AU5948198A - Method and apparatus for rapid reduction of iron oxide in a rotary hearth furnace - Google Patents

Description

P/00/011 28/5/91 Regulation 3.2

AUSTRALIA

Patents Act 1990

ORIGINAL

COMPLETE

SPECIFICATION

STANDARD

PATENT

Name of Applicant: Su Actual Inventor Address for service is: MIDREX DIRECT REDUCTION

CORPORATION

DAVID CHARLES

MEISSNER,

THOMAS H BOYD, JAMES A LEPINSKI and JIMMY D SLOOP WRAY ASSOCIATES 239 Adelaide Terrace Perth, WA 6000 Attorney code: WR Invention Title: "Method and Apparatus for Rapid Reduction of Iron Oxide in a Rotary Hearth Furnace" The following statement is a full description of this invention, including the best method of performing it known to me:- -2- FIELD OF THE INVENTION The present invention relates to a method and apparatus for achieving rapid and efficient reduction of iron oxide in a rotary hearth furnace.

BACKGROUND OF THE INVENTION All previous patents and literature covering direct reduction of iron oxide in a rotary hearth (Heat Fast, Inmetco and Zia) have incorporated a low to medium temperature (below about 1315 0 C) preheat zone in the rotary hearth furnace (hereinafter also referred to as RHF) to dry and devolatize the pellets in order to avoid pellet exfoliation. The disadvantage of this method is that it decreases productivity due to the long time required for pellets to reach optimum reduction temperature.

DESCRIPTION OF THE PRIOR ART Applicants are aware of the following U.S. Patents concerning rotary hearth furnaces used in the direct reduction of iron ore.

0 6r 66.

US Pat. No. Inventor 5,186,741 Kotraba et al Issue Date Title 02-16-94 DIRECT REDUCTION PROCESS

IN

A ROTARY HEARTH

FURNACE

10-20-87 METHOD OF PRODUCING

IRON

USING ROTARY HEARTH

AND

APPARATUS

4,701,214 4,676,741 4,636,127 Kaneko et al.

Pargeter Olano et al.

01-30-87 RADIANTLY

HEATED

FURNACE

01-13-87

CONVEYING

FURNACE

SCREW FOR -3- 4,622,905 MacDougall 11-18-86 FURNACING et al.

4,597,564 Hanewald 07-01-86 ROTARY HEARTH et al.

3,836,353 Holley 09-17-74 PELLET RECLAMATION

PROCESS

3,452,972 Beggs 07-01-69 FURNACE

HEARTH

3,443,931 Beggs et al. 05-13-69 PROCESS FOR MAKING METALLIZED

PELLETS

FROM IRON OXIDE CONTAINING

MATERIAL

Beggs U.S. 3,443,931, teaches a method of metallizing compacts of iron oxide containing a carbonaceous material. The compacts are formed, dried, and preindurated up to a temperature between 1600 and 1800OF (870-980oC). The pellets are then rapidly heated by exposure to a radiant heat source which produces an environment at a temperature between 2300-2600OF (1260- 1430 0 C) for a sufficient time so that a liquidus phase is formed within the compacts. After the liquidus phase is formed, the compacts tend to shrink and then are immediately chilled by exposure to a cold environment.

>Beggs U.S. 3,452,972, teaches apparatus for a refractory furnace hearth having wustite (FeO) as a constituent thereof and the method of making such a refractory hearth. The subject furnace hearth has particular utility in the processing of iron oxide containing material, and is able to support such material during the reduction thereof without being destroyed during the process.

Holley U.S. 3,836,353, teaches a method of recovering iron and oxide impurities from steel furnace dust in which the dust first is mixed with finely divided coke and then this mixture is pelletized. The green pellets thus formed are deposited over a layer of burnt pellets on a rotary hearth which successively conveys the pellets first through a drying zone, then through an initial heating zone in which 1111111I -4the pellets are gradually raised to a temperature at which the coke starts to burn, then through a decontamination zone in which the pellet temperature is rapidly raised to a degree at which zinc, lead and sulfur impurities vaporize and in which these impurities are carried off and collected as oxides, and finally the pellets are carried through a reoxidation and hardening zone in which the temperature thereof is further increased to a sufficient degree and held for a long enough period of time to permit the growth of grains of an oxide of iron on the surface of the pellets, thus to form hard bonded pellets which are not fused together.

Hanewald et al. U.S. 4,597,564, teaches a rotary hearth adapted to rotate in horizontal plane having a top surface made of a loose granular refractory material, advantageously dead burned dolomite grain.

MacDougall et al. U.S. 4,622,905, teaches an improvement in furnacing objects on the top surface of an impervious rotating hearth in a directly fired rotary hearth furnace by the use of fuel burning with a luminous flame coal.

:i Olano et al. U.S. 4,636,127, teaches a countercurrent fluid cooled conveying screw is disclosed. Suitable for furnace applications, the screw includes an outer *•S'*shaft spatially circumscribing an inner tube. A plurality of hollow, fluid cooled flights are affixed to the outer shaft and are in fluid flow communication with coolant coursing through the screw. The coolant is first directed through the flights and then back through the outer shaft before exiting through the inner tube.

_Pargeter U.S. 4,676,741, teaches a radiantly heated, travelling hearth furnace having a supplementary feed means positioned intermediate the initial loading point and the final take-off point to increase the capacity of the furnace for treating objects fed thereto. When the objects are pellets of iron oxide and carbonaceous reductant the provision of supplementary feed means about half-way along the travel path of the hearth promotes uniformity of product by inhibition of reoxidation of reduced iron by exposure to a fossil-fuel-fired furnace atmosphere.

Kaneko et al. U.S. 4,701,214, teaches a method of producing iron from finely divided iron oxide comprising the steps of: mixing iron oxide or iron ore fines with finely divided coal and a binder to form a mixture, agglomerating the mixture by compacting, pelletizing, or briquetting the mixture to form agglomerates or pellets, introducing the pellets to a rotary hearth furnace to pre-reduce the iron in the pellets, introducing the pre-reduced pellets into a smelting reduction vessel as the metallic charge constituent, introducing particulate carbonaceous fuel and oxygen to the smelting reduction vessel through the bottom of the vessel to react with the melt or bath within the vessel, reduce the iron to elemental iron and form an off gas containing CO and H 2 introducing the off-gas into the rotary hearth furnace as process gas to pre-reduce the pellets therein, and drawing off the hot metal from the smelting reduction vessel.

The pre-reduced compacts are preferably discharged from the rotary hearth i• furnace at a temperature of at least 1000°C into the smelting reduction vessel to form the molten iron product.

Kotraba et al. U.S. 5,186,741, teaches a pellet reclamation process includes 20 forming green pellets of a mixture of steel furnace dust, a carbonaceous material such as coal, charcoal, lignite, petroleum coke, or coke, and an organic binder.

o.*The green pellets are fed over a layer of burnt pellets on a rotary hearth furnace which successively conveys the pellets first through a drying and coking zone in O which the pellets are dried and any volatile matter driven out of the J 25 carbonaceous material. The pellets then travel through a reduction zone where the pellets are subjected to a higher temperature at which the contained iron oxide is reduced and remains within the pellets and the zinc, lead and cadmium oxides are reduced, volatilized, re-oxidized and carried off as oxides in the waste gases. The reduced pellets (DRI) are ultimately carried into a discharge -6zone where they are discharged from the rotary hearth furnace. An apparatus for performing the process is also disclosed.

SUMMARY OF THE INVENTION This invention provides an improved method and apparatus for achieving rapid and efficient reduction of iron oxide in a rotary hearth furnace. Test results with this process, which will be known by the trade name or trademark

FASTMETTM

show that properly formed pellets (dry compacts) can be exposed immediately to a radiant heat source with a temperature of 1315-1430oC without causing exfoliation. Eliminating the low to medium temperature preheat zone and operating at high reduction temperature increases hearth productivity by 30 to 100% compared to other processes. In addition, energy efficiency can be improved by burning most of the volatiles released from the compacts inside the rotary furnace, and by causing the compacts and products of combustion to flow cocurrently in the first portion of the furnace and counter- currently in the second portion of the furnace.

OBJECTS OF THE INVENTION The principal object of the present invention is to provide an improved method of achieving rapid and efficient reduction of iron oxide in a rotary hearth furnace.

It is also a preferred object of this invention to provide means for dividing rotary hearth gas flow into two portions rather than having the gas accumulate and peak at the feed area where dust is most likely to be entrained.

SAnother preferred object of the invention is to provide a low roof height in the initial heating zone of a rotary hearth furnace to enhance the radiative heat transfer to a layer of compacts on the hearth.

-7- Another preferred object of the invention is to provide a rotary hearth furnace apparatus where the volatiles released from the compacts have a longer retention time, and can be more readily combusted.

Another preferred object of the invention is to provide a rotary hearth furnace with more efficient combustion than previously available, resulting in a lower ultimate gas volume requiring gas cleaning.

A further preferred object of the invention is to provide a rotary hearth furnace where the direction of the flue gas at the outlet is away from the hearth rather than sweeping across the hearth toward the side wall.

Another preferred object of the invention is to provide a rotary hearth furnace with a flue gas outlet of sufficient size to slow the gas velocity allowing entrained particles to fall back onto the hearth by gravity.

A further preferred object of the invention is to provide a rotary hearth furnace with improved atmosphere control at the hearth level to avoid oxidation of 15 metallic iron.

Another preferred object of the invention is to provide a rotary-hearth furnace apparatus for producing highly metallized iron having lower carbon content.

Another preferred object of the invention is to provide an improved rotary hearth furnace in which energy efficiency is improved by using sensible heat in the metallized compacts to preheat part of the fuel for the rotary hearth furnace.

O A further preferred object of the invention is to provide a rotary hearth furnace i1. capable of operating with a very short retention time of 4 to 10 minutes.

Another preferred object of the invention is to provide a rotary hearth furnace which avoids any disturbance of the protective blanket of carbon monoxide being evolved from the compacts in the final stages of reduction.

-8- Another preferred object of the invention is to provide a rotary hearth furnace which maintains at least 1 percent excess carbon in the metallized compacts.

Throughout this specification, unless the context requires otherwise, the word "comprise", or variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated integer or group of integers but not the exclusion of any other integer or group of integers.

STATEMENTS OF THE INVENTION In accordance with a first aspect of the invention there is provided a method for producing direct reduced iron from dry compacts composed of iron oxide and carbonaceous material and containing volatile materials therein, comprising: feeding said compacts no more than two layers deep onto a hearth; removing all of the volatile materials by exposing said compacts to a radiant heat source at a temperature of from about 1315 to about 1430 0 C for a first period of time of from one to three minutes and subjecting said compacts to an oxidizing atmosphere with sufficient free oxygen to burn most of the combustible gases evolved from the compacts during said first period of time, and form combusted gases; metallizing the compacts by exposing said compacts to a radiant heat source at a temperature of from about 1315 to about 1430 0 C in an atmosphere devoid of free oxygen for a second period of time of three to nine minutes; and a. .*causing said gases and said compacts to flow co-currently during said Sfirst period of time, and to flow countercurrently for said second period of time, and to form metallized iron product; and discharging said metallized iron product from the hearth.

Preferably, the metallizing of the compacts results from reducing, sintering, or partially melting the dry compacts.

-9- Preferably, the method further comprises partially cooling the compacts while discharging them from the hearth.

Preferably the metallized iron product is exposed to an atmosphere that is oxidizing to metallic iron for the final three minutes of said second period of time, but is protected by excess carbon, or a thin blanket of carbon monoxide and/or hydrogen.

Preferably the method further comprising partial cooling of said metallized iron product prior to discharge by injecting a coolant on, or near, said metallized iron product immediately prior to the discharge of metallized iron product from the hearth.

Preferably said coolant is selected from the group consisting of natural gas, pulverized coal, fuel oil, and by-product gas.

The iron oxide may be selected from the group consisting of finely divided iron ~ores, iron oxide concentrates, by-product iron oxides, and steel mill wastes.

15 The carbonaceous material may be selected from the group consisting of coal, :.**coke breeze, petroleum coke, char, and charcoal fines.

The iron oxide and carbonaceous material in said compact may be bonded together with an organic binder.

4Preferably the energy for said radiant heating source is at least partially provided by combusting volatile materials and carbon monoxide emitted from 0 said-Compacts.

Preferably or alternatively the energy for said radiant heating source is at least partially provided by combusting fuel selected from the group consisting of natural gas, pulverized coal, fuel oil and by-product gas.

Preferably oxygen is introduced into the furnace to aid combustion, the oxygen source being selected from the group consisting of preheated air, oxygen and oxygen enriched air.

Preferably the method includes controlling the proportions of iron oxide and carbonaceous material in said compact, to maintain a consistent fixed carbon to iron ratio.

Preferably the method further includes discharging the partially cooled metallized iron product from said hearth into a hot transfer bin and hot charging the metallized iron product into a melting furnace.

Preferably the method further includes discharging the partially cooled metallized iron product from said hearth into a briquetting press to produce hot briquetted iron.

Also in accordance with the invention, there is provided apparatus for producing Smetal from direct reduced iron from dry compacts of iron oxide and particulate carbonaceous material in a rotary hearth furnace, comprising: a. means for mixing iron oxide fines and particulate carbonaceous 'oo° material and forming dry compacts; b. a rotary hearth furnace having a generally flat hearth surface for *2"receiving the dry compacts; 20 c. means for feeding the dry compacts in no more than two layers on the surface of said hearth; d. means for heating, reducing, and sintering or partially melting said dry compacts on said hearth to form a reduced product; f. means for discharging said reduced compacts from said rotary hearth furnace; and g. means intermediate said feeding means and said discharge means for removing flue gas from said rotary hearth furnace.

-11 Preferably said apparatus includes means for partially cooling the compacts while discharging them from the hearth.

Preferably said means for feeding said compacts one to two layers deep onto the hearth comprises at least one adjustable vertical feed pipe having an adjustable gate, or leveller, having a lower edge to control the thickness of the layer.

Preferably said means for discharging of compacts from the hearth comprises at least one helical screw.

Preferably or alternatively said means for discharging of compacts from the hearth comprises at least one plow.

Preferably said apparatus further includes means for injecting a coolant onto or near said compacts immediately prior to the discharge of compacts from the hearth.

Preferably said apparatus further includes a water cooled probe for collecting a 15 gas sample less than one inch above the surface of said compacts immediately i.t prior to their discharge from said hearth, whereby the levels of carbon monoxide and oxygen in said gas sample are monitored for purposes of product quality control and/or optimization of productivity.

SS4 BRIEF DESCRIPTION OF THE DRAWINGS The foregoing and other objects will become more readily apparent by referring to the following detailed description and the appended drawings in which: Figure 1 is a schematic diagram of the process for an improved method of achieving rapid and efficient reduction of iron oxide in a rotary hearth furnace; -12- Figure 2 is a cross sectional view of the improved rotary hearth furnace; Figure 3 is a top view of the improved rotary hearth furnace; Figure 4 is a schematic side view of the feed apparatus showing the feed or pellet leveller; Figure 5 is a schematic side view of the discharge portion of the apparatus showing a cooling device; Figure 6 is a schematic side view of the discharge portion of the apparatus showing a plow pellet discharge and Figure 7 is a schematic top view of the discharge portion of the apparatus of Figure 6.

DETAILED

DESCRIPTION

Referring now to the drawings, and particularly to Figure 1, the invented method and apparatus for achieving rapid and efficient reduction of iron oxide in a rotary hearth furnace includes feed bins 10, 12 and 14 which contain the raw materials S- 15 for the process. Feed bin 10 contains iron oxide materials 16 which are comprised of, but not limited to, finely divided iron ore fines, concentrate, byproduct iron oxide and steel mill waste. Feed bin 12 contains carbonaceous materials 18 which are comprised of, but not limited to, pulverized coal, coke breeze, char, anthracite, charcoal and petroleum coke. Feed bin 14 contains 20 binder materials 20 which are comprised of, but not limited to, organic binders, bentonite, or hydrated lime.

Materials from the feed bins 10, 12 and 14 are mixed together in proper proportions, in a mixing unit 22. This mixture 24 is sent to an agglomerating unit 26 which either pelletizes, briquettes, extrudes or compacts mixture 24 into -13consolidated units 28 which are then transported to a drying unit 30 and dried at approximately 1200 to 180C to remove moisture and form dry compacts 32.

The dry compacts 32 are fed into a rotary hearth furnace (RHF) 34 through feed chute 102, which preferably can move vertically, and associated adjustable leveller gate 104, and deposited on the solid hearth 36, Figure 2, in a layer 38 one to two compacts deep. The hearth 36 shown in Figure 1 moves clockwise.

The compacts pass under a radiation barrier 100 and are exposed to a radiant heat source 40 at a temperature of about 1315-1430oC for a period of 4 to minutes during which time the volatiles and carbon monoxide are evolved from the compacts and combusted inside the furnace and most of the iron oxide is reduced to metallic iron and iron carbide. The metallic iron results from reducing, sintering, and/or partially melting the dry compacts.

As shown in Figure 4, the compacts 38 are fed one to two layers deep onto the hearth from at least one vertical feed pipe 102, which can have an adjustable gate 104, or leveller, having a lower edge to control the thickness of the layer of S• compacts. Alternatively, an independently mounted leveller 112, such as a water-cooled leveling roll, also shown in Figure 4, extends across the hearth 36 an appropriate height above the hearth just downstream from the feed pipe 102.

The impact of rapid heating and high reduction temperature on the reduction 20 rate of dry compacts 32 containing a mixture of iron oxide and carbonaceous material can be seen in the following table. The tests were conducted in an electrically heated tube furnace having a nitrogen atmosphere. The dry too. compacts (made with a mixture of magnetite concentrate, low-volatile bituminous coal and binder), were placed inside the preheated tube furnace and removed at 2 minute intervals and analyzed for total and metallic iron to develop a '4 metallization (percent of total iron content in the form of metallic iron) versus time curve.

-14- Radiant Heat Source Time to Reach 93% Temperature (OF) (0C) Metallization (in minutes) 2150 1177 More than 2250 1232 7.6 2350 1288 6.4 2450 1343 5.8 The productivity (lb/h-ft 2 in a rotary hearth furnace 34 for a given feed material and hearth loading is inversely proportional to the retention time. For example, a retention time of 5.8 minutes should result in a productivity 31% higher than a retention time of 7.6 minutes.

The impact of rapid heating in an oxygen rich atmosphere on the reduction rate of dry compacts containing a mixture of iron oxide 16 and carbonaceous material 18 was determined by comparing results of one test conducted in a nitrogen atmosphere and a second test conducted in an air atmosphere for the first 2 minutes followed by a nitrogen atmosphere for the remaining time. The same test procedures were used as mentioned above. The radiant heat source temperature was kept constant at 13430c in both tests. Results were similar when using dry compacts made with a mixture of hematite concentrate, o 606110 low-volatile bituminous coal and binder.

20 Since the temperature is kept uniformly high throughout all the heating zones of the furnace, it is not necessary to locate the flue duct near the feed end to take advantage of the sensible heat of the products of combustion. The flue gas °O 6temperature would be approximately the same regardless of the location of flue gas outlet 42 on the RHF 34. Therefore, it is possible to improve fuel efficiency, when using carbonaceous materials containing volatiles, by locating the flue gas outlet 42 at the mid-section of the RHF 34, between the charging and 4O discharging locations. This results in the compacts and products of combustion flowing co-currently in the first portion 44 of the RHF and counter- currently in the second portion 46 of the RHF.

The gas flow through the RHF 34 is divided into two portions 47 and 48 rather than growing cumulatively and peaking at the feed area 102 of the RHF where dust is most likely to be entrained. This allows the height of the roof in the initial heating zone in the RHF 34 to be low due to the passage of low gas volume through the zone, thus enhancing the radiative heat transfer to the layer of compacts. Volatiles released from the compacts have a longer retention time inside the RHF and can be more readily combusted. The more efficient combustion inside the RHF lowers the ultimate volume of gas requiring gas cleaning.

Locating the flue gas outlet 42 in the roof of the RHF 34 provides additional advantages like the direction of the flue gas at the outlet is away from the hearth rather than sweeping across the hearth toward the side wall. The flue gas outlet 42 can be made sufficiently large in diameter to slow the gas velocity down, allowing entrained particles to fall back onto the hearth by gravity.

The high temperature radiant heat source 40 is initially generated by burning fuel. Burner fuel is provided from a source 50, the fuels used are, without limitation to natural gas, fuel oil, by-product gas and pulverized coal. This fuel is distributed to roof burners or wall mounted burners 52. Oxygen for combustion is supplied by preheated or oxygen enriched air 54. Additional preheated or •:oo oxygen enriched air is supplied to burn volatiles and CO evolved from the compacts. Efficient combustion is achieved due to the high operating 20 temperature, and the longer retention time of volatiles and carbon monoxide .*ooinside the furnace due to locating the flue gas outlet 42 at the mid-section of the RHF 34 instead of at the feed end of the RHF.

Operating with an oxidizing atmosphere and high temperature in the early stage of heating and reduction causes the volatiles to ignite on or near the surface of the dry compacts forming a radiant flame which enhances the heat transfer to the compacts.

*In the final stage of reduction, the atmosphere maintained inside the furnace is overall oxidizing to metallic iron. This allows the burners to operate more I

I

-16efficiently, resulting in lower fuel consumption and the flexibility to use fuels such as pulverized coal and fuel oil. The reduced iron is protected from oxidation by: operating with a very short retention time of 4 to 10 minutes; avoiding disturbance of the protective blanket of carbon monoxide being evolved from the compacts in the final stages of reduction; and maintaining at least 1 percent excess carbon in the metallized compacts.

One method of partially cooling the metallized compacts is injecting a coolant from injector 116 on, or near, the compacts immediately prior to their discharge from the rotary hearth furnace. This coolant can comprise natural gas, pulverized coal, fuel oil or by-product gas. The coolant may dissociate into carbon and hydrogen. Some, or all, of the carbon may form carbon monoxide by reacting with carbon dioxide and water vapor. Free carbon deposited on the surface of the compacts will add further protection from oxidation. Reformed gases, carbon monoxide and hydrogen, provide additional blanket protection from the oxidizing products of combustion above the compacts. The dissociation and/or reforming of the coolant partially cools the hot compacts, transferring the heat to the reformed gases which are then allowed to be combusted in the rotary hearth furnace 34.

The advantages of this method are: improved atmosphere control at the hearth 20 level to avoid oxidation of metallic iron; highly metallized iron can be produced Shaving lower carbon content; energy efficiency is improved by using sensible heat in the metallized compacts to preheat part of the fuel for the rotary hearth S- furnace.

A second radiation barrier 100A is provided immediately prior to the cooling and S 25 discharge zone.

To assist in optimizing productivity and monitoring product quality, a water cooled gas sampling probe 118 is installed inside the rotary hearth furnace to collect gas samples less than one inch above the surface of the compacts just ___3111111 -17prior to discharge. As the metallization level of the compacts approaches 90 to the rate of reduction begins to slow and the amount of carbon monoxide evolved begins to decrease. By monitoring the carbon monoxide and oxygen content of the gas at this location, it is possible to predict product quality prior to obtaining chemical analyses of the product. A high carbon monoxide level indicates the reduction rate is still high and product metallization may be low. A medium level of carbon monoxide indicates the reduction rate has slowed and product metallization is high. A low carbon monoxide level and/or presence of oxygen indicates the reduction rate has stopped and the product may be oxidized. Based on this knowledge, adjustments can be made to hearth speed, loading, temperature and/or atmosphere as necessary to -maintain optimum productivity and product quality. The specific level of carbon monoxide and oxygen for the above three conditions must be calibrated for each furnace condition and feed mix.

The metallized compacts are discharged from the hearth 36 via one or more helical water-cooled screws 56. The discharge device also levels the hearth.

The hearth 36 is solid, is made of about 4 inches of the material being processed, and has wustite as a major constituent thereof. In this regard, it is a self-healing hearth. Any cracks or pits which develop are automatically filled with 20 fresh fines without concern for buckling of the refractory underneath.

i Alternative means for discharging of compacts from the hearth comprises at least one plow 120, as shown in Figures 6 and 7. The plow may be either straight or curved. As with a screw discharge, a plow discharge device also levels the hearth.

The temperature of the discharged product 58 is approximately 900 to 1210oC.

The product 58 can be hot charged into a melter 60, hot briquetted 62, or cooled 64 and stockpiled. If the discharged product is to be sent to a melter 60, then it may be placed in a transfer can 66 as hot direct reduced iron. It may also be desirable to send discharged product 58 to a briquetting press 68 for formation ~1111 -18of hot briquetted iron. Alternatively discharged product 58 can be sent to a rotary drum cooler 70 which produces cold direct reduced iron.

The reduction gas 72 after leaving the RHF 34 enters a flue gas conditioner 74.

Conditioned gas 76 is transferred to a heat exchanger 78 which is also fed with combustion air 80 through fan 82. Heat exchanger 78 serves to warm combustion air 80 into preheated air 54. After the conditioned flue gas 76 leaves the heat exchanger it is sent to the appropriate pollution control equipment 84.

Pollution control equipment is comprised of scrubbers, electrostatic precipitators, cyclones, and bag houses. Treated gas 86 is drawn out of the pollution control equipment 84 by a fan 88 and delivered to a stack 90 for discharge to the atmosphere 92. The hearth is conventionally sealed to the hearth enclosure by a water seal 106, as described in Beggs US Patent 3,452,972. The annular hearth is supported on wheeled members 108 which can be driven by any conventional driving means, as shown in Beggs US Patent 3,452,972 or in Hanewald et al. US Patent 4,597,564.

SUMMARY OF THE ACHIEVEMENT OF THE OBJECTS OF THE INVENTION ~From the foregoing, it is readily apparent that we have invented an improved method and apparatus for of achieving rapid and efficient reduction of iron oxide in a rotary hearth furnace. Advantages of this method are: improved atmosphere S 20 control at the hearth level to avoid oxidation of metallic iron; highly metallized iron can be produced having lower carbon content; energy efficiency is improved by using sensible heat in the metallized compacts to preheat part of the fuel for the rotary hearth furnace.

It is to be understood that the foregoing description and specific embodiments 25 are merely illustrative of the best mode of the invention and the principles thereof, and that various modifications and additions may be made to the apparatus by those skilled in the art, without departing from the spirit and scope -19of this invention which is therefore understood to be limited only by the scope of the appended claims.

a ea a a. a.

p a.

a.

a. pa a.

I. a

Claims (20)

1. A method for producing direct reduced iron from dry compacts composed of iron oxide and carbonaceous material and containing volatile materials therein, comprising: feeding said compacts no more than two layers deep onto a hearth; removing all of the volatile materials by exposing said compacts to a radiant heat source at a temperature of from about 1315 to about 1430oC for a first period of time of from one to three minutes and subjecting said compacts to an oxidizing atmosphere with sufficient free oxygen to burn most of the combustible gases evolved from the compacts during said first period of time, and form combusted gases; metallizing the compacts by exposing said compacts to a radiant heat source at a temperature of from about 1315 to about 1430 0 C in an atmosphere devoid of free oxygen for a second period of time of three to nine minutes; and causing said gases and said compacts to flow co-currently during said first period of time, and to flow countercurrently for said second period of time, and to form metallized iron product; and discharging said metallized iron product from the hearth. A method according to claim 1, wherein said metallizing of the compacts results from reducing, sintering, or partially melting the dry compacts.

3. A method according to claim 1 or 2, further comprising partially cooling the compacts while discharging them from the hearth.

4. A method according to any one of the preceding claims, wherein said metallized iron product is exposed to an atmosphere that is oxidizing to metallic 25 iron for the final three minutes of said second period of time, but is protected by excess carbon, or a thin blanket of carbon monoxide and/or hydrogen. -21- A method according to any one of the preceding claims, further comprising partial cooling of said metallized iron product prior to discharge by injecting a coolant on, or near, said metallized iron product immediately prior to the discharge of metallized iron product from the hearth.

6. A method according to claim 5, wherein said coolant is selected from the group consisting of natural gas, pulverized coal, fuel oil, and by-product gas.

7. A method according to any one of the preceding claims, wherein said iron oxide is selected from the group consisting of finely divided iron ores, iron oxide concentrates, by-product iron oxides, and steel mill wastes.

8. A method according to claim 1, wherein said carbonaceous material is selected from the group consisting of coal, coke breeze, petroleum coke, char, and charcoal fines.

9. A method according to any one of the preceding claims, wherein the iron oxide and carbonaceous material in said compact are bonded together with an organic binder. o.

10. A method according to any one of the preceding claims, wherein the energy for said radiant heating source is at least partially provided by combusting volatile materials and carbon monoxide emitted from said-Compacts.

11. A method according to any one of the preceding claims, wherein the 20 energy for said radiant heating source is at least partially provided by combusting fuel selected from the group consisting of natural gas, pulverized coal, fuel oil and by-product gas.

12. A method according to any one of the preceding claims, wherein oxygen :is introduced into the furnace to aid combustion, the oxygen source being 25 selected from the group consisting of preheated air, oxygen and oxygen enriched air. -22-

13. A method according to any one of the preceding claims, wherein the proportions of iron oxide and carbonaceous material in said compact are controlled to maintain a consistent fixed carbon to iron ratio.

14. A method according to any one of the preceding claims, further comprising discharging the partially cooled metallized iron product from said hearth into a hot transfer bin and hot charging the metallized iron product into a melting furnace. A method according to any one of the preceding claims, further comprising discharging the partially cooled metallized iron product from said hearth into a briquetting press to produce hot briquetted iron.

16. Apparatus for producing metal from direct reduced iron from dry compacts of iron oxide and particulate carbonaceous material in a rotary hearth furnace, comprising: a. means for mixing iron oxide fines and particulate carbonaceous material and forming dry compacts; b. a rotary hearth furnace having a generally flat hearth surface for receiving the dry compacts; Sc. means for feeding the dry compacts in no more than two layers on *S.o the surface of said hearth; 20 d. means for heating, reducing, and sintering or partially melting said "dry compacts on said hearth to form a reduced product; f. means for discharging said reduced compacts from said rotary hearth furnace; and g. means intermediate said feeding means and said discharge means P:S 25 for removing flue gas from said rotary hearth furnace.

17. Apparatus according to claim 16, further comprising means for partially cooling the compacts while discharging them from the hearth. -23-

18. Apparatus according to claim 16 or 17, wherein said means for feeding said compacts one to two layers deep onto the hearth comprises at least one adjustable vertical feed pipe having an adjustable gate, or leveller, having a lower edge to control the thickness of the layer.

19. Apparatus according to any one of claims 16 to 18, wherein said means for discharging of compacts from the hearth comprises at least one helical screw. Apparatus according to any one of claims 16 to 19, wherein said means for discharging of compacts from the hearth comprises at least one plow.

21. Apparatus according to any one of claims 16 to 20, further comprising means for injecting a coolant onto or near said compacts immediately prior to the discharge of compacts from the hearth.

22. Apparatus according to any one of claims 16 to 21, further comprising a watercooled probe for collecting a gas sample less than one inch above the surface of said compacts immediately prior to their discharge from said hearth, whereby the levels of carbon monoxide and oxygen in said gas sample are ,',*,monitored for purposes of product quality control and/or optimization of °productivity.

23. Apparatus for producing metal from direct reduced iron substantially as herein described with reference to the description of the embodiment and 0 6* drawings. a __ili I-^i ~I -_L11 I~ I -24-

24. A method for producing direct reduced iron from dry compacts composed of iron oxide and carbonaceous material and containing volatile materials therein, substantially as herein described with reference to the description of the embodiment. DATED this twentieth day of March 1998 MIDREX DIRECT REDUCTION CORPORATION Applicant WRAY ASSOCIATES Perth, Western Australia Patent Attorneys for Applicant a 0.e *be *be be* be be 0