AU600086B2 - Controlled percolation system and method for heap leach mining - Google Patents

Description

p i 00 8 6 S F Ref: 50329 FORM COMMONWEALTH OF AUSTRALIA PATENTS ACT 1952 COMPLETE SPECIFICATION

(ORIGINAL)

FOR OFFICE USE: Class Int Class ,I I Complete Spec ification Lodged: Accepted: Published: This document contains the atmendnents made under Section 49 and is correct for printing. 0 0, 00 0 Priority: Related Art: Name and Address of Applicant: Address for Service: Richard G. Krauth 7466 N. 4th Street Fresno California 93710 UNITED STATES OF AMERICA SpDuson Ferguson, Patent Attorneys Level 33 St Martins Tower, 31 Market Street Sydney, New South Nales, 2000, Australia Complete Specification for the invention entitled: Controlled Percolation System and Method for M ring The following statement is a full description of this best method of performing it known to me/us Heap Leach invention, including the 5845/3 i i 2.

CONTROLLED PERCOLATION SYSTEM AND METHOD FOR HEAP LEACH MINING TECHNICAL FIELD This invention relates to hydrometallurgy and more particularly to the application of a leaching solution over a bed of crushed metal-laden ore to separateout a pregnant solution of metals therefrom.

BACKGROUND OF THE INVENTION Fydrometallurgy is the art of recovering metals from ores by first effecting solution of the metals in os the form of a salt, separating the solution from the o"n? 10 impoverished solid, then decomposing the metallic salt in such a way as to cause precipitation of the metal in a o* t state of comparative purity. The leaching solution or lixiviant for reclaiming go..d and silver from a bed of low-grade ore generally constitutes aqueous solutions of 15 sodium cyanide mixed with oxygen (air) to convert the noble metal to soluble NaM(CN) 2 from which M can be recovered either by precipitation with zinc dust or aluminum powder, carbon absorption, or by electrowinning.

Sulfuric acid or sulfuric acid-ferric sulfate is the principle practical copper mineral lixiviant.

The term "heap," as used in the art of hydrometallurgy, means a bed of run-of-mine or granular lowgrade ore that has been suitably spread over a prepared surface or "pad" that will ensure solution recovery. The 3.

pad is formed as an impervious base, such as by sheets of plastic film polyethylene), asphalt and/or compacted clay. The ore is normally heaped onto each impervious pad to a depth of ten to thirty feet, after the ore has been pre-crushed to sufficiently small size to enable the leaching solution to reach the metallicmineral particles contained in the ore. Gold and silver ores, for example, are run-of-mine or more commonly crushed to 40-200 mesh size with recovery increasing with the increased fineness of the crushed ore. The pad is usually sloped with the pregnant solution recovered for subsequent processing by perforated drain pipes or I o channels positioned on the impervious base, at the "toe" 0 of the pad, S 15 Lixiviation is the process effecting contact 0 between the ore and the leaching solution. The process is normally accomplished by circulating the solution D 0 E through the stationary ore mass, commonly known as "per- 00 8 colation." The rate of percolation will depend on a S 20 number of factors, such as the particle size of the ore, the depth of the pad, the strength of the leaching solution one to four pounds of sodium cyanide per Ston of water for recovering gold) and the quantity of leaching solution distributed over the bed of crushed ore per unit area.

Conventional percolation systems for heap leach mining normally include sprayers mounted above the bed of -I crushed ore which function to spray the leaching solution onto the ore in a non-uniform and uncontrolled manner.

The leaching solution is thus prone to rapid evaporation and degradation by its exposure to ultra-violet rays, requiring constant monitoring and replenishing of the leaching solution with added water and/or sodium cyanide.

Evaporation is further increased by exposure of the leaching solution to wind friction when it is sprayed through the air.

Surface spraying also induces ice build-up over the pad in freezing weather which in many instances requires complete operation shut-down or a risk of washout or blow-out, as will be appreciated by those skilled .in the heap leach mining arts, As an alternative to shutting down the operation, the leaching solution and/or the ore itself may be heated, but at substantial cost.

The aforementioned wind factor may give rise to an unsafe working environment for the operating and maintenance personnel and also tends to contaminate the surrounding environment (air, ground water, soil) with the highly toxic leaching solution.

FFurther disadvantages of conventional surface "spraying techniques include the formation of surface ponding and run-off, giving rise to serious channeling problems and potential for blow-outs. Ice melt-downs, ponding and other adverse effects, resulting from uneven solution distribution common to surface spraying, will 5 result in pad channeling. The fines washed-down by solution channels form hard pans that eventually divert and internally erode the ore bed and pad.

Should these conditions persist, pad blow-out will oftentimes result.

The sprayers used for surface spraying also require constant repair to unplug their spraying heads. Conventional systems of this type are also unusable when the pad is siturated over uneven terrain, due to the above-mentioned channeling and pad blow-out problems.

SUMMARY OF THE INVENTION It is the object of the present invention to overcome or substantially ameliorate the above disadvantages.

There is disclosed herein a controlled percolation system for heap leach mining over an ore bed composed of crushed metal-laden ore deposited on an impervious pad comprising: supply means for conducting a leaching solution adjacent to said ore bed, 00 00 00 0 0 040 0 0 0 0 0 0:020 0000 004001 0 000*00 0 a plurality of spaced tube means connected to said supply means for receiving said leaching solution therefrom; and a plurality of emitter means positioned in spaced relationshp along each of said tube means for directly emitting said leaching solution into said ore bed at a controlled and substantial uniform rate.

There is further disclosed herein a method for percolating a leaching solution through an ore bed composed of granular metal-laden ore positioned on an impervious pad comprising the steps of: supplying and conducting a leaching solution adjacent to said 2b ore bed, 0o°, dispersing said leaching solution across said ore bed with a 'oo plurality of spaced tubes, and 0° emitting said leaching solution from a plurality of emitters connected to each of said tubes and into said ore bed directly at a 30 controlled and substantially uniform rate.

BRIEF DESCRIPTION OF THE DRAWINGS A preferred form of the present invention will now be described by way of example with reference to the accompanying drawings, wherein: o KLN/23861 Other objects and advantage is invention will become appare -the following description and pAyIn n drawings wherein.

Figure 1 is a perspective view partially illustrating an ore bed composed of crushed metal-laden ore deposited on an impervious pad and having a controlled percolation system embodiment of this invention disposed thereon; Figure 2 is an enlarged sectional view in ele- 'vation, taken in the direction of arrows XI-II in Figure 1, illustrating a header pipe and one connecting tube having a plurality of emitters for directly emitting a leaching solution onto the ore bed; o •15 Figure 3 is an enlarged perspective view illustrating connection of the header pipe to a plurality of tubes; Figure 4 is an enlarged longitudinal sectional oo view of one of one type of emitting unit suitable for use in the percolation system of this invention.

Figure 5 is a cross-sectional view, similar to Figure 2, but illustrating the tube and emitters positioned beneath an upper surface of the ore bed; and Figure 6 is similar to Figure 1, but illustrates multiple layers of ore beds having the percolation system disposed thereon, WA lI4 ;iUI rii-. DESCRIPTION OF THE PREFERRED EMBODIMENTS General Description Figure 1 illustrates a controlled percolation system 10 of this invention mounted on the upper surface of an ore bed or "heap" 11 composed of crushed metalladen ore, such as low-grade gold, silver or copper bearing ores. The ore bed is deposited on an pad 12, shown, for example, in the form of one or more plastic sheets 13 which can be placed over an asphalt or compacted clay base. As described above, heap leach mining is typically So employed in conjunction with low grade ore that is normally pre-crushed to suitable size and then treated with a leaching solution (lixiviation), such as an S aqueous solution of sodium cyanide, potassium cyanide, 15 acidothiourea, ammoniacal thiosulfate or malononitrile in the case of gold and silver. It should be understood that the system and method of this invention are equally applicable to the reclamation of other types of metals, such as copper wherein sulfuric acid or sulfuric acidferric sulfate is used as the lixiviant.

o. The illustrated embodiment of controlled percolation system 10 includes supply means in the form of a mainline pipe 14 and a plurality of header pipes 15 for conducting the liquid leaching solution to separate series of tubes 16, suitably corrected to the header pipes. Each tube has a plurality of spaced emitters 17 secured thereon for directly emitting the leaching solui r _I~I ___YYIII___YIIli tion into ore bed 11 at a controlled and substantially uniform rate, in a manner described more fully hereinafter. The pregnant solution is recovered by strategically positioned drain pipes 18 (one shown in Figure 1) positioned on pad 12. Thereafter, the metals, such as gold, silver or copper, are recovered from the pregnant solution in any well-known conventional manner, such as by precipitation with zinc dust or aluminum powder, carbon absorption or by electrowinning.

DETAILED DESCRIPTION Mainline pipe 14 is connected to a source of 4 4 the liquid leaching solution in a conventional manner to "o receive the solution at a suitable pressure 10-100 o400 oqe psi). Emitters 17 may be constructed to be non-pressure 15 compensating or pressure compensating and self-cleaning to maintain a substantially uniform flow rate therefrom, independent of upstream pressure fluctuations. The maino0' line and header pipes are preferably constructed from a a° standard plastic material, such as a semi-rigid polyvinylchloride (PVC). A twelve to sixteen inch diao*o meter mainline pipe and six inch diameter header pipes O have been found acceptable for this purpose.

A series of tubes 16 are connected to one or both sides of a header pipe 15 to extend transversely therefrom. In each series, the generally parallel tubes are preferably spaced apart one from another at a distance selected from the approximate range of from 1.0 ft.

L-

0 0 n 0r~ 0 0 0 a to 12.0 ft. (vigure Tubes 16 are preferably composed of a flexible plastic tubing, such as low density polyethylene, that will exhibit sufficient flexibility to at least generally conform to an irregular upper surface 19 of ore bed 1. Although the diameters of the tubes may vary, in one working embodiment of this invention, each tube had a sta:,dard outer diameter of 0.620 in. and an inside diameter of 0.520 in. to facilitate assembly of the system from commercially available components.

As shown in Figure 2, each tube is positioned on upper surface 19 of ore bed 11 to emit the leaching solution directly into the ore, even though portions of the tubes and emitters 17 may be slightly out of contact with the l'pper surface of the ore bed due to surface irregularities. The term "emit" (or "emitting") as used herein means a process for dispensing a leaching solution in such a manner that the solution flows or drops down from the dispensing site without being projected horizontally to any substantial extent above ground level (such as in surface spraying) prior to contact with the bed of crushed ore. The leaching solution will typically in a generally umbrella-shap i pattern with the adjacent patterns overlapping as shown. The solution will further penetrate and soak the volume of ore between the patterns under the influence of capillary and related principles influencing fluid flow. Ore bed 11 is normally formed to a depth of from ten to thirty feet.

Figure 4 illustrates one type of in-line emitter 17 that can be used in controlled percolation system 10. As shown, the emitter comprises a cylindrical outer housing 21 having a cylindrical inner flow control member 22 snap-fit and held therein by an interengaging flange and groove arrangement 23. Tubes connect in sealing relationship to either side of the emitter 17 at cylindrical barbs 24 and This general type of emitter (further described in U.S. Patent No. 3,792,588) is commonly used for drip o. irrigation purposes. The emitter includes an inlet 26 o o defined at the upstream end of member 22 to communicate the liquid leaching solution through a labyrinth-type flow passage 27 in a conventional manner, the flow 15 reverses direction longitudinally, back and forth, throughout its travel through the passages. An outlet 28 0of is defined at the upstream end of member 22 and passage 0 O1 'o 27 to permit the solution to flow in a controlled manner from the passage to outlet 28 and thence through an outlet passage 29. The solution then seeps out at a pre- 0. determined flow rate between housing 21 and member 22 for 0 e distribution over pad i1, as shown in Figure 2. A typical emitter of this type is manufactured by the OreMax Division of Wade Manufacturing co. of Fresno, California and can be pre-calibrated and constructed to have a flow rate selected from the range of from 0.2 gph to 6.0 gph, L i 11.

Other types of emitters can be substituted in lieu of emitter 17, so long as they provide the abovedescribed controlled and substantially uniform rate of distribution of the leaching solution over the pad. For example, the well-known "In-Line," Micro-Flapper Emitter (Model MF) or the "On-Line (Button) Emitter", all manufactured by Wade Manufacturing Co. of Fresno, California may prove useful for this purpose. Emitters of these type are normally clog resistant (self-cleaning) and pressure compensating to ensure continuous and uniform distribution of the leaching solution over the pad.

The composite average flow rate from the array of emitters 17 is preferably at a rate selected from the approximate range of from 0.05 to 1.50 gph/ft 2 of the surface area of ore bed 11. A more limited preferred range is from 0.06 to 1.20 gph/ft2, As suggested above, each emitter 17 preferably has a flow rate selected from the approximate range of 0.2 gph to 6.0 gph and still more preferably within the range of from 0.5 to 5.0 gph.

As shown in Figure 1, each series of tubes 16 and emitters 17 are preferably positioned to form at least generally parallel lines separated one from another at a distance selected from the approximate range of from ft. to 12.0 ft. The emitters are spaced apart one from anther on each of the tubes at a linear distance preferably selected from the approximate range of from ft. to 12.0 ft, As shown in Figure 3, the majority j of the emitters in one tube are preferably staggered relative to the emitters in the next adjacent, parallel line of emitters to further aid in the substantially uniform saturation of ore bed 11 with the solution.

The rate at which the leaching solution is distributed over a unit area of the pad will depend on a number of predetermined design and related factors, such as the viscosity of the leaching solution, the size of the outlet of each of the emitters and the spacing of the emitters relative to each other. The required time of contact of the leaching solution with the ore bed will be oU largely determined by the degree of pulverization of the ore, the strength of the leaching solution, the degree of S, solubility of the mineral or the form in which it occurs, o 15 and the effectiveness of the contact, Such contact time may be from four hours to sixty days with many of the o 0 applications requiring from seven to forty-five days, In a many instances the process can be accelerated by heating 4 the leaching solution and/or by aeration wh~t is injected and mixed with the solution prior to a, I-ing its distribution over the pad.

4 Figure 5 illustrates positioning the major portions of tubes 16 and emitters 17 at least substantially beneath upper surface 19 of ore bed 11, prcferably at an approximate depth of from 4.0 in# to 72.0 in, Additional piles or heaps 30 of ore bed 11 can be used to cover header pipes 15, as Wall au the tube portions anO iC;:.l~ii~il.ll. iiiiil i 1 ;1 I -rrr~-r^-ir~ 13.

emitters disposed above surface 19. This modified system is particularly useful for the percolation process when aAbient temperatures fall below freezing.

Figure 6 illustrates a further modification and use of the system wherein multiple layers ("lifts") of underlying and previously processed ore beds 11' and 11'' are covered with another ore bed 11, processed with the addition of air injection. In particular, after first and second ore beds 11' and 11'' have been sequentially processed in the above-described manner, newly deposited n ore bed 11 can beo processed in a like manner by system 0 0 Underlying systems 10' and/or 10'' are left intact and can be supplied with injected pressurized air (in 0 I lieu of the leaching solution) to enhance oxidation S 15 (arrows 31) of the leaching solution emitted from system (arrows 32). This added feature will not only aid in increasing the percolation efficiency of the leaching solution, but will also aid in the further solubilization oa of metals from previously processed ore beds 11' and 2. 11D.

From the above description it can be appreciated that this invention constitutes a marked improvement over conventional percolation systems for heap leach mining which include sprayers mounted above an ore bed to spray a leaching solution onto the ore bed, The system and method of this invention function to emit and distribute a leaching solution in an uniform and controlled 14.

manner to render it far less susceptible to evaporation and degradation by its exposure to ultra-violet rays.

Constant monitorina And replenishing of the leaching solution with added water and/or sodium cyanide is thus normally not required. Evaporation is further deterred since the bulk of the leaching solution is not exposed to wind friction.

Inducement of ice build-up over the pad in freezing weather is also substantially eliminated (particularly with use of the Figure 5 system) whereby the need for expensive supplemental heat input is eliminated and operation shut-down or a risk of wash-out or °j blow-out do not pose problems. Elimination of the wind 0 factor also provides a safe working environment for 15 operating and maintenance personnel. Contamination o, the surrounding environment (air, ground water, soil) with the highly toxic leaching solution is also eliminated to thus materially enhance the quality of such environment. The cost savings realized with the use of this invention have proved substantial twenty-five cents per ounce of recovered silver). It should be understood that system 10 could be covered with an insulative blanket, such as plastic sheets to further enhance the system's efficiency in certain applications.

1~ 1 .I

Claims (10)

1. A controlled percolation system for heap leach mining over an ore bed composed of crushed metal- laden ore deposited on an impervious pad comprising supply means for conducting a leaching solution adjacent to said ore bed, a plurality of spaced tube means connected to said supply means for receiving said leaching solution therefrom; and a plurality of emitter means positioned in spaced relationship along each of said tube means for directly emitting said leaching solution into said ore bed at a controlled and substantially uniform rate.

2. The system of claim 1 wherein said plural- ity of emitter means emit said leaching solution at a rate selected from th- appreimato range of i*69 0.05 to 1.50 gph/ft 2 of the surface area of said ore bed. oa 3. The system of claim 2 whrein said range So is from 0.06 to 1.20 gph/ft 2

4. The system of claim 1 or 2 wherein said Stube means comprise a plurality of generally parallel and flexible plastic tubes spaced apart one from another at a distance selected from -he--a-pre-4-te- range of ft. to 12.0 ft. The system of claim 1 or 2 wherein said emitter means are spaced apart one from another on each N4 L, i _i0

16. of said tube means at a linear distance selected from the Sapproxiat -&\range of f -e 1.0 ft. to 12.0 ft. 2A 6. The system of claim 2 wherein each of said emitter means has a flow rate selected from the appro::- 0- *imate\range of fm 0.2 gph. to 6.0 gph. 7. The system of claim 6 wherein said range is from 0.5 to 5.0 gph. 8. The system of claim 1 wherein said tube means are positioned on an upper surface of said ore bed. 9. The system of claim 1 wherein said tube means are at least substantially positioned beneath an upper surface of said ore bed at an approximat: depth of from 4.0 in. to 72.0 in. S' 10. The system of claim 1 wherein said leach- ing solution comprises an aqueous solution of sodium cya- nide or potassium cyanide or a sulfuric acid solution. 11. The system of claim 1 wherein the emitter means on one of said tube means are staggered longitud- inally relative to the emitter means on an adjacent one of said tube means, 12. The system of claim 1 further comprising at least one second ore bed underlying said first-men- tioned ore bed, additional ones of each of said plurality of tube means and emitters positioned between said ore beds and means for injecting pressurized air into at least one of said ore beds. i 17 3 S- 17 13. A method for percolating a leaching solution through an ore bed 'composed of granular metal-laden ore positioned on an impervious pad comprising the steps of: supplying and conducting a leaching solution adjacent to said ore bed, dispersing said leaching solution across said ore bed with a plurality of spaced tubes, and emitting said leaching solution from a plurality of emitters connected to each of said tubes and into said ore bed directly at a controlled and substantially uniform rate. 14. The method of claim 13 wherein said leaching solution is emitted at a rate selected from a range of 0.05 to 1.50 gph/ft 2 of surface area of said ore bed. The method of claim 14 wherein said leaching solution is emitted f-om a substantial number of emitters positioned at spaced locations relative to each other on each of said tubes. 16. The method of claim 15 wherein said range is from 0.06 to 1.20 goh/ft 2

17. The method of claim 15 further comprising positioning said o° enitters to at least generally form parallel lines of emitters separated S: from each other at a distance selected from a range of 1.0 ft. 12,0 ft.

18. The method of claim 17 further comprising spacing a plurality of eiitters one from another on each of said lines of emitters at a distance selected from a range of 1.0 ft. to 12.0 ft.

19. The method of claim 15 wherein said leaching solution is emitted from each of said emitters at a flow rate selected from a range of 0,2 gph to 6.0 gph. The method of claim 15 further comprising placing said emitters 1 on an upper surface of said ore bed.

21. The method of claim 15 further comprising placing at least a substantial number of said emitters beneath an upper surface of said ore bed at a depth of from 4.0 in. to 72.0 in. .N/23861 18 A 22. The method of claim 13 wherein an aqueous solution of sodium cynanide or potassium cyanide or sulfuric ?cid is emitted directly into said ore bed.

23. The method of claim 14 further comprising depositing a second ore bed on said first-mentioned ore bed and injecting pressurized air between and into at least one of said ore beds while simultaneously emitting said leaching solution directly into said second ore bed.

24. A controlled percolation system for heap leach mining substantially as hereinbefore described with reference to the accompanying drawings. A method for percolating a leaching solution through an ore bed, the method being substantially as hereinbefore described with reference to the accompanying drawings, DATED this TENTH day of MAY 1990 Richard G, Krauth Patent Attorneys for the Applicant SSPRUSON FERGUSON N/23861