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BR0206966A - Processo para realizar reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta para processar metano - Google Patents

Processo para realizar reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta para processar metano

Info

Publication number
BR0206966A
BR0206966A BR0206966-0A BR0206966A BR0206966A BR 0206966 A BR0206966 A BR 0206966A BR 0206966 A BR0206966 A BR 0206966A BR 0206966 A BR0206966 A BR 0206966A
Authority
BR
Brazil
Prior art keywords
methane
steam
carbon monoxide
hydrogen
generate carbon
Prior art date
Application number
BR0206966-0A
Other languages
English (en)
Inventor
Michael Joseph Bowe
Clive Derek Lee-Tuffnell
Jason Andrew Maude
John William Stairmand
Ian Frederick Zimmerman
Original Assignee
Accentus Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB0129054.3A external-priority patent/GB0129054D0/en
Priority claimed from GB0204677A external-priority patent/GB0204677D0/en
Application filed by Accentus Plc filed Critical Accentus Plc
Publication of BR0206966A publication Critical patent/BR0206966A/pt

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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/2495—Net-type reactors
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
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    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
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Abstract

"PROCESSO PARA REALIZAR REFORMA DE VAPOR/METANO PARA GERAR MONóXIDO DE CARBONO E HIDROGêNIO, E, PLANTA PARA PROCESSAR METANO". Metano é reagido com vapor para gerar monóxido de carbono e hidrogênio em um primeiro reator catalítico (14); a mistura de gás resultante pode ser, então, usada para realizar a síntese Fischer-Tropsch em um segundo reator catalítico (26). Para realizar a reforma vapor/metano, a mistura de gás é passada através de um canal estreito em que a temperatura média e a temperatura de saída estão, ambas, na faixa de 750<198>C a 900<198>C, o tempo de residência sendo menor que 0,5 segundo, e o canal contendo um catalisador, de modo que somente as reações que tem uma cinética comparativamente rápida irão ocorrer. O calor é provido por combustão de metano em canais adjacentes (17). A relação de vapor para metano deve ser preferivelmente de 1,4 a 1,6, por exemplo cerca de 1,5. Quase todo o metano irá sofrer a reação de reforma, quase formando completamente monóxido de carbono. Após realizar a síntese Fischer-Tropsch, o hidrogênio restante é preferivelmente alimentado de volta (34) para os canais de combustão (17). O vapor para a etapa de reforma é preferivelmente gerado a partir da água gerada pelas reações químicas, por condensação (30, 32) dos produtos de síntese FischerTropsch e por condensação de vapor d'água (19) gerado na combustão.
BR0206966-0A 2001-12-05 2002-12-02 Processo para realizar reforma de vapor/metano para gerar monóxido de carbono e hidrogênio, e, planta para processar metano BR0206966A (pt)

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GBGB0129054.3A GB0129054D0 (en) 2001-12-05 2001-12-05 Catalytic reactor and process
GB0204677A GB0204677D0 (en) 2002-02-28 2002-02-28 Catalytic reactor and process
PCT/GB2002/005424 WO2003048034A1 (en) 2001-12-05 2002-12-02 Process an apparatus for steam-methane reforming

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BRPI0216052-8A BR0216052B1 (pt) 2001-12-05 2002-12-02 planta gás para lìquido para processar metano e processo para processar metano.

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GB2399516A (en) 2004-09-22
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NO20033454D0 (no) 2003-08-04
US8753589B2 (en) 2014-06-17
NO20033454L (no) 2003-10-06
GB0412152D0 (en) 2004-06-30
BR0216052B1 (pt) 2012-12-11
US20050171217A1 (en) 2005-08-04
GB2399516B (en) 2005-03-16
US20120058028A1 (en) 2012-03-08
US8021633B2 (en) 2011-09-20
TW200300703A (en) 2003-06-16
US20080194712A1 (en) 2008-08-14
MY129719A (en) 2007-04-30
WO2003048034A1 (en) 2003-06-12
US20140234168A1 (en) 2014-08-21

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