AU2018202315B2

AU2018202315B2 - Power generating system using low quality coal

Info

Publication number: AU2018202315B2
Application number: AU2018202315A
Authority: AU
Inventors: Shintaro Honjo; Makoto Susaki; Takahito Yonekawa
Original assignee: Mitsubishi Heavy Industries Engineering Ltd
Current assignee: Mitsubishi Heavy Industries Engineering Ltd
Priority date: 2014-03-13
Filing date: 2018-04-03
Publication date: 2019-11-14
Anticipated expiration: 2034-03-13
Also published as: CN106062482A; DE112014006458T5; CA2941843A1; JP6278576B2; JPWO2015136678A1; DE112014006458B4; CA2941843C; AU2018202315A1; WO2015136678A1; AU2014386062A1

Abstract

Il:\NZL\Interwovn\NRPortbl\DCC\NZL\ 6729408 I.docx-304/2018 Abstract A power generating system (A) using low quality coal includes a low quality coal refining facility (3) that heats the low quality coal (2) to refine the low quality coal into high grade coal (4), a CO 2 recovery facility (6) that recovers CO 2 from an exhaust gas (7) generated by refining the low quality coal (2) in the low quality coal refining facility (3), while using steam (8) generated by refining the low quality coal (2) in the low quality coal refining facility (3), and a power generating facility (5) that performs the power generation using, as fuel, the high-grade coal obtained by refining the low quality coal (2) in the low quality coal refining facility (3). LO> C-,) 00 (D r-L. a- >

Description

POWER GENERATING SYSTEM USING LOW QUALITY COAL [0001]

The entire content of the complete specification of Australian Patent Application No. 2014386062 as originally filed is incorporated herein by reference.

[0001A]

The present invention relates to, for example, a power generating system using low quality coal such as subbituminous coal or lignite.

[0002]

For example, low quality coal such as subbituminous coal or lignite generally contains moisture, has a low carbonization degree, and has a low calorific value at the combustion. Further, if such low quality coal is directly used as fuel for a power generating facility (a power generating plant) such as a coal-fired power plant, the power generation efficiency decreases and the amount of CO2 emission per unit greatly increases. Accordingly, low quality coal is used as a fuel of a power generating facility, for example, by supplying low quality coal dried and refined in advance to a boiler or by providing a drying process before combustion in a power generating facility to perform refining for increasing a calorific value (e.g., see Patent Literature 1).

Citation List

Patent Literature [0003] [Patent Literature 1] Japanese Unexamined Patent Application, First Publication No. Hl 1-082991 [0004]

However, when low quality coal is refined, it is necessary to obtain a heat source

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ I .docx-15/10/2019

-2for drying the low quality coal by burning the low quality coal itself or by burning different fuel. Accordingly, the amount of CO2 emission can be reduced by only several percent, e.g., about 2 to 3%, even when the low quality coal is refined by applying labor and cost.

[0005]

Further, a CO2 recovery facility (a CO2 recovery apparatus) for recovering and removing CO2 from an exhaust gas exhausted from a boiler or the like in a power generating facility such as a coal-fired power plant has been proposed. This CO2 recovery facility includes, for example, an absorption tower that brings an amine-based CO2 absorption liquid into contact with an exhaust gas so that CO2 in the exhaust gas is absorbed into the CO2 absorption liquid, and a regeneration tower that dissociates and recovers CO2 by heating, using steam, the CO2 absorption liquid that has absorbed CO2 in the absorption tower to regenerate the amine CO2 absorption liquid.

[0006]

Further, when such a CO2 recovery facility is applied to a power generating facility such as a coal-fired power plant, steam generated in a boiler is used for regeneration of the CO2 absorption liquid in the regeneration tower, which may cause degradation of turbine efficiency, and thus degradation of the amount of power generated of, for example, 20 to 30%. Furthermore, when low quality coal is used as fuel, degradation of recovery efficiency of CO2 and degradation of the amount of power generated may be caused.

[0007]

Further, when a CO2 recovery apparatus is applied to a coal-fired power plant, it is necessary to treat a large amount of exhaust gas, which may increase facility cost and cause a great increase in the cost of power generation.

[0008]

According to the present invention, there is provided a power generating system using low quality coal as fuel for a boiler to perform power generation, the power generating system

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ I .docx-15/10/2019

-3 comprising: a low quality coal refining facility comprising a drying/dry distillation apparatus that heats the low quality coal to refine the low quality coal into high-grade coal and to generate steam and exhaust gas including CO2 by heating the low quality coal; a CO2 recovery facility comprising an absorption tower which absorbs CO2 included in the exhaust gas generated by the low quality coal refining facility, and a regeneration tower which discharges the CO2 using the steam generated by the low quality coal refining facility; a power generating facility that performs the power generating using, as fuel, the high-grade coal obtained by refining the low quality coal in the low quality coal refining facility; wherein the absorption tower receives the exhaust gas and brings the exhaust gas into contact with CO2 absorption liquid comprising amines to absorb and remove CO2 from the exhaust gas, and the regeneration tower dissociates CO2 from the CO2 absorption liquid that has absorbed CO2 in the absorption tower, by heating the CO2 absorption liquid with the steam generated by the low quality coal refining facility to separate and recover CO2 in a gaseous state.

[0008A]

The system according to the preferred embodiments of the invention includes a steam supplier supplying the steam generated by refining the low quality coal in the low quality coal refining facility to the CO2 recovery facility.

[0009]

In the power generating system using low quality coal, the power generating system may include a CO2 transportation facility for transporting CO2 recovered in the CO2 recovery facility to an oil production plant.

[0010]

In the power generating system using low quality coal, the low quality coal refining facility may be provided near a coal mine from which the low quality coal is produced.

[0011]

In the power generating system using low quality coal, the CO2 transportation facility may be a pipeline that connects the low quality coal refining facility with the CO2

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ I .docx-15/10/2019

-4recovery facility.

[0012]

In the power generating system using low quality coal described above, it is possible to improve a calorific value and thus improve power generation efficiency of a coal-fired power plant by refining the low quality coal in the low quality coal refining facility provided separately from a power generating facility.

[0013]

Further, it is possible to reduce the amount of exhaust gas at the time of use as boiler fuel by treating, in the CO2 recovery facility provided separately from the power generating facility, the exhaust gas exhausted by refining the low quality coal in the low quality coal refining facility, and reduce the amount of emissions of environmental pollution such as CO2, SOx, NOx, and Hg. Accordingly, it is possible to reduce capital costs and operational costs of a pollution control facility.

[0013 A]

The present invention will now be described, by way of non-limiting example only, with reference to the accompanying drawings briefly described as follows.

[0014]

Fig. 1 is a diagram illustrating a power generating system according to an embodiment of the present invention.

[0015]

Hereinafter, a power generating system using low quality coal according to an embodiment of the present invention will be described with reference to Fig. 1.

[0016]

A power generating system A using low quality coal of the present embodiment

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ 1 .docx-15/10/2019

-5 includes a low quality coal refining facility 3 that refines low quality coal (coal having low quality) 2 such as subbituminous coal or lignite produced from a mine 1, a power generating facility 5 that performs power generation using, as a fuel, high-grade coal (coal having high quality) 4 obtained by refining the low quality coal 2 in the low quality coal refining facility 3, and a CO2 recovery facility 6 that recovers CO2 generated in the low quality coal refining facility 3, as shown in Fig. 1.

[0017]

The low quality coal refining facility 3 is a facility that heats the low quality coal 2 to refine the low quality coal 2 into the high-grade coal 4, and includes, for example, a drying/dry distillation apparatus that performs a drying treatment or a dry distillation treatment to heat the low quality coal 2 and vaporize moisture.

[0018]

The power generating facility 5 is a coal-fired power generating facility that includes a boiler that generates steam using coal as fuel, and a turbine driven by the steam generated in the boiler. Further, this power generating facility 5 is configured to perform power generation, for example, by driving a high pressure turbine by high pressure and high temperature steam generated in the boiler, overheating an exhaust gas of the high pressure turbine in a re-superheater of the boiler, driving a moderate pressure turbine by reoverheated moderate pressure steam, and driving a low pressure turbine using an exhaust gas of the moderate pressure turbine. Further, the power generating facility 5 includes an exhaust gas treating facility such as a condenser, a desulfurization apparatus, and a chimney.

[0019]

The CO2 recovery facility 6 includes an absorption tower for receiving exhaust gas 7 and steam 8 generated by heating the low quality coal 2 in the low quality coal refining facility 3 and bringing the exhaust gas 7 into contact with CO2 absorption liquid to absorb and remove CO2 from the exhaust gas 7, and a regeneration tower for receiving the CO2 absorption liquid that has absorbed CO2 in the absorption tower and separating and

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ I .docx-15/10/2019

-6recovering CO2 absorbed into the CO2 absorption liquid.

[0020]

In the absorption tower, an absorption liquid scrubber that sprays the CO2 absorption liquid in a mist form is provided therein, and the CO2 absorption liquid sprayed from this absorption liquid scrubber and the exhaust gas 7 introduced from the low quality coal refining facility 3 to the inside of the absorption tower through a communication duct and flowing from a lower part of the absorption tower to an upper part thereof are brought into contact with each other. Accordingly, CO2 in the exhaust gas 7 is dissolved in and absorbed into the CO2 absorption liquid, and the treated exhaust gas from which CO2 has been removed is released from the upper part to the outside. Further, the CO2 absorption liquid having absorbed CO2 is accumulated in the lower part of the absorption tower.

[0021]

Further, it is desirable for the absorption tower to be configured to include a scrubber or a demister that sprays cooling water in a mist form, which is provided above the internal absorption liquid scrubber, and to capture and remove, using the cooling water, gaseous substances and particulate substances in the exhaust gas 7 that have not been collected into the CO2 absorption liquid.

[0022]

Further, for example, an amine-based absorption liquid may be adopted as the CO2 absorption liquid. Specifically, an alkanolamine such as monoethanolamine, diethanolamine, triethanolamine, methyldiethanolamine, diisopropanolamine, or diglycolamine may be adopted as the CO2 absorption liquid. Further, hindered amines may be adopted. Further, each water solution of the material or a water solution obtained by mixing two or more of the materials may be used as the CO2 absorption liquid.

[0023]

The regeneration tower separates and recovers CO2 from the CO2 absorption liquid that has absorbed CO2 or the like in the absorption tower. An absorption liquid

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ 1 .docx-15/10/2019

-7transportation pipe for introducing the CO2 absorption liquid from the absorption tower is connected to an upper part of the regeneration tower. Further, the CO2 absorption liquid accumulated in the lower part of the absorption tower is sprayed and supplied from the upper part to the inside of the regeneration tower by driving a liquid transportation pump of the absorption liquid transportation pipe. Further, in the regeneration tower, high temperature steam is supplied from the lower part and the sprayed CO2 absorption liquid is heated. Accordingly, CO2 is dissociated from the CO2 absorption liquid and desorbed, and the desorbed CO2 is derived from the upper part of the regeneration tower to the outside. Further, the derived CO2 is cooled, compressed in a compressor, and is recovered as compressed CO2.

[0024]

In this case, in the present embodiment, the steam 8 generated when the low quality coal 2 is heated and refined into the high-grade coal 4 in the low quality coal refining facility 3 is provided to the regeneration tower, and the CO2 absorption liquid is heated using the steam 8 generated in the low quality coal refining facility 3. Accordingly, it is unnecessary to separately supply steam generated in a boiler or the like to the regeneration tower.

[0025]

Further, the CO2 absorption liquid from which CO2 has been dissociated and removed in this way is accumulated in the lower part of the regeneration tower, a return pump provided in an absorption liquid supply pipe is driven, and the CO2 absorption liquid is cooled by a cooler and sent to the absorption tower. In other words, in the present embodiment, the CO2 absorption liquid having absorbed CO2 or the like is sent from the absorption tower to the regeneration tower through the absorption liquid transportation pipe, and the CO2 absorption liquid from which CO2 has been recovered in the regeneration tower is returned from the regeneration tower to the absorption tower through the absorption liquid supply pipe again, to thereby circulate the CO2 absorption liquid between the absorption tower and the regeneration tower so that the recovery of CO2 is performed.

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ 1 .docx-15/10/2019

-8[0026]

A simulation result for the power generating system using low quality coal of the present embodiment will be described herein. First, for example, the low quality coal refining facility 3 produces the high-grade coal 4 whose calorific value is 11,340 Btu/lb at a rate of 178 ton/h by treating the low quality coal 2 whose calorific value is 8,000 Btu/lb at a rate of 308 ton/h. Accordingly, it was confirmed that when the high-grade coal 4 is used as fuel of the boiler of the coal fired power generating facility 5, a great calorific value can be obtained with a small amount of the high-grade coal 4 and the power generation efficiency increases by 2%. Further, when the low quality coal 2 is refined into the high-grade coal 4 in the low quality coal refining facility 3 in this way, CO2 (10% -wet) of 2,778 tpd and the exhaust gas 7 of 586,835 Nm³/h are generated.

[0027]

Further, when the high-grade coal 4 refined in the low quality coal refining facility 3 is used as the fuel of the boiler of the coal fired power generating facility 5, the amount of CO2 emissions are reduced to 9,246 tpd as compared with the amount of CO2 emissions being 9,703 tpd when the lower coal 2 is used. Further, when the exhaust gas 7 exhausted from the low quality coal refining facility 3 is treated in the CO2 recovery facility 6 configured as described above, CO2 in the exhaust gas 7 can be recovered at a recovery rate of 90%, recovering CO2 of 2,500 tpd.

[0028]

Further, according to the power generating system using low quality coal of the present embodiment, it was confirmed that a total CO2 exhaust ratio is changed from 940 ton/GWh to 881 ton/GWh, and a reduction of about 6%, as compared with a case in which the low quality coal 2 is directly used.

[0029]

Here, in an oil production plant, when the amount of collection of the oil using a primary collection method is decreased, artificial oil discharge energy is given to an oil

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ I .docx-15/10/2019

-9layer to increase the amount of collection of the oil and increase a recovery rate of the oil. Further, an enhanced oil (crude oil) recovery technique (EOR: Enhanced Oil Recovery) includes a water flooding method of injecting water, a method of injecting natural gas, CO2 or the like, a thermal recovery method, or a chemical method.

[0030]

For example, the low quality coal refining facility 3 is provided near the coal mine 1 from which the low quality coal 2 is produced, the CO2 recovery facility 6 is provided near the low quality coal refining facility 3, and a CO2 transportation facility that transports CO2 recovered in the CO2 recovery facility 6 to the oil production plant is provided, and this CO2 transportation facility includes a pipeline that connects the CO2 recovery facility 6 with the oil production plant, thereby constituting the power generating system A. With this configuration, it is possible to efficiently refine the low quality coal 2 in the low quality coal refining facility 3, the low quality coal 2 produced from the coal mine 1 and produce the high-grade coal 4, and to efficiently treat the exhaust gas 7 in the CO2 recovery facility 6, the exhaust gas 7 generated by refining the low quality coal 2 in the low quality coal refining facility 3.

[0031]

Further, when the CO2 transportation facility such as the pipeline transporting CO2 recovered in the CO2 recovery facility 6 to the oil production plant is provided, compressed CO2 recovered in the CO2 recovery facility 6 can be supplied to the oil production plant and used as CO2 for EOR. Further, CO2 recovered in the CO2 recovery facility 6 may be accumulated deep underground to prevent CO2 from being released to the atmosphere and causing global warming.

[0032]

Accordingly, in the power generating system using low quality coal of the present embodiment, it is possible to improve a calorific value and thus to improve the power generation efficiency of the coal-fired power plant 5 by refining the low quality coal 2. Further, it is necessary to pulverize the low quality coal 2 when the low quality coal 2 is

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ I .docx-15/10/2019

- loused as the fuel of the boiler, while it is possible to reduce mill power by refining the low quality coal 2. Furthermore, when there is a sufficient turbine capacity, it is possible to increase the amount of power generated and achieve increase in power generating revenue by increasing the amount of using of the low quality coal 2 (the amount of supply of the refined low quality coal).

[0033]

Further, it is possible to reduce the amount of exhaust gas at the time of use as the boiler fuel and reduce the amount of emissions of environmental pollution such as CO2, SOx, NOx, and Hg, by refining the low quality coal 2. Accordingly, it is possible to reduce capital costs and operational cost of a pollution control facility.

[0034]

Further, it is possible to remove the environmental pollution such as CO2, SOx, NOx, and Hg, and minimize emission reduction measure costs for the environmental pollution, by treating the exhaust gas 7 from the low quality coal refining facility 3 with the CO2 recovery facility 6,.

[0035]

Further, it is possible to reduce the amount of CO2 emissions and use recovered CO2 for, for example, EOR by treating CO2 in the exhaust gas 7 from the low quality coal refining facility 3 with the CO2 recovery facility 6 which provided separately from the power generating facility 5,.

[0036]

Further, since the amount of exhaust gas can be reduced in the case in which the low quality coal 2 is refined in the low quality coal refining facility 3 compared with a case in which the low quality coal 2 is directly used in the power generating facility 5, remodeling of an existing facility is minimized and facility costs can be greatly reduced.

[0037]

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ 1 .docx-15/10/2019

- 11 Furthermore, by using the steam 8 generated with the low quality coal refining facility 3 with the CO2 recovery facility 6, it is possible to cause a power penalty to be zero and build an efficient power generating system using low quality coal.

[0038]

While the embodiment of the power generating system using low quality coal according to the present invention has been described above, the present invention is not limited to the embodiment and may be appropriately modified without departing from the scope and spirit of the present invention.

[0039]

In the power generating system using low quality coal described above, it is possible to improve a calorific value and thus improve power generating efficiency of a coal-fired power plant by refining the low quality coal in the low quality coal refining facility provided separately from the power generating facility.

Further, it is possible to reduce the amount of exhaust gas at the time of use as boiler fuel and reduce the amount of environmental pollution such as CO2, SOx, NOx, or Hg, by treating, in the CO2 recovery facility provided separately from the power generating facility, the exhaust gas exhausted by refining the low quality coal in the low quality coal refining facility. Accordingly, it is also possible to reduce the capital cost and operational costs of a pollution control facility.

Reference signs List [0040] mine (coal mine) low quality coal low quality coal refining facility high-grade coal

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ I .docx-15/10/2019 power generating facility

CO2 recovery facility exhaust gas steam

A power generating system using low quality coal [0041]

While various embodiments of the present invention have been described above, it should be understood that they have been presented by way of example only, and not by way of limitation. It will be apparent to a person skilled in the relevant art that various changes in form and detail can be made therein without departing from the spirit and scope of the invention. Thus, the present invention should not be limited by any of the above described exemplary embodiments.

[0042]

The reference in this specification to any prior publication (or information derived from it), or to any matter which is known, is not, and should not be taken as an acknowledgment or admission or any form of suggestion that that prior publication (or information derived from it) or known matter forms part of the common general knowledge in the field of endeavour to which this specification relates.

[0043]

Throughout this specification and the claims which follow, unless the context requires otherwise, the word comprise, and variations such as comprises and comprising, will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.

Claims

THE CLAIMS DEFINING THE INVENTION ARE AS FOLLOWS:

1. A power generating system using low quality coal as fuel for a boiler to perform power generation, the power generating system comprising:

a low quality coal refining facility comprising a drying/dry distillation apparatus that heats the low quality coal to refine the low quality coal into high-grade coal and to generate steam and exhaust gas including CO2 by heating the low quality coal;

a CO2 recovery facility comprising an absorption tower which absorbs CO2 included in the exhaust gas generated by the low quality coal refining facility, and a regeneration tower which discharges the CO2 using the steam generated by the low quality coal refining facility;

a power generating facility that performs the power generating using, as fuel, the high-grade coal obtained by refining the low quality coal in the low quality coal refining facility; wherein the absorption tower receives the exhaust gas and brings the exhaust gas into contact with CO2 absorption liquid comprising amines to absorb and remove CO2 from the exhaust gas, and the regeneration tower dissociates CO2 from the CO2 absorption liquid that has absorbed CO2 in the absorption tower, by heating the CO2 absorption liquid with the steam generated by the low quality coal refining facility to separate and recover CO2 in a gaseous state.
2. The power generating system using low quality coal according to claim 1, further comprising:

a CO2 transportation facility for transporting CO2 recovered in the CO2 recovery facility to an oil production plant or a geological storage site.
3. The power generating system using low quality coal according to claim 1, wherein:

the low quality coal refining facility is provided near a coal mine from which the low quality coal is produced.
4. The power generating system using low quality coal according to claim 2, wherein:

the low quality coal refining facility is provided near a coal mine from which the low quality coal is produced.

C:\Interwoven\NRPortbl\DCC\MAS\ 19421870_ I .docx-15/10/2019

2018202315 15 Oct 2019
5. The power generating system using low quality coal according to claim 2, wherein: the CO2 transportation facility is a pipeline that connects the low quality coal refining facility with the CO2 recovery facility.
6. The power generating system using low quality coal according to claim 3, wherein:

5 the CO2 transportation facility is a pipeline that connects the low quality coal refining facility with the CO2 recovery facility.
7. The power generating system using low quality coal according to claim 4, wherein: the CO2 transportation facility is a pipeline that connects the low quality coal refining facility with the CO2 recovery facility.