BRPI0412310A - uso de um agente controlador de reologia, agente modificador de reologia, concentrados, e, composições com reologia melhorada - Google Patents
uso de um agente controlador de reologia, agente modificador de reologia, concentrados, e, composições com reologia melhoradaInfo
- Publication number
- BRPI0412310A BRPI0412310A BRPI0412310-7A BRPI0412310A BRPI0412310A BR PI0412310 A BRPI0412310 A BR PI0412310A BR PI0412310 A BRPI0412310 A BR PI0412310A BR PI0412310 A BRPI0412310 A BR PI0412310A
- Authority
- BR
- Brazil
- Prior art keywords
- rheology
- concentrates
- compositions
- agent
- improved
- Prior art date
Links
- 238000000518 rheometry Methods 0.000 title abstract 6
- 239000012141 concentrate Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 229920000768 polyamine Polymers 0.000 abstract 2
- 229920001228 polyisocyanate Polymers 0.000 abstract 2
- 239000005056 polyisocyanate Substances 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000008199 coating composition Substances 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 238000007665 sagging Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/285—Nitrogen containing compounds
- C08G18/2865—Compounds having only one primary or secondary amino group; Ammonia
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/71—Monoisocyanates or monoisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/04—Thixotropic paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/02—Polyureas
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
"USO DE UM AGENTE CONTROLADOR DE REOLOGIA, AGENTE MODIFICADOR DE REOLOGIA, CONCENTRADOS, E, COMPOSIçõES COM REOLOGIA MELHORADA". A invenção refere-se ao uso como agente controlador de decaimento (SCA) em composições de revestimento de agentes controladores de reologia obteníveis pela reação de um ou mais poliisocianatos com uma ou mais aminas opticamente ativas ou pela reação de uma ou mais poliaminas com um ou mais isocianatos opticamente ativos. A invenção também se refere aos agentes controladores de reologia obteníveis como descrito acima usando poliaminas ou poliisocianatos específicos. Em adição a invenção refere-se ao uso destes agentes controladores de reologia em várias aplicações.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03077152.1 | 2003-07-08 | ||
| EP03077152 | 2003-07-08 | ||
| US53024003P | 2003-12-18 | 2003-12-18 | |
| US60/530,240 | 2003-12-18 | ||
| PCT/EP2004/007597 WO2005005557A1 (en) | 2003-07-08 | 2004-07-08 | Carbon-substituted methyl amine derivatives and their use as a rheology control agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0412310A true BRPI0412310A (pt) | 2006-08-22 |
| BRPI0412310B1 BRPI0412310B1 (pt) | 2015-08-18 |
Family
ID=34923960
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0412310-7A BRPI0412310B1 (pt) | 2003-07-08 | 2004-07-08 | Uso de um agente controlador de reologia, agente modificador de reologia, concentrados, e, composições com reologia melhorada |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7851530B2 (pt) |
| EP (1) | EP1641887B1 (pt) |
| JP (1) | JP5336043B2 (pt) |
| KR (1) | KR101103105B1 (pt) |
| CN (2) | CN100471918C (pt) |
| AT (1) | ATE483769T1 (pt) |
| BR (1) | BRPI0412310B1 (pt) |
| DE (1) | DE602004029466D1 (pt) |
| ES (1) | ES2358404T3 (pt) |
| PL (1) | PL1641887T3 (pt) |
| WO (1) | WO2005005557A1 (pt) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7799858B2 (en) * | 2005-01-11 | 2010-09-21 | Nuplex Resins B.V. | Commixtures for use in rheology modification |
| US7632882B2 (en) | 2005-01-13 | 2009-12-15 | E.I. Du Pont De Nemours And Company | Rheology control agents for coating compositions |
| CA2594594C (en) * | 2005-01-13 | 2010-12-21 | E.I. Du Pont De Nemours And Company | Rheology control agents for coating compositions |
| US8207268B2 (en) * | 2005-06-28 | 2012-06-26 | Nuplex Resins B.V. | Polyurea product as thixotropic rheology modifying agent |
| DE102006010721B4 (de) | 2006-03-08 | 2010-04-15 | Byk-Chemie Gmbh | Biuretverbindungen zur Rheologiesteuerung |
| FR2907337A1 (fr) * | 2006-10-19 | 2008-04-25 | Oreal | Vernis a ongles contenant un compose issu de la reaction d'au moins un polyisocyanate et d'au moins une amine primaire |
| FR2907336A1 (fr) * | 2006-10-19 | 2008-04-25 | Oreal | Vernis a ongles contenant un agent gelifiant polyuree |
| CN101864055B (zh) * | 2010-06-13 | 2012-06-13 | 东南大学 | 一种旋光螺旋聚氨酯材料及其制备方法 |
| WO2012113739A1 (de) * | 2011-02-22 | 2012-08-30 | Basf Se | Rheologiemittel für strahlungshärtbare beschichtungsmassen |
| PL2995636T3 (pl) * | 2011-10-07 | 2017-12-29 | Allnex Netherlands B.V. | Kompozycja do zastosowania w sposobie otrzymywania kompozycji sieciowalnej RMA |
| ES2669524T3 (es) | 2013-04-08 | 2018-05-28 | Allnex Netherlands B.V. | Composición reticulable por reacción de adición de Michael Real (RMA) |
| JP6295706B2 (ja) * | 2014-02-19 | 2018-03-20 | 東ソー株式会社 | ポリオール組成物 |
| KR102349137B1 (ko) | 2015-04-17 | 2022-01-07 | 알넥스 네덜란드 비. 브이. | 바닥 코팅 조성물 |
| CN107660228B (zh) | 2015-04-17 | 2021-07-06 | 欧尼克斯荷兰有限公司 | 用于固化rma可交联树脂涂层的方法、其中使用的rma可交联组合物和树脂 |
| CN107667146B (zh) | 2015-04-17 | 2021-01-01 | 欧尼克斯荷兰有限公司 | 制造可交联组合物的方法 |
| CA2983152A1 (en) | 2015-04-17 | 2016-10-20 | Allnex Netherlands B.V. | A rma crosslinkable composition with improved adhesion |
| KR102555666B1 (ko) * | 2015-07-27 | 2023-07-18 | 비와이케이-케미 게엠베하 | 리올로지 제어용 우레아우레탄 |
| CN109923144B (zh) | 2016-11-07 | 2022-03-22 | 湛新荷兰有限公司 | 制备触变性组合物的方法 |
| CN106634788B (zh) * | 2016-12-27 | 2019-07-30 | 苏州中材非金属矿工业设计研究院有限公司 | 装配式建筑聚氨酯密封胶及其制备方法 |
| US10370555B2 (en) | 2017-05-16 | 2019-08-06 | Ppg Industries Ohio, Inc. | Curable film-forming compositions containing hydroxyl functional acrylic polymers and bisurea compounds and multilayer composite coatings |
| ES2974695T3 (es) | 2017-07-14 | 2024-07-01 | Ppg Ind Ohio Inc | Composiciones formadoras de película curables que contienen polímeros funcionales reactivos y resinas de polisiloxano, recubrimientos compuestos multicapa y métodos para su uso |
| US20220073670A1 (en) * | 2019-01-04 | 2022-03-10 | Byk-Chemie Gmbh | Urea group containing rheology control additive |
| US11760897B2 (en) | 2019-07-30 | 2023-09-19 | Axalta Coating Systems Ip Co., Llc | Coating compositions including a sag control agent and wax |
| CN111349370A (zh) * | 2020-04-24 | 2020-06-30 | 湖南湘江关西涂料有限公司 | 高触变性树脂及其制备方法与应用、涂料 |
| KR20220141258A (ko) | 2021-04-12 | 2022-10-19 | 악살타 코팅 시스템즈 게엠베하 | 고 전달 효율 어플리케이터를 이용하여 기재에 용매계 코팅 조성물을 적용하여 그 위에 코팅 층을 형성하는 방법 |
| WO2022229209A1 (en) | 2021-04-28 | 2022-11-03 | Allnex Netherlands B.V. | Process for overspray-free application of a resin composition and resin compositions for use in the process |
| DE202024101935U1 (de) * | 2024-04-18 | 2024-05-27 | Nippon Paint Automotive Europe Gmbh | Glitzernde Klarlackzusammensetzung und mehrschichtige Kraftfahrzeugbeschichtung, die diese Zusammensetzung enthält |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL176864C (nl) * | 1976-11-25 | 1985-06-17 | Akzo Nv | Werkwijze voor de bereiding van een thixotrope bekledingssamenstelling. |
| US4528319A (en) * | 1984-07-20 | 1985-07-09 | General Motors Corporation | Sag control of high solid polyurethane clearcoats by urea thixotrope/silica systems |
| NL8500475A (nl) * | 1985-02-20 | 1986-09-16 | Akzo Nv | Thixotrope bekledingssamenstelling. |
| US5039801A (en) | 1985-12-20 | 1991-08-13 | The United States Of America As Represented By The Department Of Health & Human Services | Thermal fragmentation of methylbenzylurea disastereomers or secondary amines and preparation of optically active secondary amines |
| US4965317A (en) * | 1989-10-16 | 1990-10-23 | Ppg Industries, Inc. | Coating composition with sag control agent |
| JPH05322866A (ja) * | 1992-05-15 | 1993-12-07 | Showa Denko Kk | クロマトグラフィー用吸着担体 |
| WO2000037520A1 (en) * | 1998-12-22 | 2000-06-29 | Akzo Nobel N.V. | Thixotropic amino formaldehyde resin |
| JP3817082B2 (ja) * | 1999-02-08 | 2006-08-30 | サンアプロ株式会社 | エポキシ樹脂の硬化促進剤 |
| DE19924170A1 (de) * | 1999-05-25 | 2000-11-30 | Basf Coatings Ag | Thixotropierungsmittel |
| JP3904349B2 (ja) * | 1999-08-05 | 2007-04-11 | 三井化学株式会社 | 揺変性付与剤およびその製造方法 |
| DE10039837C2 (de) * | 2000-08-16 | 2003-03-20 | Byk Chemie Gmbh | Verfahren zur Herstellung einer lagerstabilen, rheologisch wirksamen Harnstoffurethan-Lösung mit breiter Verträglichkeit |
| DE10126647A1 (de) * | 2001-06-01 | 2002-12-12 | Basf Coatings Ag | Rheologiehilfsmittel, Verfahren zu seiner Herstellung und seine Verwendung |
| DE10139262C1 (de) * | 2001-08-09 | 2003-01-02 | Basf Coatings Ag | Rheologiehilfsmittel, Verfahren zu seiner Herstellung und seine Verwendung |
| WO2003037849A2 (en) * | 2001-10-26 | 2003-05-08 | Akzo Nobel N.V. | Acicular crystals of hydrazine-based diurea derivatives and their use as rheology modifiers in coating and adhesive compositions |
| JP4057290B2 (ja) * | 2001-12-13 | 2008-03-05 | 楠本化成株式会社 | 非水系塗料用垂れ防止剤 |
| US6815501B2 (en) * | 2002-04-09 | 2004-11-09 | E. I. Du Pont De Nemours And Company | Dual cure coating compositions and process for the production of multilayer coatings |
| EP1497387A1 (de) * | 2002-04-24 | 2005-01-19 | BASF Coatings Aktiengesellschaft | Carbamat- und/oder allophanatgruppen enthaltende, thermisch härtbare, thixotrope gemische |
| CN1175072C (zh) * | 2002-08-12 | 2004-11-10 | 中国化工建设总公司常州涂料化工研究院 | 含流变改性树脂的溶剂型高固体分涂料 |
-
2004
- 2004-07-08 JP JP2006518166A patent/JP5336043B2/ja not_active Expired - Lifetime
- 2004-07-08 ES ES04740876T patent/ES2358404T3/es not_active Expired - Lifetime
- 2004-07-08 PL PL04740876T patent/PL1641887T3/pl unknown
- 2004-07-08 EP EP04740876A patent/EP1641887B1/en not_active Expired - Lifetime
- 2004-07-08 US US10/564,046 patent/US7851530B2/en active Active
- 2004-07-08 CN CNB2004800192311A patent/CN100471918C/zh not_active Expired - Lifetime
- 2004-07-08 DE DE602004029466T patent/DE602004029466D1/de not_active Expired - Lifetime
- 2004-07-08 CN CNB2004800192326A patent/CN100457837C/zh not_active Expired - Lifetime
- 2004-07-08 AT AT04740876T patent/ATE483769T1/de not_active IP Right Cessation
- 2004-07-08 KR KR1020067000442A patent/KR101103105B1/ko not_active Expired - Lifetime
- 2004-07-08 BR BRPI0412310-7A patent/BRPI0412310B1/pt active IP Right Grant
- 2004-07-08 WO PCT/EP2004/007597 patent/WO2005005557A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| PL1641887T3 (pl) | 2011-04-29 |
| KR20060086931A (ko) | 2006-08-01 |
| CN1816597A (zh) | 2006-08-09 |
| KR101103105B1 (ko) | 2012-01-04 |
| US20060289828A1 (en) | 2006-12-28 |
| JP5336043B2 (ja) | 2013-11-06 |
| JP2009513739A (ja) | 2009-04-02 |
| CN100457837C (zh) | 2009-02-04 |
| DE602004029466D1 (de) | 2010-11-18 |
| WO2005005557A1 (en) | 2005-01-20 |
| CN1816598A (zh) | 2006-08-09 |
| US7851530B2 (en) | 2010-12-14 |
| ES2358404T3 (es) | 2011-05-10 |
| ATE483769T1 (de) | 2010-10-15 |
| EP1641887A1 (en) | 2006-04-05 |
| CN100471918C (zh) | 2009-03-25 |
| EP1641887B1 (en) | 2010-10-06 |
| BRPI0412310B1 (pt) | 2015-08-18 |
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