CA1295364C - Piles alcalines rechargeables a cathode de manganese et anode de zinc - Google Patents
Piles alcalines rechargeables a cathode de manganese et anode de zincInfo
- Publication number
- CA1295364C CA1295364C CA000571629A CA571629A CA1295364C CA 1295364 C CA1295364 C CA 1295364C CA 000571629 A CA000571629 A CA 000571629A CA 571629 A CA571629 A CA 571629A CA 1295364 C CA1295364 C CA 1295364C
- Authority
- CA
- Canada
- Prior art keywords
- cathode
- rechargeable
- alkaline
- electrochemical cell
- separator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011701 zinc Substances 0.000 title claims abstract description 37
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 18
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title abstract description 6
- 239000011572 manganese Substances 0.000 title abstract description 6
- 229910052748 manganese Inorganic materials 0.000 title abstract description 6
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003792 electrolyte Substances 0.000 claims abstract description 19
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 19
- 239000001301 oxygen Substances 0.000 claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011230 binding agent Substances 0.000 claims abstract description 11
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 7
- 239000010439 graphite Substances 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 24
- 239000011787 zinc oxide Substances 0.000 claims description 11
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 230000002787 reinforcement Effects 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 210000004027 cell Anatomy 0.000 description 28
- 229960001296 zinc oxide Drugs 0.000 description 9
- 239000000843 powder Substances 0.000 description 8
- 210000001787 dendrite Anatomy 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000004568 cement Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 229910018663 Mn O Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000001351 cycling effect Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical class O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 150000008360 acrylonitriles Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 235000019256 formaldehyde Nutrition 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- 230000000153 supplemental effect Effects 0.000 description 2
- -1 vinyl alcohols Chemical class 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910003307 Ni-Cd Inorganic materials 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000779 depleting effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000037427 ion transport Effects 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/34—Gastight accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/429—Natural polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0014—Alkaline electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/44—Fibrous material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000571629A CA1295364C (fr) | 1988-07-08 | 1988-07-08 | Piles alcalines rechargeables a cathode de manganese et anode de zinc |
| US07/234,926 US4957827A (en) | 1988-07-08 | 1988-08-22 | Rechargeable alkaline manganese cells with zinc anodes |
| PCT/US1989/002849 WO1990000818A1 (fr) | 1988-07-08 | 1989-06-26 | Piles alcalines rechargeables au manganese a anodes en zinc |
| EP89908311A EP0389578A1 (fr) | 1988-07-08 | 1989-06-26 | Piles alcalines rechargeables au manganese a anodes en zinc |
| AU38789/89A AU3878989A (en) | 1988-07-08 | 1989-06-26 | Rechargeable alkaline manganese cells with zinc anodes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000571629A CA1295364C (fr) | 1988-07-08 | 1988-07-08 | Piles alcalines rechargeables a cathode de manganese et anode de zinc |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1295364C true CA1295364C (fr) | 1992-02-04 |
Family
ID=4138349
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000571629A Expired - Fee Related CA1295364C (fr) | 1988-07-08 | 1988-07-08 | Piles alcalines rechargeables a cathode de manganese et anode de zinc |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4957827A (fr) |
| CA (1) | CA1295364C (fr) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5108852A (en) * | 1990-03-23 | 1992-04-28 | Battery Technologies Inc. | Manganese dioxide cathode for a rechargeable alkaline cell, and cell containing the same |
| US5340666A (en) * | 1991-03-11 | 1994-08-23 | Battery Technologies Inc. | Rechargeable alkaline manganese cell having improved capacity and improved energy density |
| US5244754A (en) * | 1991-06-04 | 1993-09-14 | Display Matrix Corporation | Battery charge indicator |
| HUT67932A (en) * | 1991-12-19 | 1995-05-29 | Environmental Batteries System | Alkaline manganese dioxide cell of low mercury content or withot mercury |
| AU1333792A (en) * | 1992-03-09 | 1993-10-05 | Battery Technologies Inc. | High capacity rechargeable cell having manganese dioxide electrode |
| US5424145A (en) * | 1992-03-18 | 1995-06-13 | Battery Technologies Inc. | High capacity rechargeable cell having manganese dioxide electrode |
| US5312457A (en) * | 1992-07-01 | 1994-05-17 | Kerr-Mcgee Chemical Corporation | Use of hydroquinone to precondition manganese dioxide for use in rechargeable electrochemical cells |
| US5324332A (en) * | 1992-10-30 | 1994-06-28 | Rayovac Corporation | Alkaline manganese dioxide cells |
| US5543702A (en) * | 1993-02-08 | 1996-08-06 | Jdp Innovations, Inc. | Alkaline battery charging method and battery charger |
| JP3359164B2 (ja) * | 1994-10-19 | 2002-12-24 | キヤノン株式会社 | 二次電池 |
| US6472103B1 (en) | 1997-08-01 | 2002-10-29 | The Gillette Company | Zinc-based electrode particle form |
| US6521378B2 (en) | 1997-08-01 | 2003-02-18 | Duracell Inc. | Electrode having multi-modal distribution of zinc-based particles |
| US6833217B2 (en) * | 1997-12-31 | 2004-12-21 | Duracell Inc. | Battery cathode |
| US6126704A (en) * | 1998-08-27 | 2000-10-03 | Duracell Inc. | Method of forming a terminal pip protrusion on the casing of an alkaline cell |
| JP2002538584A (ja) | 1999-02-26 | 2002-11-12 | ザ ジレット カンパニー | 高性能アルカリ蓄電池 |
| US6258132B1 (en) | 1999-04-27 | 2001-07-10 | Eveready Battery Company, Inc. | Process for producing in an alkaline cell an in situ silver layer on a cathode container |
| RU2183877C2 (ru) * | 1999-08-27 | 2002-06-20 | Закрытое акционерное общество "ЭЛЛИТ ХОЛДИНГ" | Электрохимический конденсатор с двойным электрическим слоем |
| KR20030060883A (ko) | 2000-08-29 | 2003-07-16 | 유니버셜 리소시즈 에이지 | 전기화학적 이중층 캐패시터 |
| SG104277A1 (en) * | 2001-09-24 | 2004-06-21 | Inst Of Microelectronics | Circuit for measuring changes in capacitor gap using a switched capacitor technique |
| WO2004114442A2 (fr) * | 2003-06-17 | 2004-12-29 | The Gillette Company | Accumulateur d'anode |
| KR100515356B1 (ko) * | 2003-06-19 | 2005-09-15 | 삼성에스디아이 주식회사 | 이차 전지 및 이의 안전변 제조 방법 |
| RU2296383C2 (ru) * | 2004-12-23 | 2007-03-27 | Сергей Николаевич Разумов | Электрохимический конденсатор |
| US7776471B2 (en) * | 2005-04-15 | 2010-08-17 | Rocket Electric Co., Ltd. | Electrode of ultra thin manganese battery and manufacturing method therefor |
| CA2886256C (fr) | 2012-02-21 | 2019-04-02 | Research Foundation Of The City University Of New York | Methodologie de fonctionnement de batterie alcaline |
| US20150311503A1 (en) | 2012-11-09 | 2015-10-29 | Research Foundation Of The City University Of New York | Secondary Zinc-Manganese Dioxide Batteries for High Power Applications |
| AU2015333767B2 (en) | 2014-10-13 | 2020-10-01 | Research Foundation Of The City University Of New York | Mixed material cathode for secondary alkaline batteries |
| US11152615B2 (en) | 2015-10-29 | 2021-10-19 | Research Foundation Of The City University Of New York | Electrode designs for high energy density, efficiency, and capacity in rechargeable alkaline batteries |
| WO2017160691A1 (fr) * | 2016-03-14 | 2017-09-21 | Urban Electric Power Inc | Accumulateur à grande efficacité de recharge et bonne stabilité à long terme |
| CN106571461B (zh) * | 2016-09-29 | 2019-01-25 | 中山大学 | 一种长寿命、可充放的Zn-MnO2电池及其应用 |
| US11335918B2 (en) | 2016-10-21 | 2022-05-17 | Form Energy, Inc. | Corrugated fuel electrode |
| WO2019133702A1 (fr) | 2017-12-29 | 2019-07-04 | Staq Energy, Inc. | Batteries secondaires alcalines scellées à longue durée de vie |
| CA3105128A1 (fr) | 2018-07-27 | 2020-01-30 | Form Energy, Inc. | Electrodes negatives pour cellules electrochimiques |
| US12294086B2 (en) | 2019-07-26 | 2025-05-06 | Form Energy, Inc. | Low cost metal electrodes |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1274101A (en) * | 1968-08-08 | 1972-05-10 | Matsushita Electric Industrial Co Ltd | Dry cells |
| US3888699A (en) * | 1970-07-29 | 1975-06-10 | Union Carbide Corp | Primary dry cell |
| US3945847A (en) * | 1971-12-28 | 1976-03-23 | Union Carbide Corporation | Coherent manganese dioxide electrodes, process for their production, and electrochemical cells utilizing them |
| US4011103A (en) * | 1976-03-29 | 1977-03-08 | Union Carbide Corporation | Cathode contact member for alkaline round cells |
| IL50024A (en) * | 1976-07-12 | 1979-05-31 | Israel State | Secondary cells |
| US4091178A (en) * | 1977-09-01 | 1978-05-23 | Union Carbide Corporation | Rechargeable alkaline MnO2 -zinc cell |
| DE3026065A1 (de) * | 1980-07-10 | 1982-02-04 | Varta Batterie Ag, 3000 Hannover | Wiederaufladbares galvanisches element |
-
1988
- 1988-07-08 CA CA000571629A patent/CA1295364C/fr not_active Expired - Fee Related
- 1988-08-22 US US07/234,926 patent/US4957827A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US4957827A (en) | 1990-09-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |