CA1267979A - Collector composition for froth flotation - Google Patents

Collector composition for froth flotation

Info

Publication number: CA1267979A
Authority: CA; Canada
Prior art keywords: sulfide; alkyl; metal; composition; hydrocarbon
Prior art date: 1985-07-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

CA000501881A

Other languages

English (en)

French (fr)

Inventor

Richard R. Klimpel

Robert D. Hansen

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Dow Chemical Co

Original Assignee

Dow Chemical Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-07-12

Filing date

1986-02-14

Publication date

1990-04-17

1986-02-14 Application filed by Dow Chemical Co filed Critical Dow Chemical Co

1990-04-17 Application granted granted Critical

1990-04-17 Publication of CA1267979A publication Critical patent/CA1267979A/en

2007-04-17 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 67
238000009291 froth flotation Methods 0.000 title claims abstract description 21
125000000217 alkyl group Chemical group 0.000 claims abstract description 62
229910052751 metal Inorganic materials 0.000 claims abstract description 57
239000002184 metal Substances 0.000 claims abstract description 57
229910052569 sulfide mineral Inorganic materials 0.000 claims abstract description 45
229930195733 hydrocarbon Natural products 0.000 claims abstract description 36
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 35
229910052592 oxide mineral Inorganic materials 0.000 claims abstract description 30
238000000034 method Methods 0.000 claims abstract description 24
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 21
230000008569 process Effects 0.000 claims abstract description 21
229910052799 carbon Inorganic materials 0.000 claims abstract description 19
125000001931 aliphatic group Chemical group 0.000 claims abstract description 18
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
229910052717 sulfur Inorganic materials 0.000 claims abstract description 14
239000002245 particle Substances 0.000 claims abstract description 12
RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 claims abstract description 12
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
230000002209 hydrophobic effect Effects 0.000 claims abstract description 9
125000004434 sulfur atom Chemical group 0.000 claims abstract description 7
-1 hydrocarbon sulfide Chemical class 0.000 claims description 56
239000010949 copper Substances 0.000 claims description 25
238000005188 flotation Methods 0.000 claims description 23
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 16
229910052802 copper Inorganic materials 0.000 claims description 16
125000004093 cyano group Chemical group *C#N 0.000 claims description 16
125000004356 hydroxy functional group Chemical group O* 0.000 claims description 15
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical group CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 14
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 13
125000003342 alkenyl group Chemical group 0.000 claims description 13
125000003118 aryl group Chemical group 0.000 claims description 13
239000011133 lead Substances 0.000 claims description 13
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
239000011701 zinc Substances 0.000 claims description 12
125000003710 aryl alkyl group Chemical group 0.000 claims description 9
125000000753 cycloalkyl group Chemical group 0.000 claims description 9
125000000623 heterocyclic group Chemical group 0.000 claims description 8
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
125000002877 alkyl aryl group Chemical group 0.000 claims description 7
229910052750 molybdenum Inorganic materials 0.000 claims description 7
229910052759 nickel Inorganic materials 0.000 claims description 7
229910052725 zinc Inorganic materials 0.000 claims description 7
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
125000000304 alkynyl group Chemical group 0.000 claims description 6
239000011651 chromium Substances 0.000 claims description 6
125000000392 cycloalkenyl group Chemical group 0.000 claims description 6
125000001183 hydrocarbyl group Chemical group 0.000 claims description 6
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
239000011733 molybdenum Substances 0.000 claims description 6
229910052709 silver Inorganic materials 0.000 claims description 6
125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 5
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
229910052770 Uranium Inorganic materials 0.000 claims description 5
229910052804 chromium Inorganic materials 0.000 claims description 5
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 5
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical class OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 claims description 4
229910052951 chalcopyrite Inorganic materials 0.000 claims description 4
DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 claims description 4
125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 claims description 4
229910052739 hydrogen Inorganic materials 0.000 claims description 4
239000001257 hydrogen Substances 0.000 claims description 4
XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 4
229910052954 pentlandite Inorganic materials 0.000 claims description 4
239000004332 silver Substances 0.000 claims description 4
229910052708 sodium Inorganic materials 0.000 claims description 4
239000011734 sodium Substances 0.000 claims description 4
239000012989 trithiocarbonate Substances 0.000 claims description 4
229910052783 alkali metal Inorganic materials 0.000 claims description 3
229910052948 bornite Inorganic materials 0.000 claims description 3
150000001721 carbon Chemical group 0.000 claims description 3
125000004122 cyclic group Chemical group 0.000 claims description 3
229910052949 galena Inorganic materials 0.000 claims description 3
229910052961 molybdenite Inorganic materials 0.000 claims description 3
229910052760 oxygen Inorganic materials 0.000 claims description 3
125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
229910052785 arsenic Inorganic materials 0.000 claims description 2
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 2
229910017052 cobalt Inorganic materials 0.000 claims description 2
239000010941 cobalt Substances 0.000 claims description 2
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
229910052737 gold Inorganic materials 0.000 claims description 2
239000010931 gold Substances 0.000 claims description 2
229910052697 platinum Inorganic materials 0.000 claims description 2
229910052950 sphalerite Inorganic materials 0.000 claims description 2
125000001475 halogen functional group Chemical group 0.000 claims 6
125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 1
NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 claims 1
229910000037 hydrogen sulfide Inorganic materials 0.000 claims 1
238000011084 recovery Methods 0.000 abstract description 32
229910052500 inorganic mineral Inorganic materials 0.000 description 49
235000010755 mineral Nutrition 0.000 description 49
239000011707 mineral Substances 0.000 description 49
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
239000000306 component Substances 0.000 description 15
239000012990 dithiocarbamate Substances 0.000 description 12
239000012141 concentrate Substances 0.000 description 11
235000008504 concentrate Nutrition 0.000 description 11
125000005843 halogen group Chemical group 0.000 description 11
WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 8
229910052742 iron Inorganic materials 0.000 description 8
239000007787 solid Substances 0.000 description 8
239000007789 gas Substances 0.000 description 7
235000008733 Citrus aurantifolia Nutrition 0.000 description 6
235000011941 Tilia x europaea Nutrition 0.000 description 6
239000004571 lime Substances 0.000 description 6
239000007788 liquid Substances 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000011593 sulfur Substances 0.000 description 6
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
235000016768 molybdenum Nutrition 0.000 description 5
229910052700 potassium Inorganic materials 0.000 description 5
235000007686 potassium Nutrition 0.000 description 5
239000011591 potassium Substances 0.000 description 5
229960003975 potassium Drugs 0.000 description 5
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
238000013019 agitation Methods 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
239000000463 material Substances 0.000 description 4
YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 4
239000012991 xanthate Substances 0.000 description 4
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
150000001335 aliphatic alkanes Chemical class 0.000 description 3
238000003556 assay Methods 0.000 description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
150000001924 cycloalkanes Chemical class 0.000 description 3
150000001925 cycloalkenes Chemical class 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
150000004659 dithiocarbamates Chemical class 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
HYWYRSMBCFDLJT-UHFFFAOYSA-N nimesulide Chemical compound CS(=O)(=O)NC1=CC=C([N+]([O-])=O)C=C1OC1=CC=CC=C1 HYWYRSMBCFDLJT-UHFFFAOYSA-N 0.000 description 3
229960000965 nimesulide Drugs 0.000 description 3
239000002002 slurry Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
150000003568 thioethers Chemical class 0.000 description 3
FOJGPFUFFHWGFQ-UHFFFAOYSA-N 1-(Methylthio)pentane Chemical compound CCCCCSC FOJGPFUFFHWGFQ-UHFFFAOYSA-N 0.000 description 2
VSSRSPLEFYQIEK-UHFFFAOYSA-N 1-ethylsulfanyldecane Chemical compound CCCCCCCCCCSCC VSSRSPLEFYQIEK-UHFFFAOYSA-N 0.000 description 2
PYPULUCCVXMPFP-UHFFFAOYSA-N 1-ethylsulfanylheptane Chemical compound CCCCCCCSCC PYPULUCCVXMPFP-UHFFFAOYSA-N 0.000 description 2
MGVUJBCOCITTRS-UHFFFAOYSA-N 1-ethylsulfanylhexane Chemical group CCCCCCSCC MGVUJBCOCITTRS-UHFFFAOYSA-N 0.000 description 2
LUAABLIRQSWMGZ-UHFFFAOYSA-N 1-ethylsulfanylnonane Chemical compound CCCCCCCCCSCC LUAABLIRQSWMGZ-UHFFFAOYSA-N 0.000 description 2
WAITXWGCJQLPGH-UHFFFAOYSA-N 1-ethylsulfanyloctane Chemical compound CCCCCCCCSCC WAITXWGCJQLPGH-UHFFFAOYSA-N 0.000 description 2
LHNRHYOMDUJLLM-UHFFFAOYSA-N 1-hexylsulfanylhexane Chemical compound CCCCCCSCCCCCC LHNRHYOMDUJLLM-UHFFFAOYSA-N 0.000 description 2
HKGUUZAACYBIID-UHFFFAOYSA-N 1-methylsulfanyldecane Chemical compound CCCCCCCCCCSC HKGUUZAACYBIID-UHFFFAOYSA-N 0.000 description 2
FJDWJOQOEZRIDJ-UHFFFAOYSA-N 1-methylsulfanylheptane Chemical compound CCCCCCCSC FJDWJOQOEZRIDJ-UHFFFAOYSA-N 0.000 description 2
LZRXQHHKXDXOIC-UHFFFAOYSA-N 1-methylsulfanylhexane Chemical compound CCCCCCSC LZRXQHHKXDXOIC-UHFFFAOYSA-N 0.000 description 2
FCRSULZJMFDBIK-UHFFFAOYSA-N 1-methylsulfanylnonane Chemical compound CCCCCCCCCSC FCRSULZJMFDBIK-UHFFFAOYSA-N 0.000 description 2
AHCJTMBRROLNHV-UHFFFAOYSA-N 1-methylsulfanyloctane Chemical compound CCCCCCCCSC AHCJTMBRROLNHV-UHFFFAOYSA-N 0.000 description 2
LOXRGHGHQYWXJK-UHFFFAOYSA-N 1-octylsulfanyloctane Chemical compound CCCCCCCCSCCCCCCCC LOXRGHGHQYWXJK-UHFFFAOYSA-N 0.000 description 2
JOZDADPMWLVEJK-UHFFFAOYSA-N 1-pentylsulfanylpentane Chemical compound CCCCCSCCCCC JOZDADPMWLVEJK-UHFFFAOYSA-N 0.000 description 2
DUNFQSVAOIAQPH-UHFFFAOYSA-N 2-methylpropoxymethanethioic s-acid Chemical compound CC(C)COC(S)=O DUNFQSVAOIAQPH-UHFFFAOYSA-N 0.000 description 2
241001279686 Allium moly Species 0.000 description 2
HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 2
229910002555 FeNi Inorganic materials 0.000 description 2
ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
241000212342 Sium Species 0.000 description 2
238000003723 Smelting Methods 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
150000001345 alkine derivatives Chemical class 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
230000003750 conditioning effect Effects 0.000 description 2
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
229910052745 lead Inorganic materials 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
229910052976 metal sulfide Inorganic materials 0.000 description 2
150000002894 organic compounds Chemical class 0.000 description 2
QWENMOXLTHDKDL-UHFFFAOYSA-N pentoxymethanedithioic acid Chemical compound CCCCCOC(S)=S QWENMOXLTHDKDL-UHFFFAOYSA-N 0.000 description 2
235000011007 phosphoric acid Nutrition 0.000 description 2
239000010665 pine oil Substances 0.000 description 2
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
229910052952 pyrrhotite Inorganic materials 0.000 description 2
238000000926 separation method Methods 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
235000017550 sodium carbonate Nutrition 0.000 description 2
RFKHZOHSRQNNPW-UHFFFAOYSA-M sodium;pentoxymethanedithioate Chemical compound [Na+].CCCCCOC([S-])=S RFKHZOHSRQNNPW-UHFFFAOYSA-M 0.000 description 2
229910052959 stibnite Inorganic materials 0.000 description 2
WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical group [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
229910052718 tin Inorganic materials 0.000 description 2
239000011135 tin Substances 0.000 description 2
XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
239000010936 titanium Substances 0.000 description 2
229910052719 titanium Inorganic materials 0.000 description 2
229910000442 triuranium octoxide Inorganic materials 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical class C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 1
BGPJLYIFDLICMR-UHFFFAOYSA-N 1,4,2,3-dioxadithiolan-5-one Chemical compound O=C1OSSO1 BGPJLYIFDLICMR-UHFFFAOYSA-N 0.000 description 1
CLBLVLKZMJDLOT-UHFFFAOYSA-N 1-butylsulfanyldecane Chemical compound CCCCCCCCCCSCCCC CLBLVLKZMJDLOT-UHFFFAOYSA-N 0.000 description 1
BGSBXDJLUNXANY-UHFFFAOYSA-N 1-butylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCC BGSBXDJLUNXANY-UHFFFAOYSA-N 0.000 description 1
HYUPOCGXBZUYFY-UHFFFAOYSA-N 1-butylsulfanylheptane Chemical compound CCCCCCCSCCCC HYUPOCGXBZUYFY-UHFFFAOYSA-N 0.000 description 1
YZUHMAFUXBPUKH-UHFFFAOYSA-N 1-butylsulfanylhexane Chemical compound CCCCCCSCCCC YZUHMAFUXBPUKH-UHFFFAOYSA-N 0.000 description 1
FWRIVMHSSSZAFD-UHFFFAOYSA-N 1-butylsulfanylnonane Chemical compound CCCCCCCCCSCCCC FWRIVMHSSSZAFD-UHFFFAOYSA-N 0.000 description 1
UNIAPWPIAGJFDG-UHFFFAOYSA-N 1-butylsulfanyloctane Chemical compound CCCCCCCCSCCCC UNIAPWPIAGJFDG-UHFFFAOYSA-N 0.000 description 1
RNEUXBDXTNIASG-UHFFFAOYSA-N 1-butylsulfanylpentane Chemical compound CCCCCSCCCC RNEUXBDXTNIASG-UHFFFAOYSA-N 0.000 description 1
LVTHBOGDYURNJG-UHFFFAOYSA-N 1-butylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCC LVTHBOGDYURNJG-UHFFFAOYSA-N 0.000 description 1
RKYMVQJWYYOIJB-UHFFFAOYSA-N 1-decylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCCCC RKYMVQJWYYOIJB-UHFFFAOYSA-N 0.000 description 1
XLWHZUYTRGNUML-UHFFFAOYSA-N 1-decylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCCC XLWHZUYTRGNUML-UHFFFAOYSA-N 0.000 description 1
KISJDFYRGLOOKC-UHFFFAOYSA-N 1-decylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCCCCCC KISJDFYRGLOOKC-UHFFFAOYSA-N 0.000 description 1
XJIRSLHMKBUGMR-UHFFFAOYSA-N 1-ethylsulfanylbutane Chemical compound CCCCSCC XJIRSLHMKBUGMR-UHFFFAOYSA-N 0.000 description 1
QECBTJWQRXCSCU-UHFFFAOYSA-N 1-ethylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCC QECBTJWQRXCSCU-UHFFFAOYSA-N 0.000 description 1
OSWITQLVZPPUIR-UHFFFAOYSA-N 1-ethylsulfanylundecane Chemical compound CCCCCCCCCCCSCC OSWITQLVZPPUIR-UHFFFAOYSA-N 0.000 description 1
HYNUNWWVWIDFNI-UHFFFAOYSA-N 1-heptylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCC HYNUNWWVWIDFNI-UHFFFAOYSA-N 0.000 description 1
BMONIUVCBPWHMH-UHFFFAOYSA-N 1-heptylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCC BMONIUVCBPWHMH-UHFFFAOYSA-N 0.000 description 1
LEMIDOZYVQXGLI-UHFFFAOYSA-N 1-heptylsulfanylheptane Chemical compound CCCCCCCSCCCCCCC LEMIDOZYVQXGLI-UHFFFAOYSA-N 0.000 description 1
RGMJJEGCPWGPIO-UHFFFAOYSA-N 1-heptylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCC RGMJJEGCPWGPIO-UHFFFAOYSA-N 0.000 description 1
YIQMNWHXSGQHED-UHFFFAOYSA-N 1-heptylsulfanyloctane Chemical compound CCCCCCCCSCCCCCCC YIQMNWHXSGQHED-UHFFFAOYSA-N 0.000 description 1
VOSRYWCOCVSNOU-UHFFFAOYSA-N 1-heptylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCCC VOSRYWCOCVSNOU-UHFFFAOYSA-N 0.000 description 1
AHFXEIBVMODMFA-UHFFFAOYSA-N 1-hexylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCC AHFXEIBVMODMFA-UHFFFAOYSA-N 0.000 description 1
UUGCJTQYUMVCAB-UHFFFAOYSA-N 1-hexylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCC UUGCJTQYUMVCAB-UHFFFAOYSA-N 0.000 description 1
MPSAONKRRWETTC-UHFFFAOYSA-N 1-hexylsulfanylheptane Chemical compound CCCCCCCSCCCCCC MPSAONKRRWETTC-UHFFFAOYSA-N 0.000 description 1
OSCWDJOYYNCZON-UHFFFAOYSA-N 1-hexylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCC OSCWDJOYYNCZON-UHFFFAOYSA-N 0.000 description 1
LENOFRMWVZUVHH-UHFFFAOYSA-N 1-hexylsulfanylundecane Chemical compound CCCCCCCCCCCSCCCCCC LENOFRMWVZUVHH-UHFFFAOYSA-N 0.000 description 1
WCXXISMIJBRDQK-UHFFFAOYSA-N 1-methylsulfanylbutane Chemical compound CCCCSC WCXXISMIJBRDQK-UHFFFAOYSA-N 0.000 description 1
KJWHJDGMOQJLGF-UHFFFAOYSA-N 1-methylsulfanyldodecane Chemical compound CCCCCCCCCCCCSC KJWHJDGMOQJLGF-UHFFFAOYSA-N 0.000 description 1
HDOADYQJIBYVGE-UHFFFAOYSA-N 1-methylsulfanylundecane Chemical compound CCCCCCCCCCCSC HDOADYQJIBYVGE-UHFFFAOYSA-N 0.000 description 1
UWHYFRCJGNMMSJ-UHFFFAOYSA-N 1-nonylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCCC UWHYFRCJGNMMSJ-UHFFFAOYSA-N 0.000 description 1
ARGFAAQZPLNHAK-UHFFFAOYSA-N 1-nonylsulfanyldodecane Chemical compound CCCCCCCCCCCCSCCCCCCCCC ARGFAAQZPLNHAK-UHFFFAOYSA-N 0.000 description 1
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239000003607 modifier Substances 0.000 description 1
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HGPWSQKPCIYOSL-UHFFFAOYSA-N nonylsulfanylcyclohexane Chemical compound CCCCCCCCCSC1CCCCC1 HGPWSQKPCIYOSL-UHFFFAOYSA-N 0.000 description 1
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FFIIPKBXAWXOHB-UHFFFAOYSA-N octylsulfanylcyclooctane Chemical compound CCCCCCCCSC1CCCCCCC1 FFIIPKBXAWXOHB-UHFFFAOYSA-N 0.000 description 1
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GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
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QELIZJUXYUEORW-UHFFFAOYSA-N pentylsulfanylcycloheptane Chemical compound CCCCCSC1CCCCCC1 QELIZJUXYUEORW-UHFFFAOYSA-N 0.000 description 1
RKCRLYNCLIKFOM-UHFFFAOYSA-N pentylsulfanylcyclohexane Chemical compound CCCCCSC1CCCCC1 RKCRLYNCLIKFOM-UHFFFAOYSA-N 0.000 description 1
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WNVZCNDFBUPCTL-UHFFFAOYSA-M potassium;ethoxymethanethioate Chemical compound [K+].CCOC([O-])=S WNVZCNDFBUPCTL-UHFFFAOYSA-M 0.000 description 1
LTRSVXVWFXWPRZ-UHFFFAOYSA-M potassium;pentoxymethanethioate Chemical compound [K+].CCCCCOC([S-])=O LTRSVXVWFXWPRZ-UHFFFAOYSA-M 0.000 description 1
ZMWBGRXFDPJFGC-UHFFFAOYSA-M potassium;propan-2-yloxymethanedithioate Chemical compound [K+].CC(C)OC([S-])=S ZMWBGRXFDPJFGC-UHFFFAOYSA-M 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
HTEXOEMPGABQHS-UHFFFAOYSA-N propan-2-yloxymethanethioic s-acid Chemical compound CC(C)OC(S)=O HTEXOEMPGABQHS-UHFFFAOYSA-N 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
ZBXVHTJPXJLHKM-UHFFFAOYSA-N propylsulfanylcycloheptane Chemical compound CCCSC1CCCCCC1 ZBXVHTJPXJLHKM-UHFFFAOYSA-N 0.000 description 1
GRTPNKMNAOQMOK-UHFFFAOYSA-N propylsulfanylcyclohexane Chemical compound CCCSC1CCCCC1 GRTPNKMNAOQMOK-UHFFFAOYSA-N 0.000 description 1
RQCUQPZTBNLEHH-UHFFFAOYSA-N propylsulfanylcyclooctane Chemical compound CCCSC1CCCCCCC1 RQCUQPZTBNLEHH-UHFFFAOYSA-N 0.000 description 1
OJXDFADLRHATCY-UHFFFAOYSA-N propylsulfanylcyclopentane Chemical compound CCCSC1CCCC1 OJXDFADLRHATCY-UHFFFAOYSA-N 0.000 description 1
229910052683 pyrite Inorganic materials 0.000 description 1
NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
239000011028 pyrite Substances 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
239000010944 silver (metal) Substances 0.000 description 1
FSJWWSXPIWGYKC-UHFFFAOYSA-M silver;silver;sulfanide Chemical compound [SH-].[Ag].[Ag+] FSJWWSXPIWGYKC-UHFFFAOYSA-M 0.000 description 1
239000000344 soap Substances 0.000 description 1
MXWLPOQBCCHRIR-UHFFFAOYSA-M sodium bis(3-methylbutoxy)-oxido-sulfanylidene-lambda5-phosphane Chemical compound [Na+].CC(C)CCOP([O-])(=S)OCCC(C)C MXWLPOQBCCHRIR-UHFFFAOYSA-M 0.000 description 1
HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
229910052979 sodium sulfide Inorganic materials 0.000 description 1
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
DRWPVEQJXKTFFL-UHFFFAOYSA-M sodium;(4-methylphenoxy)-(4-methylphenyl)sulfanyl-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].C1=CC(C)=CC=C1OP([O-])(=S)SC1=CC=C(C)C=C1 DRWPVEQJXKTFFL-UHFFFAOYSA-M 0.000 description 1
FSFACTZWHMNCPB-UHFFFAOYSA-M sodium;2-methylpropylsulfanylmethanedithioate Chemical compound [Na+].CC(C)CSC([S-])=S FSFACTZWHMNCPB-UHFFFAOYSA-M 0.000 description 1
YZLQFRKSOZCHCJ-UHFFFAOYSA-M sodium;3-methylbutoxy-(3-methylbutylsulfanyl)-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CC(C)CCOP([O-])(=S)SCCC(C)C YZLQFRKSOZCHCJ-UHFFFAOYSA-M 0.000 description 1
VVTVDXPOGQYVFX-UHFFFAOYSA-M sodium;bis(2-methylpropoxy)-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CC(C)COP([O-])(=S)OCC(C)C VVTVDXPOGQYVFX-UHFFFAOYSA-M 0.000 description 1
FOYPFIDVYRCZKA-UHFFFAOYSA-M sodium;bis(2-methylpropoxy)-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Na+].CC(C)COP([S-])(=S)OCC(C)C FOYPFIDVYRCZKA-UHFFFAOYSA-M 0.000 description 1
PHLSTZGDRQZNJF-UHFFFAOYSA-M sodium;butan-2-yloxy-butan-2-ylsulfanyl-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CCC(C)OP([O-])(=S)SC(C)CC PHLSTZGDRQZNJF-UHFFFAOYSA-M 0.000 description 1
ZVLBYZQIYKVZEO-UHFFFAOYSA-M sodium;butan-2-ylsulfanylmethanethioate Chemical compound [Na+].CCC(C)SC([S-])=O ZVLBYZQIYKVZEO-UHFFFAOYSA-M 0.000 description 1
KZDRUTJVEBMGDR-UHFFFAOYSA-M sodium;di(butan-2-yloxy)-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CCC(C)OP([O-])(=S)OC(C)CC KZDRUTJVEBMGDR-UHFFFAOYSA-M 0.000 description 1
YMPPRYJBYFNJTO-UHFFFAOYSA-M sodium;diethoxy-oxido-sulfanylidene-$l^{5}-phosphane Chemical compound [Na+].CCOP([O-])(=S)OCC YMPPRYJBYFNJTO-UHFFFAOYSA-M 0.000 description 1
ZKDDJTYSFCWVGS-UHFFFAOYSA-M sodium;diethoxy-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Na+].CCOP([S-])(=S)OCC ZKDDJTYSFCWVGS-UHFFFAOYSA-M 0.000 description 1
SCEWVYKGCFYQDU-UHFFFAOYSA-M sodium;ethoxymethanethioate Chemical compound [Na+].CCOC([S-])=O SCEWVYKGCFYQDU-UHFFFAOYSA-M 0.000 description 1
VGZJEVUOJSBXEJ-UHFFFAOYSA-M sodium;ethylsulfanylmethanethioate Chemical compound [Na+].CCSC([S-])=O VGZJEVUOJSBXEJ-UHFFFAOYSA-M 0.000 description 1
UUCBWOHOAMHVSO-UHFFFAOYSA-M sodium;pentylsulfanylmethanethioate Chemical compound [Na+].CCCCCSC([S-])=O UUCBWOHOAMHVSO-UHFFFAOYSA-M 0.000 description 1
JEBXWAFOOSDQDR-UHFFFAOYSA-M sodium;propan-2-yloxymethanethioate Chemical compound [Na+].CC(C)OC([S-])=O JEBXWAFOOSDQDR-UHFFFAOYSA-M 0.000 description 1
XQTKKXWWPWOCPF-UHFFFAOYSA-M sodium;propan-2-ylsulfanylmethanethioate Chemical compound [Na+].CC(C)SC([S-])=O XQTKKXWWPWOCPF-UHFFFAOYSA-M 0.000 description 1
229910052596 spinel Inorganic materials 0.000 description 1
239000011029 spinel Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229910052970 tennantite Inorganic materials 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
229910052969 tetrahedrite Inorganic materials 0.000 description 1
125000000101 thioether group Chemical group 0.000 description 1
150000003585 thioureas Chemical class 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
GWBUNZLLLLDXMD-UHFFFAOYSA-H tricopper;dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Cu+2].[Cu+2].[Cu+2].[O-]C([O-])=O.[O-]C([O-])=O GWBUNZLLLLDXMD-UHFFFAOYSA-H 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
YIIYNAOHYJJBHT-UHFFFAOYSA-N uranium;dihydrate Chemical compound O.O.[U] YIIYNAOHYJJBHT-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910000010 zinc carbonate Inorganic materials 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/025—Precious metal ores

Landscapes

Manufacture And Refinement Of Metals (AREA)

CA000501881A 1985-07-12 1986-02-14 Collector composition for froth flotation Expired - Lifetime CA1267979A (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US75432885A	1985-07-12	1985-07-12
US754,328		1985-07-12

Publications (1)

Publication Number	Publication Date
CA1267979A true CA1267979A (en)	1990-04-17

Family

ID=25034323

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000501881A Expired - Lifetime CA1267979A (en)	1985-07-12	1986-02-14	Collector composition for froth flotation

Country Status (16)

Country	Link
CN (1)	CN1011945B (fi)
AU (1)	AU576422B2 (fi)
BR (1)	BR8606770A (fi)
CA (1)	CA1267979A (fi)
ES (1)	ES8706046A1 (fi)
FI (1)	FI81975C (fi)
MX (1)	MX165319B (fi)
PH (1)	PH22952A (fi)
PL (1)	PL148165B1 (fi)
RU (1)	RU1831373C (fi)
SE (1)	SE461256B (fi)
WO (1)	WO1987000451A1 (fi)
YU (1)	YU45767B (fi)
ZA (1)	ZA861172B (fi)
ZM (1)	ZM1386A1 (fi)
ZW (1)	ZW3986A1 (fi)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1268565A (en) *	1985-11-29	1990-05-01	Richard R. Klimpel	Collector compositions for the froth flotation of mineral values
US4904374A (en) *	1987-10-08	1990-02-27	Sentrachem Limited	Froth flotation
CN105344491B (zh) *	2015-09-30	2017-09-15	广西大学	一种锑金矿物捕收剂的制备方法
CN107442267B (zh) *	2017-07-28	2019-03-15	西部矿业股份有限公司	一种微细粒难选铁闪锌矿的浮选方法
WO2019075169A2 (en) *	2017-10-12	2019-04-18	Cytec Industries Inc.	METHODS OF RECOVERING BY FLOTATION OF VALUE MATERIAL FROM PARTICLES OF RUGGED SIZE
CN108435432B (zh) *	2018-04-03	2019-11-05	中南大学	一种用于高砷含碳黄铁矿型金矿浮选的组合浮选剂及其应用
CN108816521B (zh) *	2018-05-22	2019-10-08	中南大学	三羟基苯及其衍生物作为铋抑制剂在浮选过程中的应用
CN110280393A (zh) *	2019-06-09	2019-09-27	沈阳有研矿物化工有限公司	一种异丙基黄原酸丙炔酯及其制备方法
CN110280394A (zh) *	2019-06-09	2019-09-27	沈阳有研矿物化工有限公司	一种异戊基黄原酸丙炔酯及其制备方法
CN113680535B (zh) *	2021-08-24	2023-03-21	中南大学	一种烷基醚基二硫代磷酸盐捕收剂及其制备方法与应用
CN114011583B (zh) *	2021-11-09	2022-07-12	中国矿业大学(北京)	一种煤泥浮选剂及其制备方法
CN120243282B (zh) *	2025-05-29	2025-08-15	湖南明珠选矿药剂有限责任公司	一种铜钼矿用选矿药剂及其制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US1833740A (en) *	1926-03-19	1931-11-24	Peter C Reilly	Process of ore flotation
US1819112A (en) *	1929-04-22	1931-08-18	Nat Aniline & Chem Co Inc	Froth flotation of minerals
US2127375A (en) *	1935-07-17	1938-08-16	Du Pont	Esters of dithiocarbamic acids
US2169313A (en) *	1938-09-24	1939-08-15	Minerals Separation North Us	Concentration of metalliferous ores by flotation
US2691635A (en) *	1953-05-20	1954-10-12	Dow Chemical Co	Process for the manufacture of dialkyl thionocarbamates
AU509346B2 (en) *	1976-12-02	1980-05-08	The Dow Chemical Company	Forth flotation process
CA1105156A (en) *	1978-10-11	1981-07-14	William A. Rickelton	Flotation of sulfide minerals
ES8800077A1 (es) *	1985-05-31	1987-10-16	Dow Chemical Co	Un procedimiento para recuperar minerales de sulfuro, que contienen metales, o minerales de oxido sulfurados, que contienen metales, a partir de una mena

1986
- 1986-02-07 ZM ZM13/86A patent/ZM1386A1/xx unknown
- 1986-02-14 PH PH33417A patent/PH22952A/en unknown
- 1986-02-14 ES ES552028A patent/ES8706046A1/es not_active Expired
- 1986-02-14 CA CA000501881A patent/CA1267979A/en not_active Expired - Lifetime
- 1986-02-17 PL PL1986257992A patent/PL148165B1/pl unknown
- 1986-02-17 YU YU23186A patent/YU45767B/sh unknown
- 1986-02-17 ZW ZW39/86A patent/ZW3986A1/xx unknown
- 1986-02-17 MX MX001574A patent/MX165319B/es unknown
- 1986-02-17 CN CN86101646A patent/CN1011945B/zh not_active Expired
- 1986-02-17 ZA ZA861172A patent/ZA861172B/xx unknown
- 1986-02-18 WO PCT/US1986/000336 patent/WO1987000451A1/en not_active Ceased
- 1986-02-18 BR BR8606770A patent/BR8606770A/pt not_active IP Right Cessation
- 1986-02-18 AU AU55497/86A patent/AU576422B2/en not_active Expired
1987
- 1987-03-09 FI FI871017A patent/FI81975C/fi not_active IP Right Cessation
- 1987-03-11 SE SE8701018A patent/SE461256B/sv not_active IP Right Cessation
- 1987-03-11 RU SU4202192A patent/RU1831373C/ru active

Also Published As

Publication number	Publication date
FI81975C (fi)	1991-01-10
CN86101646A (zh)	1987-01-07
CN1011945B (zh)	1991-03-13
BR8606770A (pt)	1987-10-13
YU23186A (en)	1988-06-30
PL257992A1 (en)	1987-05-18
FI871017L (fi)	1987-03-09
MX165319B (es)	1992-11-05
RU1831373C (ru)	1993-07-30
ES8706046A1 (es)	1987-06-01
ZA861172B (en)	1987-10-28
AU576422B2 (en)	1988-08-25
PH22952A (en)	1989-02-03
SE8701018D0 (sv)	1987-03-11
ZM1386A1 (en)	1988-12-30
FI871017A0 (fi)	1987-03-09
SE8701018L (sv)	1987-03-11
YU45767B (sh)	1992-07-20
ZW3986A1 (en)	1987-09-09
SE461256B (sv)	1990-01-29
FI81975B (fi)	1990-09-28
ES552028A0 (es)	1987-06-01
PL148165B1 (en)	1989-09-30
AU5549786A (en)	1987-02-10
WO1987000451A1 (en)	1987-01-29

Publication	Publication Date	Title
AU576665B2 (en)	1988-09-01	Froth flotation of metal-containing sulphide minerals
US5057209A (en)	1991-10-15	Depression of the flotation of silica or siliceous gangue in mineral flotation
US4684459A (en)	1987-08-04	Collector compositions for the froth flotation of mineral values
EP0174866B1 (en)	1993-03-10	Novel collectors for the froth flotation of mineral values
CA2014882C (en)	1996-02-20	Depression of the flotation of silica or siliceous gangue in mineral flotation
US4797202A (en)	1989-01-10	Froth flotation method
AU660858B2 (en)	1995-07-06	Selective flotation process for separation of sulphide minerals
US4582596A (en)	1986-04-15	Frothers demonstrating enhanced recovery of coarse particles in froth floatation
AU588579B2 (en)	1989-09-21	Collector compositions for the froth flotation of mineral values
AU586471B2 (en)	1989-07-13	Collectors for froth flotation
CA1267979A (en)	1990-04-17	Collector composition for froth flotation
US4822483A (en)	1989-04-18	Collector compositions for the froth flotation of mineral values
US5126038A (en)	1992-06-30	Process for improved precious metals recovery from ores with the use of alkylhydroxamate collectors
US4676890A (en)	1987-06-30	Collector compositions for the froth flotation of mineral values
US4702822A (en)	1987-10-27	Novel collector composition for froth flotation
US4735711A (en)	1988-04-05	Novel collectors for the selective froth flotation of mineral sulfides
US4793852A (en)	1988-12-27	Process for the recovery of non-ferrous metal sulfides
US4511464A (en)	1985-04-16	1,3-Oxathiolane-2-thiones as sulfide mineral collectors in froth flotation
US4789392A (en)	1988-12-06	Froth flotation method
US4732668A (en)	1988-03-22	Novel collectors for the selective froth flotation of mineral sulfides
USRE32778E (en)	1988-11-08	Frothers demonstrating enhanced recovery of coarse particles in froth floatation
CA1271273A (en)	1990-07-03	Collectors for froth flotation of minerals
RU1837988C (ru)	1993-08-30	Способ извлечени ценных минералов
NO168991B (no)	1992-01-20	Samlerblanding for skumflotasjon av metallholdige mineraler
NO168992B (no)	1992-01-20	Fremgangsmaate for utvinning av metallholdige sulfidmineraler eller sulfifiserte metallholdige oksydmineraler fra enmalm

Legal Events

Date	Code	Title	Description
2007-04-17	MKEX	Expiry