CA1113898A - Coextruded laminar thermoplastic bags - Google Patents
Coextruded laminar thermoplastic bagsInfo
- Publication number
- CA1113898A CA1113898A CA318,490A CA318490A CA1113898A CA 1113898 A CA1113898 A CA 1113898A CA 318490 A CA318490 A CA 318490A CA 1113898 A CA1113898 A CA 1113898A
- Authority
- CA
- Canada
- Prior art keywords
- layer
- bag
- mil
- bags
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001169 thermoplastic Polymers 0.000 title abstract description 5
- 239000004416 thermosoftening plastic Substances 0.000 title abstract description 5
- -1 polypropylene Polymers 0.000 claims abstract description 12
- 239000004743 Polypropylene Substances 0.000 claims abstract description 9
- 229920001155 polypropylene Polymers 0.000 claims abstract description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- 229920005992 thermoplastic resin Polymers 0.000 claims description 5
- 239000004711 α-olefin Substances 0.000 claims description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 3
- 235000013305 food Nutrition 0.000 abstract description 7
- 229920001903 high density polyethylene Polymers 0.000 abstract description 2
- 239000004700 high-density polyethylene Substances 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 238000003303 reheating Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 3
- 238000010411 cooking Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 229940099514 low-density polyethylene Drugs 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 241000905957 Channa melasoma Species 0.000 description 1
- 229920001074 Tenite Polymers 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000021190 leftovers Nutrition 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D31/00—Bags or like containers made of paper and having structural provision for thickness of contents
- B65D31/02—Bags or like containers made of paper and having structural provision for thickness of contents with laminated walls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
- B32B2250/242—All polymers belonging to those covered by group B32B27/32
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/08—Dimensions, e.g. volume
- B32B2309/10—Dimensions, e.g. volume linear, e.g. length, distance, width
- B32B2309/105—Thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/04—Polyethylene
- B32B2323/043—HDPE, i.e. high density polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2323/00—Polyalkenes
- B32B2323/10—Polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/40—Closed containers
- B32B2439/46—Bags
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Wrappers (AREA)
- Bag Frames (AREA)
Abstract
ABSTRACT
A thermoplastic bag particularly adapted for the containment and storage of foods comprising a laminar bag structure having an interior layer of a high density polyethylene copolymer and an exterior layer of polypropylene. The layers are intimately and continu-ously bonded together at their interface. Such bag structures are suitable for the containment of food-stuffs while they are being heated or reheated following storage.
A thermoplastic bag particularly adapted for the containment and storage of foods comprising a laminar bag structure having an interior layer of a high density polyethylene copolymer and an exterior layer of polypropylene. The layers are intimately and continu-ously bonded together at their interface. Such bag structures are suitable for the containment of food-stuffs while they are being heated or reheated following storage.
Description
1~13~
COEXTRUDED LA~INAR THE~MOPLASTIC BAGS
The present invention relates to thermoplastic bag structures which have been fabricated from a thermo-plastlc fllm lamlnate comprising two layers of fllm whlch are formed from dissimilar thermoplastic resins.
In the past, polyethylene bags have been used for food storage and, in particular, refrigerated food stora~e. Such food container bags are particularly con-venient for the storage of food left-overs which may be lntended for later reheating. The bulk of such food storage bags have been formed from low den~ity, i.e.
0.91 to 0.93 g/cc, polyethylene. For reheating pur-poses foodstuffs must be removed from such low density polyethylene bags be¢ause of their tendency to partlally melt and adhere to the surfaces Or ¢ooking ve3sels at temperature~ on the order of 212F and below.
To remedy this deficiency of low density poly-ethylene bags, attempts have been made to employ polyester bags, such as polyethylene terephthalate, for such elevated temperature appllcations as "boil" bags, however such rilms are difficult to seal and more importantly are prohibitively expensive for such dispos-able bag applicationq.
~' `
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1~13B~3!B
COEXTRUDED LA~INAR THE~MOPLASTIC BAGS
The present invention relates to thermoplastic bag structures which have been fabricated from a thermo-plastlc fllm lamlnate comprising two layers of fllm whlch are formed from dissimilar thermoplastic resins.
In the past, polyethylene bags have been used for food storage and, in particular, refrigerated food stora~e. Such food container bags are particularly con-venient for the storage of food left-overs which may be lntended for later reheating. The bulk of such food storage bags have been formed from low den~ity, i.e.
0.91 to 0.93 g/cc, polyethylene. For reheating pur-poses foodstuffs must be removed from such low density polyethylene bags be¢ause of their tendency to partlally melt and adhere to the surfaces Or ¢ooking ve3sels at temperature~ on the order of 212F and below.
To remedy this deficiency of low density poly-ethylene bags, attempts have been made to employ polyester bags, such as polyethylene terephthalate, for such elevated temperature appllcations as "boil" bags, however such rilms are difficult to seal and more importantly are prohibitively expensive for such dispos-able bag applicationq.
~' `
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. ~ ;
:..
. .
.. : .. . . : .
. . . .. .
1~13B~3!B
-2-The present invention provides for an economi-cal thermoplastic bag which may be employed to contain roods during storage and, most importantly, may be used to contain such foods during reheating preparatory to serving. The bag structureq Or the present inventlon comprise a two layer laminar structure, the inner bag layer or that surrace layer in contact with the food-sturrs, being rormed from polyethylene and preferably a high density ethylene copolymer. The outer layer Or the bag laminate or that sur~ace Or the bag which comes into direct contact with the cooking vessel, comprises a ply Or relatively thin polypropylene film. The outer poly-propylene film layer maintainq the inner more thermally suscept~ble polyethylene layer out Or contact with the surraces Or the cooking vessel and hence improves the bag's ability to withstand higher temperaturea. The polypropylene layer, having a melting or sticking tem-perature on the order Or above 150C is stable and will not atick to the vesqel side walls while roodsturr~ are being reheated therein. Obviously the bag containing roodsturrs i~ intended to be immersed in a rluid such as water during the reheating operation. Accordingly, the present invention provide~ laminar bags for the optimum storage and containment of roodsturfs which may then be reheated without rirst removing them ~rom the bag. The bag ls oon~tru¢ted from a two-ply laminate comprislng an lnner rllm layer Or a high density ethylene/alpha-olefin copolymer and an outer layer Or polypropylene rilm. The hlgh density ethylene copolymer preferably comprises ethylene which has been copolymerized with a minor amount, on the order Or le~s than 10S, Or another alpha-olerin having rrom about 3 up to about 10 carbon atoms, for example octene-1.
~, , A tubular thermoplastic laminate waq prepared utilizing conventional blown tubular rilm coextrusion ~ . ~ ................. .
~::
,~
,, ~:: . - - : . .
. : , --- . .- . :
:,..................... , . .. -, .
: ~ . , - . . .
techniques whereby the final inner-tube layer comprised a 1.0 mil thick layer of high density polyethylene copolymer and a 0.2 mil thick outer layer o~ polypro-pylene. me continuous laminar tube was subsequently converted lnto bag ~tructures utilizing techniques well known in the prior art. The high den~ity polyethylene copolymer inner layer was a copolymer of ethylene and about 3% by weight of octene-1. This re~in is identi-fied by the manufacturer as ~Alathon 78lO"* and has the following typical physical properties for a 1.25 mil ~ilm extruded at a 4.3/1 blow-up ratio:
Density .945 g/cc Melt Index .25 g/10 min.
Tensile Yield (MD) 3000 psi ~
tTD) 3100 psi ~-Elongation (MD) 660%
(2n/min) 7~0S
Secant Modulus (MD~ 80M psi (TD) 82M psi Elmendorf Tear (MD) 45 gm/mil ~-(TD) 247 gm/mil ~
Spencer Impact 2.8 in. lbs/mil Dart Drop (26") 115 gm/mil Tear Propagation (MD) 3.2 Kg force ASTM D-2582 (TD) 3.7 Kg ~orce The propylene outer layer was fabricated from resin identified by the manu~acturer as ~Tenite 612 F"**
which has the ~ollowing typical physical properties:
Density .902 g/cc Flow Rate 4.5 g/10 min Tensile, Yield 5000 psi Vicat So~tening Point 145C ~, Trademark ** Trademark , .. .
~ - . . . . . . . . .
, : ; . - ' ,; , :: ,: .; ,, - ` : . ~:
. . . . .
4 1~13~
The two ply laminated film comprising inte-grally adhered layers of the high density ethylene-octene-l copolymer and the polypropylene outer layer had the following physical properties:
Film Gauge 1.20 mil 91OW-Up Ratio 2.5/1 Tensile Yield (MD) 3200 psi (TD) 3400 psi Elongation (HD) 525S
(TD) 850S
Tear-Elmendorf(MD) 24 gms/mil (TD) 477 gms/mil Modulus (HD) 80M psi (TD) 105M psi For purposes of the present invention the : thicknes~ of the inner high density poiyethylene copoly-mer layer may vary from about 0.5 mils up to about 3.0 ` mils and is preferably 1.0 mils thick. The outer poly-propylene layer may vary from about 0.1 mil up to about
~, , A tubular thermoplastic laminate waq prepared utilizing conventional blown tubular rilm coextrusion ~ . ~ ................. .
~::
,~
,, ~:: . - - : . .
. : , --- . .- . :
:,..................... , . .. -, .
: ~ . , - . . .
techniques whereby the final inner-tube layer comprised a 1.0 mil thick layer of high density polyethylene copolymer and a 0.2 mil thick outer layer o~ polypro-pylene. me continuous laminar tube was subsequently converted lnto bag ~tructures utilizing techniques well known in the prior art. The high den~ity polyethylene copolymer inner layer was a copolymer of ethylene and about 3% by weight of octene-1. This re~in is identi-fied by the manufacturer as ~Alathon 78lO"* and has the following typical physical properties for a 1.25 mil ~ilm extruded at a 4.3/1 blow-up ratio:
Density .945 g/cc Melt Index .25 g/10 min.
Tensile Yield (MD) 3000 psi ~
tTD) 3100 psi ~-Elongation (MD) 660%
(2n/min) 7~0S
Secant Modulus (MD~ 80M psi (TD) 82M psi Elmendorf Tear (MD) 45 gm/mil ~-(TD) 247 gm/mil ~
Spencer Impact 2.8 in. lbs/mil Dart Drop (26") 115 gm/mil Tear Propagation (MD) 3.2 Kg force ASTM D-2582 (TD) 3.7 Kg ~orce The propylene outer layer was fabricated from resin identified by the manu~acturer as ~Tenite 612 F"**
which has the ~ollowing typical physical properties:
Density .902 g/cc Flow Rate 4.5 g/10 min Tensile, Yield 5000 psi Vicat So~tening Point 145C ~, Trademark ** Trademark , .. .
~ - . . . . . . . . .
, : ; . - ' ,; , :: ,: .; ,, - ` : . ~:
. . . . .
4 1~13~
The two ply laminated film comprising inte-grally adhered layers of the high density ethylene-octene-l copolymer and the polypropylene outer layer had the following physical properties:
Film Gauge 1.20 mil 91OW-Up Ratio 2.5/1 Tensile Yield (MD) 3200 psi (TD) 3400 psi Elongation (HD) 525S
(TD) 850S
Tear-Elmendorf(MD) 24 gms/mil (TD) 477 gms/mil Modulus (HD) 80M psi (TD) 105M psi For purposes of the present invention the : thicknes~ of the inner high density poiyethylene copoly-mer layer may vary from about 0.5 mils up to about 3.0 ` mils and is preferably 1.0 mils thick. The outer poly-propylene layer may vary from about 0.1 mil up to about
3.0 mil in thlckness and is preferably about 0.2 mil thick.
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Claims (4)
1. A thermoplastic resin bag made of a two layer laminate, the outer layer of which comprises polypropylene and the inner layer a high density ethylene/alpha-olefin copolymer comprising ethylene copolymerized with less than 10% by weight of the alpha-olefin.
2. A thermoplastic resin bag as claimed in claim l in which the ethylene/alpha-olefin copolymer comprises ethylene copolymerized with less than 10% by weight of octene-1.
3. A thermoplastic resin bag as claimed in claim 2 in which the thickness of the inner layer is from 0.5 to 3.0 mils.
4. A thermoplastic resin bag as claimed in claim 3 in which the thickness of the outer layer is from 0.1 to 3.0 mils.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86508877A | 1977-12-27 | 1977-12-27 | |
| US865,088 | 1977-12-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1113898A true CA1113898A (en) | 1981-12-08 |
Family
ID=25344683
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA318,490A Expired CA1113898A (en) | 1977-12-27 | 1978-12-22 | Coextruded laminar thermoplastic bags |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS54100475A (en) |
| BE (1) | BE873112A (en) |
| CA (1) | CA1113898A (en) |
| DE (1) | DE2855053A1 (en) |
| FR (1) | FR2413853A7 (en) |
| GB (1) | GB2011317B (en) |
| IT (1) | IT7823615V0 (en) |
| NL (1) | NL7812412A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5288531A (en) * | 1991-08-09 | 1994-02-22 | The Dow Chemical Company | Pouch for packaging flowable materials |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4439478A (en) * | 1980-05-23 | 1984-03-27 | W. R. Grace & Co., Cryovac Division | Heat sealable, multi-ply polypropylene film |
| US4390385A (en) | 1980-05-23 | 1983-06-28 | W. R. Grace & Co., Cryovac Div. | Heat sealable, multi-ply polypropylene film |
| US4903859B1 (en) * | 1988-09-23 | 2000-04-18 | Better Agricultural Goals Inc | Container for flowable materials |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS598228B2 (en) * | 1975-02-04 | 1984-02-23 | 吉崎 鴻造 | food packaging bags |
| JPS5268279A (en) * | 1975-12-04 | 1977-06-06 | Toyobo Co Ltd | Composite films of polypropylene withexcellent processability |
-
1978
- 1978-12-20 DE DE19782855053 patent/DE2855053A1/en not_active Withdrawn
- 1978-12-21 IT IT7823615U patent/IT7823615V0/en unknown
- 1978-12-21 NL NL7812412A patent/NL7812412A/en not_active Application Discontinuation
- 1978-12-21 GB GB7849554A patent/GB2011317B/en not_active Expired
- 1978-12-22 CA CA318,490A patent/CA1113898A/en not_active Expired
- 1978-12-26 JP JP16443578A patent/JPS54100475A/en active Granted
- 1978-12-27 FR FR7836532A patent/FR2413853A7/en not_active Expired
- 1978-12-27 BE BE192594A patent/BE873112A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5288531A (en) * | 1991-08-09 | 1994-02-22 | The Dow Chemical Company | Pouch for packaging flowable materials |
| US5364486A (en) * | 1991-08-09 | 1994-11-15 | The Dow Chemical Company | Pouch for packaging flowable materials |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2413853A7 (en) | 1979-07-27 |
| JPS54100475A (en) | 1979-08-08 |
| JPS6151548B2 (en) | 1986-11-10 |
| GB2011317A (en) | 1979-07-11 |
| DE2855053A1 (en) | 1979-07-05 |
| BE873112A (en) | 1979-06-27 |
| IT7823615V0 (en) | 1978-12-21 |
| NL7812412A (en) | 1979-06-29 |
| GB2011317B (en) | 1982-03-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |