BR9810128A - Mistura, agente de estabilização, e, processo para inibir a polimerização prematura de compostos contendo vinila - Google Patents
Mistura, agente de estabilização, e, processo para inibir a polimerização prematura de compostos contendo vinilaInfo
- Publication number
- BR9810128A BR9810128A BR9810128-5A BR9810128A BR9810128A BR 9810128 A BR9810128 A BR 9810128A BR 9810128 A BR9810128 A BR 9810128A BR 9810128 A BR9810128 A BR 9810128A
- Authority
- BR
- Brazil
- Prior art keywords
- compounds
- constituent
- stabilizing agent
- vinyl
- premature polymerization
- Prior art date
Links
- 239000003381 stabilizer Substances 0.000 title abstract 5
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 230000002028 premature Effects 0.000 title abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title abstract 3
- 238000002156 mixing Methods 0.000 title abstract 2
- 229920002554 vinyl polymer Polymers 0.000 title abstract 2
- 239000000470 constituent Substances 0.000 abstract 9
- ODUCDPQEXGNKDN-UHFFFAOYSA-N nitroxyl Chemical class O=N ODUCDPQEXGNKDN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- -1 aromatic nitro compounds Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 150000002506 iron compounds Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B63/00—Purification; Separation; Stabilisation; Use of additives
- C07B63/04—Use of additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/32—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing two or more of boron, silicon, phosphorus, selenium, tellurium or a metal
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Hydrogenated Pyridines (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
"MISTURA, AGENTE DE ESTABILIZAçãO, E, PROCESSO PARA INIBIR A POLIMERIZAçãO PREMATURA DE COMPOSTOS CONTENDO VINILA". A invenção está relacionada a uma mistura de substâncias contendo um ou diversos compostos com grupos vinila como o constituinte (A) e um agente de estabilização (B) como um outro constituinte contendo um ou diversos compostos nitroxila facilmente voláteis como um constituinte (b~ 1~), um ou vários compostos nitroxila não facilmente voláteis como um constituinte (b~ 2~), opcinalmente um ou vários compostos nitro aromáticos como um constituinte (b~ 3~) e opcionalmente um ou vários compostos de ferro como um constituinte (b~ 4~). A invenção está ainda relacionada a agentes de estabilização (B) contendo os constituintes (b~ 1~) e (b~ 2~), (b~ 1~) e (b~ 2~) e (b~ 3~), (b~ 1~) e (b~ 2~ ) e (b~ 4~), em adição a (b~ 1~), (b~ 2~), (b~ 3~) e (b~ 4~). A invenção está relacionada também a um processo para inibir a polimerização prematura de compostos com grupos vinila durante a sua purificação ou a sua destilação pela adição de um agente de estabilização (B), ou pela adição dos constituintes do agente de estabilização (B) na forma de substâncias individuais ou em pelo menos dois grupos de constituintes.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19725519A DE19725519A1 (de) | 1997-06-17 | 1997-06-17 | Stoffmischung, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
| PCT/EP1998/003338 WO1998058038A1 (de) | 1997-06-17 | 1998-06-04 | Stoffmischung, enthaltend vinylgruppenhaltige verbindungen und stabilisatoren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9810128A true BR9810128A (pt) | 2000-08-08 |
Family
ID=7832693
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9810128-5A BR9810128A (pt) | 1997-06-17 | 1998-06-04 | Mistura, agente de estabilização, e, processo para inibir a polimerização prematura de compostos contendo vinila |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6475348B1 (pt) |
| EP (1) | EP0991733A1 (pt) |
| JP (1) | JP2002504128A (pt) |
| KR (1) | KR20010013936A (pt) |
| CN (1) | CN1260822A (pt) |
| AU (1) | AU8435998A (pt) |
| BG (1) | BG103970A (pt) |
| BR (1) | BR9810128A (pt) |
| CA (1) | CA2293577A1 (pt) |
| DE (1) | DE19725519A1 (pt) |
| EA (1) | EA199901084A1 (pt) |
| ID (1) | ID23525A (pt) |
| PL (1) | PL337673A1 (pt) |
| WO (1) | WO1998058038A1 (pt) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19859391A1 (de) * | 1998-12-22 | 2000-06-29 | Basf Ag | Verfahren zum Verdichten ethylenisch ungesättigter Monomerer |
| DE19922103A1 (de) * | 1999-05-17 | 2000-11-23 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
| DE19946136A1 (de) * | 1999-09-27 | 2001-03-29 | Basf Ag | Inhibitorzusammensetzung |
| US6639026B2 (en) | 2001-05-22 | 2003-10-28 | Ge Betz, Inc. | Methods and compositions for inhibiting polymerization of vinyl monomers |
| US20100143580A1 (en) * | 2008-05-28 | 2010-06-10 | American Air Liquide, Inc. | Stabilization of Bicycloheptadiene |
| CN102399310B (zh) | 2010-09-09 | 2013-07-24 | 通用电气公司 | 抑制过早聚合的组合物和方法 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5010281B1 (pt) * | 1970-03-20 | 1975-04-19 | ||
| US3733326A (en) | 1971-03-10 | 1973-05-15 | Sankyo Co | Inhibition of the polymerization of vinyl monomers |
| JPS5015001B1 (pt) * | 1971-03-30 | 1975-06-02 | ||
| SU1027150A1 (ru) * | 1981-10-21 | 1983-07-07 | Научно-Исследовательский Институт Механики И Физики При Саратовском Ордена Трудового Красного Знамени Государственном Университете Им.Н.Г.Чернышевского | Способ стабилизации стирола или метилметакрилата |
| SU1139722A1 (ru) * | 1983-04-12 | 1985-02-15 | Ереванское Отделение Охтинского Ордена Ленина И Ордена Трудового Красного Знамени Научно-Производственного Объединения "Пластполимер" | Способ ингибировани полимеризации стирола |
| ATE49588T1 (de) * | 1984-10-10 | 1990-02-15 | Amoco Corp | Verfahren zur reinigung von methacrylsaeure. |
| AU1891388A (en) | 1987-07-31 | 1989-02-02 | Hoechst Celanese Corporation | Inhibition of polymerization during distillation of monomers |
| SU1558888A1 (ru) | 1987-12-11 | 1990-04-23 | Всесоюзный Научно-Исследовательский Институт Химических Реактивов И Особочистых Химических Веществ | Способ ингибировани полимеризации стирола |
| JPH01165534A (ja) | 1987-12-22 | 1989-06-29 | Mitsubishi Petrochem Co Ltd | スチレン類の重合防止剤 |
| KR100193146B1 (ko) * | 1990-07-20 | 1999-06-15 | 월터 클리웨인, 한스-피터 위트린 | 안정화된 단량체 조성물 |
| US5254760A (en) * | 1992-07-29 | 1993-10-19 | Ciba-Geigy Corporation | Inhibiting polymerization of vinyl aromatic monomers |
| JPH06161023A (ja) * | 1992-11-24 | 1994-06-07 | Nissan Motor Co Ltd | フォトクロミック感光性材料 |
| US5728872A (en) * | 1994-06-27 | 1998-03-17 | Lutz Riemenschneider | Stabilized acrylic acid compositions |
| EP0697386B1 (de) * | 1994-08-19 | 1998-11-25 | Hüls Aktiengesellschaft | Inhibierung der Polymerisation von Styrol |
| US5888356A (en) * | 1994-08-19 | 1999-03-30 | Huels Aktiengesellschaft | Inhibition of polymerization of vinylaromatic or vinylaliphatic |
| US5545786C1 (en) | 1994-11-28 | 2001-10-16 | Ciba Geigy Corp | Method for inhibiting premature polymerization of vinyl aromatic monomers |
| DE19510184A1 (de) | 1995-03-21 | 1996-09-26 | Basf Ag | 4-Acylaminopiperidin-N-oxyle |
| DE19609312A1 (de) | 1996-03-09 | 1997-09-11 | Basf Ag | Stabilisierte Monomerenzusammensetzung |
| JPH09268138A (ja) * | 1996-04-02 | 1997-10-14 | Hakuto Co Ltd | スチレン類の重合抑制方法 |
| EP0906257B2 (de) * | 1996-06-05 | 2010-04-07 | Basf Se | Mischungen, enthaltend monomere und stabilisatoren |
| DE19638868A1 (de) | 1996-09-23 | 1998-03-26 | Basf Ag | Stabilisierte Monomerenzusammensetzung |
| US5844025A (en) * | 1996-12-02 | 1998-12-01 | Ciba Specialty Chemicals Corporation | 1,2-Bis-adducts of stable nitroxides with substituted ethylenes and stabilized compositions |
| DE19651307A1 (de) | 1996-12-10 | 1998-06-18 | Basf Ag | Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren |
| US5907071A (en) * | 1998-04-21 | 1999-05-25 | Betzdearborn Inc. | Compositions and methods for inhibiting vinyl aromatic monomer polymerization |
| AU1863100A (en) * | 1998-12-17 | 2000-07-03 | Ciba Specialty Chemicals Holding Inc. | Inhibiting polymerization of vinyl aromatic monomers using synergistic mixtures containing nitroxide stabilizers |
| DE19926758A1 (de) * | 1999-06-11 | 2000-12-14 | Basf Ag | Verfahren zur Verhinderung unerwünschter Polymerisation in einem ethylenisch ungesättigte Verbindungen enthaltenden Stoffgemisch |
-
1997
- 1997-06-17 DE DE19725519A patent/DE19725519A1/de not_active Withdrawn
-
1998
- 1998-06-04 ID IDW991535A patent/ID23525A/id unknown
- 1998-06-04 WO PCT/EP1998/003338 patent/WO1998058038A1/de not_active Ceased
- 1998-06-04 CA CA002293577A patent/CA2293577A1/en not_active Abandoned
- 1998-06-04 PL PL98337673A patent/PL337673A1/xx unknown
- 1998-06-04 AU AU84359/98A patent/AU8435998A/en not_active Abandoned
- 1998-06-04 EP EP98934913A patent/EP0991733A1/de not_active Withdrawn
- 1998-06-04 KR KR1019997011958A patent/KR20010013936A/ko not_active Withdrawn
- 1998-06-04 US US09/446,192 patent/US6475348B1/en not_active Expired - Lifetime
- 1998-06-04 EA EA199901084A patent/EA199901084A1/ru unknown
- 1998-06-04 BR BR9810128-5A patent/BR9810128A/pt unknown
- 1998-06-04 JP JP50366199A patent/JP2002504128A/ja not_active Ceased
- 1998-06-04 CN CN98806312A patent/CN1260822A/zh active Pending
-
1999
- 1999-12-08 BG BG103970A patent/BG103970A/bg unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0991733A1 (de) | 2000-04-12 |
| CA2293577A1 (en) | 1998-12-23 |
| PL337673A1 (en) | 2000-08-28 |
| KR20010013936A (ko) | 2001-02-26 |
| US6475348B1 (en) | 2002-11-05 |
| CN1260822A (zh) | 2000-07-19 |
| AU8435998A (en) | 1999-01-04 |
| DE19725519A1 (de) | 1998-12-24 |
| JP2002504128A (ja) | 2002-02-05 |
| ID23525A (id) | 2000-04-27 |
| EA199901084A1 (ru) | 2000-06-26 |
| WO1998058038A1 (de) | 1998-12-23 |
| BG103970A (bg) | 2000-11-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 5A, 6A, 7A E 8A ANUIDADES. |