de) Verfahren zum süssen von kohlenwasserstoffen.
HK1048490A1 (zh) 由烴中除去汞的方法
CS407889A3 (en) Process of hydrocarbons fine desulfurization
DE3260273D1 (en) Process for separating normal paraffins from branched and/or cyclic hydrocarbons
CA2231659A1 (fr) Agent epurateur contenant des bisoxazolidines pour eliminer le sulfure d'hydrogene
WO2003083015A3 (fr) Procede d'elimination d'arsine contenue dans une vapeur d'hydrocarbures au moyen d'un adsorbent
BR8303178A (pt) Processo para separacao e obtencao de gases (componentes de gas-produto), passiveis de adsorcao relativamente forte em agentes de adsorcao, especialmente metano ou dioxido de carbono, a partir de misturas de gases contendo ademais essencialmente apenas gases (componentes de gas residual) mais levemente adsorviveis, bem como equipamento para a realizacao desse processo
CA2374660A1 (fr) Procede d'adsorption destine a la production de flux d'hydrocarbure a teneur ultra-faible en soufre
US20040118751A1 (en) Multicomponent sorption bed for the desulfurization of hydrocarbons
EP0525602A3 (en) Removal of arsenic compounds from light hydrocarbon streams
GB2045222B (en) Sulphur sorbent for removing residual sulphur from hydrocarbon feed streams
ATE84437T1 (de) Entfernen von schwefelwasserstoff aus einer gasmischung.
AU542194B2 (en) Removing hydrogen sulphide from gaseous hydrocarbons using active carbon
TW372883B (en) Method for removing sulfur-containing contaminants, aromatics and hydrocarbons from gas
DE59006576D1 (de) Verfahren zum Entschwefeln eines Schwefelwasserstoff enthaltenden Gases.
JPH11128737A5 (fr)
AU4965785A (en) Sorbent and processes for removing nitrogen oxides, sulfur oxides and hydrogen sulfide from gas streams
FI944333A0 (fi) Menetelmä arsiinin ja karbonyylisulfidin poistamiseksi syöttöhiilivedyistä, jotka sisältävät kevyitä olefiinejä
SU833553A1 (ru) Способ очистки водных растворов отРТуТи
RU98115535A (ru) Способ удаления серосодержащих загрязняющих веществ, углеводородов ароматического ряда и углеводородов из газа
JPS55127146A (en) Regeneration of catalyst used in catalytic cracking of heavy oil with sulfur content
ZA806567B (en) Method for removing hydrogen sulfide from gas streams

Legal Events

Date Code Title Description
EEER Examination request
MKEX Expiry