AU751700B2 - Process for the oxidative dyeing of human hair - Google Patents
Process for the oxidative dyeing of human hair Download PDFInfo
- Publication number
- AU751700B2 AU751700B2 AU32259/99A AU3225999A AU751700B2 AU 751700 B2 AU751700 B2 AU 751700B2 AU 32259/99 A AU32259/99 A AU 32259/99A AU 3225999 A AU3225999 A AU 3225999A AU 751700 B2 AU751700 B2 AU 751700B2
- Authority
- AU
- Australia
- Prior art keywords
- hair
- acid
- composition
- process according
- value
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000004043 dyeing Methods 0.000 title claims abstract description 17
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 46
- 230000003647 oxidation Effects 0.000 claims abstract description 13
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 13
- 230000002378 acidificating effect Effects 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims abstract description 7
- 239000007800 oxidant agent Substances 0.000 claims abstract description 5
- 239000000975 dye Substances 0.000 claims description 16
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 238000011282 treatment Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 7
- 230000008878 coupling Effects 0.000 claims description 6
- 238000010168 coupling process Methods 0.000 claims description 6
- 238000005859 coupling reaction Methods 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000015165 citric acid Nutrition 0.000 claims description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 4
- 239000011975 tartaric acid Substances 0.000 claims description 4
- 235000002906 tartaric acid Nutrition 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 7
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 6
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 239000002453 shampoo Substances 0.000 description 4
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 3
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 description 3
- 229940018563 3-aminophenol Drugs 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- -1 aromatic carboxylic acids Chemical class 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- HQNIMNQVKVPZES-UHFFFAOYSA-N 2-amino-1h-pyridin-4-one Chemical compound NC1=CC(O)=CC=N1 HQNIMNQVKVPZES-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 229940093915 gynecological organic acid Drugs 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- KWSVXCAQFTWTEF-UHFFFAOYSA-N 2-(2,5-diaminophenyl)ethanol Chemical compound NC1=CC=C(N)C(CCO)=C1 KWSVXCAQFTWTEF-UHFFFAOYSA-N 0.000 description 1
- SWFNPENEBHAHEB-UHFFFAOYSA-N 2-amino-4-chlorophenol Chemical compound NC1=CC(Cl)=CC=C1O SWFNPENEBHAHEB-UHFFFAOYSA-N 0.000 description 1
- HCPJEHJGFKWRFM-UHFFFAOYSA-N 2-amino-5-methylphenol Chemical compound CC1=CC=C(N)C(O)=C1 HCPJEHJGFKWRFM-UHFFFAOYSA-N 0.000 description 1
- BMTSZVZQNMNPCT-UHFFFAOYSA-N 2-aminopyridin-3-ol Chemical compound NC1=NC=CC=C1O BMTSZVZQNMNPCT-UHFFFAOYSA-N 0.000 description 1
- ZTMADXFOCUXMJE-UHFFFAOYSA-N 2-methylbenzene-1,3-diol Chemical compound CC1=C(O)C=CC=C1O ZTMADXFOCUXMJE-UHFFFAOYSA-N 0.000 description 1
- MESJRHHDBDCQTH-UHFFFAOYSA-N 3-(dimethylamino)phenol Chemical compound CN(C)C1=CC=CC(O)=C1 MESJRHHDBDCQTH-UHFFFAOYSA-N 0.000 description 1
- JQVAPEJNIZULEK-UHFFFAOYSA-N 4-chlorobenzene-1,3-diol Chemical compound OC1=CC=C(Cl)C(O)=C1 JQVAPEJNIZULEK-UHFFFAOYSA-N 0.000 description 1
- QGNGOGOOPUYKMC-UHFFFAOYSA-N 4-hydroxy-6-methylaniline Chemical compound CC1=CC(O)=CC=C1N QGNGOGOOPUYKMC-UHFFFAOYSA-N 0.000 description 1
- GKYMYSOKMATKAB-UHFFFAOYSA-N 6-methoxy-2-methylpyridine-3,4-diamine Chemical compound COC1=CC(N)=C(N)C(C)=N1 GKYMYSOKMATKAB-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- 241000158728 Meliaceae Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000008043 acidic salts Chemical class 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- KDNFLUWYIMPBSA-UHFFFAOYSA-N hydrogen peroxide;1,3,5-triazine-2,4,6-triamine Chemical compound OO.NC1=NC(N)=NC(N)=N1 KDNFLUWYIMPBSA-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- PSHKMPUSSFXUIA-UHFFFAOYSA-N n,n-dimethylpyridin-2-amine Chemical compound CN(C)C1=CC=CC=N1 PSHKMPUSSFXUIA-UHFFFAOYSA-N 0.000 description 1
- QWIDXEUVWSDDQX-SVMKZPJVSA-N octadecanoic acid;(z)-octadec-9-enoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCC\C=C/CCCCCCCC(O)=O QWIDXEUVWSDDQX-SVMKZPJVSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- ATGUVEKSASEFFO-UHFFFAOYSA-N p-aminodiphenylamine Chemical compound C1=CC(N)=CC=C1NC1=CC=CC=C1 ATGUVEKSASEFFO-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
Process for oxidative dyeing of human hair comprises (1) treating the hair with an alkaline oxidation dye mixture containing at least 1 developer, at least 1 coupler and an oxidizing agent and leaving it to act for 5-30 minutes; (2) treating the hair, without an intermediate rinse, with an acidic composition containing at least 1 acid; and (3) rinsing.
Description
AUSTRALIA
Patents Act 1990 Goldwell GmbH C
C.
ORIGINAL
COMPLETE SPECIFICATION STANDARD PATENT Invention Title.
Process for the oxidative dyeing of human hair The following statement is a full description of this invention including the best method of performing it known to us:- A-21/98 Process for the Oxidative Dyeing of Human Hair The present invention concerns a new process for the oxidative dyeing of human hair which is not only more gentle to the hair than customary processes but which also provides improved coverage, color intensity and stability.
It is still customary to dye human hair by the use of oxidation hair dyestuffs mixed immediately prior to use with oxidizing agent compositions, in particular on the basis of diluted hydrogen peroxide, and then applying to the hair.
The pH-value of these ready-to-use compositions is generally in the alkaline range, in particular at pH-values between about 9 and about 11.
This alkaline treatment of the hair may damage the structure thereof, in particular in the event of frequent repetition, and especially when the hair so treated was already subjected to previous damage. After coloration, this porous hair also shows poor color fastness.
It has already been proposed to overcome these disadvantages of customary hair dyeing by replacing the alkaline dyeing compositions by an analogous composition with a pH-value within the slightly acidic area between about 5.9 and 6.9.
Such compositions as described, for example, in DE-A No. 35 30 270, 36 28 397 and 36 28 398, have indeed proven substantially less damaging to hair than alkaline products.
In some cases, however, i.e. in the preparation of special shades, the intensity and stability of the colorations achieved with these compositions is not fully satisfactory.
The invention intends to overcome these disadvantages.
The solution of this problem consists in the use of a new process for the oxidative dyeing of human hair, comprising the following steps: Application to the hair of an alkaline oxidation dyestuff mixture comprising at least one developing and at least one coupling substance as well as an oxidizing agent, subsequently, preferably after about ten to thirty minutes processing, without rinsing, application of a composition comprising at least one acid, and rinsing the hair after processing.
o* go. o O** A-21/98 -2- By use of this process, a gentle dyeing of the hair is achieved, providing excellent color intensity. The time required for dyestuff processing can be reduced by about 25% to through application of heat, preferably about 300 bis 50 for example about 40 C.
The alkaline oxidation dyestuff compositions used in the first step of the treatment, comprising at least one developing and one coupling substance as well as an oxidizing agent, are known per se.
Regarding these ready-to-use mixtures containing the peroxide), the pH-value of which ranges between about 8 and 11, preferably 9 and 10, in particular about 9.5, reference is made, for example, to the monography of K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd Ed., pp. 784-804 (1989); the compositions described therein are useful within the scope of the invention, as well as additional developing and coupling substances and shading agents, known from the extensive state of the art.
Examples of developing substances are in particular 1.4-diaminobenzene, tetraaminopyrimidines, triaminohydroxypyrimidines, 1.2.4-triaminobenzene, 2-(2.5-diaminophenyl)ethanol, 2-(2'-hydroxyethyl amino)-5-aminotoluene and 1 -amino-4-bis-(2'hydroxyethyl)-aminobenzene, or the water-soluble salts thereof; examples for coupling substances are resorcinol, 2-methyl resorcinol, 4-chlororesorcinol, 2-amino-4-chlorophenol,4- (N-methyl) aminophenol, 2-aminophenol, 3-aminophenol, 1 -methyl-2-hydroxy-4aminobenzene, 3-N,N-dimethyl aminophenol, 4-amino-3-methyl phenol, 5-amino-2-methyl phenol, 6-amino-3-methyl phenol, 3-amino-2-methyl amino-6-methoxypyridine, 2-amino-3hydroxypyridine, 4-aminodiphenylamine, 4.4'-diaminodiphenylamine, 2-dimethyl aminopyridine, 2.6-diaminopyridine, 1.3-diaminobenzene, 1-amino-3-(2'-hydroxyethyl amino)benzene, 1 -amino-3-[bis(2'-hydroxyethyl) amino]benzene, a-naphthol, 1.4-diamino-2chlorobenzene, 4.6-dichlororesorcinol, 1.3-diaminotoluene, 4-hydroxy-1.2-methylene dioxybenzene, 1.5-dihydroxynaphthaline, 1.7-dihydroxynaphthaline, 2.7dihydroxynaphthaline, 1-hydroxynaphthaline, 4-hydroxy-1.2-methylene dioxybenzene, 2.4diamino-3-chlorophenol and/or 1-methoxy-2-amino-4-(2'-hydroxyethyl amino)benzene, whereby this list is just exemplary.
Developing and coupling substances are preferably contained in a molar proportion of 1:3 to 5:1, in particular about 1:1 and about 3:1; their proportion in the dyestuff compositions according to the invention may range from about 0.25% to about 5% by weight, depending on the desired coloration.
S. *S 5* A-21/98 -3- Useful as oxidation agents are especially diluted hydrogen peroxide solutions, emulsions or gels; possible but less customary is also the use of further peroxides such as earth alkali peroxides, urea peroxide, melamine peroxide, etc., in the respective stoichiometrical amounts.
The oxidation dyestuff compositions can be used as solutions, creams, pastes, gels, aerosols, etc..
The processing time on the hair preferably is about five to thirty minutes, especially about to about 20 minutes, for example, about 15 minutes each for the alkaline and acidic dyestuff mixtures. The process according to the invention is suited both for overall, i.e. first-time coloration of the hair and for freshen-up treatments.
It may be advisable to have a slightly longer processing time of the alkaline dyeing composition compared to the acidic composition.
The acidic composition, applied to the hair after processing of the alkaline oxidation dyestuff precursor composition, has a pH-value ranging especially between about 2 and about 6, in particular about 2.5 and 5, and can be a solution or a thickened gel.
Useful as acids are basically all inorganic and organic acids, such as, in particular phosphoric acid, acetic acid, propionic acid, oxalic acid, malonic acid, amino acids, hydroxycarboxylic acids, such as lactic acid, tartaric acid, citric acid, malic acid, gluconic acid, glycolic acid, sorbic acid, aromatic carboxylic acids, such as benzoic acid, salicylic acid, phthalic acid, the acidic salts and mixtures thereof.
Preferred are organic acids, such as citric acid, tartaric acid, lactic acid, maleic acid, etc..
Upon application to the hair of the acidic dyeing composition, the pH-value preferably ranges between about 5 and 8, especially about 6 to The following Examples illustrate the invention.
A-21/98 -4- Example 1 A hair dyeing composition obtained by admixture of equal weight proportions of a 6% hydrogen peroxide solution and an oxidation dyestuff precursor of the following composition with a pH-value of 9.8 was applied onto strands of bleached human hair.
Carrier composition Cetyl stearyl alcohol Oleic acid Stearic acid monoethanolamide Coco fatty acid monoethanolamide Sodium lauryl sulfate Sodium sulfite 1.2-Propanediol Ascorbic acid Ammonium chloride EDTA, Tetrasodium salt Perfume Wheat protein hydrolyzate Silica Oxidation dyestuff composition 11.00 by wt.) 5.00 2.50 2.50 2.50 1.70 1.00 1.00 0.50 0.50 0.20 0.40 0.20 0.10 2.5.6-Triamino-4-hydroxypyrimidine sulfate sulfate 4-Chlororesorcinol Resorcinol 3-Aminophenol 0.01 0.55 0.17 0.05 0.03 Water ad 100.00 After 15 minutes processing without rinsing, a 12.5% aqueous citric acid gel was applied to the hair in an amount corresponding to the initially used dyeing composition. The mixture was thoroughly combed through the hair, achieving a pH-value of about 7, was processed for further 15 minutes and subsequently rinsed with water, and dried.
A-21/98 A strong, intensive, expressive medium-blond coloration was obtained, which remained unchanged even after five shampoo treatments.
Strands treated in the same manner for 30 minutes with only the alkaline dyestuff composition by comparison showed a weaker coloration, which was clearly less intensive in color after five shampoo treatments than the coloration obtained by the process according to the invention. Furthermore, after the exclusively alkaline color treatment the hair had a clearly more rough feeling.
Example 2 Into a carrier composition according to Example 1, the following oxidation dyestuff mixture was incorporated: 2.5.6-Triamino-4-hydroxypyrimidine sulfate 0.01 by wt.) sulfate 0.90 2-Amino-4-hydroxypyridine 0.80 1 -Naphthol 0.17 3-Aminophenol 0.10 Resorcinol 0.03 This composition was mixed with a 6% H 2 0 2 solution in a weight proportion of 1:1 (pH and applied to strands of bleached human hair.
After 15 minutes processing without rinsing, an aqueous 15% tartaric acid gel was applied to the hair in an amount corresponding to the initially used dyeing composition. The hair was combed through thoroughly, thus achieving a pH-value of about 6; after further processing of minutes the hair was rinsed with water, shampooed and dried.
An intensive, glossy mahogany coloration was obtained, which was still stable after five shampoo treatments.
After application of an alkaline composition only, the hair not only showed a less intensive coloration, it also had a rough feeling.
A-21/98 -6- Example 3 Into a carrier composition according to Example 1 the following oxidation dyestuff mixture was incorporated: sulfate 0.80 by wt.) Resorcinol 0.30 2-Amino-4-hydroxypyridine 0.06 3-Aminophenol 0.03 This composition was mixed with a 6% H 2 0 2 solution in a weight proportion of 1:1 (pH 9.6) and applied to strands of bleached human hair.
After 20 minutes processing, without rinsing, an aqueous 15% citric acid solution was applied to the hair in an amount corresponding to the initially used dyeing composition. The hair was combed through thoroughly, thus achieving a pH-value of about 6; after further processing of minutes the hair was thoroughly rinsed and dried.
An intensive red-brown coloration was obtained, which was still stable after five shampoo treatments, giving the hair a soft, supple body.
Claims (6)
1. Process for the oxidative dyeing of human hair, wherein first an alkaline oxidation dyestuff composition, comprising at least one developing and at least one coupling substance as well as an oxidizing agent is applied-to the hair, and subsequently, after about five to thirty minutes processing, without rinsing, an acidic composition comprising at least one acid is applied, and the hair is rinsed after processing.
2. Process according to claim 1, wherein the processing time of the composition in the second treatment step is equal to or shorter than that of the first treatment step.
3. Process according to claims 1 or 2, wherein the dyestuff composition is processed at about 300 to about 50' C.
4. Process according to one or more of claims 1 to 3, wherein the alkaline oxidation dyestuff composition has a pH-value of 8 to 11. Process according to one or more of claims 1 to 4, wherein the composition comprising at least one acid has a pH-value of 2 to 6.
6. Process according to one or more of claims 1 to 5, wherein at least one of the acidic components is selected from the following acids: citric acid, tartaric acid, lactic acid and/or malic acid.
7. Process according to one or more of claims 1 to 6, wherein, after application of the composition comprising the acid, the pH-value of the dyeing mixture on the hair ranges between about 5 and 8.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19825133A DE19825133C1 (en) | 1998-06-05 | 1998-06-05 | Process for the oxidative dyeing of human hair |
| DE19825133 | 1998-06-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU3225999A AU3225999A (en) | 1999-12-16 |
| AU751700B2 true AU751700B2 (en) | 2002-08-22 |
Family
ID=7870000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU32259/99A Ceased AU751700B2 (en) | 1998-06-05 | 1999-05-26 | Process for the oxidative dyeing of human hair |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0962218B1 (en) |
| AT (1) | ATE311170T1 (en) |
| AU (1) | AU751700B2 (en) |
| DE (2) | DE19825133C1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE50107952D1 (en) * | 2000-06-29 | 2005-12-15 | Kpss Kao Gmbh | Process for the oxidative dyeing of human hair |
| DE102004005769A1 (en) * | 2004-02-05 | 2005-08-25 | Wella Ag | Coloring agent with pearlescent for keratin fibers |
| FR2907668B1 (en) † | 2006-10-26 | 2012-08-17 | Oreal | USE OF A ZINC-BASED COMPOUND FOR PROTECTING THE COLOR FROM THE WASHING OF ARTIFICIALLY ARTIFICIENT KERATIN FIBERS; COLORING PROCESSES |
| DE102010038963A1 (en) | 2010-08-05 | 2011-08-25 | Henkel AG & Co. KGaA, 40589 | Treating keratin fibers, comprises applying a coloring agent on the keratin fibers, applying an acid-containing composition on the fibers exposed with the coloring agent, and heating the keratin fibers |
| DE102013226587A1 (en) * | 2013-12-19 | 2015-06-25 | Henkel Ag & Co. Kgaa | Oxidation dye with reduced hair damage |
| EP3346973B1 (en) | 2015-09-08 | 2020-09-23 | Kao Germany GmbH | Process for oxidative dyeing hair |
| EP3346972B1 (en) | 2015-09-08 | 2021-05-26 | Kao Germany GmbH | Process for treating hair |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0462883A1 (en) * | 1990-06-21 | 1991-12-27 | L'oreal | Keratinous fibres dyeing process with indols, compositions and devices |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3530732A1 (en) * | 1985-08-28 | 1987-03-12 | Wella Ag | AGENT AND METHOD FOR COLORING HAIR WITH 2,6-DIAMINO-PYRIDINE DERIVATIVES |
| DE3628398C2 (en) * | 1986-08-21 | 1994-04-21 | Goldwell Ag | Agent for the oxidative dyeing of hair, process for its preparation and use of the agent |
| DE4123941A1 (en) * | 1991-07-19 | 1993-01-21 | Wella Ag | METHOD FOR THE OXIDATIVE COLORING OF HAIR |
| DE4219981C2 (en) * | 1992-06-19 | 1996-07-04 | Goldwell Gmbh | Hair Dye |
-
1998
- 1998-06-05 DE DE19825133A patent/DE19825133C1/en not_active Revoked
-
1999
- 1999-05-17 EP EP99109689A patent/EP0962218B1/en not_active Expired - Lifetime
- 1999-05-17 AT AT99109689T patent/ATE311170T1/en active
- 1999-05-17 DE DE59912853T patent/DE59912853D1/en not_active Expired - Lifetime
- 1999-05-26 AU AU32259/99A patent/AU751700B2/en not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0462883A1 (en) * | 1990-06-21 | 1991-12-27 | L'oreal | Keratinous fibres dyeing process with indols, compositions and devices |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0962218A2 (en) | 1999-12-08 |
| AU3225999A (en) | 1999-12-16 |
| DE19825133C1 (en) | 2000-02-17 |
| ATE311170T1 (en) | 2005-12-15 |
| EP0962218A3 (en) | 2001-05-09 |
| EP0962218B1 (en) | 2005-11-30 |
| DE59912853D1 (en) | 2006-01-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1125173A (en) | Amino methyl phenol as an oxidation hair dye | |
| AU655234B2 (en) | Oxidative hair dyeing process with catalytic pretreatment | |
| US4840639A (en) | Agent for dyeing hair | |
| US4992077A (en) | Agent for the oxidative dyeing of hair, method for the preparation of the agent and use of the agent | |
| EP0630642B1 (en) | Naphthol couplers | |
| DE19713698C1 (en) | Dyeing and perming hair | |
| HUP0001230A2 (en) | Hair coloring preparations and their application | |
| US4776856A (en) | Process and means for oxidized dyeing of hair using a manganese dioxide catalyst | |
| US5431698A (en) | Process for oxidative dyeing and re-dyeing of human hair | |
| EP0545257B1 (en) | Oxidative hair coloring compositions and process for dyeing human keratinous fibers | |
| AU751700B2 (en) | Process for the oxidative dyeing of human hair | |
| US5350424A (en) | Dyestuff composition for the gradual dyeing of hair by atmospheric oxidation and process using the same | |
| JPH04117322A (en) | Oxidative hair dye and hair dyeing method | |
| AU770657B2 (en) | Process for the oxidative dyeing of human hair | |
| US6224637B1 (en) | Composition for the dyeing of human hair | |
| DE19904291C2 (en) | Process for the oxidative dyeing of human hair | |
| EP1378228B1 (en) | Composition for the dyeing of human hair | |
| EP0818192B2 (en) | Hair dyeing composition | |
| JP3802430B2 (en) | Method for dyeing human hair | |
| EP1374840B1 (en) | Composition for the dyeing of human hair | |
| JPH09157141A (en) | Oxidative hair-dyeing agent | |
| EP1501471B1 (en) | Use of alpha-dialdehydes in the presence of an ammonium salt of a brönsted acid for dyeing keratin fibres | |
| EP0897713B1 (en) | Hair-dye | |
| EP1378229B1 (en) | Composition for the dyeing of human hair | |
| EP1374841A2 (en) | Composition for dyeing of human hair |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| HB | Alteration of name in register |
Owner name: KPSS-KAO PROFESSIONAL SALON SERVICES GMBH Free format text: FORMER NAME WAS: GOLDWELL GMBH |