CA2060802A1 - Utilisation d'un copolymere a base de mono-olefines a chaine longue et (ou) d'esters alkylvinyliques et d'anhydrides dicarboxyliques ethyleniquement insatures, destines a hydrophobiser des produits colloidaux comme des aagents de scellement, des melanges de platre, des peintures et des adhesifs de construction - Google Patents

Utilisation d'un copolymere a base de mono-olefines a chaine longue et (ou) d'esters alkylvinyliques et d'anhydrides dicarboxyliques ethyleniquement insatures, destines a hydrophobiser des produits colloidaux comme des aagents de scellement, des melanges de platre, des peintures et des adhesifs de construction

Info

Publication number: CA2060802A1
Authority: CA; Canada
Prior art keywords: copolymer; polymerization; olefins; hydrophobizing; dicarboxylic anhydrides
Prior art date: 1991-02-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2060802

Other languages

English (en)

Inventor

Oral Aydin

Walter Denzinger

Rolf Dersch

Gernot Franzmann

Norbert Greif

Heinrich Hartmann

Eckehardt Wistuba

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BASF SE

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-02-08

Filing date

1992-02-06

Publication date

1992-08-09

1992-02-06 Application filed by Individual filed Critical Individual

1992-08-09 Publication of CA2060802A1 publication Critical patent/CA2060802A1/fr

Status Abandoned legal-status Critical Current

Links

229920001577 copolymer Polymers 0.000 title claims abstract description 90
150000008064 anhydrides Chemical class 0.000 title claims abstract description 37
150000001875 compounds Chemical class 0.000 title claims abstract description 26
238000007789 sealing Methods 0.000 title claims abstract description 24
150000002170 ethers Chemical class 0.000 title claims abstract description 22
239000003973 paint Substances 0.000 title claims abstract description 22
239000000853 adhesive Substances 0.000 title claims abstract description 12
230000001070 adhesive effect Effects 0.000 title claims abstract description 12
150000005673 monoalkenes Chemical class 0.000 title abstract description 3
238000007334 copolymerization reaction Methods 0.000 claims abstract description 10
239000000178 monomer Substances 0.000 claims description 39
238000006116 polymerization reaction Methods 0.000 claims description 36
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 20
238000000034 method Methods 0.000 claims description 19
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
239000011505 plaster Substances 0.000 claims description 14
239000000126 substance Substances 0.000 claims description 13
150000001412 amines Chemical class 0.000 claims description 12
239000002585 base Substances 0.000 claims description 12
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
229910021529 ammonia Inorganic materials 0.000 claims description 9
229910052783 alkali metal Inorganic materials 0.000 claims description 7
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 7
238000003797 solvolysis reaction Methods 0.000 claims description 6
230000002209 hydrophobic effect Effects 0.000 claims description 5
238000009877 rendering Methods 0.000 claims description 4
150000003335 secondary amines Chemical class 0.000 claims description 4
150000001340 alkali metals Chemical class 0.000 claims description 3
150000001342 alkaline earth metals Chemical class 0.000 claims description 3
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 38
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 27
229940044600 maleic anhydride Drugs 0.000 description 21
239000000203 mixture Substances 0.000 description 21
150000001336 alkenes Chemical class 0.000 description 20
239000003999 initiator Substances 0.000 description 20
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 20
239000006185 dispersion Substances 0.000 description 17
239000002904 solvent Substances 0.000 description 17
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 16
-1 n-docosylvinyl Chemical group 0.000 description 15
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 11
238000006386 neutralization reaction Methods 0.000 description 11
238000003756 stirring Methods 0.000 description 11
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 10
125000004432 carbon atom Chemical group C* 0.000 description 9
239000003795 chemical substances by application Substances 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
235000011121 sodium hydroxide Nutrition 0.000 description 9
239000000243 solution Substances 0.000 description 9
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
150000001298 alcohols Chemical class 0.000 description 8
229910000019 calcium carbonate Inorganic materials 0.000 description 8
238000005299 abrasion Methods 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
239000000084 colloidal system Substances 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
238000004519 manufacturing process Methods 0.000 description 7
230000001681 protective effect Effects 0.000 description 7
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
239000001993 wax Substances 0.000 description 6
150000003863 ammonium salts Chemical class 0.000 description 5
239000000839 emulsion Substances 0.000 description 5
230000007062 hydrolysis Effects 0.000 description 5
238000006460 hydrolysis reaction Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 4
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 4
239000013011 aqueous formulation Substances 0.000 description 4
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
230000003472 neutralizing effect Effects 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
239000004014 plasticizer Substances 0.000 description 4
229920000058 polyacrylate Polymers 0.000 description 4
229920001296 polysiloxane Polymers 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000000344 soap Substances 0.000 description 4
239000000725 suspension Substances 0.000 description 4
239000003760 tallow Substances 0.000 description 4
239000004408 titanium dioxide Substances 0.000 description 4
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 3
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical group CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
230000009471 action Effects 0.000 description 3
238000000576 coating method Methods 0.000 description 3
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
230000032050 esterification Effects 0.000 description 3
238000005886 esterification reaction Methods 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000000463 material Substances 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
239000003505 polymerization initiator Substances 0.000 description 3
238000001556 precipitation Methods 0.000 description 3
238000012673 precipitation polymerization Methods 0.000 description 3
230000002028 premature Effects 0.000 description 3
150000003141 primary amines Chemical class 0.000 description 3
238000010557 suspension polymerization reaction Methods 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 description 2
QEGNUYASOUJEHD-UHFFFAOYSA-N 1,1-dimethylcyclohexane Chemical compound CC1(C)CCCCC1 QEGNUYASOUJEHD-UHFFFAOYSA-N 0.000 description 2
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
NSOAQRMLVFRWIT-UHFFFAOYSA-N 1-ethenoxydecane Chemical compound CCCCCCCCCCOC=C NSOAQRMLVFRWIT-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000004435 Oxo alcohol Substances 0.000 description 2
URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
229920002125 Sokalan® Polymers 0.000 description 2
239000000654 additive Substances 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
230000002776 aggregation Effects 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 2
239000000378 calcium silicate Substances 0.000 description 2
229910052918 calcium silicate Inorganic materials 0.000 description 2
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
235000013539 calcium stearate Nutrition 0.000 description 2
239000008116 calcium stearate Substances 0.000 description 2
OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
239000013530 defoamer Substances 0.000 description 2
JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 2
IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
150000002191 fatty alcohols Chemical class 0.000 description 2
238000010528 free radical solution polymerization reaction Methods 0.000 description 2
230000009477 glass transition Effects 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 2
IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 2
239000000391 magnesium silicate Substances 0.000 description 2
229910052919 magnesium silicate Inorganic materials 0.000 description 2
235000019792 magnesium silicate Nutrition 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
239000002245 particle Substances 0.000 description 2
FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
239000000049 pigment Substances 0.000 description 2
239000004584 polyacrylic acid Substances 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000003755 preservative agent Substances 0.000 description 2
230000002335 preservative effect Effects 0.000 description 2
230000008569 process Effects 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
238000010526 radical polymerization reaction Methods 0.000 description 2
229920005989 resin Polymers 0.000 description 2
239000011347 resin Substances 0.000 description 2
150000003333 secondary alcohols Chemical class 0.000 description 2
GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 2
235000019982 sodium hexametaphosphate Nutrition 0.000 description 2
229920003002 synthetic resin Polymers 0.000 description 2
239000000057 synthetic resin Substances 0.000 description 2
RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 2
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 2
DEUGOISHWHDTIR-UHFFFAOYSA-N (1-hydroxy-5,5-dimethylhexyl) 2-methylpropanoate Chemical compound C(C(C)C)(=O)OC(CCCC(C)(C)C)O DEUGOISHWHDTIR-UHFFFAOYSA-N 0.000 description 1
KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
RQHGZNBWBKINOY-PLNGDYQASA-N (z)-4-tert-butylperoxy-4-oxobut-2-enoic acid Chemical compound CC(C)(C)OOC(=O)\C=C/C(O)=O RQHGZNBWBKINOY-PLNGDYQASA-N 0.000 description 1
JTQQDDNCCLCMER-CLFAGFIQSA-N (z)-n-[(z)-octadec-9-enyl]octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCNCCCCCCCC\C=C/CCCCCCCC JTQQDDNCCLCMER-CLFAGFIQSA-N 0.000 description 1
QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
UGCSPKPEHQEOSR-UHFFFAOYSA-N 1,1,2,2-tetrachloro-1,2-difluoroethane Chemical compound FC(Cl)(Cl)C(F)(Cl)Cl UGCSPKPEHQEOSR-UHFFFAOYSA-N 0.000 description 1
AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
HSLFISVKRDQEBY-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)cyclohexane Chemical compound CC(C)(C)OOC1(OOC(C)(C)C)CCCCC1 HSLFISVKRDQEBY-UHFFFAOYSA-N 0.000 description 1
GCYUJISWSVALJD-UHFFFAOYSA-N 1,1-diethylcyclohexane Chemical compound CCC1(CC)CCCCC1 GCYUJISWSVALJD-UHFFFAOYSA-N 0.000 description 1
KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
KQDDMFCWCZIWOL-UHFFFAOYSA-N 1-ethenoxy-10-methylundecane Chemical compound CC(C)CCCCCCCCCOC=C KQDDMFCWCZIWOL-UHFFFAOYSA-N 0.000 description 1
ZGNCMYIGUNROMY-UHFFFAOYSA-N 1-ethenoxy-11-methyldodecane Chemical compound CC(C)CCCCCCCCCCOC=C ZGNCMYIGUNROMY-UHFFFAOYSA-N 0.000 description 1
OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 1
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239000007788 liquid Substances 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
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WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
229940043265 methyl isobutyl ketone Drugs 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
PXSXRABJBXYMFT-UHFFFAOYSA-N n-hexylhexan-1-amine Chemical compound CCCCCCNCCCCCC PXSXRABJBXYMFT-UHFFFAOYSA-N 0.000 description 1
HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
ZWRUINPWMLAQRD-UHFFFAOYSA-N nonan-1-ol Chemical class CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 1
229940078552 o-xylene Drugs 0.000 description 1
CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
229940055577 oleyl alcohol Drugs 0.000 description 1
XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
235000011181 potassium carbonates Nutrition 0.000 description 1
235000011118 potassium hydroxide Nutrition 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003138 primary alcohols Chemical class 0.000 description 1
238000000746 purification Methods 0.000 description 1
239000007870 radical polymerization initiator Substances 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
UIIMBOGNXHQVGW-UHFFFAOYSA-N sodium;hydron;carbonate Chemical compound [Na+].OC(O)=O UIIMBOGNXHQVGW-UHFFFAOYSA-N 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
WMXCDAVJEZZYLT-UHFFFAOYSA-N tert-butylthiol Chemical compound CC(C)(C)S WMXCDAVJEZZYLT-UHFFFAOYSA-N 0.000 description 1
150000003509 tertiary alcohols Chemical class 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
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229910052721 tungsten Inorganic materials 0.000 description 1
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238000005303 weighing Methods 0.000 description 1
239000012224 working solution Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/12—Hydrolysis
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/50—Chemical modification of a polymer wherein the polymer is a copolymer and the modification is taking place only on one or more of the monomers present in minority

Landscapes

Chemical & Material Sciences (AREA)
General Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Adhesives Or Adhesive Processes (AREA)
Paints Or Removers (AREA)
Building Environments (AREA)
Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Compositions Of Macromolecular Compounds (AREA)

CA 2060802 1991-02-08 1992-02-06 Utilisation d'un copolymere a base de mono-olefines a chaine longue et (ou) d'esters alkylvinyliques et d'anhydrides dicarboxyliques ethyleniquement insatures, destines a hydrophobiser des produits colloidaux comme des aagents de scellement, des melanges de platre, des peintures et des adhesifs de construction Abandoned CA2060802A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DEP4103865.7		1991-02-08
DE19914103865 DE4103865A1 (de)	1991-02-08	1991-02-08	Verwendung von copolymerisaten auf basis von langkettigen monoolefinen und/oder alkylvinylethern und ethylenisch ungesaettigten dicarbonsaeureanhydriden zum hydrophobieren von dispersionsgebundenen dichtungsmassen, putzen, anstrichstoffen und bauklebern

Publications (1)

Publication Number	Publication Date
CA2060802A1 true CA2060802A1 (fr)	1992-08-09

Family

ID=6424671

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2060802 Abandoned CA2060802A1 (fr)	1991-02-08	1992-02-06	Utilisation d'un copolymere a base de mono-olefines a chaine longue et (ou) d'esters alkylvinyliques et d'anhydrides dicarboxyliques ethyleniquement insatures, destines a hydrophobiser des produits colloidaux comme des aagents de scellement, des melanges de platre, des peintures et des adhesifs de construction

Country Status (4)

Country	Link
EP (1)	EP0498195A3 (fr)
JP (1)	JPH0570654A (fr)
CA (1)	CA2060802A1 (fr)
DE (1)	DE4103865A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8716384B2 (en)	2009-07-28	2014-05-06	Clariant Finance (Bvi) Limited	Pigment concentrates

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4137476A1 (de) †	1991-11-14	1993-05-19	Basf Ag	Verwendung von pigmentzubereitungen zur herstellung von pasten, druckfarben und lacken
DE4300239A1 (de) *	1993-01-07	1994-07-14	Basf Ag	Verwendung von partiell veresterten Carboxylgruppen enthaltenden Copolymerisaten als Dispergiermittel
US5976382A (en) *	1996-07-10	1999-11-02	Ligochem, Inc.	Removal of proteins from aqueuos media by precipitation
DE19936324A1 (de)	1999-08-02	2001-02-22	Geodur Cis Ag Zug	Gemisch zur Behandlung von Abfallmaterial
DE102004001990A1 (de) *	2004-01-13	2005-08-04	Basf Ag	Wässrige Beschichtungsmassen mit hoher Pigmentvolumenkonzentration
EP1900756A1 (fr) *	2006-09-14	2008-03-19	Basf Se	Procédé de préparation d'une dispersion aqueuse de polymère
JP5758849B2 (ja) *	2012-06-15	2015-08-05	ミサワホーム株式会社	外構部材および外構構造物
WO2014120593A1 (fr)	2013-02-01	2014-08-07	3M Innovative Properties Company	Compositions adhésives autocollantes et articles adhésifs comprenant celles-ci
CN110219377A (zh) *	2019-05-28	2019-09-10	吴义付	一种防水涂料及其防水施工方法

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4045172A (en) *	1973-05-10	1977-08-30	Gaf Corporation	Textile soil release composition and method
DE3108100A1 (de) *	1981-03-04	1982-09-16	Basf Ag, 6700 Ludwigshafen	Verfahren zur herstellung von copolymerisaten des maleinsaeureanhydrids
DE3479318D1 (en) *	1983-06-28	1989-09-14	Johnson & Son Inc S C	Alphaolefin terpolymer and coating composition including said terpolymer
US4859752A (en) *	1987-09-11	1989-08-22	S. C. Johnson & Son, Inc.	Alkene/excess maleic anhydride polymer manufacture
DE3736996A1 (de) *	1987-10-31	1989-05-11	Basf Ag	Verfahren zur herstellung von copolymerisaten aus ethylenisch ungesaettigten dicarbonsaeureanhydriden und alkylvinylethern
DE3926168A1 (de) *	1989-08-08	1991-02-14	Basf Ag	Verwendung von copolymerisaten auf basis von langkettigen alkylvinylethern und ethylenisch ungesaettigten dicarbonsaeureanhydriden zum hydrophobieren von leder und pelzfellen

1991
- 1991-02-08 DE DE19914103865 patent/DE4103865A1/de not_active Withdrawn
1992
- 1992-01-20 EP EP19920100813 patent/EP0498195A3/de not_active Withdrawn
- 1992-02-06 CA CA 2060802 patent/CA2060802A1/fr not_active Abandoned
- 1992-02-07 JP JP2225792A patent/JPH0570654A/ja not_active Withdrawn

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8716384B2 (en)	2009-07-28	2014-05-06	Clariant Finance (Bvi) Limited	Pigment concentrates

Also Published As

Publication number	Publication date
JPH0570654A (ja)	1993-03-23
EP0498195A3 (en)	1992-09-16
EP0498195A2 (fr)	1992-08-12
DE4103865A1 (de)	1992-08-13

Publication	Publication Date	Title
EP1015523B1 (fr)	2003-06-11	Latex produit avec un agent de surface reticulable
US4102843A (en)	1978-07-25	Dispersing paint pigments
US5679735A (en)	1997-10-21	Process for the preparation of synthetic resin dispersions
CA2060802A1 (fr)	1992-08-09	Utilisation d'un copolymere a base de mono-olefines a chaine longue et (ou) d'esters alkylvinyliques et d'anhydrides dicarboxyliques ethyleniquement insatures, destines a hydrophobiser des produits colloidaux comme des aagents de scellement, des melanges de platre, des peintures et des adhesifs de construction
US5286263A (en)	1994-02-15	Use of copolymers based on long-chain alkyl vinyl ethers and ethylenically unsaturated dicarboxylic anhydrides for rendering leathers and skins water-repellent
EP0986611B1 (fr)	2005-01-26	Revetements de surface reticulables et procede de preparation
US4395500A (en)	1983-07-26	Protective colloid-free plastics dispersion having a bimodal particle size distribution
GB2052520A (en)	1981-01-28	Coating compositions and coatings comprising polymer-transition metal chelates
US6054526A (en)	2000-04-25	Finely particulate composite latices and use thereof in solvent-free paints
JPH0224310A (ja)	1990-01-26	尿素基を含有し且つエチレン性不飽和単量体を基礎とする分散物重合体、その製造方法およびその用途
GB1574721A (en)	1980-09-10	Process for preparing aqueous copolymer emulsions
JP2603173B2 (ja)	1997-04-23	水性化ポリオレフィン樹脂組成物及びその製造方法
US4144388A (en)	1979-03-13	Film-forming and thermocurable vinyl alcohol-substituted acrylamide copolymers and process for production thereof
US4169086A (en)	1979-09-25	Aqueous dispersion paint having a high wet adhesion and process for preparing same
US3485785A (en)	1969-12-23	Ethylene interpolymer compositions and processes
KR20010030851A (ko)	2001-04-16	스크럽 내성 라텍스
US6336942B1 (en)	2002-01-08	Processes of treating leather and skins employing polymer compositions
CA2404856A1 (fr)	2002-10-02	Dispersion aqueuse, procede d'elaboration, et utilisation
JP2519995B2 (ja)	1996-07-31	エマルジョン組成物
EP0040498A1 (fr)	1981-11-25	Polymères à propriétés biocides
GB2108976A (en)	1983-05-25	Aqueous coating composition
KR100230140B1 (ko)	1999-11-15	알킬렌, 비닐 아세테이트 및 비닐 피발레이트의 중합으로 얻을 수 있는 중합체
JPH051246A (ja)	1993-01-08	防汚塗料組成物
JP3357710B2 (ja)	2002-12-16	エマルジョン組成物
US4260533A (en)	1981-04-07	Vinyl acetate/allylic amine copolymer emulsions for paint having wet adhesion properties

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Date	Code	Title	Description
1994-08-06	FZDE	Dead

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Family

ID=6424671

Family Applications (1)

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Cited By (1)

Families Citing this family (9)

Family Cites Families (6)

Cited By (1)

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