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AU2018247222B2 - High-carbon and high-strength and toughness pearlitic rail and manufacturing method thereof - Google Patents

High-carbon and high-strength and toughness pearlitic rail and manufacturing method thereof Download PDF

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AU2018247222B2
AU2018247222B2 AU2018247222A AU2018247222A AU2018247222B2 AU 2018247222 B2 AU2018247222 B2 AU 2018247222B2 AU 2018247222 A AU2018247222 A AU 2018247222A AU 2018247222 A AU2018247222 A AU 2018247222A AU 2018247222 B2 AU2018247222 B2 AU 2018247222B2
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Prior art keywords
rail
railhead
toughness
strength
pearlitic
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AU2018247222A1 (en
Inventor
Hua Guo
Zhenyu Han
Jun Yuan
Ming Zou
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Angang Steel Co Ltd
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Angang Steel Co Ltd
Pangang Group Research Institute Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/08Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel
    • B21B1/085Rail sections
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/74Temperature control, e.g. by cooling or heating the rolls or the product
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/62Quenching devices
    • C21D1/667Quenching devices for spray quenching
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/005Modifying the physical properties by deformation combined with, or followed by, heat treatment of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/04Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rails
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B2001/225Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length by hot-rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/001Austenite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/003Cementite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/009Pearlite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention relates to the technical field of rail manufacturing, and particularly to a high-carbon and high-strength and toughness pearlitic rail and its manufacturing method. In view of the problem of uneven performance of railhead sections of the pearlitic rail manufactured with existing technique and the poor performance of the pearlitic rail obtained, the invention provides a manufacturing method for high-carbon and high-strength and toughness pearlitic rail, comprising the following steps to: a. hot roll the steel billet into rail, with a final rolling temperature of 900-1000°C; b. blow a cooling medium to the top surface of railhead, wherein, the two sides of railhead and the lower jaws on two sides of railhead when the center of top surface of rail is air-cooled to 800-850°C; then air-cool the rail to room temperature after the center of top surface of rail is cooled to 480-530°C. By controlling the composition of steel and adopting a two-stage accelerated cooling, the invention is able to produce a high-carbon rail with better strength and excellent toughness which is suitable for heavy-haul railway.

Description

High-Carbon and High-Strength and toughness Pearlitic Rail and
Manufacturing Method Thereof
Related Application
This application claims priority from Chinese patent application 201710934583.9 filed
10 October 2017, the contents of which are to be taken as incorporated herein by this
reference.
Field of the Invention
The invention relates to a rail, particularly to a high-carbon and high-strength and
toughness pearlitic rail and the manufacturing method thereof.
Background of the Invention
The rapid development of railway has higher requirements for the service performance
of rail. With the continuous improvement of China's high-speed railway network,
heavy-haul transformation will be conducted gradually for the existing main railway lines
with passenger and freight mixed traffic. And the heavy-haul railway will develop towards
large volume, high axle load and high density. As a key component of railway, the quality
and performance of rail are closely related to the transport efficiency of railway and the
safety of traffic. With the improvement of the transportation capacity of railway, the service
environment of rail has become increasingly harsh and complex and all kinds of defects and
failures have occurred. Some rails at small radius curves have defects and failures such as
rapid abrasive wear and peeling-off simultaneously, making their service life inconsistent
with that of the main line rail, thus limiting the further development of railway
transportation.
Currently, the method of on-line or off-line heat treatment for pearlitic rail is mainly
adopted to improve performance of the rail at curves. By blowing compressed air or
water-air spray mixture to the railhead of austenitic rail, the railhead is rapidly cooled, and
it is able to produce refined and lamellar perlite structure from the surface of the railhead to
a certain depth. The strength and toughness of rail can be improved synchronously through grain refinement, so that the wear resistance and contact fatigue resistance can be improved simultaneously. In terms of accelerated cooling process, few research reports on the influence of cooling nozzle layout to the performance of rail are available at home and abroad. Patent CN101646795B, Internal High-Hardness Type Pearlitic Rail with Excellent Wear Resistance and Fatigue Damage Resistance and Manufacturing Method Thereof, specifies a manufacturing method for an internal high-hardness pearlitic rail, characterized in that, the steel is hot rolled into a rail-like shape with a final rolling temperature of 850-950°C, and then the surface of railhead is rapidly cooled from the temperature above the pearlitic transformation temperature to 400-650°C at a rate of 1.2-5°C/s. The patent only specifies the temperature to start and end cooling as well as corresponding range of cooling rate at different stages of heat treatment for rail, but does not specify any cooling methods. Patent CN105483347A discloses A Heat Treatment Technique for Hardening Pearlitic Rail, characterized in that a rail is heated to 880-920°C and insulated for 10-15min, and then cooled to specific temperature range at specific range of cooling rate according to different steel types and insulated for 30s, and then air-cooled, with specific conditions as follows: the process for hardening U75V pearlitic rail is: to insulate the rail at 880-920°C for 10-15min, and cool the rail to 570-600°C at a cooling rate of 8-15°C/s, and then air cool the rail to 20-25°C at a cooling rate of 0.2-0.5°C/s; the process for hardening U76CrRE pearlitic rail is: to insulate the rail at 850-900°C for 10-15min, and cool the rail to 590-610°C at a cooling rate of 6-10°C/s, and then air cool the rail to 20-25°C at a cooling rate of 0.2-0.5°C/s. The heat treatment technique for the two grades of materials, i.e. U75V and U76CrRE, disclosed by the patent also does not specify any cooling methods. Patent CN103898303A discloses A Heat Treatment Method for Turnout Rail and Turnout Rail, characterized in that, accelerated cooling is carried out for a turnout rail to be treated with temperature of the top surface of the railhead of 650-900°C to get the turnout rail with fully pearlitic structures, wherein, the accelerated cooling rate of the working side of the railhead of the turnout rail is higher than that of the non-working side of the railhead of the turnout rail, with a difference of 0.1-1.0°C/s. The patent specifies the benefits of different cooling rates on two sides of the railhead for the rail, especially for improving performance and controlling flatness of the rail with asymmetric section, but it does not clarify the influence of nozzle layout and cooling rate at different stages to the performance of rail after heat treatment. In prior art, the heat treatment for rail is mainly focused on controlling different cooling rates in different temperature ranges to control heat treatment processes, it does not specify the refined control such as various nozzle layout and blowing method, therefore, no high-carbon pearlitic rail with excellent strength and toughness can be obtained. A reference herein to a patent document or any other matter identified as prior art, is not to be taken as an admission that the document or other matter was known or that the information it contains was part of the common general knowledge as at the priority date of any of the claims.
Summary of the Invention Embodiments of the invention may solve a technical problem in prior art. In particular the methods adopting different cooling rates in different temperature ranges are used for the heat treatment of rail, therefore the pearlitic rail obtained may have poor performance. According to an aspect of the present invention, there is provided a manufacturing method for high-carbon and high-strength and toughness pearlitic rail, comprising the following steps: a. Rolling of rail to hot roll steel billet into rail, with a final rolling temperature range of 900-100 0 °C; b. Cooling of rail (i) air cooling the rail after hot rolling; (ii) blowing a cooling medium to a top surface of a railhead, to two sides of the railhead, and lower jaws on the two sides of the railhead after a center of the top surface of the rail is air-cooled to 800-850°C; (iii) air-cooling the rail to room temperature after the center of the top surface of the rail is cooled to 480-530°C, a composition (in weight percentage) of the rail in step a is: C: 0.86%-1.05%, Si: 0.20% 0.50%, Mn: 0.50%-0.95%, Cr: 0.20%-0.40%, at least one of V, Nb and Ti, wherein V of
0.02%-0.10% if any, Ti of 0.001%-0.030% if any and Nb of 0.005%-0.08% if any, and the rest of Fe and inevitable impurities. In one embodiment, in the manufacturing method for high-carbon and high-strength and toughness pearlitic rail, the cooling medium in step b is at least one of compressed air and water-air spray mixture. In one embodiment, in the manufacturing method for high-carbon and high-strength and toughness pearlitic rail, the cooling rate in step b is 2.0-5.0°C/s. Embodiments of the invention also provides a high-carbon high-strength and toughness pearlitic rail, with the composition (in weight percentage) of: C: 0.86%-1.05%, Si: 0.20% 0.50%, Mn: 0.50%-0.95%, Cr: 0.20%-0.40%, at least one of V, Nb and Ti, wherein V of 0.02%-0.10% if any, Ti of 0.001%-0.030% if any and Nb of 0.005%-0.08% if any, and the rest of Fe and inevitable impurities. Compared with the prior art, the beneficial effects of various embodiments of the invention lie in that: embodiments of the invention uses a rail with specific composition and adopts a method of two-stage accelerated cooling, therefore, compared with the existing single method for heat treatment, the pearlitic rail manufactured in this method has more excellent strength, hardness, toughness and plasticity, especially a much better strength and toughness. The method according to embodiments of the invention can be easily conducted and has low requirement for equipment, and the high-carbon and high-strength and toughness pearlitic rail manufactured can enhance the overall strength and toughness of railhead and prolong the service life of rail under the same conditions.
Detailed Description of the Preferred Embodiments The invention provides a manufacturing method for a high-carbon and high-strength and toughness pearlitic rail, comprising the following steps: a. Rolling of rail to hot roll steel billet into rail, with a final rolling temperature range of 900-1000°C; b. Cooling of rail to blow a cooling medium to the top surface of railhead, wherein, the two sides of railhead and the lower jaws on two sides of railhead when the center of top surface of rail is air-cooled to 800-850°C; then to air-cool the rail to the room temperature after the center of top surface of rail is cooled to 480-530°C.
The high-carbon and high-strength and toughness pearlitic rail of the invention has the
composition (in weight percentage) of: C: 0.86%-1.05%, Si: 0.20%-0.50%, Mn:
0.50%-0.95%, Cr: 0.20%-0.40%, at least one of V, Nb and Ti, wherein V of 0.02%-0.10%
if any, Ti of 0.001%-0.030% if any and Nb of 0.005%-0.08% if any, and the rest of Fe and
inevitable impurities.
C is the most important and cheapest element to improve strength and hardness of
pearlitic rail and to promote pearlitic transformation. Under the conditions of the present
invention, when the content of C<0.86%, the strength and hardness obtained by using the
manufacturing technique of the invention are too low and the wear resistance required for
the heavy-haul railway cannot be guaranteed; when the content of C>1.05%, massive
secondary cementite is precipitated at grain boundaries even though accelerated cooling is
adopted after final rolling, thus deteriorating the toughness and plasticity of the rail.
Therefore, the content of C is limited within the range of 0.86%-1.05%.
As the solid-solution strengthening element of steel, Si is present in ferrite and
austenite to improve strength of structure, meanwhile, it can suppress precipitation of
proeutectoid cementite, thus improving the toughness and plasticity of the rail. Under the
conditions of the present invention, when the content of Si<0.20%, the solid solubility is
relatively low, leading to low strengthening effects; when the content of Si>0.50%, the
toughness and plasticity of the rail degrades and the transverse performance of the rail
deteriorates. Therefore, the content of Si is limited within the range of 0.20%-0.5 0 %.
Mn can form solid solution with Fe, strengthening ferrite and austenite. Meanwhile,
Mn is also a carbide former and can partially replace Fe atom after entering cementite,
improving hardness of carbide and finally improving hardness of the rail. Under the conditions of the present invention, when the content of Mn<0.50%, the strengthening effect is not obvious and the performance of steel can only be slightly improved through solid-solution strengthening; when the content of Mn>0.95%, the hardness of the carbide in steel is too high and the toughness and plasticity significantly degrade; meanwhile, Mn has obvious diffusion effect to carbon when in steel, and the segregation zone of Mn can still produce B, M and other abnormal structures even under the air-cooling condition. Therefore, the content of Mn is limited within the range of 0.50%-0.95%. As a medium carbide former, Cr can form multiple carbides with carbon in steel; meanwhile, Cr can produce even distribution of carbides in steel, reduce the size of carbides and improve wear resistance of the rail. Under the conditions of the present invention, when the content of Cr<0.20%, the carbide formed has low hardness and low proportion, and aggregates in the form of sheet, in this way, the wear resistance of the rail cannot be improved effectively; when the content of Cr>0.40%, coarse carbide is prone to form, thus deteriorating the toughness and plasticity of the rail. Therefore, the content of Cr is limited within the range of 0.20%-0.40%. V has low solubility in steel when under room temperature, and if V is present in austenite grain boundaries and other zones during hot rolling, it is precipitated through fine-grained V carbonitride [V (C, N)] or together with Ti in steel, suppressing the growth of austenite grains and thus refining grain and improving performance. Under the conditions of the present invention, when the content of V<0.02%, the precipitation of V carbonitride is limited and the rail cannot be strengthened effectively; when the content of V>0.10%, coarse carbonitride is prone to form, thus deteriorating the toughness and plasticity of the rail. Therefore, the content of V is limited within the range of 0.02%-0.10%. The main function of Ti in steel is to refine austenite grains during heating, rolling and cooling, and finally improve extensibility and rigidity of the rail. When the content of Ti<0.001%, the amount of carbides formed in the rail is extremely limited. Under the condition of the present invention, when the content of Ti>0.030%, on one hand, excessive TiC forms since Ti is a strong carbonitride former, making the hardness of the rail too high, and on the other hand, excessive TiN and TiC may lead to segregation enrichment and form coarse carbonitride, degrading the toughness and plasticity and making the contact surface of the rail prone to crack under impact load and leading to fracture. Therefore, the content of Ti is limited within the range of 0.001%-0.030%.
The main function of Nb in steel is similar to that of V, i.e., to refine austenite grains
with the Nb carbonitride precipitated and to make precipitation strengthening occur with
the carbonitride produced during the cooling process after rolling. Nb can improve hardness
of the rail, enhance toughness and plasticity of the rail and help prevent softening of welded
joints. Under the condition of the present invention, when the content of Nb<0.005%, the
precipitation of Nb carbonitride is limited and the rail cannot be strengthened effectively;
when the content of Nb>0.08%, coarse carbonitride is prone to form, thus deteriorating the
toughness and plasticity of the rail. Therefore, the content of Nb is limited within the range
of 0.005%-0.08%. The common smelting method in the art is adopted to smelt steel for the above rail: to
conduct continuous casting for the molten steel in compliance with the above composition
requirements to produce steel billet with the section of 250mmx250mm-450mmx450mm,
cool the steel billet, put it into a heating furnace to heat to 1200-1300°C, insulate the steel
billet for a certain period of time and take it out of the furnace, remove phosphorus with
high-pressure water, and then roll the billet into 50-75kg/m rail with the required section by
universal rolling or groove rolling.
Currently, the main method to conduct heat treatment for rail is to carry out
accelerated cooling to the railhead of the austenitic rail, while the cooling nozzles are
mainly arranged on the top surface and two sides of the railhead. This is determined by the
characteristics of rail: the top surface and one side of the rail bear multiple complex stress
of the wheel, and the rail has a symmetrical section along the vertical direction. Both sides
may be subjected to the stress of the wheel since their installation location varies.
Therefore, the performance of the in-service top surface and two sides of the railhead
should be higher than that of other parts of the rail.
In the process of accelerated cooling of the top surface and both sides of the railhead, with the sudden drop of surface temperature, the core of railhead transfers heat with the surface, the performance of the surface of railhead may not degrade but improve instead with the release of latent heat during phase change of pearlite. This means the supercooling of the core of railhead drops during phase change. Eventually, under room temperature, not only the hardness of the core of railhead is obviously lower than that of the surface, but also the toughness is relatively low. The invention adopts the method of adding nozzles at lower jaws on two sides of railhead to blow cooling medium. During the heat treatment, since the difference of cooling rate decreases between the core of railhead and the surface of railhead, the phase change of the surface of railhead can start at a much lower temperature, and the strength and toughness of the rail can be further improved. Although the improvement is quite limited, it can still improve the comprehensive strength and toughness of steel rail such as pearlite heat-treated rail, with the strength and toughness already reaching the limit. When the rail is air-cooled to 800-850°C, the "top surface of railhead, the two sides of railhead and the lower jaws on two sides of railhead" are cooled to 480-530°C at a cooling rate of 2.0-5.0°C/s. During the cooling process, the surface temperature drops rapidly under the action of the cooling medium, and the heat from the core of railhead and the rail web is continuously circulated and supplemented to the surface of railhead and a certain depth, leading to a drop of the supercooling of the core of railhead, which shows a decrease of strength and toughness of the rail under room temperature; if cooling for lower jaws of railhead is adopted simultaneously, new channels for heat losses are provided for the railhead, and the heat supplement for the core of railhead is significantly reduced, thus raising the supercooling of the section of railhead, especially the core of railhead. Since the grains of the whole railhead are further refined, the rail will have more excellent comprehensive strength and toughness under room temperature. When the temperature of the top surface of the railhead decreases to 480-530°C, air cooling is carried out until the railhead reaches room temperature, and straightening, flaw detection and processing, etc. are carried out in later stages to obtain finished rail.
The preferred embodiments of the invention will be further illustrated as follows, but it does not indicate that the protection scope of the invention is limited as described in the embodiments.
Embodiments 1-6 Manufacturing pearlitic rail with the method of the invention
The chemical composition of the steel billet for the pearlitic rail in embodiments 1-6 is shown in table 1: Table 1 List of Chemical Composition of the Steel Billet for the Pearlitic Rail (%) C Si Mn P S Cr V/Ti/Nb Embodiment 0.96 0.37 0.59 0.011 0.005 0.37 0.008Ti 1 Embodiment 0.91 0.43 0.90 0.008 0.004 0.20 0.09V 2 Embodiment 1.05 0.34 0.50 0.012 0.006 0.40 0.04Nb 3 Embodiment 0.94 0.50 0.72 0.009 0.004 0.32 0.07Nb 4 Embodiment 0.86 0.29 0.76 0.010 0.003 0.28 0.026Ti 5 Embodiment 0.98 0.20 0.84 0.010 0.005 0.25 0.03V 6
The steel billets shown in the above table are all rolled into 60kg/m rails and cooled by the following method: a. Rolling of rail to hot roll steel billet into rail, with a final rolling temperature range of 900-1000°C; b. Cooling of rail to blow a cooling medium to the top surface of railhead, wherein, the two sides of railhead and the lower jaws on two sides of railhead when the center of top surface of rail is
air-cooled to 800-850°C; then to air-cool the rail to the room temperature after the center of
top surface of rail is cooled to 480-530°C.
The cooling rate in embodiments 1-6 is shown in table 2.
Table 2 Cooling Rate under Different Methods
Temperature to start Average accelerated Temperature to end accelerated cooling/°C cooling rate °C/s accelerated cooling/°C
Embodiment 1 832 2.9 517 Embodiment 2 841 2.0 530 Embodiment 3 800 3.0 526 Embodiment 4 846 4.2 504 Embodiment 5 850 4.7 496 Embodiment 6 811 5.0 480
References 1-6 Manufacturing pearlitic rail with existing methods
The composition of the steel billet used in references 1-6 is the same as that of
embodiments 1-6, wherein the steel billet of reference 1 is the same as that of embodiment
1, and so forth.
References 1-6 adopt existing cooling method: a cooling medium is blown only to the
top surface of railhead and two sides of railhead, and the rail is air-cooled to room
temperature after the surface of railhead is cooled to 480-530°C.
The cooling rate in references 1-6 is shown in table 3:
Table 3 Cooling Rate under Different Methods
Average accelerated Temperature to end Joint Temperature to start accelerated cooling/°C cooling rate °C/s accelerated cooling/°C Reference 1 829 3.0 527 Reference 2 840 2.2 536 Reference 3 800 3.1 530 Reference 4 848 4.2 509 Reference 5 850 4.6 499 Reference 6 814 4.9 535
Air cool the rail treated according to the embodiments and the references to room
temperature, take double-shoulder circular tensile specimen with do=10mm,10=5do at 10mm
and 30mm below the surface of railhead of the rail respectively, and detect Rpo. 2 , Rm, A and
Z respectively according to GB/T 228.1; and take U-type Charpy impact specimen of
10mmxlOmmx55mm at the same position, and detect impact energy according to GB/T
229. Besides, take transverse hardness specimen from the railhead of rail respectively, and test Rockwell hardness respectively at the upper corner and the center of the top surface at
10mm and 30mm from the surface of railhead according to GB/T 230.1. The test positions
and methods are the same for the embodiments and the references. The detailed results are
shown in tables 4 and 5.
Table 4 Mechanical Properties of Rails Prepared with Different Methods (10mm below the surface of
railhead) Tensile properties Room Hardness/HRC temperatureTo Rp/MPa Rm/MPa A/% Z/% Corner Top Aku/J surface Embodiment 847 1398 12.0 25 18 40.6 40.4 1 Embodiment 845 1390 12.5 24 20 40.1 40.3 2 Embodiment 862 1426 11.5 22 18 41.9 41.6 3 Embodiment 821 1368 11.5 22 19 40.0 40.1 4 Embodiment 826 1359 12.0 25 21 390 39.1 5 Embodiment 866 1420 11.0 22 17 41.2 41.4 6 Reference 1 831 1376 11.0 21 16 40.2 40.1 Reference 2 823 1359 12.0 22 18 39.8 39.6 Reference 3 858 1410 10.5 17 16 41.8 41.7 Reference 4 852 1366 11.0 18 15 39.2 39.1 Reference 5 812 1339 11.0 20 18 38.5 38.7 Reference 6 852 1402 10.0 19 15 40.2 40.4
Table 5 Mechanical Properties of Rails Prepared with Different Methods (30mm below the surface of
railhead) Tensile properties Room Hardness/HRC temperatureTo Rp/MPa Rm/MPa A/% Z/% Corner Top Aku/J surface Embodiment 832 1327 11.5 21 20 39.7 39.6
Embodiment 798 1308 11.0 24 22 38.1 38.0 2 Embodiment 828 1367 11.5 22 20 38.9 38.8 3 Embodiment 792 1298 11.5 21 22 37.2 37.5 4 Embodiment 767 1268 11.5 23 24 36.3 36.7 5 Embodiment 832 1376 10.5 21 22 39.2 39.4 6 Reference 1 762 1274 10.5 19 19 36.8 36.7 Reference 2 754 1258 11.0 22 20 36.2 36.4 Reference 3 769 1298 10.5 19 17 37.2 37.1 Reference 4 753 1269 10.0 15 16 36.2 36.0 Reference 5 739 1241 10.0 19 18 35.2 35.4 Reference 6 800 1331 10.0 15 17 39.0 38.8
It can be concluded from the above embodiments and references that, the embodiments
adopting the heat treatment technique of the invention are compared with the references
adopting the existing heat treatment technique for the material with the same chemical
composition. In the embodiments, the cooling medium is blown to the top surface of
railhead and the two sides of railhead and the lower jaws on two sides of railhead after the
heat treated rail is air-cooled to 800-850°C, and the rail is air-cooled again to room
temperature after the center of top surface of rail is cooled to 480-530°C at a cooling rate of
2.0-5.0°C/s. On the contrary, the existing technique adopts the single method for heat
treatment for the top surface of railhead and the two sides of railhead at a cooling rate of
2.0-5.0°C/s. The comparison results in tables 4 and 5 indicate that the strength, hardness,
toughness and plasticity of the part within 10mm below the surface of the railhead under
the technique of the invention are slightly higher than those of the references; more
importantly, the strength and toughness of the part at 30mm below the surface of the
railhead is obviously higher than those with the existing heat treatment technique. Thus, it
can be concluded that, adding accelerated cooling for the lower jaws of railhead can
enhance the overall strength and toughness of railhead and prolong the service life of rail under the same conditions. The invention may provide a high-carbon and high-strength and toughness rail and its manufacturing method. With the same composition and the same manufacturing technique, the method can improve the strength and toughness of rail. The product may be suitable for heavy-haul railway with high requirements for contact fatigue resistance and wear resistance. Where the terms "comprise", "comprises", "comprised" or "comprising" are used in this specification (including the claims) they are to be interpreted as specifying the presence of the stated features, integers, steps or components, but not precluding the presence of one or more other features, integers, steps or components, or group thereto.

Claims (4)

The claims defining the invention are as follows:
1. A manufacturing method for high-carbon and high-strength and toughness pearlitic rail, comprising the following steps: a. Rolling of rail to hot roll steel billet into rail, with a final rolling temperature range of 900-1000°C; b. Cooling of rail (i) air cooling the rail after hot rolling; (ii) blowing a cooling medium to a top surface of a railhead, to two sides of the railhead, and lower jaws on the two sides of the railhead after a center of the top surface of the rail is air-cooled to 800-850°C; (iii) air-cooling the rail to room temperature after the center of the top surface of the rail is cooled to 480-530°C, a composition (in weight percentage) of the rail in step a is: C: 0.86%-1.05%, Si: 0.20% 0.50%, Mn: 0.50%-0.95%, Cr: 0.20%-0.40%, at least one of V, Nb and Ti, wherein V of 0.02%-0.10% if any, Ti of 0.001%-0.030% if any and Nb of 0.005%-0.08% if any, and the rest of Fe and inevitable impurities.
2. The manufacturing method for high-carbon and high-strength and toughness pearlitic rail according to claim 1, wherein the cooling medium in step b is at least one of compressed air and water-air spray mixture.
3. The manufacturing method for high-carbon and high-strength and toughness pearlitic rail according to claim 1, wherein the cooling rate in step b is 2.0-5.0°C/s.
4. A high-carbon and high-strength and toughness pearlitic rail manufactured with the method according to any one of claims 1 to 4, wherein the composition (in weight percentage) of the rail is: C: 0.86%-1.05%, Si: 0.20%-0.50%, Mn: 0.50%-0.95%, Cr: 0.20%-0.40%, at least one of V, Nb and Ti, wherein V of 0.02%-0.10% if any, Ti of 0.001%-0.030% if any and Nb of 0.005%-0.08% if any, and the rest of Fe and inevitable impurities.
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