BRPI0511007A - oligomerização de compostos olefìnicos em um meio alifático - Google Patents
oligomerização de compostos olefìnicos em um meio alifáticoInfo
- Publication number
- BRPI0511007A BRPI0511007A BRPI0511007-6A BRPI0511007A BRPI0511007A BR PI0511007 A BRPI0511007 A BR PI0511007A BR PI0511007 A BRPI0511007 A BR PI0511007A BR PI0511007 A BRPI0511007 A BR PI0511007A
- Authority
- BR
- Brazil
- Prior art keywords
- oligomerization
- olefinic compounds
- aliphatic medium
- aliphatic
- medium
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 125000001931 aliphatic group Chemical group 0.000 title abstract 3
- 238000006384 oligomerization reaction Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- -1 olefin compounds Chemical class 0.000 abstract 1
- 230000003606 oligomerizing effect Effects 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B01J31/188—Amide derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
OLIGOMERIZAçãO DE COMPOSTOS OLEFìNICOS EM UM MEIO ALIFáTICO. A presente invenção refere-se a um processo para produzir um produto oligomérico pela oligomerização de pelo menos um composto olefinica contatando-se o pela menos um composto olefinico com um catalisador de oligomerização em um meio líquido alifático em uma temperatura de reação de pelo menos 50<198>C. O catalisador compreende a combinação de uma fonte de um metal de transição; e um composto de ligação da fórmula (R¬ 1¬)~ m~ X¬ 1¬ (Y) X¬ 2¬ (R¬ 2¬)~ n~.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA2004/4841 | 2004-06-18 | ||
| ZA200404841 | 2004-06-18 | ||
| PCT/IB2005/051940 WO2005123633A1 (en) | 2004-06-18 | 2005-06-13 | Oligomerisation of olefinic compounds in an aliphatic medium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0511007A true BRPI0511007A (pt) | 2007-11-27 |
| BRPI0511007B1 BRPI0511007B1 (pt) | 2021-03-16 |
Family
ID=35241333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0511007-6A BRPI0511007B1 (pt) | 2004-06-18 | 2005-06-13 | processo para produzir um produto oligomérico contendo octeno |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7964763B2 (pt) |
| EP (1) | EP1756024B1 (pt) |
| CN (1) | CN101052605B (pt) |
| BR (1) | BRPI0511007B1 (pt) |
| CA (1) | CA2570054C (pt) |
| ES (1) | ES2695001T3 (pt) |
| MY (1) | MY145458A (pt) |
| WO (1) | WO2005123633A1 (pt) |
| ZA (1) | ZA200610495B (pt) |
Families Citing this family (81)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7273959B2 (en) | 2003-10-10 | 2007-09-25 | Shell Oil Company | Catalytic trimerization of olefinic monomers |
| ATE475633T1 (de) | 2005-03-09 | 2010-08-15 | Exxonmobil Chem Patents Inc | Verfahren zur oligomerisation von olefinen |
| US7414006B2 (en) | 2005-03-09 | 2008-08-19 | Exxonmobil Chemical Patents Inc. | Methods for oligomerizing olefins |
| US7259123B2 (en) | 2005-04-08 | 2007-08-21 | Shell Oil Company | Catalytic trimerization and tetramerization of olefinic monomers |
| US8461406B2 (en) † | 2005-07-12 | 2013-06-11 | Sasol Technology (Pty) Limited | Oligomerisation of olefinic compounds in the presence of a diluted metal containing activator |
| WO2008004986A1 (en) * | 2006-07-05 | 2008-01-10 | National University Of Singapore | Catalyst system for oligomerization of olefins |
| US7378537B2 (en) * | 2006-07-25 | 2008-05-27 | Chevron Phillips Chemical Company Lp | Olefin oligomerization catalysts and methods of using same |
| KR101074202B1 (ko) * | 2007-01-18 | 2011-10-14 | 에스케이종합화학 주식회사 | 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법 |
| KR101057576B1 (ko) * | 2007-08-16 | 2011-08-17 | 에스케이종합화학 주식회사 | 선택적 에틸렌 올리머고화 촉매계 |
| ES2476242T3 (es) | 2009-02-16 | 2014-07-14 | Sasol Technology (Pty) Ltd | Oligomerización de compuestos olefínicos en presencia de un catalizador de oligomerización activado |
| ES2447293T3 (es) | 2009-10-16 | 2014-03-11 | Sasol Technology (Proprietary) Limited | Separación de los componentes de una corriente hidrocarbonada de componentes múltiples que incluye etileno |
| EP2490990B1 (en) | 2009-10-19 | 2013-12-04 | Sasol Technology (Proprietary) Limited | Oligomerisation of olefinic compounds with reduced polymer formation |
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| US3635937A (en) | 1969-11-05 | 1972-01-18 | Shell Oil Co | Ethylene polymerization |
| US3676523A (en) | 1971-07-16 | 1972-07-11 | Shell Oil Co | Alpha-olefin production |
| US3906053A (en) | 1971-08-10 | 1975-09-16 | Ethyl Corp | Process for the production of olefins |
| EP0121965B1 (en) * | 1983-04-06 | 1989-12-27 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of polyketones |
| US6096676A (en) * | 1997-07-02 | 2000-08-01 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| US6184428B1 (en) | 1998-04-22 | 2001-02-06 | Saudi Basic Industries Corporation | Catalyst and process for ethylene oligomerization |
| US6137012A (en) * | 1998-10-13 | 2000-10-24 | E. I. Du Pont De Nemours And Company | Phosphole and diphosphole ligands for catalysis |
| GB0016895D0 (en) * | 2000-07-11 | 2000-08-30 | Bp Chem Int Ltd | Olefin oligomerisation |
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| BR0215086B1 (pt) * | 2001-12-20 | 2013-02-05 | sistema catalisador de conversço de hidrocarboneto, e, processo para a oligomerizaÇço de olefinas. | |
| CN100540514C (zh) | 2002-12-20 | 2009-09-16 | Sasol技术股份有限公司 | 烯烃的三聚 |
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2005
- 2005-06-13 CN CN2005800259458A patent/CN101052605B/zh not_active Expired - Lifetime
- 2005-06-13 WO PCT/IB2005/051940 patent/WO2005123633A1/en not_active Ceased
- 2005-06-13 BR BRPI0511007-6A patent/BRPI0511007B1/pt active IP Right Grant
- 2005-06-13 ES ES05746315.0T patent/ES2695001T3/es not_active Expired - Lifetime
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- 2005-06-13 EP EP05746315.0A patent/EP1756024B1/en not_active Expired - Lifetime
- 2005-06-13 CA CA2570054A patent/CA2570054C/en not_active Expired - Lifetime
- 2005-06-16 MY MYPI20052754A patent/MY145458A/en unknown
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2006
- 2006-12-14 ZA ZA200610495A patent/ZA200610495B/xx unknown
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| ES2695001T3 (es) | 2018-12-28 |
| MY145458A (en) | 2012-02-15 |
| US20110086991A1 (en) | 2011-04-14 |
| WO2005123633A1 (en) | 2005-12-29 |
| CN101052605A (zh) | 2007-10-10 |
| ZA200610495B (en) | 2008-08-27 |
| US7964763B2 (en) | 2011-06-21 |
| BRPI0511007B1 (pt) | 2021-03-16 |
| CN101052605B (zh) | 2011-12-21 |
| EP1756024A1 (en) | 2007-02-28 |
| EP1756024B1 (en) | 2018-08-15 |
| CA2570054C (en) | 2012-10-02 |
| CA2570054A1 (en) | 2005-12-29 |
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