CA2059130A1 - Procede d'obtention d'esters de cellulose par utilisation d'acides carboxyliques - Google Patents
Procede d'obtention d'esters de cellulose par utilisation d'acides carboxyliquesInfo
- Publication number
- CA2059130A1 CA2059130A1 CA2059130A CA2059130A CA2059130A1 CA 2059130 A1 CA2059130 A1 CA 2059130A1 CA 2059130 A CA2059130 A CA 2059130A CA 2059130 A CA2059130 A CA 2059130A CA 2059130 A1 CA2059130 A1 CA 2059130A1
- Authority
- CA
- Canada
- Prior art keywords
- cellulose
- carboxylic acids
- cellulose esters
- preparing cellulose
- propionate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920002678 cellulose Polymers 0.000 title abstract 3
- 150000001735 carboxylic acids Chemical class 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920008347 Cellulose acetate propionate Polymers 0.000 abstract 1
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 abstract 1
- 229920002301 cellulose acetate Polymers 0.000 abstract 1
- 229920006217 cellulose acetate butyrate Polymers 0.000 abstract 1
- 229920001727 cellulose butyrate Polymers 0.000 abstract 1
- 229920006218 cellulose propionate Polymers 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000003797 solvolysis reaction Methods 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B3/00—Preparation of cellulose esters of organic acids
- C08B3/22—Post-esterification treatments, including purification
- C08B3/24—Hydrolysis or ripening
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
L'invention concerne un procédé permettant de réduire le degré de substitution d'esters de cellulose, en utilisant des acides carboxyliques comme promoteurs de la solvolyse. Comme exemples d'esters de cellulose, on peut citer l'acétocellulose, le propionate de cellulose, le butyrate de cellulose, l'acétopropionate de cellulose et l'acétobutyrate de cellulose.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US50938590A | 1990-04-16 | 1990-04-16 | |
| US509,385 | 1990-04-16 | ||
| PCT/US1991/002293 WO1991016358A1 (fr) | 1990-04-16 | 1991-04-09 | Procede de preparation d'esters de cellulose a l'aide d'acides carboxyliques |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2059130A1 true CA2059130A1 (fr) | 1991-10-17 |
| CA2059130C CA2059130C (fr) | 1999-05-11 |
Family
ID=24026446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002059130A Expired - Fee Related CA2059130C (fr) | 1990-04-16 | 1991-04-09 | Procede d'obtention d'esters de cellulose par utilisation d'acides carboxyliques |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5597912A (fr) |
| EP (1) | EP0477347B1 (fr) |
| JP (1) | JP3315980B2 (fr) |
| KR (1) | KR100205465B1 (fr) |
| AT (1) | ATE139544T1 (fr) |
| CA (1) | CA2059130C (fr) |
| DE (1) | DE69120360T2 (fr) |
| DK (1) | DK0477347T3 (fr) |
| ES (1) | ES2088003T3 (fr) |
| GR (1) | GR3020847T3 (fr) |
| WO (1) | WO1991016358A1 (fr) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5214137A (en) * | 1991-02-08 | 1993-05-25 | Eastman Kodak Company | Preparation of cellulose diacetate by recycling processed film |
| MY106937A (en) * | 1992-01-13 | 1995-08-30 | Eastman Chem Co | Continuous hydrolysis of cellulose acetate |
| EP0763544B1 (fr) * | 1995-03-31 | 2003-09-24 | Daicel Chemical Industries, Ltd. | Acetate de cellulose a bonne aptitude au moulage et procede de preparation associe |
| JP3942669B2 (ja) * | 1995-03-31 | 2007-07-11 | ダイセル化学工業株式会社 | 物理強度に優れたセルロースアセテート、及びその製造法 |
| EP0769500B1 (fr) * | 1995-03-31 | 2003-02-19 | Daicel Chemical Industries, Ltd. | Acetate de cellulose hautement resistant et procede de preparation associe |
| IT1286510B1 (it) * | 1996-11-29 | 1998-07-15 | Cooperativa Centro Ricerche Po | Esteri butirrici ad attivita' antiproliferativa e composizioni farmaceutiche che li contengono |
| US20100175691A1 (en) * | 2009-01-15 | 2010-07-15 | Celanese Acetate Llc | Process for recycling cellulose acetate ester waste |
| EP2975063A4 (fr) * | 2013-03-13 | 2016-08-17 | Daicel Corp | Acétocellulose faiblement substituée |
| CN105848500B (zh) * | 2013-12-20 | 2020-02-07 | 株式会社大赛璐 | 具有脂质代谢改善作用的营养组合物 |
| KR102356094B1 (ko) | 2014-03-24 | 2022-01-26 | 주식회사 다이셀 | 약학 조성물 |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB317088A (en) * | 1928-08-11 | 1930-08-28 | Ver Fuer Chemische Ind Ag | Process and apparatus for saponification of cellulose acetate solutions |
| GB329704A (en) * | 1929-02-25 | 1930-05-26 | Rhone Poulenc Sa | Manufacture of cellulose esters |
| GB356012A (en) * | 1929-10-22 | 1931-09-03 | Kodak Ltd | Improvements relating to the manufacture of cellulose esters |
| US1984147A (en) * | 1929-10-22 | 1934-12-11 | Eastman Kodak Co | Process for the production of cellulose esters and corresponding alkyl esters |
| US1880560A (en) * | 1929-12-14 | 1932-10-04 | Eastman Kodak Co | Process for the hydrolysis of cellulose acetate |
| GB398626A (en) * | 1931-07-17 | 1933-09-21 | Kodak Ltd | Improved treatment of mixed organic esters of cellulose |
| US2026583A (en) * | 1931-07-17 | 1936-01-07 | Eastman Kodak Co | Process of changing the solubility of mixed esters of cellulose and the product resulting therefrom |
| US2005383A (en) * | 1932-02-20 | 1935-06-18 | Eastman Kodak Co | Hydrolysis of cellulose esters |
| US2129052A (en) * | 1936-02-04 | 1938-09-06 | Eastman Kodak Co | Hydrolyzed cellulose acetate |
| GB488946A (en) * | 1937-01-18 | 1938-07-18 | Henry Dreyfus | Improvements in the manufacture and treatment of fibres, yarns, fabrics, films and like materials having a basis of an organic ester of cellulose |
| GB496065A (en) * | 1937-06-07 | 1938-11-24 | Ig Farbenindustrie Ag | Manufacture of improved cellulose esters |
| US2327770A (en) * | 1940-11-23 | 1943-08-24 | Eastman Kodak Co | Method of preparing far-hydrolyzed cellulose esters |
| GB568932A (en) * | 1943-07-30 | 1945-04-26 | John Guilfoyle Williams | Improvements in or relating to the manufacture of cellulose esters |
| GB581157A (en) * | 1944-03-09 | 1946-10-02 | British Celanese | Improvements in or relating to the production of organic esters of cellulose |
| US2448082A (en) * | 1945-05-03 | 1948-08-31 | Celanese Corp | Recovery of water-soluble cellulose esters |
| US2470191A (en) * | 1945-12-06 | 1949-05-17 | Celanese Corp | Rapid ripening of cellulose esters |
| GB696903A (en) * | 1950-08-03 | 1953-09-09 | Courtaulds Ltd | Improvements in and relating to the production of cellulose acetate |
| GB755018A (en) * | 1952-10-31 | 1956-08-15 | Rhodiaceta | Improvements in or relating to the continuous hydrolysis of esters in homogeneous phase and apparatus therefor |
| FR1143485A (fr) * | 1953-06-05 | 1957-10-01 | Procédé de saponification des triesters de cellulose | |
| US2801239A (en) * | 1954-06-07 | 1957-07-30 | Eastman Kodak Co | Method of hydrolyzing cellulose esters |
| US2836590A (en) * | 1955-05-05 | 1958-05-27 | Hercules Powder Co Ltd | Method for partial deacylation of organic acid esters of cellulose |
| US3482011A (en) * | 1965-12-02 | 1969-12-02 | Celanese Corp | Process for producing water-soluble cellulose acetate fibers |
| JPS6017441B2 (ja) * | 1981-07-10 | 1985-05-02 | ダイセル化学工業株式会社 | 新規なセルロ−スアセテ−トの製造方法 |
| DE3246417C2 (de) * | 1982-12-15 | 1987-04-09 | Akzo Gmbh, 5600 Wuppertal | Wasserunlösliche Fasern aus Celluloseacetat, Cellulosepropionat und Cellulosebutyrat mit einem extrem hohen Absorptionsvermögen für Wasser und physiologische Flüssigkeiten |
| US4480090A (en) * | 1983-10-21 | 1984-10-30 | Eastman Kodak Company | Process for esterification of cellulose using as the catalyst the combination of sulfuric acid, phosphoric acid and a hindered aliphatic alcohol |
-
1991
- 1991-04-09 ES ES91908408T patent/ES2088003T3/es not_active Expired - Lifetime
- 1991-04-09 WO PCT/US1991/002293 patent/WO1991016358A1/fr not_active Ceased
- 1991-04-09 DE DE69120360T patent/DE69120360T2/de not_active Expired - Fee Related
- 1991-04-09 EP EP91908408A patent/EP0477347B1/fr not_active Expired - Lifetime
- 1991-04-09 AT AT91908408T patent/ATE139544T1/de not_active IP Right Cessation
- 1991-04-09 CA CA002059130A patent/CA2059130C/fr not_active Expired - Fee Related
- 1991-04-09 JP JP50800691A patent/JP3315980B2/ja not_active Expired - Lifetime
- 1991-04-09 DK DK91908408.7T patent/DK0477347T3/da active
- 1991-04-09 KR KR1019910701871A patent/KR100205465B1/ko not_active Expired - Fee Related
-
1994
- 1994-03-04 US US08/206,236 patent/US5597912A/en not_active Expired - Lifetime
-
1996
- 1996-08-22 GR GR960402204T patent/GR3020847T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0477347B1 (fr) | 1996-06-19 |
| US5597912A (en) | 1997-01-28 |
| EP0477347A1 (fr) | 1992-04-01 |
| ES2088003T3 (es) | 1996-08-01 |
| DK0477347T3 (da) | 1996-07-15 |
| DE69120360T2 (de) | 1996-10-31 |
| WO1991016358A1 (fr) | 1991-10-31 |
| KR920702693A (ko) | 1992-10-06 |
| JPH05501129A (ja) | 1993-03-04 |
| ATE139544T1 (de) | 1996-07-15 |
| DE69120360D1 (de) | 1996-07-25 |
| CA2059130C (fr) | 1999-05-11 |
| JP3315980B2 (ja) | 2002-08-19 |
| GR3020847T3 (en) | 1996-11-30 |
| KR100205465B1 (ko) | 1999-07-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |