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BRPI0505212A - aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise - Google Patents

aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise

Info

Publication number
BRPI0505212A
BRPI0505212A BRPI0505212-2A BRPI0505212A BRPI0505212A BR PI0505212 A BRPI0505212 A BR PI0505212A BR PI0505212 A BRPI0505212 A BR PI0505212A BR PI0505212 A BRPI0505212 A BR PI0505212A
Authority
BR
Brazil
Prior art keywords
reactor
hydrolysis
liquid phase
levels
lignocellulosic material
Prior art date
Application number
BRPI0505212-2A
Other languages
English (en)
Inventor
Antonio Geraldo Proenca Hilst
Original Assignee
Dedini Sa Ind De Base
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dedini Sa Ind De Base filed Critical Dedini Sa Ind De Base
Priority to BRPI0505212-2A priority Critical patent/BRPI0505212A/pt
Priority to ARP060104735A priority patent/AR057564A1/es
Priority to CA002613745A priority patent/CA2613745A1/en
Priority to AU2006308733A priority patent/AU2006308733B2/en
Priority to MX2008005647A priority patent/MX2008005647A/es
Priority to CN2006800261306A priority patent/CN101223288B/zh
Priority to EP06804597A priority patent/EP1945823B1/en
Priority to DE602006007374T priority patent/DE602006007374D1/de
Priority to PCT/BR2006/000239 priority patent/WO2007051269A1/en
Priority to US11/916,617 priority patent/US7988788B2/en
Priority to ZA200711049A priority patent/ZA200711049B/xx
Priority to RU2008117424/13A priority patent/RU2008117424A/ru
Publication of BRPI0505212A publication Critical patent/BRPI0505212A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13KSACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00Glucose; Glucose-containing syrups
    • C13K1/02Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08HDERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00Macromolecular compounds derived from lignocellulosic materials
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/04Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00Regeneration of pulp liquors or effluent waste waters
    • D21C11/0007Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/20Pulping cellulose-containing materials with organic solvents or in solvent environment
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C7/00Digesters
    • D21C7/14Means for circulating the lye

Landscapes

  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Processing Of Solid Wastes (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

APERFEIçOAMENTOS EM PROCESSO DE HIDRóLISE áCIDA RáPIDA DE MATERIAL LIGNOCELULóSICO E EM REATOR DE HIDRóLISE, dito material lignocelulósico sendo alimentado em diferentes níveis de um reator (10) e contactado com fluxos de solvente orgânico de lignina, água e uma solução extremamente diluída de um ácido inogârnico forte, para obter uma fase líquida de extrato de hidrólise e uma fase sólida de material não reagido e não dissolvido. Um fluxo controlado de vapor é injetado nos diferentes níveis do reator, de modo a prover temperaturas adequadas de solvente orgânico e de ácido inorgânico forte e a formar os produtos (açúcares) desejados. Um fluxo da fase líquida é recirculado em diferentes níveis do reator. O remanescente da fase liquida é retirado do reator, resfriado bruscamente e submetido à evaporação do solvente para obter um concentrado dos produtos de reação, sendo a lignina transferida por decantação e sendo o concentrado transferido a etapas processuais subseqüentes.
BRPI0505212-2A 2005-11-01 2005-11-01 aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise BRPI0505212A (pt)

Priority Applications (12)

Application Number Priority Date Filing Date Title
BRPI0505212-2A BRPI0505212A (pt) 2005-11-01 2005-11-01 aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise
ARP060104735A AR057564A1 (es) 2005-11-01 2006-10-30 Proceso de hidrolisis acida rapida de material lignocelulosico y un reactor de hidrolisis
CA002613745A CA2613745A1 (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
AU2006308733A AU2006308733B2 (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
MX2008005647A MX2008005647A (es) 2005-11-01 2006-10-31 Mejoras en un procedimiento para hidrolisis acida rapida de material lignocelulosico y en un reactor de hidrolisis.
CN2006800261306A CN101223288B (zh) 2005-11-01 2006-10-31 改进的对木质纤维素材料快速酸水解的方法和水解反应器
EP06804597A EP1945823B1 (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
DE602006007374T DE602006007374D1 (de) 2005-11-01 2006-10-31 Verbesserung bei einem verfahren zur schnellen sauren hydrolyse von lignocellulosematerial und bei einem hydrolysereaktor
PCT/BR2006/000239 WO2007051269A1 (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
US11/916,617 US7988788B2 (en) 2005-11-01 2006-10-31 Process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
ZA200711049A ZA200711049B (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
RU2008117424/13A RU2008117424A (ru) 2005-11-01 2006-10-31 Усовершенствования способа быстрого кислотного гидролиза лигноцеллюлозного материала и реактора гидролиза

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0505212-2A BRPI0505212A (pt) 2005-11-01 2005-11-01 aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise

Publications (1)

Publication Number Publication Date
BRPI0505212A true BRPI0505212A (pt) 2007-08-07

Family

ID=37696763

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0505212-2A BRPI0505212A (pt) 2005-11-01 2005-11-01 aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise

Country Status (12)

Country Link
US (1) US7988788B2 (pt)
EP (1) EP1945823B1 (pt)
CN (1) CN101223288B (pt)
AR (1) AR057564A1 (pt)
AU (1) AU2006308733B2 (pt)
BR (1) BRPI0505212A (pt)
CA (1) CA2613745A1 (pt)
DE (1) DE602006007374D1 (pt)
MX (1) MX2008005647A (pt)
RU (1) RU2008117424A (pt)
WO (1) WO2007051269A1 (pt)
ZA (1) ZA200711049B (pt)

Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009028969A1 (en) 2007-08-31 2009-03-05 Biojoule Ltd Lignin and other products isolated from plant material, and methods and compositions therefor
CA2651628C (en) 2006-05-08 2015-01-06 Biojoule Ltd. Process for the production of biofuel from plant materials
US9260818B2 (en) 2007-05-23 2016-02-16 Andritz Inc. Single vessel reactor system for hydrolysis and digestion of wood chips with chemical enhanced wash method
US8734610B2 (en) * 2007-05-23 2014-05-27 Andritz Inc. Two vessel reactor system and method for hydrolysis and digestion of wood chips with chemical enhanced wash method
CN101121735B (zh) * 2007-07-06 2011-04-06 陈培豪 植物纤维原料水解液及利用该水解液预处理植物纤维原料的方法
EP2185734B1 (en) * 2007-07-25 2011-03-23 Haarslev A/S A method and a system for the pretreatment of lignocellulosic material
US8057639B2 (en) * 2008-02-28 2011-11-15 Andritz Inc. System and method for preextraction of hemicellulose through using a continuous prehydrolysis and steam explosion pretreatment process
BRPI0910959B1 (pt) * 2008-04-03 2021-02-09 Cellulose Sciences International, Inc método para desagregação ou descristalização de celulose, celulose descristalizada ou desagregada produzida pelo dito método, kit para realizar o mesmo e método para produção de biocombustíveis
US8192549B2 (en) 2008-06-10 2012-06-05 Andritz Inc. Apparatus and method for hydrolysis of cellulosic material in a two-step process
US20090308383A1 (en) 2008-06-10 2009-12-17 Andritz Inc. Apparatus and method for hydrolysis of cellulosic material in a multi-step process to produce c5 and c6 sugars using a single vessel
GB0819406D0 (en) 2008-10-22 2008-11-26 Weyland As Process
US8353989B2 (en) 2008-11-10 2013-01-15 Andritz Inc. Apparatus and method for treating, pressing and washing biomass
US8216809B2 (en) 2008-12-19 2012-07-10 E I Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
US8241873B2 (en) * 2008-12-19 2012-08-14 E I Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
US8304213B2 (en) 2008-12-19 2012-11-06 E I Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
US8278070B2 (en) 2008-12-19 2012-10-02 E I Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
JP5752047B2 (ja) 2008-12-19 2015-07-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーE.I.Du Pont De Nemours And Company 酵素糖化を促進させるためのバイオマスの有機溶剤前処理
BRPI1007109A2 (pt) * 2009-04-20 2018-02-20 Greenfield Ethanol Inc "pré- tratamento de biomassa lignocelulósica através da remoção de compostos inibitórios"
US20120329116A1 (en) * 2009-04-20 2012-12-27 Greenfield Ethanol Inc. Pretreatment of lignocellulosic biomass through removal of inhibitory compounds
GB0907879D0 (en) 2009-05-07 2009-06-24 Weyland As Process
WO2010135377A1 (en) 2009-05-20 2010-11-25 Xyleco, Inc. Bioprocessing
MY161122A (en) * 2009-05-20 2017-04-14 Xyleco Inc Processing biomass
US8636402B2 (en) 2009-05-20 2014-01-28 Xyleco, Inc. Processing biomass
CA2798161C (en) * 2009-05-28 2018-06-19 Lignol Innovations Ltd. Derivatives of native lignin from softwood feedstocks
US8597431B2 (en) 2009-10-05 2013-12-03 Andritz (Usa) Inc. Biomass pretreatment
CA2783942A1 (en) 2009-12-16 2011-06-23 Shell Internationale Research Maatschappij B.V. Method for producing furfural from lignocellulosic biomass material
SG10201408689YA (en) * 2010-01-20 2015-02-27 Xyleco Inc Dispersing feedstocks and processing materials
US8691526B2 (en) 2010-01-20 2014-04-08 Xyleco, Inc. Processing materials
BR112012030819A2 (pt) * 2010-06-03 2018-03-13 Virdia Ltd composições de lignina, sistemas e métodos para processar lignina e/ou hcl
CN105803118B (zh) 2010-06-26 2021-08-13 威尔迪亚有限责任公司 糖混合物及其生产和使用方法
IL206678A0 (en) 2010-06-28 2010-12-30 Hcl Cleantech Ltd A method for the production of fermentable sugars
IL207329A0 (en) 2010-08-01 2010-12-30 Robert Jansen A method for refining a recycle extractant and for processing a lignocellulosic material and for the production of a carbohydrate composition
IL207945A0 (en) 2010-09-02 2010-12-30 Robert Jansen Method for the production of carbohydrates
CA2809289A1 (en) * 2010-09-03 2012-03-08 Greg Naterer Thermochemical reactors and processes for hydrolysis of cupric chloride
RU2013117010A (ru) 2010-09-14 2014-10-20 Сельюлоуз Сайенсиз Интернэшнл, Инк. Нано-дезагрегированная целлюлоза
PT106039A (pt) 2010-12-09 2012-10-26 Hcl Cleantech Ltd Processos e sistemas para o processamento de materiais lenhocelulósicos e composições relacionadas
PL2675907T3 (pl) 2011-02-14 2018-03-30 Xyleco, Inc. Przetwarzanie surowców papierowych
US9512495B2 (en) 2011-04-07 2016-12-06 Virdia, Inc. Lignocellulose conversion processes and products
US9150936B2 (en) * 2011-07-15 2015-10-06 Greenfield Specialty Alcohols Inc. Conditioning of biomass for improved C5/C6 sugar release prior to fermentation
US9228243B2 (en) 2011-08-24 2016-01-05 Red Shield Acquistion, LLC System and method for conditioning a hardwood pulp liquid hydrolysate
WO2013055785A1 (en) 2011-10-10 2013-04-18 Virdia Ltd Sugar compositions
GB2496001A (en) * 2011-10-24 2013-05-01 Virdia Ltd Hydrolysis systems and methods
BR112014027476B1 (pt) 2012-05-03 2019-12-10 Virdia Ltd métodos de processamento de materiais lingnocelulósicos
US9493851B2 (en) 2012-05-03 2016-11-15 Virdia, Inc. Methods for treating lignocellulosic materials
CN102816877A (zh) * 2012-08-29 2012-12-12 上海交通大学 一种纤维素类生物质水热糖化方法及装置
US9657146B2 (en) 2013-03-14 2017-05-23 Virdia, Inc. Methods for treating lignocellulosic materials
US9255187B2 (en) * 2013-03-15 2016-02-09 Synergy Horizon Limited Method for production of dry hydrolytic lignin
CN105358608B (zh) 2013-05-03 2018-11-16 威尔迪亚公司 用于制备热稳定的木质素级分的方法
AU2013388054B2 (en) 2013-05-03 2017-09-21 Virdia, Inc. Methods for treating lignocellulosic materials
AU2015252877A1 (en) 2014-05-01 2016-10-27 Renmatix, Inc. Upgrading lignin from lignin-containing residues through reactive extraction
EP3166954B1 (en) 2014-07-09 2019-03-27 Virdia, Inc. Methods for separating and refining lignin from black liquor and compositions thereof
WO2016112134A1 (en) 2015-01-07 2016-07-14 Virdia, Inc. Methods for extracting and converting hemicellulose sugars
EP3303639B1 (en) 2015-05-27 2020-08-05 Virdia, Inc. Integrated methods for treating lignocellulosic material
WO2019067526A1 (en) 2017-09-26 2019-04-04 Poet Research, Inc. SYSTEMS AND METHODS FOR TREATING LIGNOCELLULOSIC BIOMASS
WO2020112701A1 (en) 2018-11-26 2020-06-04 Board Of Trustees Of Michigan State University Methods for cellulose hydrolysis using sulfonated polyaromatic catalysts
SE542991C2 (en) * 2019-03-29 2020-09-22 Valmet Oy A method and a system for extracting hydrolyzate in a continuous cooking process for producing pulp
CN110541320B (zh) * 2019-09-12 2021-12-17 武汉轻工大学 从木质纤维素原料中分离木质素和纤维素的方法
CN113304671B (zh) * 2021-05-28 2022-02-01 江西海尔思药业股份有限公司 一种含乳果糖的口服溶液制备用装置及其使用方法
LU102852B1 (en) * 2021-08-02 2023-02-02 Technische Univ Hamburg Process for continuous extraction of lignocellulosic material
US20240376272A1 (en) * 2021-08-02 2024-11-14 Mushlabs Gmbh Process for continuous extraction of lignocellulosic material
CN114029022B (zh) * 2021-12-01 2023-05-16 合肥智慧环境研究院 一种木质素分离系统及其方法
PL4337758T3 (pl) 2022-02-24 2025-08-04 Mushlabs Gmbh Wytwarzanie barwionej grzybni grzybowej

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR227462A1 (es) * 1981-03-26 1982-10-29 Thermoform Bau Forschung Procedimiento mejorado para la produccion de hidrolizados de carbohidratos a partir de material celulosico triturado
CA1225636A (en) * 1984-07-13 1987-08-18 Robert P. Chang Method for continuous countercurrent organosolv saccharification of wood and other lignocellulosic materials
BR9600672A (pt) * 1996-03-08 1997-12-30 Dedini S A Administracao E Par Processo de hidrólise ácido de material lignocelulósico e reator de hidrólise

Also Published As

Publication number Publication date
CN101223288A (zh) 2008-07-16
AR057564A1 (es) 2007-12-05
DE602006007374D1 (de) 2009-07-30
CN101223288B (zh) 2011-12-14
RU2008117424A (ru) 2009-11-20
WO2007051269A1 (en) 2007-05-10
US20080202504A1 (en) 2008-08-28
MX2008005647A (es) 2008-10-03
AU2006308733B2 (en) 2011-02-03
AU2006308733A1 (en) 2007-05-10
EP1945823B1 (en) 2009-06-17
CA2613745A1 (en) 2007-05-10
ZA200711049B (en) 2009-04-29
EP1945823A1 (en) 2008-07-23
US7988788B2 (en) 2011-08-02

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 10A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2331 DE 08-09-2015 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.