CA1061574A - Recuperation des metaux au moyen d'un solvant derive de la quinoline - Google Patents

Recuperation des metaux au moyen d'un solvant derive de la quinoline

Info

Publication number: CA1061574A
Authority: CA; Canada
Prior art keywords: copper; molybdenum; aqueous; values; process according
Prior art date: 1974-08-21
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA232,495A

Other languages

English (en)

Inventor

Gordon M. Ritcey

Bernard H. Lucas

Kenneth T. Price

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Canada Minister of Energy Mines and Resources

Original Assignee

Canada Minister of Energy Mines and Resources

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-08-21

Filing date

1975-07-29

Publication date

1979-09-04

1975-07-29 Application filed by Canada Minister of Energy Mines and Resources filed Critical Canada Minister of Energy Mines and Resources

1979-09-04 Application granted granted Critical

1979-09-04 Publication of CA1061574A publication Critical patent/CA1061574A/fr

Status Expired legal-status Critical Current

Links

229910052751 metal Inorganic materials 0.000 title claims abstract description 46
239000002184 metal Substances 0.000 title claims abstract description 46
238000000638 solvent extraction Methods 0.000 title claims abstract description 14
238000011084 recovery Methods 0.000 title claims abstract description 9
150000002739 metals Chemical class 0.000 title abstract description 7
125000002943 quinolinyl group Chemical class N1=C(C=CC2=CC=CC=C12)* 0.000 title 1
239000010949 copper Substances 0.000 claims abstract description 70
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 65
229910052802 copper Inorganic materials 0.000 claims abstract description 64
229910052750 molybdenum Inorganic materials 0.000 claims abstract description 59
239000011733 molybdenum Substances 0.000 claims abstract description 59
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 57
238000000605 extraction Methods 0.000 claims abstract description 49
239000003153 chemical reaction reagent Substances 0.000 claims abstract description 29
239000010941 cobalt Substances 0.000 claims abstract description 29
229910017052 cobalt Inorganic materials 0.000 claims abstract description 29
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 29
238000000034 method Methods 0.000 claims abstract description 26
239000011701 zinc Substances 0.000 claims abstract description 23
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 22
229910052725 zinc Inorganic materials 0.000 claims abstract description 22
239000000284 extract Substances 0.000 claims abstract description 10
150000004325 8-hydroxyquinolines Chemical class 0.000 claims abstract description 6
239000005725 8-Hydroxyquinoline Substances 0.000 claims abstract description 5
229960003540 oxyquinoline Drugs 0.000 claims abstract description 5
239000000243 solution Substances 0.000 claims description 30
239000012074 organic phase Substances 0.000 claims description 21
239000002253 acid Substances 0.000 claims description 13
239000012071 phase Substances 0.000 claims description 13
239000011260 aqueous acid Substances 0.000 claims description 12
YWACCMLWVBYNHR-UHFFFAOYSA-N 7-(5-ethylnonan-2-yl)quinolin-8-ol Chemical group C1=CC=NC2=C(O)C(C(C)CCC(CC)CCCC)=CC=C21 YWACCMLWVBYNHR-UHFFFAOYSA-N 0.000 claims description 8
239000008346 aqueous phase Substances 0.000 claims description 5
238000011068 loading method Methods 0.000 claims description 4
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical group [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 claims description 2
238000001556 precipitation Methods 0.000 claims description 2
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 1
239000007864 aqueous solution Substances 0.000 claims 1
238000006243 chemical reaction Methods 0.000 claims 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
239000003960 organic solvent Substances 0.000 claims 1
239000003929 acidic solution Substances 0.000 abstract description 8
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical class N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract 1
235000016768 molybdenum Nutrition 0.000 description 42
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 12
239000002904 solvent Substances 0.000 description 12
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
239000003085 diluting agent Substances 0.000 description 8
238000002386 leaching Methods 0.000 description 8
238000000926 separation method Methods 0.000 description 8
239000012141 concentrate Substances 0.000 description 6
239000000203 mixture Substances 0.000 description 6
230000000694 effects Effects 0.000 description 5
229910052742 iron Inorganic materials 0.000 description 5
238000005406 washing Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 4
239000012527 feed solution Substances 0.000 description 4
229910052759 nickel Inorganic materials 0.000 description 4
235000011149 sulphuric acid Nutrition 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
229910052951 chalcopyrite Inorganic materials 0.000 description 3
DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
229910000365 copper sulfate Inorganic materials 0.000 description 3
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
239000003607 modifier Substances 0.000 description 3
-1 150 - 200 g H2S04/1 Chemical compound 0.000 description 2
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
239000011575 calcium Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
238000004094 preconcentration Methods 0.000 description 2
239000000047 product Substances 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000011877 solvent mixture Substances 0.000 description 2
239000001117 sulphuric acid Substances 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
238000011282 treatment Methods 0.000 description 2
STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
239000005751 Copper oxide Substances 0.000 description 1
229910000570 Cupronickel Inorganic materials 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
238000003723 Smelting Methods 0.000 description 1
VDGMIGHRDCJLMN-UHFFFAOYSA-N [Cu].[Co].[Ni] Chemical compound [Cu].[Co].[Ni] VDGMIGHRDCJLMN-UHFFFAOYSA-N 0.000 description 1
UXNBTDLSBQFMEH-UHFFFAOYSA-N [Cu].[Zn].[Pb] Chemical compound [Cu].[Zn].[Pb] UXNBTDLSBQFMEH-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
238000009835 boiling Methods 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
238000000658 coextraction Methods 0.000 description 1
YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
229910000431 copper oxide Inorganic materials 0.000 description 1
MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 description 1
238000005868 electrolysis reaction Methods 0.000 description 1
238000005363 electrowinning Methods 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
238000000622 liquid--liquid extraction Methods 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
239000011572 manganese Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
239000011684 sodium molybdate Substances 0.000 description 1
235000015393 sodium molybdate Nutrition 0.000 description 1
TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
239000000126 substance Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Manufacture And Refinement Of Metals (AREA)

CA232,495A 1974-08-21 1975-07-29 Recuperation des metaux au moyen d'un solvant derive de la quinoline Expired CA1061574A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US49913574A	1974-08-21	1974-08-21

Publications (1)

Publication Number	Publication Date
CA1061574A true CA1061574A (fr)	1979-09-04

Family

ID=23983976

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA232,495A Expired CA1061574A (fr)	1974-08-21	1975-07-29	Recuperation des metaux au moyen d'un solvant derive de la quinoline

Country Status (1)

Country	Link
CA (1)	CA1061574A (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4389379A (en) *	1980-08-15	1983-06-21	Societe Miniere Et Metallurgique De Penarroya	Process for selective liquid-liquid extraction of germanium
US4568526A (en) *	1980-08-15	1986-02-04	Societe Miniere Et Metallurgique De Penarroya	Process for selective liquid-liquid extraction of germanium
US4654145A (en) *	1984-06-07	1987-03-31	Canadian Patents And Development Limited	Direct recovery of precious metals by solvent extraction and selective removal
US4659683A (en) *	1985-03-06	1987-04-21	Basf Aktiengesellschaft	Regeneration of inactive and poisoned platinum catalysts
FR2593167A1 (fr) *	1986-01-23	1987-07-24	Mokta Cie Fse	Procede de separation du molybdene par extraction liquide-liquide.
US4818504A (en) *	1987-04-29	1989-04-04	Rhone-Poulenc Chimie	Purified, strontium-free barium values
US4942023A (en) *	1988-01-18	1990-07-17	Metallurgie Hoboken-Overpelt	Metal extraction process with substituted 8-hydroxyquinoline

1975
- 1975-07-29 CA CA232,495A patent/CA1061574A/fr not_active Expired

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4389379A (en) *	1980-08-15	1983-06-21	Societe Miniere Et Metallurgique De Penarroya	Process for selective liquid-liquid extraction of germanium
US4568526A (en) *	1980-08-15	1986-02-04	Societe Miniere Et Metallurgique De Penarroya	Process for selective liquid-liquid extraction of germanium
AU567416B2 (en) *	1980-08-15	1987-11-19	Societe Miniere Et Metallurgique De Penarroya	Selective liquid-luquid extraction of germanium
US4654145A (en) *	1984-06-07	1987-03-31	Canadian Patents And Development Limited	Direct recovery of precious metals by solvent extraction and selective removal
US4659683A (en) *	1985-03-06	1987-04-21	Basf Aktiengesellschaft	Regeneration of inactive and poisoned platinum catalysts
FR2593167A1 (fr) *	1986-01-23	1987-07-24	Mokta Cie Fse	Procede de separation du molybdene par extraction liquide-liquide.
US4818504A (en) *	1987-04-29	1989-04-04	Rhone-Poulenc Chimie	Purified, strontium-free barium values
US4942023A (en) *	1988-01-18	1990-07-17	Metallurgie Hoboken-Overpelt	Metal extraction process with substituted 8-hydroxyquinoline

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JP2760956B2 (ja)	1998-06-04	ニッケルおよびコバルトの湿式精錬法
US4008076A (en)	1977-02-15	Method for processing manganese nodules and recovering the values contained therein
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US3981966A (en)	1976-09-21	Zinc recovery from acidic aqueous streams
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US5174812A (en)	1992-12-29	Separation and recovery of nickel and cobalt in ammoniacal systems
US3923615A (en)	1975-12-02	Winning of metal values from ore utilizing recycled acid leaching agent
CA2090062A1 (fr)	1993-08-26	Procede chimique
CA1057507A (fr)	1979-07-03	Procede de recuperation de cobalt d'une solution ammoniacale aqueuse contenant du cobalt et autres metaux dissous a l'etat de sulphates d'amines
US4654145A (en)	1987-03-31	Direct recovery of precious metals by solvent extraction and selective removal
CA1061574A (fr)	1979-09-04	Recuperation des metaux au moyen d'un solvant derive de la quinoline
US4778520A (en)	1988-10-18	Process for leaching zinc from partially desulfurized zinc concentrates by sulfuric acid
US8916116B2 (en)	2014-12-23	Separation of iron from value metals in leaching of laterite ores
CA2252592C (fr)	2008-10-21	Procede de recuperation de nickel
Bautista	2003	Processing to obtain high-purity gallium
US3883634A (en)	1975-05-13	Liquid-liquid extraction of germanium from aqueous solution using hydroxy-oximes
CA2391394A1 (fr)	2001-05-31	Procede permettant de recuperer des metaux de valeur
CA1091038A (fr)	1980-12-09	Methode de separation du cobalt dans une liqueur comportant plusieurs autres metaux
US4568526A (en)	1986-02-04	Process for selective liquid-liquid extraction of germanium
IE61666B1 (en)	1994-11-16	Process for the recovery of gallium by liquid-liquid extraction
WO1997001649A1 (fr)	1997-01-16	Procede pour la separation selective du cadmium contenu dans une solution aqueuse acide