AU2014203147B2 - High level haloxyfop emulsifiable concentrate formulation - Google Patents
High level haloxyfop emulsifiable concentrate formulation Download PDFInfo
- Publication number
- AU2014203147B2 AU2014203147B2 AU2014203147A AU2014203147A AU2014203147B2 AU 2014203147 B2 AU2014203147 B2 AU 2014203147B2 AU 2014203147 A AU2014203147 A AU 2014203147A AU 2014203147 A AU2014203147 A AU 2014203147A AU 2014203147 B2 AU2014203147 B2 AU 2014203147B2
- Authority
- AU
- Australia
- Prior art keywords
- ionic surfactant
- haloxyfop
- teric
- surfactant
- agriculturally acceptable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- GOCUAJYOYBLQRH-UHFFFAOYSA-N 2-(4-{[3-chloro-5-(trifluoromethyl)pyridin-2-yl]oxy}phenoxy)propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl GOCUAJYOYBLQRH-UHFFFAOYSA-N 0.000 title claims abstract description 593
- 239000000203 mixture Substances 0.000 title claims abstract description 349
- 238000009472 formulation Methods 0.000 title claims abstract description 336
- 239000004495 emulsifiable concentrate Substances 0.000 title claims abstract description 49
- 239000002904 solvent Substances 0.000 claims abstract description 337
- 239000004094 surface-active agent Substances 0.000 claims abstract description 83
- 239000002736 nonionic surfactant Substances 0.000 claims description 416
- 239000003945 anionic surfactant Substances 0.000 claims description 223
- -1 alkylbenzene sulfonate Chemical class 0.000 claims description 129
- 229920001400 block copolymer Polymers 0.000 claims description 114
- 239000002563 ionic surfactant Substances 0.000 claims description 68
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 41
- 150000001412 amines Chemical class 0.000 claims description 31
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 29
- 239000003760 tallow Substances 0.000 claims description 27
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 11
- 239000008096 xylene Substances 0.000 claims description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 9
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- 235000009967 Erodium cicutarium Nutrition 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
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- 150000001346 alkyl aryl ethers Chemical class 0.000 claims 5
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 claims 2
- 239000007921 spray Substances 0.000 claims 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 1
- 150000005215 alkyl ethers Chemical class 0.000 claims 1
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- 239000007788 liquid Substances 0.000 abstract description 458
- 239000007787 solid Substances 0.000 abstract description 17
- 239000000839 emulsion Substances 0.000 description 405
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 238
- 230000032683 aging Effects 0.000 description 223
- 239000006071 cream Substances 0.000 description 219
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 207
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- MFSWTRQUCLNFOM-SECBINFHSA-N haloxyfop-P-methyl Chemical group C1=CC(O[C@H](C)C(=O)OC)=CC=C1OC1=NC=C(C(F)(F)F)C=C1Cl MFSWTRQUCLNFOM-SECBINFHSA-N 0.000 description 120
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- 238000011056 performance test Methods 0.000 description 110
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- 229940092714 benzenesulfonic acid Drugs 0.000 description 103
- 238000000926 separation method Methods 0.000 description 102
- 238000012360 testing method Methods 0.000 description 79
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 33
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- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 description 23
- 239000012321 sodium triacetoxyborohydride Substances 0.000 description 23
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 20
- 239000004698 Polyethylene Substances 0.000 description 20
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 19
- 239000000463 material Substances 0.000 description 18
- 150000003839 salts Chemical class 0.000 description 16
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 15
- 229920001983 poloxamer Polymers 0.000 description 15
- 229910021653 sulphate ion Inorganic materials 0.000 description 15
- 239000003995 emulsifying agent Substances 0.000 description 14
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 13
- 238000004458 analytical method Methods 0.000 description 13
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
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- 239000002253 acid Substances 0.000 description 9
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical compound [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 8
- MUXOBHXGJLMRAB-UHFFFAOYSA-N Dimethyl succinate Chemical compound COC(=O)CCC(=O)OC MUXOBHXGJLMRAB-UHFFFAOYSA-N 0.000 description 8
- 229920005682 EO-PO block copolymer Polymers 0.000 description 8
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- 125000002091 cationic group Chemical group 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
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- FKHOMYAEAGQWJN-UHFFFAOYSA-N [Ca].C(C)OCCOCCO Chemical compound [Ca].C(C)OCCOCCO FKHOMYAEAGQWJN-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000009418 agronomic effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical compound BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- WKYKFSWMPFMBEW-UHFFFAOYSA-N dimethyl butanedioate;dimethyl hexanedioate Chemical compound COC(=O)CCC(=O)OC.COC(=O)CCCCC(=O)OC WKYKFSWMPFMBEW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- VAIZTNZGPYBOGF-CYBMUJFWSA-N fluazifop-P-butyl Chemical group C1=CC(O[C@H](C)C(=O)OCCCC)=CC=C1OC1=CC=C(C(F)(F)F)C=N1 VAIZTNZGPYBOGF-CYBMUJFWSA-N 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- BACHBFVBHLGWSL-UHFFFAOYSA-N methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate Chemical group C1=CC(OC(C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- 239000010690 paraffinic oil Substances 0.000 description 1
- 238000003359 percent control normalization Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 125000005554 pyridyloxy group Chemical group 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- BACHBFVBHLGWSL-JTQLQIEISA-N rac-diclofop methyl Natural products C1=CC(O[C@@H](C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-JTQLQIEISA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 150000003445 sucroses Chemical class 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 239000004557 technical material Substances 0.000 description 1
- FHYUCVWDMABHHH-UHFFFAOYSA-N toluene;1,2-xylene Chemical group CC1=CC=CC=C1.CC1=CC=CC=C1C FHYUCVWDMABHHH-UHFFFAOYSA-N 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000583 toxicological profile Toxicity 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
11/06/14,jb20952 cap specification.doex,222 - 222 An emulsifiable concentrate formulation of haloxyfop or at least one haloxyfop derivative or a mixture thereof including: haloxyfop or at least one haloxyfop derivative or a mixture thereof comprising at least 650 g/L of the emulsifiable concentrate formulation on a gram haloxyfop acid equivalent per litre basis, at least one solid, liquid-containing or liquid agriculturally acceptable surfactant, and, optionally, at least one agriculturally acceptable solvent, wherein the liquid components of the emulsifiable concentrate formulation form a solubilising moiety for haloxyfop or haloxyfop derivative and wherein the weight ratio of haloxyfop or haloxyfop derivative to solubilising moiety is greater than 2, preferably greater than 3, and more preferably greater than 4.
Description
FIELD OF THE INVENTION [0001] This invention relates to liquid formulations of the selective herbicide haloxyfop. In particular the invention relates to emulsifiable concentrate formulations of haloxyfop that contain a high level of active agent.
BACKGROUND OF THE INVENTION [0002] Haloxyfop is a member of the aryloxyphenoxy-propionate (or
FOP) class of herbicides. Other members of the class include diclofop-methyl, fluazifop-P-butyl and quizalofop-P-methyl. FOPs are generally used for the post-emergent control of grasses in broad-leaf crops.
[0003] Haloxyfop in formulations may be presented as haloxyfop acid (molecular weight 361.7), haloxyfop methyl ester (molecular weight 375.73), or as another haloxyfop acid derivative. Different enantiomers of haloxyfop have different herbicidal activity, and it is usual that the most active enantiomer is used in formulations. It is conventional to quote the amount of haloxyfop in a formulation on an acid equivalent basis. Thus for example a formulation containing haloxyfop-methyl at 540 g/L will be quoted as containing haloxyfop at 520 g/L on an acid-equivalent (a.e.) basis.
[0004] Teachings in patent literature have included combinations of
FOPs and safeners to increase weed control (US 2006/0014643), the use of delayed-release liquid formulations of fatty acid synthase inhibitors (including FOPs), for example, microcapsule formulations or wax dispersions, and the use of FOPs as synergistic agents in conjunction with herbicidal 2-phenyl-4(hetero-)aryloxypyrimidines.
11/06/14,jb20952 cap specification.docx,2
-22014203147 11 Jun2014 [0005] A range of haloxyfop emulsifiable concentrates comprising 520 g/L Haloxyfop have been sold in Australia by the following organisations or businesses: 4 Farmers (as Haloxyfop 520), Agri West (as AW Harpoon 520), Imtrade Australia (as Chemag Haloxyfop 520, and as Imtrade haloxyfop 520 EC), Chemforce 2010 (as Chemforce Haloxyfop 520), Grow Choice (as Choice Halofop 520), Conquest Crop Protection (as Conquest Recon 520), Ospray (as Convict), Crop Care Australasia (as Exert 520), Farmalinx (as Farmalinx Haloxyfop 520 EC), Farmoz (as Farmoz Firepower), Macspred (as Generex Haloxyfop, and as Macspred Halomac 520), Fandmark Operations (as Genfarm Haloxyfop 520), Echem Australia (as Halox 520), Sipcam Pacific Australia (as Inquest), Kenso Corporation (as Kenso Agcare Haloxyken 520), Shandong rainbow International (as Rainbow Haloxyfop 520), Rygel Australia (as Rygel Haloxyfop 520), Dow Agrosciences Australia (as verdict 520), and Agricultural Product Services (as Whitestar Haloxyfop 520).
[0006] Each of the above commercially available haloxyfop EC formulations contains at most 520 g/E of haloxyfop active ingredient (acid equivalent basis), which suggests that 520 g/L represents an upper practical limit in the amount of haloxyfop that can be packaged in EC form using methods currently known to the art.
[0007] Many general characteristics of emulsifiable concentrate formulations have been described in US 2003/0072776 (Sun et al., filed July 2001). The Sun specification provides the following teachings about emulsifiers, solvents and optional ingredients.
Emulsifiers [0008] The emulsifiers of the emulsifiable concentrates comprise at least one emulsifier, which may be a non-ionic surfactant, an ionic surfactant, or a blend of both types of surfactants. It is also possible that an emulsifier in an emulsifiable concentrate may be a cationic surfactant. Useful non-ionic
11/06/14,jb20952 cap specification.docx,3
-32014203147 11 Jun2014 surfactants are said to include alkoxylated block polymers, alkoxylated alcohols, alkoxylated alkylphenols, alkoxylated amines, alkoxylated amides, alkoxylated fatty esters, alkoxylated oils, fatty esters, alkoxylated fatty acids, sorbitan derivatives, and the like.
[0009] It is possible that the emulsifier comprises a zwitterionic surfactant (i.e., a surfactant which simultaneously carries anionic and cationic charge). Examples of zwitterioninc surfactants include betaine surfactants.
[0010] Typical ionic surfactants found in emulsifiers include alkylaryl sulfonates; alkylarylsulfonic acids; carboxylated alcohol ethoxylates and alkylphenol ethoxylates; carboxylic acids/fatty acids; diphenyl sulfonate derivatives; olefin sulfonates; phosphate esters; phosphorus organic derivatives; quaternary surfactants; sulfates and sulfonates of oils and fatty acids; sulfates and sulfonates of ethoxylated alkylphenols; sulfates of ethoxylated alcohols; sulfates of fatty esters; sulfonates of dodecyl and tridecylbenzenes; sulfonates of naphthalene and alkyl naphthalene; sulfonates of petroleum; sulfosuccinamates; alkanolamides; alkoxylated amines (with low EO values); sarcosine derived surfactants such as, ammonium lauroyl sarcosinate, and the like.
[0011] Preferred emulsifiers may be alkoxylated alcohols and alkyphenols, preferably of from about 4 to about 50 ethylene oxide units and a hydrophobe of from about 4 to about 16 carbon atoms. Other preferred surfactants may be alkylphenol EO/PO block copolymers, e.g., that sold under the trade name WITCONOL NS 108 LQ, and alkoxylated amine salts of ethoxylated alkylphenol sulfates, e.g., that supplied under the trade name WITCOLATE 1335 by Crompton Corporation, Witco Group.
[0012] Developing an effective emulsifier package (blend of emulsifiers) requires careful screening of potential emulsifiers (surfactants), conducting emulsion tests according to prescribed methods or established
11/06/14,jb20952 cap specification.docx,4
-42014203147 11 Jun2014 laboratory protocols, and optimizing the performance of the most promising emulsifier(s). The screening of potential emulsifier packages is dependent upon pesticide active type, and solvents. Those skilled in the art of EC technology understand the importance of hydrophilic-lipophilic balance and surfactant choice for such formulations. The emulsifier (surfactant) is preferably present at from about 1 to about 50 weight percent of the emulsifiable concentrate, more preferably from about 3 to about 10 weight percent.
Solvents [0013] The selection of a suitable solvent system is made by taking into consideration the solubility of the active(s) and the chemical and toxicological profiles of the solvent(s). The solvents include all EPA approved solvents, and the list of suitable solvents may include aliphatic paraffinic oils, such as kerosene or refined paraffins; aromatic solvents, such as xylenes; C9-C12 aromatic solvents, such as supplied under the trade names AROMATIC 100, 150, and 200 (as sold by Exxon Chemical), ISOPAR L, SOLVESSO 100, 150, and 200; chlorinated hydrocarbons, such as chlorobenzene; alcohols, such as butanol and benzyl alcohol; ketones, such as cyclohexanone and N-methyl pyrollidone; and ethers, such as diethylene glycol and diethoxol. In addition, the solvent may include vegetable oils, methylated vegetable oils, petrol-oils, sugar esters of fatty acids, e.g., sucrose esters, and the like.
[0014] Preferred solvents may be C9-C12 hydrocarbon solvents because of their low cost and their ability to solubilize many pesticide toxicants.
[0015] Sun teaches that the solvent may be present at from 0 to about weight percent of the emulsifiable concentrate, preferably from about 20 to about 50 weight percent.
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-52014203147 11 Jun2014
Optional Ingredients [0016] Other additives may be included in emulsifiable concentrate formulations of active ingredient and at levels less than about 5 weight percent. Such additives can include, for example, an antifreeze, a pH buffer, a finely divided hydrophobic filler, a perfume, an antifoam, a stenching agent, or an embittering agent (the latter two agents to discourage ingestions).
[0017] Sun also teaches that emulsifiable concentrates according to the invention disclosed therein can be diluted with water to a desired solids or active ingredient level and applied to the targets using suitable means. Typically according to Sun, the amount of active component in the final formulations prior to dilution is from about 1 to about 95 weight percent.
[0018] Hereafter in this specification, the term “haloxyfop” will be taken to refer to each and any haloxyfop acid or haloxyfop acid derivative moiety present in the formulation.
[0019] In the present specification, the term “solubilising moiety for haloxyfop” is to be taken to refer to any liquid system in which haloxyfop is miscible, including liquid systems that include conventional agriculturally acceptable solvents and also liquid systems that include conventional agriculturally acceptable liquid, or liquid-containing, surfactants, provided that haloxyfop dissolves in said liquid systems. A solubilising moiety for haloxyfop may contain one, two or even more liquid components. The weight of a solubilising moiety for haloxyfop is taken to be the sum of weights of liquid components that constitute the solubilising moiety system for haloxyfop. For the avoidance of doubt, if a solubilising moiety for haloxyfop happens to include one or more solubilised solids (e.g. a solid dissolved surfactant), the weight of the solubilising moiety for haloxyfop is taken to be the sum of the weights of the liquid components of the solubilising moiety system for haloxyfop, but does not include the weights of non-haloxyfop solid
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-62014203147 11 Jun2014 components that may be dissolved. The term “agriculturally acceptable solvent for haloxyfop” will be taken to refer to solvents for haloxyfop wherein each component of the solvent has been approved for inclusion in an agricultural formulation in at least one country. “Agriculturally acceptable” means registered or otherwise approved for use in agriculture in at least one country.
[0020] Haloxyfop-methyl quantities are to be calculated in terms of haloxyfop acid equivalent.
[0021] The “haloxyfop /solubilising moiety ratio” in a haloxyfop EC, which may be calculated by dividing the weight of haloxyfop moieties (as acidequivalent weights) in a given weight of haloxyfop EC formulation by the weight of the solubilising moiety for haloxyfop in the same weight of haloxyfop EC formulation, is an important ratio in terms of:
1. The quantity of solvent released to the environment as a consequence of applying a given amount of haloxyfop formulation to a cultivation zone;
2. The amount of high-quality packaging material that is utilised in carrying a given amount of haloxyfop active ingredient to a cultivation zone;
3. The amount of used packaging material that needs to be recycled or otherwise disposed of after applying a given amount of haloxyfop active ingredient to a cultivation zone;
4. The contact toxicity of haloxyfop EC formulation to a farm worker;
5. The flammability of haloxyfop EC formulation;
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-72014203147 11 Jun2014
6. The vapour pressure of solvent (frequently aromatic hydrocarbon) that is released to air in a given time after a spill has occurred;
7. The weight of goods that must be carried by a farm worker in applying a given amount of haloxyfop active ingredient to a cultivation zone;
8. The cost of freight (volume and weight basis) in transporting the haloxyfop formulation from factory to field;
9. The capacity to demonstrate superior formulation expertise to farmers.
[0022] Most, if not all, of the above parameters are improved when a given amount of haloxyfop in an EC formulation is associated with a lesser amount of solubilising moiety, i.e., when the haloxyfop/ solubilising moiety ratio is greater.
[0023] As an illustration of prior art one may consider, a conventional commercial haloxyfop EC formulation with a density of 1160 g/L and consisting of the following ingredients:
| Component | Parts by Weight g/L |
| Haloxyfop-P-methyl 97.4% technical | 554.6 |
| Diethylene glycol monomethyl ether | 525.4 |
| Ionic surfactant (60% solid in 40% 2-ethylhexanol), e.g. alkylbenzenesulfonic acid, calcium salt (e.g. Ninate 60E) | 10 |
| Non-ionic surfactant (solvent-free solid) e.g. alkyl polyoxyalkylene ether (e.g. Termul 203) | 70 |
11/06/14,jb20952 cap specification.docx,8
-82014203147 11 Jun2014 [0024] In the above formulation haloxyfop (as methyl ester, molecular weight = 375.73) is present at 0.974 x 554.6 = 540 parts by weight. This corresponds to 520 parts by weight of haloxyfop acid equivalent, molecular weight 361.7). Solubilising moiety is present at 525.4 + 0.4x10 = 529.4 parts by weight. The haloxyfop/solubilising moiety ratio is thus 520/525.4 = 0.99. The prior art formulation may be referred to as Haloxyfop 520, reflecting the weight content of haloxyfop acid equivalents.
DESCRIPTION OF THE INVENTION [0025] According to one aspect of the present invention there is provided an emulsifiable concentrate formulation of haloxyfop or haloxyfop derivatives including haloxyfop or at least a haloxyfop derivative and an agriculturally acceptable solvent for haloxyfop, wherein the weight ratio of haloxyfop moieties on an acid equivalent basis to solvent is greater than 2, preferably greater than 3 and more preferably greater than 4.
[0026] An emulsifiable concentrate formulation of haloxyfop or haloxyfop derivative or mixture thereof including: haloxyfop or haloxyfop derivative or mixture thereof comprising at least 650 g/L of the emulsifiable concentrate formulation on a haloxyfop acid equivalent basis, at least one solid, liquid-containing or liquid agriculturally acceptable surfactant, and, optionally, at least one agriculturally acceptable solvent, wherein the liquid components of the emulsifiable concentrate formulation form a solubilising moiety for haloxyfop or haloxyfop derivative and wherein the weight ratio of haloxyfop or haloxyfop derivative to solubilising moiety is greater than 2, preferably greater than 3, and more preferably greater than 4.
[0027] The agriculturally acceptable solvent comprises at least one member of the set consisting of alkane compounds, aromatic compounds, alkylaryl compounds, alcohol-containing compounds, ether-containing compounds, ester-containing compounds, ketone-containing compounds,
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-92014203147 11 Jun2014 lactam-containing compounds, amide-containing compounds, and chlorinated compounds.
[0028] The agriculturally acceptable solvent may include at least one member of the set consisting of solvent naphtha (petroleum), heavy aromatic fraction, xylene, toluene, pyrrolidones including N-alkylated pryrrolidones such as n-methyl pyrrolidone, cyclohexanone, acetone, glycol ethers such as diethyleneglycol monomethyl ether (including the material sold under the trade name Carbitol), ethyleneglycolmonobutylethers (including the material sold under the trade name Butyl Glysolv), Propylene glycol monomethyl ether (including the material sold under the trade name Glysolv PM), methanol, ethanol, isopropanol, decanol, paraffins, hexane, and acetic acid C6-Cs branched alkyl ester (including the material sold under the trade name Exxate 700).
[0029] Preferably, the agriculturally acceptable solvent may include at least one member of the set consisting of glycol ethers and alkyl glycol ethers.
[0030] More preferably, the agriculturally acceptable solvent may comprise at least one member of the set consisting of methyl, ethyl or butyl ethers of ethylene glycol or diethylene glycol or triethylene glycol or propylene glycol or dipropylene glycol.
[0031] Alternatively, the agriculturally acceptable solvent may include at least one member of the set consisting of diethylene glycol monoethyl ether, propylene glycol monomethyl ether, and ethylene glycol monobutyl ether.
[0032] The agriculturally acceptable solvent may comprise less than
350 g/L, preferably less than 280 g/L, and more preferably less than 220 g/L of the emulsifiable concentrate formulation.
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- 102014203147 11 Jun2014 [0033] The agriculturally acceptable solvent may be in the range of 80 350 g/L, preferably in the range of 120 - 280 g/L, and more preferably in the range of 160 - 220 g/L.
[0034] An emulsifiable concentrate formulation according to the present invention may include at least one agriculturally acceptable surfactant, and wherein the cumulative amount (net of carrier solvent) of the at least one agriculturally acceptable surfactants is at least 30 g/L, preferably at least 45, and more preferably at least 60 g/L.
[0035] The at least one agriculturally acceptable surfactant may comprise a non-ionic surfactant.
[0036] The at least one agriculturally acceptable non-ionic surfactant may be chosen from the categories in the set consisting of alkoxylated block polymers, alkoxylated alcohols, alkoxylated alkylphenols, alkoxylated amines, alkoxylated amides, alkoxylated fatty esters, alkoxylated oils, fatty esters, alkoxylated fatty acids, and sorbitan derivatives.
[0037] The non-ionic surfactant may comprise at least one member of the set consisting of (i) ethylene oxide/propylene oxide block copolymers and block copolymer derivatives including alkyl derivatives, and (ii) alkyl phenol ethoxylates wherein the alkyl chain has between 7 and 11 carbon atoms and there are 7 to 11 ethylene oxide moieties (average basis).
[0038] The at least one agriculturally acceptable non-ionic surfactant may be chosen from the set consisting of (i) butyl ethylene oxide/propylene oxide copolymer having an average molecular weight in the range 2000 - 4000, (ii) alcohol alkoxylate with ethylene oxide 22-28 moles and propylene oxide 25-35 moles and a PO/EO ratio of about 1.2/1, and (iii) nonylphenol with 8 or 9 or 10 ethoxylates (average basis).
11/06/14,jb20952 cap specification.docx,ll
2014203147 11 Jun2014
- 11 [0039] The cumulative amount (net of carrier solvent if any) of nonionic surfactant may comprise at least 30 g/L, preferably at least 45 g/L, and more preferably at least 60 g/L.
[0040] Alternatively, in an emulsifiable concentrate formulation according to the present invention, the at least one agriculturally acceptable surfactant may comprise an anionic surfactant.
[0041] The at least one agriculturally acceptable ionic surfactant may be chosen from the categories in the set consisting of alkylaryl sulfonates; alkylarylsulfonic acids; carboxylated alcohol ethoxylates and alkylphenol ethoxylates; carboxylic acids/fatty acids; diphenyl sulfonate derivatives; olefin sulfonates; phosphate esters; phosphorus organic derivatives; sulfates and sulfonates of oils and fatty acids; sulfates and sulfonates of ethoxylated alkylphenols; sulfates of ethoxylated alcohols; sulfates of fatty esters; sulfonates of dodecyl and tridecylbenzenes; sulfonates of naphthalene and alkyl naphthalene; sulfonates of petroleum; sulfosuccinamates; alkoxylated amines; sarcosine derived surfactants, such as ammonium lauroyl sarcosinate, and alkoxylates as above other than ethoxylates (such as propoxylates, butoxylates).
[0042] The at least one agriculturally acceptable ionic surfactant may be chosen from the set consisting of linear and branched alkylbenzenesulphonates and salts thereof which may be provided as a solution in a solvent such as calcium C10-C14 alkylbenzenesulfonate (including materials sold under the trade name NANSA EVM70/2E which is carried in 2 ethylhexanol or under the trade name Ninate 60E which is also carried in 2 ethylhexanol), alkyl sulphates such as sodium lauryl sulphate (including material sold under the trade name Empicol LX/N), alkyl ether sulfates such as sodium lauryl ether (2EO) sulphate (including material sold under the trade name Emipmin KESX70/AU), alkyl phosphates (including material sold under the trade names Alkanate PA100, Alkanate PG30, and Alkanate PL50), alkyl
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- 122014203147 11 Jun2014 ether phosphates (including material sold under the trade name Alkanate PK100), alkylphenol ether sulfate/tallow amine ethoxylate salts (including materials sold under the trade names Toximul TANS-5, Toximul TANS-6, Toximul TANS-8, Toximul TANS-15), and alcohol ether sulphate/tallow amine ethoxylate salts (including materials sold under the trade names Toximul TAABS-5, Toximul TAABS-8).
[0043] Preferably, the at least one agriculturally acceptable ionic surfactant may be chosen from the set consisting of linear and branched alkylbenzenesulphonates and salts thereof which may be provided as a solution in a solvent such as calcium C10-C14 alkylbenzenesulfonate (including materials sold under the trade name NANSA EVM70/2E which is carried in 2 ethylhexanol, and material sold under the trade name Ninate 60E which is also carried in 2-ethyl hexanol), alkylphenol ether sulfate/tallow amine ethoxylate salts (including materials sold under the trade names Toximul TANS-5, Toximul TANS-6, Toximul TANS-8, )and alcohol ether sulphate/tallow amine ethoxylate salts (including materials sold under the trade names Toximul TAABS-5).
[0044] An emulsifiable concentrate formulation according to the present invention may include at least one agriculturally acceptable ionic surfactant, wherein the cumulative amount (net of carrier solvent) of the at least one agriculturally acceptable anionic surfactants is at least 8 g/L, preferably at least 11 g/L, and more preferably at least 14 g/L.
[0045] An emulsifiable concentrate formulation according to the present invention may include at least one agriculturally acceptable non-ionic surfactant wherein the cumulative amount (net of carrier solvent) of the at least one agriculturally acceptable non-ionic surfactant is at least 40 g/L, preferably at least 60 g/L, and more preferably at least 80 g/L.
11/06/14,jb20952 cap specification.docx,13
2014203147 11 Jun2014
- 13 [0046] An emulsifiable concentrate formulation according to the present invention may comprise about 700 - 950 g/L haloxyfop-P-methyl, 160 200 g/L diethyleneglycolmonoethyl ether, 45 - 70 g/L non-ionic surfactant comprising ethylene oxide-propylene oxide block copolymer moieties of molecular weight 1500 - 4500 , and 14 - 18 g/L of C12-C16 linear or branched calcium alkyl benzene sulfonate.
[0047] An emulsifiable concentrate formulation according to the present invention has the density of at least 1.00 g/ml and preferably at least 1.15 g/ml.
[0048] Formulations incorporating diluted emulsifiable concentrate according to the present invention may be used for selectively killing or suppressing weeds such as barley grass, brome grass, paradoxa grass, volunteer cereals, wild oats, musky or ferny leaf Storksbill, common crowsfoot, common storksbill, long or shiny leaf storksbill, couch grass, Rhodes grass, Australian millet, barnyard grass, green panic, Johnson grass, liverseed grass, Mossman river grass, summer grass, slender rats tail grass, Buffel grass, kikuyu, paspalum spp, starai spp, annual ryegrass, lesser canary grass, Rope twitch, Erodium spp.
DESCRIPTION OF PREFERRED EMBODIMENTS AND EXAMPLES OF THE INVENTION [0049] In order that the present invention may be more readily comprehended, one or more preferred embodiments are described hereinafter.
EXAMPLE 1 [0050] The following haloxyfop emulsifiable concentrate according to the invention was made by mixing the following components:
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- 142014203147 11 Jun2014
| Component | Parts by Weight (g/L) |
| Haloxyfop-P-methyl 94% tech | 994.5 |
| Diethyleneglycol monoethyl ether | 183.2 |
| Alkylbenzenesulfonic acid, calcium salt (60% solid in 40% 2-ethylhexanol) e.g. Ninate 60E | 26.2 |
| Alkyl polyoxyalkylene ether e.g. Termul 203. (solvent-free solid) | 61.1 |
[0051] In the above formulation haloxyfop (as methyl ester, molecular weight = 375.73) is present at 0.94 x 994.5 = 934.83 parts by weight. This corresponds to 900 parts by weight of haloxyfop acid equivalent (molecular weight 361.7). Solubilising moiety is present at 183.2 + 0.4x26.2 = 193.68 parts by weight. The haloxyfop/solubilising moiety ratio is thus 900/193.68 = 4.65. The density of the formulation is 1265 g/L.
[0052] In Example 1, the formulation procedure for a nominal 10,000 L batch of the material is as follows, with steps being identified numerically as 1.1, 1.2, 1.3, and so on:
[0053] 1.1 Ensure formulation vessel is empty and clean.
[0054] 1.2 Charge the formulation vessel with solvent as follows with agitator off:
| 1. Diethylene glycol monethyl ether | 1550 kg |
[0055] 1.3 Charge the formulation vessel with active ingredient, with intermittent agitation following the addition of every 1000 kg or so. As haloxyfop-P-methyl technical material can be of such a viscosity that the material is not amenable to pumping at temperatures of the order of 30°C and
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2014203147 11 Jun2014
- 15 below (depending on the ambient temperature and the means of transferring the material to the formulation), gentle heating may be required to establish a lower viscosity liquid form prior to processing:
| 2. Haloxyfop-P-methyl 94% Tech | 9945 kg |
[0056] 1.4 Charge the formulation vessel with the surfactants and remaining solvent as follows, clearing residual surfactant from any pumps or process lines used with the remaining complement of solvent:
| 3. Alkylbenzenesulfonic acid, calcium salt in 2ethylhexanol (e.g. Ninate 60E) | 262 kg |
| 4. Alkyl polyoxyalkylene ether (e.g. Termul 203) | 611kg |
| 5. Diethylene glycol monethyl ether | 282 kg |
[0057] 1.5 Continue agitating for a minimum of 30 minutes following the addition of the last ingredient.
[0058] 1.6 Sample approximately IL of product, ensuring it is representative of the formulation.
[0059] 1.7 Sub-sample 250mL from the original IL sample, and subject it to the following testing regime:
| [0060] | 1.7.1 | Specific gravity (CIPAC MT3.1) |
| 1.7.2 | pH 1% aqueous (CIPAC MT75.3) | |
| 1.7.3 | Emulsion characteristics (CIPAC MT36.1) | |
| 1.7.4 | Persistent foam (CIPAC MT47.2) |
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1.7.5 Active constituent (Haloxyfop-P-methyl) content (using a validated method meeting the requirements of APVMA).
[0061] 1.8 If specific gravity is within the bounds of the acceptable range listed in the specification, record the value and proceed to the next test. If specific gravity is outside of the bounds of the acceptable range listed in the specification, agitate the formulation charge until specific gravity is constant. If still outside of the bounds of the acceptable range, quarantine batch for further investigations and possible rework.
[0062] 1.9 If pH 1% aqueous is satisfactory, record the results and proceed to the next test. If pH 1% aqueous is outside the bounds of the acceptable range listed in the specification, quarantine the batch for further investigations and possible rework.
[0063] 1.10 If emulsion stability in standard hard water is satisfactory, record the results and proceed to the next test. If emulsion stability is outside the bounds of the acceptable range listed in the specification, adjust the contents of surfactants (Alkylbenzenesulfonic acid, calcium salt in 2ethylhexanol (Ninate 60E) and Alkyl polyoxyalkylene ether (Termul 203)). After suitable agitation time to ensure homogeneity, resample and retest.
Repeat adjustment process until emulsion stability is within the bounds of the acceptable range.
[0064] 1.11 If persistent foaming characteristics are satisfactory, record the results and proceed to the next test. If persistent foaming characteristics are outside the bounds of the acceptable range quarantine the batch for further investigations and possible rework.
[0065] 1.12 If the active constituent level is satisfactory, record results. If the active constituent level is outside the bounds of the acceptable range listed in the specification, adjust the level accordingly by adding
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- 172014203147 11 Jun2014 additional diethylene glycol monethyl ether (where the active content is high) or additional haloxyfop-P-methyl active constituent (where the active content is low). After suitable agitation time to ensure homogeneity, resample and retest. Repeat adjustment process until active constituent levels are within the bounds of the acceptable range.
[0066] 1.13 Catalogue and store a retention sample of approximately 200 g.
Tests for Confirming the Suitability of the Formulation of Example 1 [0067] For the test method identified by the prefix CIPAC, refer to
International Pesticides Analytical Council (CIPAC) published methodology.
| Parameter | Test Method | Required Outcome | Observed Outcome |
| appearance | visual | homogeneous liquid | homogeneous liquid |
| assay | validated chromatographic method, 98-102% accuracy, linearity R>0.99 | 875 to 925g/F | 899g/F |
| pH(l%) | CIPAC MT 75.3 | 4- 10 | 7.4 |
| Spec Gravity (SG) | CIPAC MT 3.1 | 1.00-3.00 | 1.265 |
| Emulsion characteristics | CIPAC MT 47.2 | <2 ml cream and < trace oil after 30 min, complete resuspension after 24 hrs | complies |
| Persistent foaming | CIPAC MT 47.2 | < 60 ml after 1 min | 5 mF |
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| cold stability | visual | no phase separation | complies |
| viscosity 20°C | Brookfield viscometer | 0 - 2000 cPs | 330 cPs |
| viscosity 5°C | Brookfield viscometer | 0 - 2000 cPs | 1350 cPs |
| long term performance | As above, after storage at 54°C for 2 weeks CIPAC MT 46.1 | complies | complies |
| Flash point of most volatile component | Abel closed cup (diethylene glycol monoethyl ether) | >60°C | 96°C |
Trials [0068] Series of trials were conducted to ascertain suitable solvent surfactant combinations. The haloxyfop used in the trials was haloxyfop technical (either 94% or 95% purity).
Solvents and Surfactants [0069] Table A identifies the solvents used in the trials and contains comments and identifying acronyms (where such were used).
TABLE A
| Name | Description | Comments |
| Recosol 150 | Petroleum-based aromatic hydrocarbon distillate fraction | Equivalent to Solvesso 150, also designated R150, distillation range approx 180 - 210°C, flash point approx 66°C |
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| Recosol 100 | Petroleum-based aromatic hydrocarbon distillate fraction | Equivalent to Solvesso 100, also designated R100, distillation range approx 160 - 180 °C, flash point approx 50°C |
| Recosol 200 | Petroleum-based aromatic hydrocarbon distillate fraction | Equivalent to Solvesso 200, also designated R200, distillation range approx 220 plus°C, flash point approx 100°C |
| Butyl Glysolv | Ethylene glycol monobutyl ether | |
| Ethylene glycol monobutyl ether | EGMBE, EGME | |
| Diethylene glycol monoethyl ether | DGME, DGMEE | |
| Dimethyl Succinate | ||
| Dimethyl Adipate | ||
| N methyl pyrrolidone | NMP | |
| Exxate 700 | C6-C8 acetate, acetic acid C6-C8 branched alkyl ester | |
| toluene | ||
| xylene | ||
| acetone | ||
| Propylene glycol monomethyl ether | PGME, PGMME | |
| Propylene glycol | ||
| Diethylene glycol | ||
| Dipropylene glycol |
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-20[0070] Table B identifies in general terms the surfactants used in the trials and Table C contains more details on the surfactants, including sources.
TABLE B
| Name | General Description | Category (A,N,C) A=anionic N=non-ionic C=cationic |
| Termul 200 | Nonylphenol alkoxylate | N |
| Termul 203 | Polypropyleneglycol alkoxylate | N |
| Toximul 8320 | Butanol alkoxylate | N |
| Toximul TANS 5 | Low-solvent alkylphenol ether sulphate/tallow amine ethoxylated salt | A,N,C |
| Toximul TANS 6 | Low-solvent alkylphenol ether sulphate/tallow amine ethoxylated salt | A,N,C |
| Toximul TANS 8 | Low-solvent alkylphenol ether sulphate/tallow amine ethoxylated salt | A,N,C |
| Toximul TANS 15 | Low-solvent alkylphenol ether sulphate/tallow amine ethoxylated salt | A,N,C |
| Toximul TAABS 5 | Low-solvent branched alcohol ether sulphate/tallow amine ethoxylated salt | A,N,C |
| Toximul TAABS 8 | Low-solvent branched alcohol ether sulphate/tallow amine ethoxylated salt | A,N,C |
| NANSA EVM 70 | Calcium alkylbenzenesulfonate in 2 ethylhexyl alcohol | A |
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| Ninate 60E | Calcium alkylbenzenesulfonate in 2 ethylhexyl alcohol | A |
| Rhodacal 60/BE-C | Calcium alkylbenzenesulfonate in 2 ethylhexyl alcohol | A |
| Rhodacal 70 | Calcium alkylbenzenesulfonate in 2 ethylhexyl alcohol | A |
| Rhodacal 70B | Calcium alkylbenzenesulfonate in 2 ethylhexyl alcohol | A |
| Kemmat HF60 | Calcium dodecyl lbenzenesulfonate | A |
| Teric N2 | Nonylphenol-2-EO | N |
| Teric N8 | N onylphenol- 8 -EO | N |
| Teric N9 | Nonylphenol-9-EO | N |
| Teric N10 | Nonylphenol-10-EO | N |
| Teric N13 | Nonylphenol-13 -EO | N |
| Teric N15 | Nonylphenol-15-EO | N |
| Teric N20 | Nonylphenol-20-EO | N |
| Teric N30 | Nonylphenol-30-EO | N |
| Termul 1284 | Castor oil-36-EO | N |
| Termul 1285 | Castor oil-54-EO | N |
| Teric PE62 | EO/PO block copolymer | N |
| Teric PE64 | EO/PO block copolymer | N |
| Teric PE68 | EO/PO block copolymer | N |
| Makon TSP 16 | Tristyryl-16-EO | N |
| Pluronic PE 6400 | PE/PO/PE block copol | N |
| Pluronic PE 6800 | PE/PO/PE block copol | N |
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| TABLE C | -22- |
| Name | |
| Termul 200 | Nonylphenol 9 EO/IOPO, HLB 16.1, solid |
| Orisurf 200 | Equivalent to Termul 200 |
| Termul 203 | Alcohol alkoxylate, HLB 17.5 PO-EO-PO triblock, 35PO-25EO-30PO |
| Toximul 8320 | Stepan, Butyl EO/PO block, HLB 12 |
| Toximul TANS 5 | Stepan, HLB 8. Ether sulphate component is anionic, tallow amine ethoxylate can be non-ionic or cationic depending on pH and chemical environment |
| Toximul TANS 6 | Stepan, HLB. 10 Ether sulphate component is anionic, tallow amine ethoxylate can be non-ionic or cationic depending on pH and chemical environment |
| Toximul TANS 8 | Stepan, HLB 12. Ether sulphate component is anionic, tallow amine ethoxylate can be non-ionic or cationic depending on pH and chemical environment |
| Toximul TANS 15 | Stepan, HLB 14. Ether sulphate component is anionic, tallow amine ethoxylate can be non-ionic or cationic depending on pH and chemical environment |
| Toximul TAABS 5 | Stepan, class of anionic detergent blend. Ether sulphate component is anionic, tallow amine ethoxylate can be non-ionic or cationic depending on pH and chemical environment |
| Toximul TAABS 8 | Stepan, class of anionic detergent blend. Ether sulphate component is anionic, tallow amine ethoxylate can be non-ionic or cationic depending on pH and chemical environment. |
| NANSA EVM70 | Linear alkylate 70% active may be in various solvents such as isobutanol or 2-ethyl hexanol |
| Ninate 60E | Stepan, 60% active linear calcium alkylbenzenesulfonate in 2-ethylhexanol, 60% active |
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| Rhodacal 60/BE-C | Rhodia, mixture of linear dodecylbenzene sulfonate calcium salt, 60% active |
| Rhodacal 70 | Rhodia, branched dodecylbenzene sulfonate calcium salt, 70% active |
| Rhodacal 70B | Rhodia, mixture of linear dodecylbenzene sulfonate calcium salt, 70% active |
| Kemmat HF60 | Handan Xindiya, calcium dodecylbenzene sulfonate 60% active |
| Teric N2 | Huntsman nonylphenolethoxlate |
| Teric N8 | Huntsman nonylphenolethoxlate |
| Teric N9 | Huntsman nonylphenolethoxlate |
| Teric N10 | Huntsman nonylphenolethoxlate |
| Teric N13 | Huntsman nonylphenolethoxlate |
| Teric N15 | Huntsman nonylphenolethoxlate |
| Teric N20 | Huntsman nonylphenolethoxlate |
| Teric N30 | Huntsman nonylphenolethoxlate |
| Termul 1284 | Huntsman, paste, HLB 12.6 |
| Termul 1285 | Huntsman, paste, HLB 14.4 |
| Teric PE62 | Huntsman PE/PO diblock copol 17 moles EO, HLB 7 |
| Teric PE64 | Huntsman PE/PO diblock copol, 25 moles EO, HLB 15 |
| Teric PE68 | Huntsman PE/PO diblock copol, 150 moles EO, HLB 29 |
| Makon TSP 16 | Stepan, HLB 13 |
| Pluronic PE 6400 | BASF, triblock copol PE/PO/PE, 1750 g/mol polypropylene glycol block, 40% polyethyleneglycol in molecule |
| Pluronic PE 6800 | BASF, triblock copol PE/PO/PE, 1750 g/mol polypropylene glycol block, 80% polyethyleneglycol in molecule |
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Varying Non-Ionic Surfactant at Constant Surfactant Ratio [0071] In this set of trials all haloxyfop formulations contained haloxyfop at a loading of 900 g/L. In each formulation trialled, a single anionic surfactant was used, namely that supplied under the trade name Ninate 60E (calcium C10-C16 alkylbenzenesulfonate, linear, CAS # 68584-23-6, as 60% in 2-ethylhexanol supplied by Stepan). In each formulation in these trials, a single solvent was used, namely, diethylene glycol monoethyl ether.
[0072] A range of non-ionic surfactants was used in this set of trials as follows, with the surfactant being identified initially by the trade name under which it was supplied:
Termul 200 (alkylphenol poly-ether EO/PO (ethyleneoxide/propylene oxide) block copolymer, 9 mol EO, 10 mol PO, CAS #37251-69-7, manufactured by Huntsman),
Teric N2 (nonylphenol 2-EO, manufactured by Huntsman),
Teric N8 (nonylphenol 8-EO, manufactured by Huntsman),
Teric N10 (nonylphenol 10-E, manufactured by Huntsman),
Teric N13 (nonylphenol 13-EO, manufactured by Huntsman),
Teric N20 (nonylphenol 20-EO, manufactured by Huntsman),
Termul 203 (alcohol alkoxylate, HLB 17.5, manufactured by
Huntsman),
Termul 1284 (castor oil PEG 36 CAS #61791-12-6, manufactured by Huntsman),
Termul 1285 (castor oil PEG 54 (polyethylene glycol) CAS #61791-12-6, manufactured by Huntsman),
Teric PE62 (EO/PO block copolymer, 17 moles EO, HLB = 7, CAS # 9003-11-6, manufactured by Huntsman),
Teric PE64 (EO/PO block copolymer, 25 Moles EO, HLB = 15, CAS # 9003-11-6, manufactured by Huntsman),
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-25 Teric PE 68 (EO/PO block copolymer, 150 Moles EO, HLB = 29, CAS # 9003-11-6, manufactured by Huntsman),
Toximul 8320 (polyoxyalkylene glycol ether, manufactured by
Stepan),
TSP 16 (tristyrylphenol ethoxylate, HLB = 13, CAS #99734-095, manufactured by Stepan company),
Pluronic PE 6400 (PE/PO/PE block copol, PO block mol wt 1750, 40% PE in molecule, contains CAS # 9003-11-6, manufactured by BASF), and
Pluronic PE 6800 (PE/PO/PE block copol, PO block mol wt 1750, 80% PE in molecule, contains CAS # 9003-11-6, manufactured by BASF).
[0073] The weight ratio of anionic to non-ionic surfactants was kept constant at 30:70. Termul 203 was selected as the control non-ionic surfactant. More details of the trials are set out in Appendix 1, which Appendix forms part of this Specification.
[0074] All formulations, apart from the control formulation, failed in terms of emulsion stability and/or cold temperature stability.
[0075] In Table 2 and subsequent Tables, which summarise the results of the trials, the following indicators apply:
E - Emulsion characteristics ascertained at 5% aq.
CTS - Cold temperature stability assessed at 2°C HLB - Hydrophilic Lipophilic Balance P - Pass
F - Fail
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TABLE 1
| Trial using different non-ionic surfactants at constant surfactant ratio | ||||
| (Control: | Termul 203 as non-ionic surfactant Ionic Surfactant: Ninate 60E Solvent: Diethylene Glycol Monoethyl Ether) | |||
| Summary | 30:70 | |||
| of Results | (a) | |||
| Code | Name | E | CTS | |
| A. Alkoxylate Alkyl Phenol | ||||
| IA1 | Termul 200 | FAIL | F | P |
| B. Nonyl Phenol Ethoxylates | ||||
| IA2 | Teric N2 | FAIL | F | P |
| IA3 | Teric N8 | FAIL | F | P |
| IA4 | Teric N10 | FAIL | F | P |
| IA5 | Teric N13 | FAIL | F | P |
| IA6 | Teric N20 | PASS | P | P |
| C. Castor Oil Ethoxylates | ||||
| IA7 | Termul 1284 | FAIL | F | P |
| IA8 | Termul 1285 | FAIL | F | P |
| D. Block Co-polymer | ||||
| IA9 | Termul 203 | PASS | P | P |
| IA10 | TSP 16 | FAIL | F | P |
| IA11 | Teric PE62 | FAIL | F | P |
| IA12 | Teric PE64 | FAIL | F | P |
| IA13 | Teric PE68 | FAIL | F | F |
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| IA14 | Pluronic PE6400 | FAIL | F | P |
| IA15 | Pluronic PE6800 | FAIL | F | F |
Varying Non-Ionic Surfactants (Nonyl phenol ethoxylated combinations at
Varying Surfactant Ratios) [0076] Formulations containing haloxyfop at a loading of 900 g/L and using combinations of non-ionic surfactants, being nonyl phenol ethoxylates, and a single ionic surfactant, namely that supplied under the trade name Ninate 60E, with the ratios of the surfactants being varied were trialled. More details of these trials are set out in Appendix 2, which Appendix forms part of this specification. All formulations gave satisfactory results for cold temperature stability but unsatisfactory results for emulsion characteristics.
TABLE 2
| Trial using different non-ionic surfactants (Nonyl phenol ethoxylated combination) at varying surfactant ratio | ||||
| (Control: | Termul 203 as non-ionic surfactant Ionic Surfactant: Ninate 60E Solvent: Diethylene Glycol Monoethyl Ether) | |||
| Summary of Results | ||||
| Code | Name | E | CTS | |
| A. Nonyl Phenol Ethoxylates | ||||
| DI | Ninate: Teric N20 (10:90) | FAIL | F | P |
| D2 | Ninate: Teric N13: Teric N20 (10:10:80) | FAIL | F | P |
| D3 | Ninate:Teric N13:Teric N20 (5:10:85) | FAIL | F | P |
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| D4 | Ninate:Teric N10:Teric N20 (10:10:80) | FAIL | F | P |
| D5 | Ninate:Teric N10:Teric N20 (5:10:85) | FAIL | F | P |
| D6 | Ninate:Teric N8:Teric N20 (10:10:80) | FAIL | F | P |
| D7 | Ninate:Teric N8:Teric N20 (5:10:85) | FAIL | F | P |
| D8 | Ninate:Teric N2:Teric N20 (10:5:85) | FAIL | F | P |
| D9 | Ninate:Teric N2:Teric N20 (5:5:90) | FAIL | F | P |
Varying Non-Ionic Surfactants (Block Copolymer Combinations) at Varying
Surfactant Ratios [0077] Formulations containing haloxyfop at a loading of 900 g/L, and using combinations of non-ionic surfactants, being block copolymers, and a single ionic surfactant, being that supplied under the trade name Ninate 60E, with the ratios of the surfactants being varied were trialled. More details of these trials are set out in Appendix 3, which Appendix forms part of this specification. All formulations gave unsatisfactory results for both emulsion characteristics and cold temperature stability.
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TABLE 3
| Trial using different non-ionic surfactants (co block polymer combination) at varying surfactant ratio | ||||
| (Control: | Termul 203 as non-ionic surfactant Ionic Surfactant: Ninate 60E Solvent: Diethylene Glycol Monoethyl Ether) | |||
| Summary of Results | ||||
| Code | Name | E | CTS | |
| A. Nonyl Phenol Ethoxylates | ||||
| El | Ninate: Teric PE62: Teric PE68 (40:28:32) | FAIL | F | F |
| E2 | Ninate: Teric PE 62: Teric PE68 (30:36:34) | FAIL | F | F |
| E3 | Ninate: Teric PE 62: Teric PE68 (20:45:35) | FAIL | F | F |
| E4 | Ninate: Teric PE 62: Teric PE68 (10:53:37) | FAIL | F | F |
| E5 | Ninate: Teric PE 64: Teric PE68 (40:45:15) | FAIL | F | F |
| E6 | Ninate: Teric PE 64: Teric PE68 (30:57:13) | FAIL | F | F |
| E7 | Ninate: Teric PE 64: Teric PE68 (20:70:10) | FAIL | F | F |
| E8 | Ninate: Teric PE 64: Teric PE68 (10:83:7) | FAIL | F | F |
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Varying Non-Ionic Surfactant (Block Co-Polymer Combinations) at Varying
Surfactant Ratios in the Absence of Solvent [0078] Formulations containing haloxyfop at a loading of 900 g/L, and incorporating combinations of non-ionic surfactants, being block co-polymers, and a single ionic surfactant, being that supplied under the trade name Ninate 60E, with no solvent being present, and with the ratios of surfactants being varied, were trialled. More details of these trials are set out in Appendix 4, which Appendix forms part of this specification. All formulations gave unsatisfactory results for both emulsion characteristics and cold temperature stability.
TABLE 4
| Trial using different non-ionic surfactants (co block polymer combination) at varying surfactant ratio without solvents | ||||
| (Control: | Termul 203 as non-ionic surfactant Ionic Surfactant: Ninate 60E Solvent: None) | |||
| Summary of Results | ||||
| Code | Name | E | CTS | |
| A. Nonyl Phenol Ethoxylates | ||||
| FI | Ninate: Teric PE62: Teric PE68 (40:28:32) | FAIL | F | F |
| F2 | Ninate: Teric PE 62: Teric PE68 (30:36:34) | FAIL | F | F |
| F3 | Ninate: Teric PE 62: Teric PE68 (20:45:35) | FAIL | F | F |
| F4 | Ninate: Teric PE 62: Teric PE68 (10:53:37) | FAIL | F | F |
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| L5 | Ninate: Teric PE 64: Teric PE68 (40:45:15) | FAIL | F | F |
| L6 | Ninate: Teric PE 64: Teric PE68 (30:57:13) | FAIL | F | F |
| L7 | Ninate: Teric PE 64: Teric PE68 (20:70:10) | FAIL | F | F |
| L8 | Ninate: Teric PE 64: Teric PE68 (10:83:7) | FAIL | F | F |
Varying Loading Only [0079] In each formulation in this set of trials, the ionic surfactant was that supplied under the trade name Ninate 60E and the non-ionic surfactant was that supplied under the trade name Termul 203, with the solvent being diethylene glycol monoethyl ether. More details of these trials are set out in Appendix 5, which Appendix forms part of this specification.
[0080] The formulations contained loadings of 950 g/L, 1000 g/L and
1050 g/L of haloxyfop, respectively. All were found to be stable, although there was a marked increase in viscosity as the loading increased with all formulations exhibiting unsatisfactory viscosity at 5°C.
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TABLE 5
| Trial using different non-ionic surfactants at constant surfactant ratio | ||||||
| (Control: | Termul 203 as non-ionic surfactant Ionic Surfactant: Ninate 60E Solvent: Diethylene Glycol Monoethyl Ether) | |||||
| Summary of Results | 30:70 | Viscosity, cPs | ||||
| Code | Name | E | CTS | @ 20°C | @ 5°C | |
| A. Block Co-polymer | ||||||
| FI | Termul 203 (Haloxyfop 950) | FAIL | P | P | 477 | 4,350 |
| F2 | Termul 203 (Haloxyfop 1000) | FAIL | P | P | 912 | 10,100 |
| F3 | Termul 203 (Haloxyfop 1050) | PASS | P | P | 1,840 | 25,000 |
Varying Solvent at Constant Surfactant Ratio [0081] In each formulation in this set of trials, the ionic surfactant was that supplied under the trade name Ninate 60E, the non-ionic surfactant was that supplied under the trade name Termul 203, and the solvent was propylene glycol mono methyl ether (PGME). More details of these trials are set out in Appendix 6, which Appendix forms part of this specification.
[0082] The formulations contained loadings of 950 g/L, 1000 g/L and
1050 g/L of haloxyfop, respectively. All formulations exhibited satisfactory emulsion characteristics and cold temperature stability, but only the formulation having a loading of 950 g/L haloxyfop met the viscosity criteria. This may indicate that 950 g/L may be an upper limit for haloxyfop loading according to the invention.
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TABLE 6
| Trial using different non-ionic surfactants at constant surfactant ratio | ||||||
| (Control: | Termul 203 as non-ionic surfactant Ninate 60E as Ionic Surfactant Solvent: Propylene Glycol Monoethyl Ether ((PGME)) | |||||
| Summary of Results | 30:70 | Viscosity, cPs | ||||
| Code | Name | E | CTS | @ 5°C | @ 20°C | |
| A. Block Co-polymer | ||||||
| Hl | Haloxyfop 950 | PASS | P | P | 1850 | 350 |
| H2 | Haloxyfop 1000 | PASS | P | P | 7100 | 635 |
| H3 | Haloxyfop 1050 | PASS | P | P | 57000 | 1660 |
Varying Ionic Surfactants at Constant Surfactant Ratio [0083] In these formulations the haloxyfop loading was maintained at substantially 900 g/L. The non-ionic surfactant was that as supplied under the trade mark Termul 203 and the solvent was diethylene glycol monoethyl ether. A single ionic surfactant chosen from a range of ionic surfactants was used in each instance, the range constituting members of the groups calcium dodecylebenzene sulphates, alkylphenol ether sulfate/tallow amine ethoxylated salts, and branched alcohol ether sulfate/tallow amine ethoxylated salts. The ratio of ionic to non-ionic surfactant was kept at 30:70. More details of these trials are set out in Appendix 7, which Appendix forms part of this specification.
[0084] All formulations, apart from that containing Toximul TAAPS 8, exhibited satisfactory emulsion characteristics and cold temperature stability.
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TABLE7
| Trial using different ionic surfactants at constant surfactant ratio | ||||
| (Control: | Termul 203 as non-ionic surfactant Ionic Surfactant: Ninate 60E Solvent: Diethylene Glycol Monoethyl Ether) | |||
| Summary of Results | 30:70 | |||
| Code | Name | E | CTS | |
| A. Calcium Dodecylbenzene Sulphonate | ||||
| IA9 | Ninate 60E | PASS | P | P |
| IB9 | Rhodacal 60//BE-C | PASS | P | P |
| IC9 | Kemmat HF60 | PASS | P | P |
| ID9 | Nansa EVM 70/2E | PASS | P | P |
| IE9 | Rhodacal 70 | PASS | P | P |
| IF9 | Rhodacal 70B | PASS | P | P |
| B. Alkylphenol ether sulfate/tallow amine ethoxylated salts | ||||
| IG9 | Toximul TANS 5 | PASS | P | P |
| IH9 | Toximul TANS 6 | PASS | P | P |
| 119 | Toximul TANS 8 | PASS | P | P |
| C. Branched alcohol ether sulfate/tallow amine ethoxylated salts | ||||
| IJ9 | Toximul TAABS 5 | PASS | P | P |
| IK9 | Toximul TAABS 8 | PASS | P | P |
Varying Solvents at Constant Surfactant Ratio [0085] In these trials the haloxyfop loading was maintained at substantially 900 g/L, the ionic surfactant was that as supplied under the trade
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-35 name Ninate 60E, the non-ionic surfactant was that as supplied under the trade name Termul 203, and the ionic surfactant:non-ionic surfactant ratio was maintained at 30:70. More details of the trials are set out in Appendix 8, which Appendix forms part of this specification.
[0086] Only these formulations in which the solvent was diethylene glycol monoethyl ether or propylene glycol monomethyl ether exhibited satisfactory emulsion characteristics and cold temperature stability.
TABLE 8
| Trial using different solvent surfactants at constant surfactant ratio (Control: Termul 203 as non-ionic surfactant Ionic Surfactant: Ninate 60E) | ||||
| Summary of Results | 30:70 | |||
| Code | Name | E | CTS | |
| Solvents | ||||
| IA9 | Diethylene glycol monoethyl ether (DGME) | Pass | P | P |
| IIA9 | Recosol 150 | Pail | F | P |
| IIIA9 | Recosol 200 | Pail | F | P |
| IVA9 | Xylene | Pail | F | P |
| VA9 | Toluene | Pail | F | P |
| VIA9 | Acetone | Pail | F | P |
| VIIA9 | Dimethyl adipate | Pail | F | F |
| VIIIA9 | Dimethyl succinate | Pail | F | F |
| IXA9 | NMP | Fail | F | P |
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| XA9 | Ethylene glycol mo no butyl ether | Pass | P | P |
| XIA9 | Propylene glycol monomethyl ether (PGME) | Pass | P | P |
| XIIA9 | Propylene glycol | Fail | N/A | F |
| XIIIA9 | Diethylene glycol | Fail | N/A | F |
| XIVA9 | Dipropylene glycol | Fail | F | F |
Varying Surfactant Loading at Constant Surfactant Ratio [0087] In these formulations the haloxyfop loading was maintained at substantially 900 g/L, the ionic surfactant used was that as supplied under the trade name Ninate 60E, the non-ionic surfactant was that as supplied under the trade name Termul 203, the ratio of ionic to non-ionic surfactant was maintained at 30:70, and the solvent was diethylene glycol monoethyl ether. The total surfactant loading was varied. More details of the trials are set out in Appendix 9, which Appendix forms part of this specification.
[0088] Decreasing the total surfactant loading below 80% of the control loading resulted in unsatisfactory emulsion characteristics.
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TABLE9
| Trial using different surfactant loadings at constant surfactant ratio (Control: Termul 203 as non-ionic surfactant | |||||
| Ionic Surfactant: Ninate 60E Solvent: Diethylene Glycol Monoethyl Ether) | |||||
| Code | Name | Summary of Results | E | CTS | HLB |
| A. Haloxyfop 900 (Control Formulation) | |||||
| J1 | Original ratio 60:40 of surfactant At 80% surfactant loading | Pass | P | P | 15.55 |
| J2 | Original ratio 60:40 of surfactant At 60% surfactant loading | Pass | P | P | 15.55 |
| J3 | Original ratio 60:40 of surfactant At 40% surfactant loading | Fail | F | P | 15.56 |
| J4 | Original ratio 60:40 of surfactant At 20% surfactant loading | Fail | F | P | 15.58 |
Varying Haloxyfop Loading and Varying Non-Ionic Surfactant [0089] In these trials the haloxyfop was set at one of 900 g/L, 800 g/L and 700 g/L and a number of formulations at those loadings using one of a range of non-ionic surfactants, being nonyl phenol ethoxylates, and a block copolymer, were prepared. The ionic surfactant used was that as supplied under the trade name Ninate 60E, and the solvent was diethylene glycol monoethyl ether. The ionic surfactantmon-ionic surfactant ratio was maintained at 30:70. More details of those trials are set out in Appendix 10, which Appendix forms part of this specification.
3472646vl
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-382014203147 29 Jan 2018 [0090] Only formulations incorporating the non-ionic surfactant as supplied under the trade name Toximul 8320 exhibited satisfactory emulsion characteristics and cold temperature stability at all three haloxyfop loadings used. At haloxyfop loadings of 900 g/L and 800 g/L formulations incorporating the non-ionic surfactant as supplied under the trade name Teric N9 exhibited satisfactory emulsion characteristics and cold temperature stability, but the formulation with 700 g/L haloxyfop loading exhibited unsatisfactory emulsion characteristics.
TABLE 10
| Trials by varying non-ionic surfactant at different Haloxyfop loading (900 g/L, 800 g/L and 700 g/L) (Control: Termul 203 as non-ionic surfactant Ninate 60E as ionic surfactant DGME as Solvent) Trials were done using the following loading: Haloxyfop tech: varies (900 g/L, 800 g/L, 700 g/L) Solvent (DGME): ~ 185 g/L Anionic Surfactant (Ninate 60E): ~ 30 g/L Non-ionic Surfactant - Nonyl phenol ethoxylates (e.g., Teric N20, N30, N13, N15, N9) and block co-polymer (Toximul 8320): ~ 62-66 g/L | |||||
| Code | Name | Summary of Results | E | CTS | HLB |
| Haloxyfop loading @ 900 g/L | |||||
| 4a | Toximul 8320 | Pass | P | P | 11.53 |
| 4b | Teric N20 | Pass | P | P | 14.20 |
| 4c | Teric N30 | Fail | F | P | 15.07 |
| 4d | Teric N13 | Pass | P | P | 13.14 |
| 4e | Teric N15 | Fail | F | P | 13.57 |
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| 4f | Teric N9 | Pass | P | P | 12.08 |
| Haloxyfop loading @ 800 g/L | |||||
| 4g | Toximul 8320 | Pass | P | P | 11.57 |
| 4h | Teric N20 | Pail | F | P | 15.22 |
| 4i | Teric N30 | Pail | F | P | 14.39 |
| 4j | Teric N13 | Pail | F | P | 13.65 |
| 4k | Teric N15 | Fail | F | P | 12.95 |
| 41 | Teric N9 | Pass | P | P | 12.08 |
| Haloxyfop loading @ 700 g/L | |||||
| 4m | Toximul 8320 | Pass | P | P | 11.55 |
| 4n | Teric N20 | Fail | F | P | 15.13 |
| 4o | Teric N30 | Fail | F | P | 14.32 |
| 4p | Teric N13 | Fail | F | P | 13.63 |
| 4q | Teric N15 | Fail | F | P | 13.00 |
| 4r | Teric N9 | Fail | F | P | 12.12 |
Varying ionic Surfactant and Non-Ionic Surfactant at Constant Surfactant Ratio [0091] The haloxyfop loading in the formulations used in these trials was maintained at substantially 900 g/L, the solvent used was diethylene glycol monoethyl ether, the non-ionic surfactant used was either a nonyl phenol ethoxylate as supplied under the trade name Teric N9 or a block co-polymer as supplied under the trade name Termul 8320. The ionic surfactant used was one selected from a range and the ionic surfactant:non-ionic surfactant ratio was maintained at 30:70. More details of the trials are set out in Appendix 11, which Appendix forms part of this specification.
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-402014203147 29 Jan 2018 [0092] Combinations of N9 and an ionic surfactant did not yield satisfactory formulations, while combinations of Toximul 8320 and anionic surfactants as supplied under the trade name Rhodacal 70 and Rhodacal 70B also did not yield satisfactory formulations, all exhibiting unsatisfactory emulsion characteristics.
TABLE 11
| Trials using different anionic surfactants and non-ionic surfactants at constant surfactant ratio | |||||
| (Control: Termul 203 as non-ionic surfactant Ninate 60E as ionic surfactant DGME as Solvent) Trials were done using the following loading: | |||||
| Haloxyfop tech: 900 g/L | |||||
| Solvent (DGME): ~ 175 g/L Anionic Surfactant: varies (Kemmat HF60, Nansa 70EVM, Rhodacal 70, Rhodacal 70B: ~ 26-33 g/L Non-ionic Surfactant (Nonyl phenol ethoxylate - Teric N9) or (Block copolymer - Toximul 8320: ~ 61-67 g/L | |||||
| Code | Name | Summary of Results | E | CTS | HLB |
| Solvents | |||||
| 4s | T8320 / Kemmat HF60 | Pass | P | P | 11.72 |
| 4t | T8320 / Nansa 70 EVM | Pass | P | P | 11.72 |
| 4u | T8320 / Rhodacal 70 | Fail | F | P | 11.70 |
| 4v | T8320 / Rhodacal 70B | Fail | F | P | 10.85 |
| 4w | TN9 / Kemmat HF60 | Fail | F | P | 12.27 |
| 4x | TN9/Nansa 70 EVM | Pass | P | P | 12.23 |
| 4y | TN9 / Rhodacal 70 | Pass | P | P | 12.25 |
| 4z | TN9 / Rhodacal 70B | Pass | P | P | 11.49 |
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-41 Varying Solvents at Constant Surfactant Ratio [0093] Further trials were carried out on formulations having a haloxyfop loading of 900 g/L. The ionic surfactant used was that as supplied under the trade name Ninate 60E and the non-ionic surfactant used was that as supplied under the trade name Termul 203, with the anionic surfactantmonionic surfactant ratio being set at 30:70. More details of these trials are set out in Appendix 12, which Appendix forms part of this specification.
[0094] Solvents giving rise to satisfactory formulations were ethylene glycol monobutyl ether (EGME), (e.g., butyl glysolv), toluene, and acetone. Dimethyl succinate and dimethyl adipate were not effective solvents and no homogenous solutions were obtained with these solvents. The unsatisfactory formulations did not exhibit desired emulsion characteristics.
TABLE 12
| Trials using different solvents (Control: Termul 203 as non-ionic surfactant Ninate 60E as ionic surfactant DGME as Solvent) Trials were done using the following loading: Haloxyfop tech: 900 g/L Solvent varies (e.g., R150, R200, EGME, Dimethyl succinate, Toluene, Acetone, Dimethyl adipate, xylene, NMP and Exxate 700): ~ 160-190 g/L Anionic Surfactant (Ninate 60E): ~ 25-29 g/L Non-ionic Surfactant (Block co-polymer - Toximul 8320: ~ 60-64 g/L | |||||
| Code | Name | Summary of Results | E | CTS | HLB |
| Solvents | |||||
| 4ae | R200 | Fail | F | P | 11.54 |
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| 4af | EGME | Pass | P | P | 11.56 |
| 4ag | R150 | Fail | F | P | 11.53 |
| 4ah | EGME | Pass | P | P | 11.55 |
| 4ai | Dimethyl Succinate | Fail * | * | * | 11.55 |
| 4aj | Toluene | Pass | P | P | 11.55 |
| 4ak | Acetone | Pass | P | P | 11.54 |
| 4al | Dimethyl Adipate | Fail * | * | * | 11.52 |
| 4am | Xylene | Fail | F | P | 11.56 |
| 4an | NMP | Fail | F | P | 11.53 |
| 4ao | Exxate 700 | Fail | F | P | 11.56 |
Examples of Formulations Exhibiting Satisfactory Characteristics [0095] Examples of haloxyfop formulations prepared according to the present invention which exhibit satisfactory characteristics (as demonstrated by the trials discussed above) are set out in Table 13 for ease of reference.
TABLE 13
| Trial Code | Appendix | Haloxyfop Loading g/L | Solvent & Loading g/L | Ionic Surfactant & Loading g/L | Non-Ionic Surfactant & Loading g/L |
| IA9 | 1 | 899 (+95) | DGME 183.5 | Ninate 60E 27 | Termul 203 63 |
| Hl | 6 | 950 (+100) | PGME 126 | Ninate 60E 26 | Termul 203 61 |
| IB9 | 7 | 898 (+94) | DGME 187 | Rhodacal 60/BE-C 27 | Termul 203 60 |
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| IC9 | 7 | 896 (+94) | DGME 187 | Kemmat HF60 28 | Termul 203 61 |
| ID9 | 7 | 899 (+95) | DGME 184 | Nansa EVM 70/2E 27 | Termul 203 62 |
| IE9 | 7 | 896 (+94) | DGME 187 | Rhodacal 70 28 | Termul 203 62 |
| IF9 | 7 | 897 (+94) | DGME 186 | Rhodacal 70B 26 | Termul 203 62 |
| IG9 | 7 | 897 (+94) | DGME 186 | Toximul TANS 5 27 | Termul 203 61 |
| IH9 | 7 | 896 (+94) | DGME 185 | Toximul TANS 6 29 | Termul 203 62 |
| 119 | 7 | 901 (+95) | DGME 183 | Toximul TANS 8 26 | Termul 203 61 |
| U9 | 7 | 897 (+94) | DGME 187 | Toximul TAABS 5 26 | Termul 203 62 |
| XIA9 | 8 | 900 (+95) | PGME 184 | Ninate 60E 26 | Termul 203 61 |
| J1 | 9 | 900 (+95) | DGME 196 | Ninate 60E 21 | Termul 203 49 |
| 4a | 10 | 900 (+95) | DGME 184 | Ninate 60E 29 | Toximul 8320 62 |
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| 4f | 10 | 901 (+95) | DGME 188 | Ninate 60E 30 | Teric N9 66 |
| 4g | 10 | 802 (+84) | DGME 274 | Ninate 60E 25 | Toximul 8320 64 |
| 41 | 10 | 802 (+84) | DGME 266 | Ninate 60E 28 | Teric N9 61 |
| 4m | 10 | 703 (+95) | DGME 338 | Ninate 60E 28 | Toximul 8320 65 |
| 4s | 11 | 900 (+95) | DGME 175 | Kemmat HF60 26 | Toximul 8320 67 |
| 4t | 11 | 900 (+95) | DGME 176 | Nansa EVM 70/2E 26 | Toximul 8320 68 |
| 4af | 12 | 900 (+95) | EGME 166 | Ninate 60E 27 | Toximul 8320 64 |
Note 1: Ninate 60E given weight includes carrier solvent
Note 2: Rhodacal 60/BE-C given weight includes carrier solvent Note 3: Kemmat HF60 given weight includes carrier solvent Note 4: Nansa EVM 70/2E given weight includes carrier solvent Note 5: Rhodacal 70 given weight includes carrier solvent Note 6: Other anionic surfactants, weight includes carrier solvent Note 7: EGME = ethyleneglycolmonobutyl ether = butyl glysolv Note 8: PGME = propyleneglycolmonoethyl ether
Source of Technical Grade Active (Haloxyfop-P-methyl (CAS# 72619-32-0)):
Manufactured by Jinan Luba Chemicals Co Ltd, 26 South Xizhou Road, Lichen, Jinan, P.R. CHINA;
Purchased from Zhejiang Chemical Industrial Co Ltd, P.R. CHINA
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-45 Agronomic Trial [0096] Haloxyfop 900 and Haloxyfop 520 were compared in the field for brome and wild oat control, and for crop phyto toxicity. Plot size was 2.5m x 10m, 3 replicates. Treatments were applied with a hand boom. % wild oat and brome grass were assessed visually. The results were:
• At all rates (50 ml/ha, 100 ml/ha and 200 ml/ha for Haloxyfop 520 and 29 ml/ha, 58 ml/ha and 116 ml/ha for Haloxyfop 900) there was found to be 100% control of wild oats and brome grass.
• Speed of kill was observed to be slightly faster at higher rates used with both formulations.
• No phytotoxicity was observed from either Haloxyfop 520 or Haloxyfop 900, even in the double rate treatments.
• Both Haloxyfop 520 and Haloxyfop 900 mixed well in the field.
• None of the ryegrass present in the trial was controlled by the haloxyfop formulations because the ryegrass was resistant to Fops (common in the trial area of Wycheproof, Victoria, Australia).
[0097] The complete disclosures of any patents, patent documents, and publications cited herein are incorporated by reference in their entirety as if each were individually incorporated. Various modifications and alterations to this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention. It should be understood that this
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-462014203147 11 Jun2014 invention is not intended to be unduly limited by the illustrative embodiments and examples set forth herein and that such examples and embodiments are presented by way of example only with the scope of the invention intended to be limited only by the claims set forth herein as follows.
[0098] Throughout this specification and the claims which follow, unless the context requires otherwise, the word “comprise”, and variations such as “comprises” or “comprising”, will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
[0099] The reference in this specification to any prior publication (or information derived from it), or to any matter which is known, is not, and should not be taken as an acknowledgment or admission or any form of suggestion that that prior publication (or information derived from it) or known matter forms part of the common general knowledge in the field of endeavour to which this specification relates.
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APPENDIX 1
Trial # IA1
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 200 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 200 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 200: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | CAS# | Function | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 72619-32-0 | Active ingredient | 4978.3 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 111-90-0 | Solvent | 917.5 | 183 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | CABS ( 68584-23-6) & 2-ethyl hexanol (104-76-7) | Surfactant | 136.7 | 27 |
| Alkoxylated alkyl phenol used: Termul 200 (non-ionic surfactant) | 37251-69-7 | Surfactant | 313.3 | 63 |
| Total | 6345.8 |
| RESULTS OF FORMULATION | ||||
| Parameter | Method | Required | Results | Remarks |
| Appearance | Visual | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | Validated chromatographic method (Accuracy: 98-102%) (Linearity: R > 0.99) (Precision: s/average < 2%) | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | MT 75.3 | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | CIPAC MT 3.1 | 1.25 to 1.27 | n/a |
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| Emulsion characteristics | CIPAC MT 36.1 | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | CIPAC MT 47.2 | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | MT75.3 | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | MT 192 | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | MT 192 | 0 to 2000cPs | n/a | |
| Long Term Performance | Various as per above | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | |||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # IA2
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N2 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N2 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N2: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4979.2 | 899 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent | 925.8 | 185 |
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| used: Diethylene Glycol Monoethyl Ether | ||
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 135.0 | 27 |
| Nonyl Phenol ethoxylates used: Teric N2 (non-ionic surfactant) | 305.0 | 61 |
| Total | 6345.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3ml oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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Trial # IA3
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N8 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N8 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N8: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 897 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 934.2 | 186 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 132.5 | 26 |
| Nonyl Phenol ethoxylates used: Teric N8 (non-ionic surfactant) | 313.3 | 62 |
| Total | 6350.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # IA4
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N10 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N10 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N10: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4971.7 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 925.0 | 185 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 132.5 | 26 |
| Nonyl Phenol ethoxylates | 304.2 | 61 |
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| used: Teric N10 (non-ionic surfactant) | ||
| Total | 6333.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # IA5
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N13 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N13 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N13: Diethylene Glycol monoethyl ether
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-53 FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4967.5 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 932.5 | 187 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 127.5 | 26 |
| Nonyl Phenol ethoxylates used: Teric N13 (non-ionic surfactant) | 302.5 | 61 |
| Total | 6330.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # IA6
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N20 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4980.8 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 917.5 | 183 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 133.3 | 27 |
| Nonyl Phenol ethoxylates used: Teric N20 (non-ionic surfactant) | 313.3 | 63 |
| Total | 6345.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a |
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| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2ml cream ©bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # IA7
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 1284 as non-ionic surfactants against Ninate 60E Ratio of N60E: Termul 1284 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 1284: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4974.2 | 899 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 922.5 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid | 135.0 | 27 |
3472646v 1
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| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | ||
| Castor Oil Ethoxylates used: Termul 1284 (non-ionic surfactant) | 305.8 | 61 |
| Total | 6337.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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Trial # IA8
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 1285 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 1285 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 1285: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4968.3 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 921.7 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 136.7 | 27 |
| Castor Oil Ethoxylates used: Termul 1285 (non-ionic surfactant) | 304.2 | 61 |
| Total | 6330.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # IA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2- pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4978.3 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 917.5 | 183 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 136.7 | 27 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 313.3 | 63 |
| Total | 6345.8 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 899g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.35 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.266 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.3ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 25ml | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1212cps | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 315cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # IA10
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using TSP 16 as non-ionic surfactants against Ninate 60E
Ratio of N60E: TSP 16 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: TSP 16: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4979.2 | 895 |
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| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 946.7 | 188 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 133.3 | 26 |
| Block Co-polymer used: TSP 16 (non-ionic surfactant) | 311.7 | 62 |
| Total | 6370.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml oil&cream@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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Trial # IA11
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE 62 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE 62 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE 62: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.3 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 926.7 | 185 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 132.5 | 26 |
| Block Co-polymer used: Teric PE 62 (non-ionic surfactant) | 307.5 | 61 |
| Total | 6340.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml oil&cream@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # IA12
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE 64 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE 64 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE 64: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4982.5 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 924.2 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 138.3 | 28 |
| Block Co-polymer | 303.3 | 60 |
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| used: Teric PE 64 (non-ionic surfactant) | ||
| Total | 6348.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml oil&cream@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # IA13
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE 68 as non-ionic surfactants against Ninate 60E Ratio of N60E: Teric PE 68 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE 68: Diethylene Glycol monoethyl ether
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4977.5 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 917.5 | 183 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 136.7 | 27 |
| Block Co-polymer used: Teric PE 68 (non-ionic surfactant) | 306.7 | 61 |
| Total | 6338.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml oil&cream@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, formed lumps | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # IA14
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Pluronic 6400 as non-ionic surfactants against Ninate 60E Ratio of N60E: Pluronic 6400 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Pluronic 6400: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 926.7 | 185 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 130.0 | 26 |
| Block Co-polymer used: Pluronic 6400 (non-ionic surfactant) | 310.0 | 62 |
| Total | 6336.7 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml oil&cream@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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Trial # IA15
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Pluronic 6800 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Pluronic 6800 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Pluronic 6800: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.5 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 925.8 | 185 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 128.3 | 26 |
| Block Co-polymer used: Teric PE 68 (non-ionic surfactant) | 304.2 | 61 |
| Total | 6330.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml oil&cream@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, formed lumps | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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APPENDIX 2
Trial # D1
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N20 (10:90)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.1 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 890.7 | 178 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 47.1 | 9 |
| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | 418.6 | 84 |
| Total | 6328.6 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3ml oil&cream @bottom | Failed |
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| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # D2
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N13 and Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N13: Teric N20 (10:10:80)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N13: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4975.0 | 901 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 892.9 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 46.4 | 9 |
| used: Ninate 60E (anionic surfactant) | ||
| Nonyl phenol ethoxylated | 46.4 | 9 |
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| used: Teric N13 (non-ionic surfactant) | ||
| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | 367.9 | 74 |
| Total | 6328.6 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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Trial # D3
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N13 and Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N13: Teric N20 (5:10:85)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N13: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4975.0 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 895.7 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 22.1 | 4 |
| Nonyl phenol ethoxylated used: Teric N13 (non-ionic surfactant) | 50.0 | 10 |
| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | 395.0 | 79 |
| Total | 6337.9 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # D4
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N10 and Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N10: Teric N20 (10:10:80)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N10: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4975.7 | 900 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 894.3 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 45.7 | 9 |
| used: Ninate 60E (anionic surfactant) | ||
| Nonyl phenol ethoxylated | 46.4 | 9 |
| used: Teric N10 (non-ionic surfactant) |
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| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | 370.0 | 74 |
| Total | 6332.1 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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Trial # D5
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N10 and Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N10: Teric N20 (5:10:85)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N10: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.7 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 892.1 | 178 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 22.9 | 5 |
| Nonyl phenol ethoxylated used: Teric N10 (non-ionic surfactant) | 46.4 | 9 |
| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | 395.7 | 79 |
| Total | 6327.9 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3ml cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # D6
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N8 and Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N8: Teric N20 (10:10:80)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N8: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4972.9 | 901 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 890.7 | 178 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 44.3 | 9 |
| used: Ninate 60E (anionic surfactant) | ||
| Nonyl phenol ethoxylated | 44.3 | 9 |
| used: Teric N8 (non-ionic surfactant) |
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| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | 370.7 | 74 |
| Total | 6322.9 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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-78 Trial # D7
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N8 and Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N8: Teric N20 (5:10:85)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N8: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 901 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 891.4 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 21.4 | 4 |
| Nonyl phenol ethoxylated used: Teric N8 (non-ionic surfactant) | 45.0 | 9 |
| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | 394.3 | 79 |
| Total | 6322.1 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # D8
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N2 and Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N2: Teric N20 (10:5:85)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N2: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4976.4 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 895.0 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 47.9 | 10 |
| Nonyl phenol ethoxylated used: Teric N2 (non-ionic surfactant) | 22.9 | 5 |
| 397.9 | 79 |
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| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | ||
| Total | 6340.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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-81 Trial # D9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N2 and Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N2: Teric N20 (5:5:90)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N2: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.7 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 893.6 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 24.3 | 5 |
| Nonyl phenol ethoxylated used: Teric N2 (non-ionic surfactant) | 22.9 | 5 |
| Nonyl phenol ethoxylated used: Teric N20 (non-ionic surfactant) | 417.1 | 83 |
| Total | 6328.6 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS FAILED |
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Trial # E1
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE62 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE62: Teric PE68 (40:28:32)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE62: Teric PE68: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.9 | 902 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 892.9 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 178.6 | 36 |
| Block co-polymer used: Teric PE 62 (non-ionic surfactant) | 125.0 | 25 |
| Co block polymer used: Teric PE 68 (non-ionic surfactant) | 145.0 | 29 |
| Total | 6314.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a |
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| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # E2
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE62 and Teric PE68 as non-ionic surfactants against Ninate 60E Ratio of N60E: Teric PE62: Teric PE68 (30:36:34)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE62: Teric PE68: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4972.1 | 903 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 890.7 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 133.6 | 27 |
| used: Ninate 60E (anionic surfactant) | ||
| 161.4 | 32 |
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| Block co-polymer used: Teric PE 62 (non-ionic surfactant | ||
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 153.6 | 31 |
| Total | 6311.4 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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Trial # E3
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE62 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE62: Teric PE68 (20:45:35)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE62: Teric PE68: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4971.4 | 902 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 892.9 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 88.6 | 18 |
| Block co-polymer used: Teric PE 62 (non-ionic surfactant | 202.1 | 41 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 157.1 | 32 |
| Total | 6312.1 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # E4
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE62 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE62: Teric PE68 (10:53:37)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE62: Teric PE68: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4971.4 | 903 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 889.3 | 178 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 45.0 | 9 |
| Block co-polymer used: Teric PE 62 (non-ionic surfactant | 238.6 | 48 |
| 165.7 | 33 |
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| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | ||
| Total | 6310.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 5ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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Trial # E5
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE64 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE64: Teric PE68 (40:45:15)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE64: Teric PE68: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.9 | 902 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 897.9 | 180 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 178.6 | 36 |
| Block co-polymer used: Teric PE 64 (non-ionic surfactant | 199.3 | 40 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 66.4 | 13 |
| Total | 6315.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2ml solid crystals & 2.5ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # E6
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE64 and Teric PE68 as non-ionic surfactants against Ninate 60E Ratio of N60E: Teric PE64: Teric PE68 (30:57:13)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE64: Teric PE68: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.1 | 903 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 893.6 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 131.4 | 26 |
| Block co-polymer used: Teric PE 64 (non-ionic surfactant | 252.1 | 51 |
| Block co-polymer | 57.9 | 12 |
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| used: Teric PE 68 (non-ionic surfactant) | ||
| Total | 6307.1 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.5ml solid crystals & 2.5ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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Trial # E7
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE64 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE64: Teric PE68 (20:70:10)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE64: Teric PE68: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.1 | 902 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 899.3 | 180 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 88.6 | 18 |
| Block co-polymer used: Teric PE 64 (non-ionic surfactant | 309.3 | 62 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 45.0 | 9 |
| Total | 6314.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4.5ml solid crystals&oil & 0.5ml cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # E8
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE64 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE64: Teric PE68 (10:83:7)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE64: Teric PE68: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4976.4 | 904 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 895.0 | 180 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 42.9 | 9 |
| Block co-polymer used: Teric PE 64 (non-ionic surfactant | 362.9 | 73 |
| 30.0 | 6 |
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| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | ||
| Total | 6307.1 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4.5ml oil &solid crystals & 0.5ml cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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Trial # F1
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE62 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE62: Teric PE68 (40:28:32)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE62: Teric PE68: no solvents
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.9 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 0.0 | 0 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 544.3 | 109 |
| Block co-polymer used: Teric PE 62 (non-ionic surfactant) | 379.3 | 76 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 435.0 | 87 |
| Total | 6331.4 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a |
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| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # F2
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE62 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE62: Teric PE68 (30:36:34)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE62: Teric PE68: no solvents
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4974.3 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 0.0 | 0 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 410.7 | 82 |
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| used: Ninate 60E (anionic surfactant) | ||
| Block co-polymer used: Teric PE 62 (non-ionic surfactant | 491.4 | 98 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 462.9 | 92 |
| Total | 6339.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 6ml cream&oil @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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-98 Trial # F3
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE62 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE62: Teric PE68 (20:45:35)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE62: Teric PE68: no solvents
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.9 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 0.0 | 0 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 273.6 | 55 |
| Block co-polymer used: Teric PE 62 (non-ionic surfactant | 615.0 | 123 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 477.9 | 95 |
| Total | 6339.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3ml cream&oil @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # F4
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE62 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE62: Teric PE68 (10:53:37)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE62: Teric PE68: no solvents FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.9 | 898 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 0.0 | 0 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 136.4 | 27 |
| Block co-polymer used: Teric PE 62 (non-ionic surfactant | 727.1 | 145 |
| Block co-polymer | 507.1 | 101 |
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| used: Teric PE 68 (non-ionic surfactant) | ||
| Total | 6343.6 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 6ml oil&cream @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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Trial # F5
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE64 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE64: Teric PE68 (40:45:15)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE64: Teric PE68: no solvents
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.1 | 897 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 0.0 | 0 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 551.4 | 110 |
| Block co-polymer used: Teric PE 64 (non-ionic surfactant | 618.6 | 123 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 205.7 | 41 |
| Total | 6347.9 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml cream&oil @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # F6
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE64 and Teric PE68 as non-ionic surfactants against Ninate 60E Ratio of N60E: Teric PE64: Teric PE68 (30:57:13)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE64: Teric PE68: no solvents
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.6 | 898 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 0.0 | 0 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 410.7 | 82 |
| Block co-polymer used: Teric PE 64 (non-ionic surfactant | 781.4 | 156 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 177.9 | 35 |
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- 103 Total
6343.6
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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Trial # F7
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE64 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE64: Teric PE68 (20:70:10)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE64: Teric PE68: no solvent
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4975.0 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 0.0 | 0 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 271.4 | 54 |
| Block co-polymer used: Teric PE 64 (non-ionic surfactant | 953.6 | 191 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 135.0 | 27 |
| Total | 6335.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 3.5ml cream&oil @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # F8
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Teric PE64 and Teric PE68 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric PE64: Teric PE68 (10:83:7)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric PE64: Teric PE68: no solvents
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.6 | 898 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 0.0 | 0 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 139.3 | 28 |
| Block co-polymer used: Teric PE 64 (non-ionic surfactant | 1135.7 | 227 |
| Block co-polymer used: Teric PE 68 (non-ionic surfactant) | 94.3 | 19 |
| Total | 6342.9 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil @bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, solidify | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING, BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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APPENDIX 5
Trial # F1
HALOXYFOP 900 TRIALS
Haloxyfop active present at 950g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 5249.4 | 950 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 701.9 | 140 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 132.5 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 307.1 | 61 |
| Total | 6390.9 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 950g/L | Passed |
| pH at 1%aq. Solution | 6 to 8 | 7.42 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.278 | Above the required result |
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| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, no cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 12ml in 1min | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 4350cps | Failed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 477cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | FAILED THE VISCOSITY TEST @ 5°C |
Trial # F2
HALOXYFOP 900 TRIALS
Haloxyfop active present at 10OOg/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 5525.2 | 1000 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 508.2 | 102 |
| Calcium C10-16 alkyl benzenesulfonic acid | 131.1 | 26 |
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| in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | ||
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 305.5 | 61 |
| Total | 6470.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 1000g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.43 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.294 | Above the required result |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.1ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 12ml in 1min | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 10100cps | Failed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 912cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | FAILED THE VISCOSITY TEST @ 5°C |
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Trial # F3
HALOXYFOP 900 TRIALS
Haloxyfop active present at 1050g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 5801.5 | 1050 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 295.8 | 59 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 131.1 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 306.7 | 61 |
| Total | 6535.1 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 1050g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.66 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.307 | Above the required result |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.1ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 4ml in 1min | Passed |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 25000cps | Failed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 1840cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | FAILED THE VISCOSITY TEST @ 5°C |
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APPENDIX 6
Trial # H1
HALOXYFOP 900 TRIALS
Haloxyfop active present at 950g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: PGME
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 5249.9 | 950 |
| Solvent used: Propylene Glycol Monomethyl Ether | 631.5 | 126 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 131.3 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 306.2 | 61 |
| Total | 6318.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Red to brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 950g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.24 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.264 | Passed |
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| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | Milky emulsion, no separation, 0.2ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 2ml in 1min | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1850cps | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 350cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | ||
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # H2
HALOXYFOP 900 TRIALS
Haloxyfop active present at 10OOg/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: PGME
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 5526.7 | 1000 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Propylene Glycol Monomethyl Ether | 439.1 | 88 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 131.9 | 26 |
| used: Ninate 60E (anionic surfactant) |
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| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 306.8 | 61 |
| Total | 6404.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Red to brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 1000g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.56 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.281 | Above Specs |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | Milky emulsion, no separation, 0.5ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 2ml in 1min | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 7100cps | Failed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 635cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | ||
| General Remarks PASS or FAIL? | PASS | ||
| Description: | VISCOSITY AT 5°C FAILED THE TRIAL |
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Trial # H3
HALOXYFOP 900 TRIALS
Haloxyfop active present at 1050g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: PGME
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 5806.6 | 1051 |
| Solvent used: Propylene Glycol Monomethyl Ether | 252.8 | 51 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 131.4 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 307.5 | 62 |
| Total | 6498.2 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Red to brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 1051 g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.63 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.300 | Above Specs |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | Milky emulsion, no separation, 1.0ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 2ml in 1min | Passed |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 57000cps | Failed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 1660cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | ||
| General Remarks PASS or FAIL? | PASS | ||
| Description: | VISCOSITY AT 5OC FAILED THE TRIAL |
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APPENDIX 7
Trial # IA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4978.3 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 917.5 | 183 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 136.7 | 27 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 313.3 | 63 |
| Total | 6345.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 899g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.35 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.266 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.3ml cream@bottom | Passed |
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| Persistent Foaming | <60mL after 1 min | 25ml | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1212cps | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 315cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # IB9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Rhodacal 60/BE-C as anionic surfactants against Termul 203 Ratio of Rhodacal 60/BE-C : Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Rhodacal 60/BE-C: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.5 | 898 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 938.3 | 187 |
| Calcium Dodecylbenzene Sulphonate in 2ethylhexanol used: Rhodacal 60/BE-C (anionic surfactant) | 133.3 | 27 |
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| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 302.5 | 60 |
| Total | 6346.7 |
| RESULTS OF FORMULATION | ||||
| Parameter | Method | Required | Results | Remarks |
| Appearance | Visual | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | Validated chromatographic method (Accuracy: 98-102%) (Linearity: R > 0.99) (Precision: s/average < 2%) | 875 to 925g/L Haloxyfop | 898g/L | Passed |
| pH at 1 % aq. Solution | MT 75.3 | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | CIPAC MT 3.1 | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | CIPAC MT 36.1 | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, traces of cream@bottom | Passed |
| Persistent Foaming | CIPAC MT 47.2 | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | MT75.3 | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | MT 192 | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | MT 192 | 0 to 2000cPs | n/a | |
| Long Term Performance | Various as per above | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | |||
| Description: | AWAITS FURTHER ANALYSIS |
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Trial # IC9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Kemmat HF60 as anionic surfactants against Termul 203
Ratio of Kemmat HF60 : Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Kemmat HF60: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4976.7 | 896 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 938.3 | 187 |
| Calcium Dodecylbenzene Sulphonate in 2ethylhexanol used: Kemmat HF60 (anionic surfactant) | 138.3 | 28 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 306.7 | 61 |
| Total | 6360.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 896g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, traces of cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | AWAITS FURTHER ANALYSIS |
Trial # ID9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Nansa EVM 70/2E as anionic surfactants against Termul 203
Ratio of Nansa EVM 70/2E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Nansa EVM 70/2E: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4971.7 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 920.0 | 184 |
| Calcium Dodecylbenzene Sulphonate in butanol used: Nansa EVM 70/2E (anionic surfactant) | 135.0 | 27 |
| Block Co-polymer | 309.2 | 62 |
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| used: Termul 203 (non-ionic surfactant) | ||
| Total | 6335.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 899g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, traces of cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | AWAITS FURTHER ANALYSIS |
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- 123 Trial # IE9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Rhodacal 70 as anionic surfactants against Termul 203
Ratio of Rhodacal 70: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Rhodacal 70: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4980.8 | 896 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 939.2 | 187 |
| Calcium Dodecylbenzene Sulphonate in butanol used: Rhodacal 70 (anionic surfactant) | 139.2 | 28 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 310.0 | 62 |
| Total | 6369.2 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 896g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, traces of cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | AWAITS FURTHER ANALYSIS |
Trial # IF9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Rhodacal 70B as anionic surfactants against Termul 203
Ratio of Rhodacal 70B: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Rhodacal 70B: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4981.7 | 897 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 933.3 | 186 |
| Calcium Dodecylbenzene Sulphonate in butanol used: Rhodacal 70B (anionic surfactant) | 132.5 | 26 |
| Block Co-polymer | 311.7 | 62 |
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| used: Termul 203 (non-ionic surfactant) | ||
| Total | 6359.2 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 897g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, traces of cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | AWAITS FURTHER ANALYSIS |
Trial # IG9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul TANS 5 as ionic surfactants against Termul 203 Ratio of Toximul TANS 5: Termul 203 (30:70) lonic/Non-ionic surfactant/ Solvent used: Toximul TANS 5: Termul 203: Diethylene Glycol monoethyl ether
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4968.3 | 897 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 933.3 | 186 |
| Alkylphenol ether sulfate/tallow amines ethoxylated used: Toximul TANS 5 (anionic surfactant) | 135.0 | 27 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 305.8 | 61 |
| Total | 6342.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 897g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 1ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | PASS |
| Description: | AWAITS FURTHER ANALYSIS |
Trial # IH9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul TANS 6 as ionic surfactants against Termul 203 Ratio of Toximul TANS 6: Termul 203 (30:70) lonic/Non-ionic surfactant/ Solvent used: Toximul TANS 6: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4965.0 | 896 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 930.0 | 185 |
| Alkylphenol ether sulfate/tallow amines ethoxylated used: Toximul TANS 6 (anionic surfactant) | 145.0 | 29 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 310.0 | 62 |
| Total | 6350.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 896g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a |
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| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.9ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | AWAITS FURTHER ANALYSIS |
Trial # 119
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul TANS 8 as ionic surfactants against Termul 203
Ratio of Toximul TANS 8: Termul 203 (30:70) lonic/Non-ionic surfactant/ Solvent used: Toximul TANS 8: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4980.0 | 901 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 916.7 | 183 |
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| Alkylphenol ether sulfate/tallow amines ethoxylated used: Toximul TANS 8 (anionic surfactant) | 130.8 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 303.3 | 61 |
| Total | 6330.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 901 g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, traces of cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | AWAITS FURTHER ANALYSIS |
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Trial # IJ9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul TAABS 5 as ionic surfactants against Termul 203
Ratio of Toximul TAABS 5: Termul 203 (30:70) lonic/Non-ionic surfactant/ Solvent used: Toximul TAABS 5: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 897 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 940.0 | 187 |
| branched alcohol ether sulfate/tallow amines ethoxylated used: Toximul TAABS 5 (anionic surfactant) | 130.0 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 309.2 | 62 |
| Total | 6349.2 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 897g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, traces of cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | AWAITS FURTHER ANALYSIS |
Trial # IK9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul TAABS 8 as ionic surfactants against Termul 203 Ratio of Toximul TAABS 8: Termul 203 (30:70) lonic/Non-ionic surfactant/ Solvent used: Toximul TAABS 8: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 933.3 | 186 |
| branched alcohol ether sulfate/tallow amines ethoxylated used: Toximul TAABS 8 (anionic surfactant) | 129.2 | 26 |
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| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 303.3 | 61 |
| Total | 6335.8 |
| RESULTS OF FORMULAT | ON | ||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1% aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
3472646vl
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APPENDIX 8
Trial # IA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4978.3 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 917.5 | 183 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 136.7 | 27 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 313.3 | 63 |
| Total | 6345.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 899g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.35 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.266 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.3ml cream@bottom | Passed |
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| Persistent Foaming | <60mL after 1 min | 25ml | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1212cps | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 315cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # IIA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Recosol 150
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4977.5 | 900 |
| Solvent used: Recosol 150 | 923.3 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 129.2 | 26 |
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| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 305.8 | 61 |
| Total | 6335.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
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Trial # III A9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Recosol 200
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 899 |
| Solvent used: Recosol 200 | 926.7 | 185 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 129.2 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 304.2 | 61 |
| Total | 6330.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # IVA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Xylene
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.3 | 900 |
| Solvent used: Xylene | 926.7 | 185 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 127.5 | 25 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 305.0 | 61 |
| Total | 6332.5 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial #VA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Toluene
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4978.3 | 901 |
| eg. Haloxyfop Tech (94% purity) |
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| Solvent used: Toluene | 922.5 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 128.3 | 26 |
| used: Ninate 60E (anionic surfactant) | ||
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 304.2 | 61 |
| Total | 6333.3 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml cream&oil@botto m | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # VIA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Acetone
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4974.2 | 900 |
| Solvent used: Acetone | 925.0 | 185 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 130.8 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 304.2 | 61 |
| Total | 6334.2 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a |
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| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 3ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # VIIA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Dimethyl adipate
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4975.0 | 900 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Dimethyl adipate | 924.2 | 185 |
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| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 127.5 | 25 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 308.3 | 62 |
| Total | 6335.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 3ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, formed lumps | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
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Trial # VIIIA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Dimethyl succinate
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4976.7 | 899 |
| Solvent used: Dimethyl succinate | 935.0 | 187 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 128.3 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 305.0 | 61 |
| Total | 6345.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, formed lumps | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial # IXA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: NMP
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4971.7 | 898 |
| Solvent used: NMP | 927.5 | 185 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 131.7 | 26 |
| Block Co-polymer | 310.0 | 62 |
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| used: Termul 203 (non-ionic surfactant) | ||
| Total | 6340.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, formed lumps | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS AND COLD STAB FAILED |
Trial #XA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: Ethylene glycol monobutyl ether
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifIuoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4971.7 | 899 |
| Solvent used: Ethylene glycol monobutyl ether | 923.3 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 130.0 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 313.3 | 63 |
| Total | 6338.3 |
| RESULTS OF FORMULAT | ON | ||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1% aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 2ml cream&oil@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a |
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| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial #XIA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: propylene glycol monomethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.3 | 900 |
| Solvent used: propylene glycol monomethyl ether | 922.5 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 131.7 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 305.0 | 61 |
| Total | 6332.5 |
RESULTS OF FORMULATION
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900g/L | n/a |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.2ml cream&oil@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASSED | ||
| Description: | AWAITS FURTHER ANALYSIS |
Trial # XIIA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: propylene glycol
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2- | 4970.8 | 900 |
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| pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: propylene glycol | 920.0 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 132.5 | 27 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 306.7 | 61 |
| Total | 6330.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | n/a | |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Yellow to brown solid | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE COLD STAB FAILED |
Trial # XIIIA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: diethylene glycol
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 900 |
| Solvent used: diethylene glycol | 920.8 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 130.0 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 305.0 | 61 |
| Total | 6325.8 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | n/a | |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Yellow to brown solid | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE COLD STAB FAILED |
Trial #XIVA9
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Trial using Termul 203 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Termul 203: dipropylene glycol
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- 152FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.5 | 900 |
| Solvent used: dipropylene glycol | 920.8 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 132.5 | 26 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 305.0 | 61 |
| Total | 6330.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | Milky white emulsion, no separation, 5ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, phase separation@top | Failed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTIC FAILED |
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APPENDIX 9
Trial # J1
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Decrease in surfactant loading to 80% from the original formulation with constant surfactant ratio
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E : Termul 203 : Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L | HLB |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.8 | 901 | |
| Solvent used: Diethylene Glycol Monoethyl Ether | 978.9 | 196 | |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 105.1 | 21 | 3.31 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 244.4 | 49 | 12.24 |
| Total | 6301.2 | 15.55 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 901 g/L | Passed |
| pH at 1%aq. Solution | 6 to 8 | 6.92 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.261 | Passed |
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| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, traces of cream@ bottom of cylinder | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | AWAITS FURTHER ANALYSIS |
Trial # J2
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Decrease in surfactant loading to 60% from the original formulation with constant surfactant ratio
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E : Termul 203 : Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L | HLB |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.6 | 900 | |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1063.1 | 213 | |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 78.8 | 16 | 3.30 |
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| used: Ninate 60E (anionic surfactant) | |||
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 183.6 | 37 | 12.24 |
| . Total | 6298.1 | 15.55 |
| RESULTS OF FORMULAT | ON | ||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900g/L | Passed |
| pH at 1% aq. Solution | 6 to 8 | 7.09 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.259 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, 1mi mixture of cream & oil @ bottom of cylinder | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
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Trial # J3
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Decrease in surfactant loading to 40% from the original formulation with constant surfactant ratio
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E : Termul 203 : Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L | HLB |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.5 | 900 | |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1157.3 | 231 | |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 52.1 | 10 | 3.29 |
| Block Co-polymer used: Termul 203 (non-ionic surfactant) | 122.2 | 24 | 12.27 |
| Total | 6305.1 | 15.56 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.26 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.261 | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 5ml mixture of cream&oil@bottom | Failed |
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| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER ANALYSIS BECAUSE EMULSION CHARACTERISTICS FAIL |
Trial # J3
HALOXYFOP 900 TRIALS
Haloxyfop active present at 900g/L
Trial details: Decrease in surfactant loading to 20% from the original formulation with constant surfactant ratio
Ratio of N60E: Termul 203 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E : Termul 203 : Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L | HLB |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.5 | 900 | |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1236.1 | 247 | |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 26 | 5 | 3.26 |
| 61.8 | 12 | 12.32 |
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| Block Co-polymer used: Termul 203 (non-ionic surfactant) | |||
| Total | 6296.4 | 15.58 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.32 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.259 | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4.5ml mixture of cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER ANALYSIS BECAUSE EMULSION CHARACTERISTICS FAIL |
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- 160APPENDIX 10
Trial# 4a
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Toximul 8320 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Toximul 8320: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.3 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 920.8 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 143.3 | 29 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 310.0 | 62 |
| Total | 6347.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.60 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.266 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.5ml cream@bottom | Passed |
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| Persistent Foaming | <60mL after 1 min | 6.0 mis | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format. | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1520 cps (LV3 @60rpm) | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 345 cps (LV2 @60rpm) | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | N/A | n/a |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # 4b
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N20 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4978.9 | 901 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 929.4 | 186 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 150.6 | 30 |
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| Nonyl Phenol Ethoxylates used: Teric N20 (non-ionic surfactant) | 309.4 | 62 |
| Total | 6368.3 |
| RESULTS OF FORMULAT | ON | ||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1% aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.0ml cream&oil@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
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Trial# 4c
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N30 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N30 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N30: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 5000.3 | 905 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 920.6 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 145.0 | 29 |
| Nonyl Phenol Ethoxylates used: Teric N30 (non-ionic surfactant) | 310.6 | 62 |
| Total | 6376.4 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3ml cream&oil@bottom | Failed |
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| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # 4d
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N13 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N13 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N13: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.1 | 899 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 931.1 | 186 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 149.6 | 30 |
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| Nonyl Phenol Ethoxylates used: Teric N13 (non-ionic surfactant) | 312.1 | 62 |
| Total | 6362.8 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1% aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2ml cream&oil@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
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Trial #4e
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N15 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N15 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N15: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4981.7 | 902 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 920.6 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 151.7 | 30 |
| Nonyl Phenol Ethoxylates used: Teric N15 (non-ionic surfactant) | 324.8 | 65 |
| Total | 6378.7 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 3ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # 4f
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N9 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N9 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N9: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4980.0 | 901 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 938.3 | 188 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 151.4 | 30 |
| Nonyl Phenol Ethoxylates | 330.4 | 66 |
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| used: Teric N9 (non-ionic surfactant) | ||
| Total | 6400.2 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 1.5ml cream&oil@bottom. | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
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HALOXYFOP 800 TRIAL
Haloxyfop active present at 800g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Toximul 8320 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Toximul 8320: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (95% purity) | 4433.2 | 802 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1371.0 | 274 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 127.0 | 25 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 320.0 | 64 |
| Total | 6251.2 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900g/L | Passed |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.270 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 1.0ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # 4h
HALOXYFOP 800 TRIAL
Haloxyfop active present at 800g/L
Trial details: Trial using Teric N30 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N30 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N30: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2- pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4420.0 | 800 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1419.0 | 284 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 127.5 | 26 |
| Nonyl Phenol Ethoxylates used: Teric N30 (non-ionic surfactant) | 303.0 | 61 |
| Total | 6269.5 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # 4i
HALOXYFOP 800 TRIAL
Haloxyfop active present at 800g/L
Trial details: Trial using Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N20 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N20: Diethylene Glycol monoethyl ether
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4432.0 | 802 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1313.0 | 263 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 126.0 | 25 |
| Nonyl Phenol Ethoxylates used: Teric N20 (non-ionic surfactant) | 304.4 | 61 |
| Total | 6175.4 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4.0ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a |
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| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # 4j
HALOXYFOP 800 TRIAL
Haloxyfop active present at 800g/L
Trial details: Trial using Teric N15 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N15 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N15: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4448.0 | 805 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1322.0 | 264 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 128.5 | 26 |
| Nonyl Phenol Ethoxylates used: Teric N15 (non-ionic surfactant) | 301.0 | 60 |
| Total | 6199.5 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # 4k
HALOXYFOP 800 TRIAL
Haloxyfop active present at 800g/L
Trial details: Trial using Teric N13 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N13 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N13: Diethylene Glycol monoethyl ether
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4448.0 | 805 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1322.0 | 264 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 128.5 | 26 |
| Nonyl Phenol Ethoxylates used: Teric N13 (non-ionic surfactant) | 301.2 | 60 |
| Total | 6199.7 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # 41
HALOXYFOP 800 TRIAL
Haloxyfop active present at 800g/L
Trial details: Trial using Teric N9 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N9 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N9: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4429.0 | 802 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1329.5 | 266 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 139.0 | 28 |
| Nonyl Phenol Ethoxylates used: Teric N9 (non-ionic surfactant) | 303.7 | 61 |
| Total | 6201.2 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1%aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2ml cream & trace of oil @ bottom | Pass |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Pass |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial# 4m
HALOXYFOP 700 TRIAL
Haloxyfop active present at 700g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Toximul 8320 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Toximul 8320: Diethylene Glycol monoethyl ether
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 3882.5 | 703 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1689.5 | 338 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 139.5 | 28 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 322.5 | 65 |
| Total | 6034.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.3ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | PASS |
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # 4n
HALOXYFOP 700 TRIAL
Haloxyfop active present at 700g/L
Trial details: Trial using Teric N30 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N30 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N30: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 3873.0 | 701 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1679.0 | 336 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 142.0 | 28 |
| Nonyl Phenol Ethoxylates used: Teric N30 (non-ionic surfactant) | 317.5 | 64 |
| Total | 6011.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a |
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| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, 4ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial #4o
HALOXYFOP 700 TRIAL
Haloxyfop active present at 700g/L
Trial details: Trial using Teric N20 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N20 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N20: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 3884.0 | 703 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Diethylene Glycol Monoethyl Ether | 1677.5 | 336 |
| 140.5 | 28 |
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| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | ||
| Nonyl Phenol Ethoxylates used: Teric N20 (non-ionic surfactant) | 320.0 | 64 |
| Total | 6022.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion,, 3.0ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
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HALOXYFOP 700 TRIAL
Haloxyfop active present at 700g/L
Trial details: Trial using Teric N15 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N15 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N15: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 3870.0 | 700 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1710.0 | 342 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 140.0 | 28 |
| Nonyl Phenol Ethoxylates used: Teric N15 (non-ionic surfactant) | 321.0 | 64 |
| Total | 6041.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion,, 3ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial #4q
HALOXYFOP 700 TRIAL
Haloxyfop active present at 700g/L
Trial details: Trial using Teric N13 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N13 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N13: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 3873.0 | 701 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1673.0 | 335 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 136.0 | 27 |
| Nonyl Phenol Ethoxylates | 338.0 | 68 |
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| used: Teric N13 (non-ionic surfactant) | ||
| Total | 6020.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, 2.5ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # 4r
HALOXYFOP 700 TRIAL
Haloxyfop active present at 700g/L
Trial details: Trial using Teric N9 as non-ionic surfactants against Ninate 60E
Ratio of N60E: Teric N9 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Ninate 60E: Teric N9: Diethylene Glycol monoethyl ether
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 3877.0 | 702 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 1670.0 | 334 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 140.0 | 28 |
| Nonyl Phenol Ethoxylates used: Teric N9 (non-ionic surfactant) | 332.5 | 67 |
| Total | 6019.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, 2.5ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a |
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| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
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APPENDIX 11
Trial# 4s
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Kemmat HF60
Ratio of Kemmat HF60: Toximul 8320 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Kemmat HF 60: Toximul 8320: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4975.1 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 876.1 | 175 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Kemmat HF 60 (anionic surfactant) | 130.8 | 26 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 334.7 | 67 |
| Total | 6316.7 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.15 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.263 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.3ml cream@bottom | Passed |
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| Persistent Foaming | <60mL after 1 min | 10 mis | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1760 cps | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 465 cps | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # 4t
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Nanssa 70 EVM
Ratio of Nansa 70 EVM: Toximul 8320 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Nansa 70 EVM: Toximul 8320: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.3 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 880.6 | 176 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Nansa 70 EVM (anionic surfactant) | 131.4 | 26 |
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| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 340.9 | 68 |
| Total | 6326.1 | 900 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900 | n/a |
| pH at 1 % aq. Solution | 6 to 8 | 7.55 | n/a |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.265 | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 0.3ml cream&oil@bottom | Pass |
| Persistent Foaming | <60mL after 1 min | 8 mis | n/a |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1640 cps | n/a |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 440 cps | n/a |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial #4u
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Rhodacal 70
Ratio of Rhodacal 70: Toximul 8320 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Rhodacal 70: Toximul 8320: Diethylene Glycol monoethyl ether
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- 190FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4974.0 | 900 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 907.0 | 181 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Rhodacal 70 (anionic surfactant) | 139.5 | 28 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 320.0 | 64 |
| Total | 6340.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3.0ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a |
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| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial #4v
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Rhodacal 70B Ratio of Rhodacal 70B: Toximul 8320 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Rhodacal 70B: Toximul 8320: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4983.5 | 902 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 837.5 | 168 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Rhodacal 70B (anionic surfactant) | 162.5 | 33 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 320.0 | 64 |
| Total | 6303.5 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial#4w
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N13 as non-ionic surfactants against Kemmat HF 60
Ratio of Kemmat HF 60: Teric N9 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Kemmat HF60: Teric N9: Diethylene Glycol monoethyl ether
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4977.0 | 901 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 894.0 | 179 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Kemmat HF 60 (anionic surfactant) | 132.5 | 27 |
| Nonyl Phenol Ethoxylates used: Teric N9 (non-ionic surfactant) | 321.0 | 64 |
| Total | 6324.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1 % aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.5ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial #4x
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N9 as non-ionic surfactants against Nansa 70 EVM
Ratio of N60E: Teric N9 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Nanasa 70 EVM : Teric N9: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4977.0 | 901 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 910.5 | 182 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Nansa 70 EVM (anionic surfactant) | 146.5 | 29 |
| Nonyl Phenol Ethoxylates used: Teric N9 (non-ionic surfactant) | 313.0 | 63 |
| Total | 6347.0 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1% aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.0ml cream&oil@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial #4y
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N9 as non-ionic surfactants against Rhodacal 70
Ratio of N60E: Teric N9 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Rhodacal 70: Teric N9: Diethylene Glycol monoethyl ether
FORMULATION
3472646vl
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| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4983.5 | 902 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 902.0 | 180 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Rhodacal 70 (anionic surfactant) | 136.0 | 27 |
| Nonyl Phenol Ethoxylates used: Teric N9 (non-ionic surfactant) | 307.0 | 61 |
| Total | 6328.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1% aq. Solution | 6 to 8 | n/a | |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.0ml cream&oil@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a |
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| General Remarks PASS or FAIL? | PASS |
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial #4z
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Teric N9 as non-ionic surfactants against Rhodacal 70B Ratio of N60E: Teric N9 (30:70)
Anionic/Non-ionic surfactant/ Solvent used: Rhodacal 70B: Teric N9: Diethylene Glycol monoethyl ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4976.5 | 901 |
| Solvent used: Diethylene Glycol Monoethyl Ether | 907.0 | 181 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Rhodacal 70B (anionic surfactant) | 142.0 | 28 |
| Nonyl Phenol Ethoxylates used: Teric N9 (non-ionic surfactant) | 313.0 | 63 |
| Total | 6338.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | orange liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | n/a | |
| pH at 1% aq. Solution | 6 to 8 | n/a |
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| Specific gravity (temperature at 20C) | 1.25 to 1.27 | n/a | |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.0ml cream&oil@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | n/a | |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | n/a | |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | n/a | |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
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APPENDIX 12
Trial #4ae
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Recosol 200
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4972.5 | 900 |
| Solvent used: Recosol 200 | 920.0 | 184 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 135.5 | 27 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 302.5 | 61 |
| Total | 6330.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | - | n/a |
| pH at 1 % aq. Solution | 6 to 8 | - | n/a |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | - | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 3.0ml cream&oil@bottom | Failed |
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| Persistent Foaming | <60mL after 1 min | - | n/a |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | - | n/a |
| Viscosity (temperature at 20C) | 0 to 2000cPs | - | n/a |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial # 4af
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Butyl Glysolv
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4974.0 | 900 |
| Solvent used: Butyl Glysolv | 831.5 | 166 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 134.5 | 27 |
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| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 321.5 | 64 |
| Total | 6261.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 900 g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.30 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.252 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, Traces of cream at the bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 14 mis of foam after 1 min. | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1140cPs | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 300cPs | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial #4ag
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Recosol 150
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FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4974.0 | 900 |
| Solvent used: Recosol 150 | 815.0 | 163 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 140.0 | 28 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 309.5 | 62 |
| Total | 6238.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | - | n/a |
| pH at 1 % aq. Solution | 6 to 8 | - | n/a |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | - | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.0ml cream&oil@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | - | n/a |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | - | n/a |
| Viscosity (temperature at 20C) | 0 to 2000cPs | - | n/a |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial #4ah
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Ethylene Glycol Monobutyl Ether
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4976.5 | 901 |
| Solvent used: Ethylene Glycol Monobutyl Ether | 850.0 | 170 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 129.0 | 26 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 299.0 | 60 |
| Total | 6254.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 901 g/L | Passed |
| pH at 1 % aq. Solution | 6 to 8 | 7.13 | Passed |
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| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.251 | Passed |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, Traces of cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 18mls of foam after 1 min. | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 1120 cPs | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 310 cPs | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # 4ai
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Dimethyl Succinate
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4982.5 | 902 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Dimethyl Succinate | 992.0 | 198 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol | 134.0 | 27 |
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| used: Ninate 60E (anionic surfactant) | ||
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 312.0 | 62 |
| Total | 6420.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Formulation is not stable | - |
| Assay | 875 to 925g/L Haloxyfop | - | n/a |
| pH at 1 % aq. Solution | 6 to 8 | - | n/a |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | - | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | - | n/a |
| Persistent Foaming | <60mL after 1 min | - | n/a |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | - | n/a |
| Viscosity (temperature at 5C) | 0 to 2000cPs | - | n/a |
| Viscosity (temperature at 20C) | 0 to 2000cPs | - | n/a |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE FORMULATION IS NOT STABLE |
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Trial # 4aj
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Toluene
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 899 |
| Solvent used: Toluene | 816.5 | 163 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 130.5 | 26 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 304.5 | 61 |
| Total | 6221.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 899 g/L | Passed |
| pH at 1%aq. Solution | 6 to 8 | 7.69 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.244 | - |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 1.0ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 12 mis of foam | Passed |
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| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 690 cPs | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 135 cPs | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial #4ak
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Acetone
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4970.0 | 899 |
| Solvent used: Acetone | 730.0 | 146 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 143.0 | 29 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 318.5 | 64 |
| Total | 6161.5 |
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| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | 899 g/L | Passed |
| pH at 1%aq. Solution | 6 to 8 | 7.69 | Passed |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | 1.232 | - |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 0.2ml cream@bottom | Passed |
| Persistent Foaming | <60mL after 1 min | 12mlsoffoam | Passed |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | 260 cPs | Passed |
| Viscosity (temperature at 20C) | 0 to 2000cPs | 73 cPs | Passed |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | PASS | ||
| Description: | SOLUTION MEETS ALL CRITERIA |
Trial # 4al
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Dimethyl Adipate
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4973.0 | 900 |
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| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: Dimethyl Adipate | 933.5 | 187 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 144.5 | 29 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 309.5 | 62 |
| Total | 6360.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Formulation is not stable | - |
| Assay | 875 to 925g/L Haloxyfop | - | n/a |
| pH at 1 % aq. Solution | 6 to 8 | - | n/a |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | - | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | - | n/a |
| Persistent Foaming | <60mL after 1 min | - | n/a |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | - | n/a |
| Viscosity (temperature at 5C) | 0 to 2000cPs | n/a | |
| Viscosity (temperature at 20C) | 0 to 2000cPs | - | n/a |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
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| General Remarks PASS or FAIL? | FAIL |
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE FORMULATION IS NOT STABLE |
Trial#4am
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: Xylene
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4975.0 | 900 |
| Solvent used: Xylene | 795.0 | 159 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 128.5 | 26 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 313.0 | 63 |
| Total | 6211.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | - | n/a |
| pH at 1 % aq. Solution | 6 to 8 | - | n/a |
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| Specific gravity (temperature at 20C) | 1.25 to 1.27 | - | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.5ml cream | Failed |
| Persistent Foaming | <60mL after 1 min | - | n/a |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | - | n/a |
| Viscosity (temperature at 20C) | 0 to 2000cPs | - | n/a |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
Trial #4an
HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E Ratio of Ninate 60E: Toximul 8320 (30:70)
Solvent: N-methylpyrrolidone
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate | 4971.0 | 900 |
| eg. Haloxyfop Tech (94% purity) | ||
| Solvent used: N-methylpyrrolidone | 924.5 | 185 |
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| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 140.0 | 28 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 306.5 | 61 |
| Total | 6342.0 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | - | n/a |
| pH at 1 % aq. Solution | 6 to 8 | - | n/a |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | - | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete reemulsion after 24h | milky emulsion, no separation, 2.5ml cream@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | - | n/a |
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | - | n/a |
| Viscosity (temperature at 20C) | 0 to 2000cPs | - | n/a |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
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HALOXYFOP 900 TRIAL
Haloxyfop active present at 900g/L
Trial details: Trial using Toximul 8320 as non-ionic surfactants against Ninate 60E
Ratioof Ninate 60E: Toximul 8320 (30:70)
Solvent: Exxate 700
FORMULATION
| Component (Chemical name) | Amount, g | Loading, g/L |
| methyl (R) -2-[4-(3-chloro-5-trifluoromethyl-2pyridyloxy)phenoxy]propanoate eg. Haloxyfop Tech (94% purity) | 4973.0 | 900 |
| Solvent used: Exxate 700 | 812.5 | 163 |
| Calcium C10-16 alkyl benzenesulfonic acid in 2-ethyl hexanol used: Ninate 60E (anionic surfactant) | 126.5 | 25 |
| Block Co-polymer used: Toximul 8320 (non-ionic surfactant) | 301.5 | 60 |
| Total | 6213.5 |
| RESULTS OF FORMULATION | |||
| Parameter | Required | Results | Remarks |
| Appearance | Red to brown liquid, homogeneous | Brown liquid, homogeneous | Passed |
| Assay | 875 to 925g/L Haloxyfop | - | n/a |
| pH at 1 % aq. Solution | 6 to 8 | - | n/a |
| Specific gravity (temperature at 20C) | 1.25 to 1.27 | - | n/a |
| Emulsion characteristics | <2mL cream after 30 min, trace of oil after 30 min and complete re-emulsion after 24h | milky emulsion, no separation, 2.5ml cream@bottom | Failed |
| Persistent Foaming | <60mL after 1 min | - | n/a |
11/06/14,jb20952 cap specification.docx,214
-2142014203147 11 Jun2014
| Cold temp, stability (Accelerated Ageing) | Dark yellow to brown liquid, homogeneous, free from phase separation in any format | Brown liquid, homogeneous, free from phase separation in any format | Passed |
| Viscosity (temperature at 5C) | 0 to 2000cPs | - | n/a |
| Viscosity (temperature at 20C) | 0 to 2000cPs | - | n/a |
| Long Term Performance | Test parameter maintained within required range after accelerated aging to approximate 2 years. | - | n/a |
| General Remarks PASS or FAIL? | FAIL | ||
| Description: | DID NOT CONTINUE ANY FURTHER TESTING BECAUSE EMULSION CHARACTERISTICS FAILED |
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Claims (23)
1. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of at least 825 g/L; an agriculturally acceptable surfactant selected from the group consisting of an alkylbenzene sulfonate, a tallow amine ethoxylate, an ether sulfate, an alcohol alkoxylate, a nonylphenol-9-ethylene oxide, a nonylphenol-20-ethylene oxide, a butyl alkylene oxide block copolymer and any combination thereof; and an agriculturally acceptable solvent comprising a monoalkyl ether.
2. The emulsifiable concentrate formulation of Claim 1, wherein the agriculturally acceptable surfactant is present at a concentration of at least about 45 g/L.
3. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of at least about 825 g/L; an agriculturally acceptable ionic surfactant;
an agriculturally acceptable non-ionic surfactant selected from the group consisting of an alcohol alkoxylate, a nonylphenol-9-ethylene oxide, a nonylphenol20-ethylene oxide, a butyl alkylene oxide block copolymer and any combination thereof; and an agriculturally acceptable solvent comprising a monoalkyl ether.
4. The emulsifiable concentrate formulation of Claim 3, wherein the ionic surfactant is selected from the group consisting of an alkylbenzene sulfonate, an alkylphenol ether sulfate, a tallow amine ethoxylate, an ether sulfate and any combination thereof.
5. The emulsifiable concentrate fonnulation of Claim 3 or Claim 4, wherein the ionic surfactant is present at a concentration of at least about 9 g/L.
6. The emulsifiable concentrate formulation of Claim 5, wherein the ionic surfactant is present at a concentration of at least about 12.5 g/L.
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7. The emulsifiable concentrate formulation of any one of Claims 3 to 6, wherein the non-ionic surfactant is present at a concentration of at least about 36 g/L.
8. The emulsifiable concentrate formulation of Claim 7, wherein the non-ionic surfactant is present at a concentration of at least about 57.5 g/L.
9. The emulsifiable concentrate formulation of any one of Claims 3 to 8, wherein the ionic surfactant is or comprises an anionic surfactant.
10. The emulsifiable concentrate formulation of any one of the preceding claims, wherein the alcohol alkoxylate is or comprises polypropylene glycol alkoxylate.
11. The emulsifiable concentrate formulation of any one of the preceding claims, wherein the solvent is or comprises a monomethyl ether, a monoethyl ether, a monobutyl ether or any combination thereof.
12. The emulsifiable concentrate formulation of any one of the preceding claims, wherein the solvent is present at a concentration of at least about 180 g/L.
13. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of at least about 650 g/L; a first agriculturally acceptable surfactant comprising an ionic surfactant; a second agriculturally acceptable surfactant selected from the group consisting of:
an alcohol alkoxylate; and a butyl alkylene oxide block copolymer; and an agriculturally acceptable solvent present at a concentration of at least about 187 g/L, wherein the solvent is or comprises a pyrrolidone.
14. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of at least about 650 g/L; a first agriculturally acceptable surfactant comprising an ionic surfactant; a second agriculturally acceptable surfactant comprising a butyl alkylene oxide block copolymer; and
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2014203147 29 Jan 2018 an agriculturally acceptable solvent selected from the group consisting of an alkyl ether, a mono-substituted benzene, a ketone and any combination thereof.
15. The emulsifiable concentrate formulation of Claim 13 or Claim 14, wherein the first agriculturally acceptable surfactant is present at a concentration of at least about 12.5 g/L.
16. The emulsifiable concentrate formulation of any one of Claims 13 to 15, wherein the second agriculturally acceptable surfactant is present at a concentration of at least about 57.5 g/L.
17. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of at least about 850 g/L; an agriculturally acceptable ionic surfactant;
an agriculturally acceptable non-ionic surfactant selected from the group consisting of:
a nonylphenol-13-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is at least about 0.3:1;
a nonylphenol-15-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is less than about 0.15:1; and an agriculturally acceptable solvent comprising a monoalkyl ether.
18. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of about 750 g/L to about
850 g/L;
an agriculturally acceptable ionic surfactant;
an agriculturally acceptable non-ionic surfactant selected from the group consisting of:
a butyl alkylene oxide block copolymer;
a nonylphenol-20-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is less than about 0.15:1;
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2014203147 29 Jan 2018 a nonylphenol-30-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is less than about 0.26:1; and a nonylphenol-15-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is at least about 0.4:1; and an agriculturally acceptable solvent comprising a monoalkyl ether.
19. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of about 650 g/L to about
750 g/L;
an agriculturally acceptable ionic surfactant;
an agriculturally acceptable non-ionic surfactant selected from the group consisting of:
a butyl alkylene oxide block copolymer;
a nonylphenol-20-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is less than about 0.26:1;
a nonylphenol-13-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is less than about 0.26:1;
a nonylphenol-15-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is at least about 0.4:1; and a nonylphenol-9-ethylene oxide present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is less than about 0.26:1; and an agriculturally acceptable solvent comprising a monoalkyl ether.
20. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of at least about 850 g/L; an agriculturally acceptable ionic surfactant;
an agriculturally acceptable non-ionic surfactant comprising a butyl alkylene oxide block copolymer, wherein the non-ionic surfactant is present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is at least about 0.4:1; and an agriculturally acceptable solvent comprising xylene.
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21. An emulsifiable concentrate formulation comprising:
haloxyfop or a derivative thereof at a concentration of at least about 850 g/L; an agriculturally acceptable ionic surfactant;
an agriculturally acceptable non-ionic surfactant comprising a butyl alkylene oxide block copolymer, wherein the non-ionic surfactant is present at a concentration such that the ratio of the ionic surfactant to the non-ionic surfactant is less than about 0.15:1;
an agriculturally acceptable solvent comprising a pyrrolidone.
22. The emulsifiable concentrate formulation of any one of Claims 13 to 21, wherein the ionic surfactant is or comprises an alkylbenzene sulfonate.
23. A method of selectively killing or suppressing weeds such as barley grass, brome grass, paradoxa grass, volunteer cereals, wild oats, musky or ferny leaf Storksbill, common crowsfoot, common storksbill, long or shiny leaf storksbill, couch grass, Rhodes grass, Australian millet, barnyard grass, green panic, Johnson grass, liverseed grass, Mossman river grass, summer grass, slender rats tail grass, Buffel grass, kikuyu, paspalum spp, starai spp, annual ryegrass, lesser canary grass, Rope twitch, Erodium spp which comprises adding an emulsifiable concentrate fonnulation as claimed in any one of claims 1 to 22 to an amount of spray water in a spray tank sufficient to make up a diluted liquor of generally accepted strength and spraying the resultant diluted liquor onto weeds or ground.
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| Application Number | Priority Date | Filing Date | Title |
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| AU2014203147A AU2014203147B2 (en) | 2013-06-28 | 2014-06-11 | High level haloxyfop emulsifiable concentrate formulation |
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| AU2013902397 | 2013-06-28 | ||
| AU2013902397A AU2013902397A0 (en) | 2013-06-28 | High level haloxyfop emulsifiable concentrate formulation | |
| AU2014203147A AU2014203147B2 (en) | 2013-06-28 | 2014-06-11 | High level haloxyfop emulsifiable concentrate formulation |
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| US20230232829A1 (en) * | 2018-01-04 | 2023-07-27 | Dow Argo Sciences LLC | High-load haloxyfop ester compositions |
| AU2021107371B4 (en) * | 2021-08-25 | 2022-07-14 | Adama Australia Pty Limited | Highly Loaded Haloxyfop Formulations |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US6444618B1 (en) * | 1999-01-29 | 2002-09-03 | Basf Aktiengesellschaft | Crop protection emulsifiable concentrate containing defoaming agents |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US6444618B1 (en) * | 1999-01-29 | 2002-09-03 | Basf Aktiengesellschaft | Crop protection emulsifiable concentrate containing defoaming agents |
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