AU2013253096B2 - Ground cover material - Google Patents
Ground cover material Download PDFInfo
- Publication number
- AU2013253096B2 AU2013253096B2 AU2013253096A AU2013253096A AU2013253096B2 AU 2013253096 B2 AU2013253096 B2 AU 2013253096B2 AU 2013253096 A AU2013253096 A AU 2013253096A AU 2013253096 A AU2013253096 A AU 2013253096A AU 2013253096 B2 AU2013253096 B2 AU 2013253096B2
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- Australia
- Prior art keywords
- regions
- tapes
- ground cover
- sheet material
- cover sheet
- Prior art date
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- 239000000463 material Substances 0.000 title claims abstract description 194
- 150000001875 compounds Chemical class 0.000 claims description 26
- 230000005855 radiation Effects 0.000 claims description 24
- 229920000642 polymer Polymers 0.000 claims description 11
- 239000012463 white pigment Substances 0.000 claims description 11
- 238000010521 absorption reaction Methods 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 230000005540 biological transmission Effects 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 229920001222 biopolymer Polymers 0.000 claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- 230000003247 decreasing effect Effects 0.000 claims description 2
- 230000007704 transition Effects 0.000 claims description 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims 2
- 239000004744 fabric Substances 0.000 description 15
- 241000196324 Embryophyta Species 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 10
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 6
- 235000013399 edible fruits Nutrition 0.000 description 6
- 238000004804 winding Methods 0.000 description 6
- -1 zkcomte Chemical compound 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000002420 orchard Substances 0.000 description 4
- 238000009941 weaving Methods 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 210000000078 claw Anatomy 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- 229910021523 barium zirconate Inorganic materials 0.000 description 2
- DQBAOWPVHRWLJC-UHFFFAOYSA-N barium(2+);dioxido(oxo)zirconium Chemical compound [Ba+2].[O-][Zr]([O-])=O DQBAOWPVHRWLJC-UHFFFAOYSA-N 0.000 description 2
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 2
- QYMGIIIPAFAFRX-UHFFFAOYSA-N butyl prop-2-enoate;ethene Chemical compound C=C.CCCCOC(=O)C=C QYMGIIIPAFAFRX-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229920006245 ethylene-butyl acrylate Polymers 0.000 description 2
- 229920006225 ethylene-methyl acrylate Polymers 0.000 description 2
- 239000005043 ethylene-methyl acrylate Substances 0.000 description 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- 229910000018 strontium carbonate Inorganic materials 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 2
- FFQALBCXGPYQGT-UHFFFAOYSA-N 2,4-difluoro-5-(trifluoromethyl)aniline Chemical compound NC1=CC(C(F)(F)F)=C(F)C=C1F FFQALBCXGPYQGT-UHFFFAOYSA-N 0.000 description 1
- DJOYTAUERRJRAT-UHFFFAOYSA-N 2-(n-methyl-4-nitroanilino)acetonitrile Chemical compound N#CCN(C)C1=CC=C([N+]([O-])=O)C=C1 DJOYTAUERRJRAT-UHFFFAOYSA-N 0.000 description 1
- 240000008100 Brassica rapa Species 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 101100328463 Mus musculus Cmya5 gene Proteins 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 206010041235 Snoring Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 241001051525 Tortus Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000549 coloured material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- HGVPOWOAHALJHA-UHFFFAOYSA-N ethene;methyl prop-2-enoate Chemical compound C=C.COC(=O)C=C HGVPOWOAHALJHA-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000001038 titanium pigment Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D17/00—Excavations; Bordering of excavations; Making embankments
- E02D17/20—Securing of slopes or inclines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protection of plants
- A01G13/30—Ground coverings
- A01G13/32—Mats; Nets; Sheets or films
Landscapes
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Toxicology (AREA)
- Environmental Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Paleontology (AREA)
- Civil Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Structural Engineering (AREA)
- Woven Fabrics (AREA)
- Textile Engineering (AREA)
Abstract
A woven ground cover sheet material woven from warp and weft tapes and in which the thickness of warp tapes is increased in longitudinally extending opposite side margins of the material and in one or more centre regions relative to the thickness of warp tapes making up the balance of the material.
Description
- 1 - PCT/KZ2013/000074 Received 10/07/2014
GROUND COVER MATERIAL
FIELD OF INVENTION
The invention relates to woven materials and particularly but not exclusively to woven materials for use as ground covers or other agricultural applications.
BACKGROUND
Ground cover materials are used in agriculture for purposes including moisture retention, water conservation, weed or sward suppression, soil warmth retention, and for light reflecting.
Typically where the material is. used primarily as a reflective ground cover for light enhancement, the material is roiled, out in lengths onto the ground between tows of trees in an orchard, rows of vines in a vineyard, or rows of berry fruit plants for example, to increase the amount of light to which the plants and in particular fruit are exposed, by reflection of tight from the material towards the fruit above. Each length of the material needs to be suitably secured in place, such that it will not be dislodged during wind or movement of traffic over the materials. A fastening system including a multiple number of prong fastening components or “claws” may be fixed to thicker edges or side margins of the sheet material by pushing the prongs of the fastening components into the material so that prongs pierce and pass through the material in turn the prongs are fixed to adjacent trees, or alternatively stakes or pegs inserted for that purpose, typically but not necessarily by a length of elastic cord. The sheet material will typically remain in place for some months, before being removed and reused in a subsequent growing season or on another crop in the same growing season.
Referring to Figure 3a a roll of woven fabric material wound around a core/spool./cylinder 4 and ready for dispatch is shown. The fabric is made woven on. a loom from warp and weft tapes. If a circular loom is used, the fabric is first made into a tube, then slit at one side along the length of the tube to form a sheet, which is subsequently folded longitudinally in half and wound into a roll about the core 4. if a flat loom is used, the fabnc is woven direct!v into a sheet., and subsequently folded longitudinally in half and wound into a roil on the core 4. The sheet is lengthwise folded before rolling onto the core 4 to reduce the size of the roll for shipping and dispatch. AMENDED SHEET i PE A At: PCT/NZ2Q13/000074 Received 10/0 7/2 014
The warp tapes are the same thickness across the entire material, but are narrower at the side margins (which are both at region 3.1 after folding the material) than the remaining tapes in the warp direction. The roll thickness is hence even as there is no variation in the 5 tape thickness across the. warp tapes. The evenness of the warp tapes allows the warp tension to IS# controlled across the width of the fabric to assist in creating an even fabric.
Referring now to Figure 3b, a nail of improved material is shown having side: margins· 3.2 of increased thickness. In particular the warp tapes are thicker in die side margins* which 10 allows the point of fastening to have greater strength than the other portions of the fabric. The manufacturing process for this material is similar to that desenbed above. However thicker warp tapes at die side tnargins (which lav adjacent one another once the material is folded) creates a roll as in Figure 3b that is difficult to stack. Also the use of thicker warp tapes for the side margins during weaving creates uneven tension on the warp tapes in the 15 weaving machine which in turn generates difficult) in maintaining the overall evenness of the weaving process. Finally, the thicker edges/side margins 3.2, when folded onto each other make it difficult to roll up the length of material evenly (with a constant axis of rotation) which places undesirable stress on the material at the fold line after it has been rolled up. 20
In Figure 3b the tapes at the opposite end to the open end 3.2 are exposed to additional winding pressure as this .is where the fold is. This pressure, is experienced especially by the weft tapes which, are exposed to added winding tension as they are folded over themselves to change direction 1:80 degrees, 25
It is an object of the present invention to provide a sheet rnafeerial. that at least partially alleviates the. above-mentioned difficulty, or to at least provide the public with a useful choice.
30 SUMMARY OF INVENTION
In a first aspect the invention may broadly be said to consist of a ground cover sheet material woven from warp and weft tapes* wherein the material comprises regions of relatively thicker (hereinafter: thicker regions) warp tapes, and regions of relatively thinner (hereinafter: thinner regions) warp tapes* the thicker regions being at or adjacent one or
AMENDED SHEET IPEA/AU PCT/NZ2013/000074 Received 10/07/2014 both longitudinally extending opposite side margins of the material, and at two ox more longiaidmally extending centre regions spaced apart on either side ot a notional centre or fold line of the material and nearer ro the notional centre or fold line of the material than to the longitudinally extending opposite side margins of the material, and the thinner regions making up the balance of the sheet material.
Preferably the two or more longitudinal!', extending centre regions spaced apart on either side ot a .notional centre or fold line of the material are between 20 to 100 mm away from the notional centre or fold litre.
Preferably the sheet material comprises two side margifls on either side of the material of thicker warp tapes and two centre regions of thicker warp tapes spaced apart on either side of the notional centre or fold line of the material Alternatively the sheer material comprises a single centre region of thicker warp tapes adjacent the notional centre or fold line.
Inferably the warp tapes have a uniform thickness in the thicker regions and a uniform thickness in the thinner regions.
Preferably the warp tapes in the thicker regions are between about 5-300% thicker or more preferably between about 10 and about 200% thicker than the warp rapes in the thinner regions,, and even more preferably between about 200 and about!00% thicker.
Preferably the width of each of the thicker regions is up to about 500mm or more preferably up to about 300mm. Even more preferably each of the thicker regions is between about 20 and about 300mm wide and most preferably between about 40 and about 200mm wide. The width of the side margin may be different from the width of the centre regions on each side of the centre fold line. The centre regions may be between about 20 and about 200mm, or more preferably between about 30 and about 100mm, and most preferable between about 40 and about 80mm in width. While the side margins may be between about 20 and about. 300mm, more preferably between about 40 and about 200mm, and most preferable between about 60 and about 180mm in width.
Preferably the width of Warp tapes is also decreased in the thicker regions relative to the width of warp tapes in the thinner regions.
AMENDED SHEET IPEA/AU PCT/N22G13/000074 Received 10/07/2014
In some embodiments the warp tapes in die thicker regions have a width between about 1 and about 4 mm, more preferably between about 2 and about 3mm and the warp tapes in the thinner regions have a width between about 2 and about 6mm, more preferably between about 3 and about 5mm,
In' some embodiments the thicker regions have a lower porosity than the thinner regions.
In some embodiments the transition between an inner edge or the inner portion of cadi side margin and a thinner region of rite material is marked by a line or other marking of contrasting colour.
In some embodiments the colour of ai least some of the warp tapes in the thicker regions contrasts to that of the balance of the sheet material.
Preferably the warp and weft tapes are of a plastics material.
Preferably the ground colter material is woven from warp tapes and weft tapes which are substantially flat.
Preferably the tapes that the material is woven from ate not folded on themselves, so they are placed or inserted into the fabric so there .is. no placement density to cause folding of the tapes.
In some embodiments the material is made of coloured materials to aw a coloured fabric V-'· including white, green, black and other colours and even dear with no apparent colour.
In some embodiments the material is reflective of at least about 50% of visible light on at least one side of the material hi some embodiments some or all tapes of a reflective material are formed itom a resin comprising a white pigment, which resin has been formed by mixing a masterbateh consisting essentially of between about 5 and about 90% bv weight of a white pigment or combination of pigments, and a first polymer, with a second polymer such that the resin
AMENDED SHEET JPEA/AU PCT/NZ2013/000074 Received 10/07/2014 (iHasterbafcb) comprising the white pigment comprises between about 0,5 and about 50% by weigh t, of the total mixture.
Preferably the white pigment is selected from zirconium, dioxide, magnesium, zkcomte, calcium zirconate, strontium zero oak-, barium zirconate, zirconium silicate., zinc oxide, zinc sulphide, calcium carbonate, barium sulphate, magnesium oxide, titanium dioxide, strontium carbonate, barium carbonate, and potassium iitamae.
In some embodiments the material incorporates a compound or compounds added to cause or increase the extent to which the material reflects and/or absorption of radiation from the earth (terrestrial (long wave or infrared) radiation).
In some embodiments the material incorporates a compound or compounds added to cause or increase the extent to which the material allows transmission and/or absorption ol radiation from the earth (terrestrial {long wave or infrared) radiation).
In some embodiments the material incorporates a compound or compounds added to cause or increase the extent to which the material reflects and/or absorbs solar radiation.
In some embodiments the material incorporates a compound or compounds added to cause or increase the extent to which the material allows transmissioti and/or absorption of solar radiation.
Prefera bly the warp and weft tapes arc formed from polyolefin, or an, ethylene alpha-olefin, or a polyester, or a biopolymer, or a blend, of any of the foregoing.
Typically sheet materials of the invention will be laid out in lengths on the ground; between sows of the crop being grown, which may be trees, vines, bushes etc, to increase the amount of light to which the plants and in particular the fruit ate exposed, by reflection of the light from the material hack up towards the crop above. At she end of a growing season, each length of material is rolled up for storage. The thicket warp tape regions as defined above enable the length of material to roll evenly after use, lire particular weight distribution achieved by employing the thicker regions allows the material to maintain alignment as it is rolled-up for storage.
AMENDED SHEET iPEA/AU PCT/N22G13/000074 Received 10/07/2014 - 6 -
At the time of manufacturing the combination of thicker side margin warp tapes and the thicker warp tapes at the centre region(s) in the even winding up of the roll by ensuring (or supporting) the wind up tension to he more even across all warp tapes. In addition the thicker warp tapes at the centre region(s) redu.ee(s) the roll up tension on the tapes around the fold line, 'lire latter being especially the ease for the weft tapes that are folded at the centre line during manufacture.
The tortus “thicker” and ‘‘thinner·7 as used in this specification and claims are relative terms and not intended to be limited to an absolute value or range of thicknesses unless otherwise specified.
The term “comprising” as used in. this specification and claims means ‘‘consisting at least in parr of”. When interpreting each statement in this specification and claims that includes the term “comprising”, features other than that or those prefaced by the term may also be present. Related terms such as “comprise” and “comprises” are to he interpreted in the same manner.
If is intended that reference to a range of numbers disclosed, herein, (for example, t to 10) also incorporates reference to all rational numbers' within, that range (for example, 1, 1.1, 2, 3, 3.9, 4, 5, 6, 6.5, 7, 8, 9 and 10} and also any range, of rational numbers within that range (for example 2 to 8, 1.5 to 5,5 and. 3,1 to 4.7) and., therefore, all sub-ranges of ail ranges expressly disclosed herein are hereby expressly disclosed. These ate only examples of what is specifically intended and all possible combinations of numerical values between the lowest value and the highest value enumerated are to be considered to be expressly stated in this application in a similar manner.
The invention consists in the foregoing and also envisages constructions of which the following gives examples only.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention is further described by way of example with reference to the accompanying drawings in which:
AMENDED SHEET IPEA/AU PCT/NZ2013/000074 Received 10/0 7/:2014 .l%ute 1 shows use of a ground ewer material of the invention between, two rows of orchard trees;
Figure 2 shows use of a ground cover material and fixing of the ground cover material in place by the use of a. claw and cord system, including a fastening component that penetrates the side margins of the material;
Figure 3a shows a possible completed roll of fabric after being rolled but with no. thicket side margin or warp tapes on either side of the fold or centre line.
Figure 3b shows a possible completed roll of another version of a woven ground cover material with thicker side margin tapes during manufacture;
Figure 3c shows a possible complete roll of a woven ground cov er material during manufacture in accordance with a preferred embodiment of the invention with thicker side margin and centre region warp tapes;
Figure 4a is an enlarged view of a. warp rape at the thinner regions of the preferred form ground cover material;
Figure 4b is an enlarged view of a warp tape at the thicker regions of the preferred form ground cover material;
Figure 5 shows a close up view of a section of the woven material of I igure 1 at a centre region;
Figure 6 shows % dose up view of two centre regions of the \voven material of Figure 1; and
Figure 7 shows a close up view at a side margin of the woven material, of Figure 1.
DETAILED DESCRIPTION
Referring to Figure 1, agricultural sheeting 1 is shown in use anchored underneath agricultural crops such as rows of orchard trees 1.2 as a ground cover, which typically has
AMENDED SHEET IPEA/A.U PCT/NZ2013/000074 '' Received )0/07/2014 reflective properties to reflect solar radiation onto the fruit trees and fruit from below. Typically long sections of the sheet material are. anchored along both edges between rows of orchard trees or vines. The material is woven from flat warp and weft tapes of a plastics material Referring also to Figure. 2, in use fastening claws 13 connect to the. sheeting along its edges, and in turn may connect: 8g clips usually by loops or lengths of extensible or optionally inextenslble material, 'Hie clips may in turn attasih to staples hammered into the Spaced trees 12 as shown, or alternatively to stakes or pegs hammered into the ground, or to a wire extending, along the row or the trees or vinesy or to twine tied around the tree trunk or vine , tor example.
The sheet material comprises regions of relatively thicker warp rapes 11 and regions of relatively thinner warp tapes (balance of material). The regions: of thicter warp tapes 11 (thicker regions) ate, at one or both side margins and at least: one wen lie region adjacent to a notional centre or fold line 30 of the material. The regions of thinner warp tapes (thinner regions) make up the balance: of the shcei material. In. the preferred embodiment, there are thicker warp tapes at both side margins and there are two spaced centre regions of thicker warp tapes as shown in Figure 1, however, the invention is not. intended to be limited to this embodiment In alternative embodiments there may be more than two or only one centre region of thicker warp tapes and/or only one or two side marginfe) with thicker tapes. The line 30 is preferably along the centre of the material but it will be appreciated that in alternative embodiments, the fold line 30 may not necessarily be exactly at the centre of she material.
Referring to Figure 3c, during manufacture, a length of material 3 is woven, then folded and rolled about a spool 4 to form a sheet of material 1 ready for dispatch. As discussed, a flat sheet, o-f material may he first formed directly from a flat loom, or from a. circular loom then, slit on one side, before being flattened/folded and rolled about the spool 4, The material .3 is woven with thicker warp regions at at least one side margin 28 and at least one centre region 29. 'The fabric or material in Figure 3c is folded (or flattencd/closed. in the ease of a slit tube made from a circular loom) in half prior to being rolled so that the two side margins are on one end of the roll 28 and the other end 29 has the folded section with the one or more centre regions of thicker warp tapes. Onlv half of the width of the material 3 is visible in Figure 3c as the other is folded underneath the first layer, so region 29 is near or adjacent the centre of the material 3. In the preferred embodiment, the other half of die AMENDED SHEET ! PEA/At PCT/N22Q13/000074 Received 10/0 7/2014 material 3 (nor visible m it is folded underneath) is a mirror image of the halt shown in Figure 3c. Once woven (and cut on one side of the rube info a folded sheet in the ease of a circular loom), the sheet can be folded longitudinally at its centre and then rolled up about a spool 4 for efficient dispatch of the material to an end. user. By employing one or more thicker warp tape regions 29 at the centre of the sheet 1, the material can be rolled up more evenly to maintain a snore even tension across the: entire warp during the manufacturing process than if the thicker warp tapes were only on the side tnargln (s), it will be appreciated, that during manufacture, the material 3 may be rolled about the core or spool. 4 any number of times depending on the desired length of the material, but in the preferred embodiment the material is woven around the spool 4 to .form a cylinder or roll and then when unwound it can be cut along the length of the roll or cylinder to then form one or more sheets 1 (one of which is shown in Figure 1) as desired by the end user.
Referring to Figure· 7,. a side portion of a sheet, of material 1 woven from warp (25a-c) and well (25d) tapes is shown. The warp tapes 25a towards the side edge 27a (the. cut and seal edge on one side of the fabric) of the sheet material have an increased thickness compared to the warp tapes 25b at the thinner regions. Figure 7 shows, one side margin 28a of thicker warp tapes 25a, The thickness of the warp tapes is mirrored in the opposite side margin (nor shown) of the sheet material. The two opposing side margins make up two of the thicker regions of the sheet material that when folded and rolled are on the same side of the fabric in die roll.
Referring now also to Figures 5 and 6, the warp tapes 25a in two centre regions 20a/b are also thicker than warp tapes 25b at the thinner regions making up the balance of the sheet material The two longitudinally' extending opposed centre regions 29a/b arc spaced apart and located on either side of a notional longitudinal centre or fold line 30 of the sheet, .material 'The regions 29a and 29b are preferably equally separated from either side of the centre line 30, They !if placed between 20 to 1.00 mm away from the. centre or fold, line. Weft tapes 25d are; common./stmslar for the entire material or fabric. .Referring' paw also to Figures 4a and 4b, typically the warp tapes 25a in the thicker regions 28/29 of the material have a. thickness, T2, that is 5 to 300% or more: preferably ill to 200% or most preferably 20 to 100'% more than the thickness, 11, of die warp tapes 25b at the thinner regions. Most preferably the thicker regions 28a, 28b and 29a, 29b comprise
AMENDED SHEET iPEA/AU PCT/NZ2013/000074 Received 10/07/2014 wasp rapes 25a that are 30 to 50% thicket than the warp tapes 25b of the thinner regions. Preferably the warp rapes have a uniform thickness, T2, in the thicker regions and a uniform thickness, T1, in the thinner regions. 5 in one embodiment, the width \v* as m Figure 7 of each of the thicker regions across the longitudinal axis of the region may be anywhere up to 500mm wide or mote preferably 300mm.Tbe width V’ may be anywhere between 20 to 300mm wide or more preferably between 40 to 2(l)tnm wide. The width of the side margin may be different from the width of the centre regions |f| each side of the centre fold line. The centre regions may be 20 to 10 200mm, or more preferably 30 to HJOmm, and most preferably 40 to 80mm in width.
While the side margins may be 20 to 300mm, more preferably 40 to 200mm, and most preferable 60 to 180mm in width. In the most preferred embodiment, each of the thicker regions is 160 mm wide for the side margins 28a/b and 50 mm wide: for the centre regions 20a/h. The width in the preferred embodiments is larger at the side margins 28a:/l> than .1..5 at file centre regions 29a/b, however in alternative embodiments, the width V may he uniform across all thicker regions 28/29 or different for each region or even wider at the centre region than the side margins.
The thickness T2, of the side margins 28a/b (28b is hot shown but is the other side 20 margin of the fabric of Figure 7) strengthen the side margins of the material, due to the thicker side warp tapes, so that when the sheet is fixed in place using a fixing system 13 (including fastening components in which prongs or similar pierce through the side margins of the material), the increased strength of the material provides, more a secure coupling, with reduced risk of tearing or enlargement of the holes formed from prongs: 25 piercing through the material. In the preferred embodiment, an indication means is provided to enable a user to easily identify the stronger region 28a/b of the material. In the: preferred embmliment shown, each, side margin 28a./b may be marked with a pair of contrasting coloured warp tapes 25c that identify a .region for Insetting a fhdag Component.: In this case 25c is away from the very edge 27a of the material or fabric as placement of the 30 fastening device so close, to the edge is not recommended... In another: embodiment, a single contrasting coloured warp tape is used at the junction bet ween a side margin 28a/b and an adjacent thinner warp tape region to identify the strengthened area. In yet another alternative, the colour of all thicker warp tapes in the side: margins 28a/b may contrast to
AMENDED SHEET iPEA/AU PCT/NZ2Q13/000074 Received 10/07/2014 those in the adjacent thinner regions. This marker or coloured lines guide the user the best place to attach the fastening device.
Thicker regions 29a/b along the: centre of the sheet are provided to allow the material to 5 roll, up evenly after it lias been sealed and cut on the edge, 27a, then flattened or Folded during the manufacturing process. This adds convenience and also helps alleviate the stresses on the material at the fold line 3.0 by allowing the thicker raised tapes to alleviate trie winding pressure on the folded centre, line of the material or fabric. When the material is folded, along its longitudinal centre line 30, the centre regions) 29a/b become opposed 10 sides/edges to the thicker side margins 28a/b. By creating a balance between the thickness of the side margins and the thickness of the material at the fold (i.e, at the centre iegion(s)),, the material is caused to maintain a more constant axis of rotation as it. is rolled up to form line balanced roll, ready for efficient stacking and dispatch. The thicker warp tapes at the centre region(s) give a raised, area 29 as shown in .Figure 3c which helps balance lire tension 15 created by raised area 28, The thicker warp tapes at. the centre therefore assist in roll evenness for stacking and transportation and also evens the tension across tin.· warp tapes during the weaving process;
It will he appreciated that the invention not intended fo be limited to the number of centre 20 regions described for the preferred embodiment, but rather is more concerned with providing a balanced thickness /density between the edges of a folded material. In other words, any number of centre regions of thicker warp tapes can be employed adjacent or proximate to (bat preferably not at) the centre/fold lines to substantially balance oar the thickness of the side margins and allow the material to roll up substantially evenly- after it 25 has been folded, at the centre/fold line during manufacture. In the preferred embodiment, the thickness of the warp tapes at the centre region(s) and side margins are substantially similar or equal, to create this balance. It will be appreciated, that the width of the thicker regions, the relative thicknesses of the warp tapes at the thicker regions, as well as the spacing/distribution of the centre regions are dependent on particular desired properties of 3:0 the material and can be altered accordingly to provide the above described benefits without departing from the scope of the invention. Preferably the centre regions are closer to the centre or fold line than the side margins of the material.
AMENDED SHEET IPEA/AU PCT/NZ2G13/000074 Received i 0/07/2014
In the preferred embodiment shown, the warp tapes 25a in the thicker regions 28/29 ot the sheet material respectively have a reduced width. w2, and a higher number of warp tapes per unit, area than the thinner regions making up the balance of the sheet material. Ί his allows the advantage of the narrower rapes 25a to be in the side margins 28a and 28h and centre regions 29a/ b and the advantages of udder tapes 25b to he captured in the remaining parts of the material. The side margins and centre region warp tapes do not have to be narrower than the tapes in 25b but would be thicker to capture the benefits as already discussed. Typically the width of die warp tapes 25a in the thicker regions, w2, will be SO' 80ba of the width, wl, of the warp tapes 25b of die thinner regions in the balance of the material. in a particularly preferred form the warp rapes 25a in thicker regions of the material will be between 1mm and 4mm or more preferably between 2mm and 3mm in width, while the other warp tapes 25b will be between 2mm and 6mm or more preferably between 3mm to 5mm in width. The weft tapes 25d which extend transversely across the woven material are woven through both the wider warp tapes 25b and the reduced width warp tapes 25a at either side:margin and at the centre regions of the material. In an alternative embodiment, only the warp tapes 25a at the side margins 28a/b may have the reduced width and higher number of warp tapes per unit area but are thicker.
Alternatively the centre region 29a/b warp tapes 23a are narrower and the side margin 2Sa/b warp tapes 25a. are of the same width as the warp tapes 25b making up the balance of the material, in another embodiment the tapes are all the same width and difference is Only in the tape thickness.
Preferably the ground cover material is woven from warp tapes and weft tapes and wherein the warp and weft tapes are substantially' flat. If the tapes are folded then this would generate: thicker tapes where they occur but also areas of extra pressure and possible weaknesses of the. tapes at the folded areas.
In an alternative embodiment, the thicker warp tape regions arc only at the· one or more centre regions, and preferably at two centre regions on either side of the fold line 30. In this embodiment, the resulting roll would not be balanced from a winding perspective but the fold line 30 would be protected from high levels of winding pressure or tension.
AMENDED SHEET iPEA/AU PCT/N22G13/000074 Received 10/07/2014
Preferably the material is reflective of at .least 50% of alternatively at least 55% or alternatively at least 60% of visible light on at least one side of the material. In one embodiment of a reflective material the material may reflect at least 40%:· solar radiation on average across the UV (wavelength about 280-400 nm), visible (wavelength about 40()- /00 nm) and very' near infrared (wavelength about 700-8()0 nm) ranges, and which transmits at least 10% or 5% on average of solar .radiation across the wavelength range about 800-2500nm. The material may reflect mote solar radiation than it transmits and absorbs in the UV, visible, and very near infrared ranges. The material may transmit at least '15% or at least 20% of solar radiation on average in the wavelength range about 800-2500nm. In another embodiment the material may reflect no UV in the 280 to 300 nm or less than 40% or only 5% of the UV. Some or all tapes of a reflective material may be formed from a resin comprising a white pigment, which resin has been formed by mixing a masterbalch consisting essentially of 5 to 9084 by weight of a white pigment or combination of pigments chosen from zirconium, strontium, barium, magnesium, zinc, calcium and titanium pigments, and a first polymer, with a second polymer Mich that the resin (masterhafeb) comprising the white pigment comprises between about 0.5 to 50% by weight of the total mixture. The material could also be made from a premised formula or compound so there is no polymer to be added and rhe mixture is then extruded as a compound without a masrerbatch, In certain embodiments the white pigment may be selected from zirconium, dioxide, magnesium, xirconate, calcium zireotmte, strontium zirconate, barium zirconate, zirconium silicate, zinc sulphide, zinc oxide, calcium carbonate, barium sulphate, magnesium oxide, strontium carbonate, barium carbonate, titanium dioxide and potassium titantac.
In some embodiments the material, may incorporate a compound. o.r compounds added to cause or increase the extent to which the material reflects and/or absorption of radiation from the earth (terrestrial (long wave or infrared) radiation). Thus when the material is placed over or adjunct to plants if will assist m retaining heat beneath the material, which may be desirable for some plants or applications.
In some embodiments the material may incorporate a compound or compounds added to cause or increase the extent to which the material allows transmission and/or absorption of radiation from the earth (terrestrial (long wave or infrared) radiation). Thus when the
AMENDED SHEET 1PEA/AU PCT/NZ2013/000074 Received 10/07/2014 material is placed over or adjacent to plants it will assist ίο releasing the heat beneath the material, which may be desirable tor some plants or applications*
In other embodiments the material may Incorporate a compound or compounds added to cause or increase the extent to which the. material reflects and/or absorbs solar radiation. Thus when the material is placed over or adjunct to plants it will assist in cooling beneath the material, which may be desirable for some plants or applications.
In other embodiments the material may incorporate a compound or compounds added to cause or increase the extent ro which the material allows transmission and/or absorption of solar radiation. Tims when the material is placed over or adjunct to plants it will assist hi increasing the heat beneath the material, which may be desirable for some plants or applications.
The tapes may be formed from any suitable polyolefin such as polyethylene or polypropylene, for example, or a mixtu re thereof, or an ethylene alpha olefin, or a polyester, or a biopolymer, or a blend of any of the foregoing. Certain plastics are particularly useful when present as minor or major components. Ethylene vinyl acetate (EVA), ethylene butyl acrylate (EEA) and ethylene methyl acrylate (EMA) are useful for imparting elasticity and other properties. Polyesters and polystyrene, styrenefoutdaenk (SB), acryiomtrfle-batadiemeTSh'retie (ABS), sty*ene-adylomtrile (SAN), polyetbylenie terephithialate (PHT), polymethylmethacrylate (ΡΜΜΛ) and polycarbonate are useful as dye carriers; and also for influencing radiation (reflecting, absorbing and transmission) properties and also other properties on the materials. Starch and other plant polymers ate useful to increase biodegradability. Alternatively the tapes, may comprise in part or whole of paper, wood of cellulose fibre, stanch based polymers, casein, latex or in any combination of the above and/or with, petroleum derived, plastic polymers. The polymer or polymer blend may incorporate agents such, as one or more pigments, UV stabilisers, or processing aids.
The foregoing describes the invention: including a preferred form thereof, alterations and modifications as will be obvious to those skilled in the art are intended to be incorporated in the scope hereof as defined in the accompanying claims.
AMENDED SHEET IPEA/AU
Claims (19)
1. A ground cover sheet material woven from warp and weft tapes, wherein the material comprises regions of relatively thicker (hereinafter: thicker regions) warp tapes and regions of relatively thinner (hereinafter: thinner regions) warp tapes, the thicker regions being at or adjacent one or both longitudinally extending opposite side margins of the material, and two or more longitudinally extending centre regions spaced apart on either side of a notional centre or fold line of the material and nearer to the notional centre or fold line of the material than to the longitudinally extending opposite side margins of the material, and the thinner regions mailing up the balance of the sheet material.
2. A ground cover sheet material according to claim 1 wherein the two or more longitudinally extending centre regions spaced apart on either side of a notional centre or fold line of the material are between 20 to 100 mm away from the notional centre or fold line.
3. A ground cover sheet material according to claim 1 or claim 2 wherein the thicker regions are at both longitudinally· extending opposite side margins on either side of the material.
4. A ground cover sheet material according to any one of claims 1 to 3 wherein the warp tapes have a uniform thickness in the thicker regions and a uniform thickness in the thinner regions.
5. A ground cover sheet material according to any one of the preceding claims wherein the warp tapes in the thicker regions are between about 10 and about 200% thicker than the warp tapes in the thinner regions.
6. A ground cover sheet material according to any one of claims 1 to 4 wherein the warp tapes in the thicker regions are between about 20 and about 100% thicker than the warp tapes in the thinner regions.
7. A ground cover sheet material according to any one of the preceding claims wherein each of the thicker regions is between about 20 and about 300mm wide.
8. A ground cover sheet material according any one of claim 1 to claim 7 wherein each of the thicker regions is, for the side margins between about 140 and about 180 mm wide, and for the centre regions between about 40 and about 60mm wide.
9. A ground cover sheet material according to any one of the preceding claims wherein the width of warp tapes is decreased in the thicker regions relative to the width of warp tapes in the thinner regions. '10. A ground cover sheet material as claimed in claim 9 in which the warp tapes in die thicker regions have a widdi between about 1 and about 3 mm and the warp tapes in the thinner regions have a widdi between about 3 and about 5 mm.
11. A ground cover sheet material according to any one of the preceding claims wherein the transition between an inner edge of each side margin and a thinner region warp tapes of the material is marked by a line or other marking of contrasting colour or wherein the colour of the warp tapes in the thicker regions contrasts to that of die balance of the sheet material.
12. A ground cover sheet material according to any one of the preceding claims wherein the warp and weft tapes are of a plastics material.
13. A ground cover sheet material according to any one of the preceding claims wherein the warp and weft tapes are substantially flat.
14. A ground cover sheet material as claimed in any one of die preceding claims wherein the material is reflective of at least about 50% of visible light on at least one side of the material
15. A ground cover sheet material as claimed in any one of the preceding claims wherein some or all tapes of a reflective material are formed from a resin comprising a white pigment, which resin has been formed by mixing a masterbatch consisting essentially of between about 5 and about 90% by weight of a white pigment or combination of pigments, and a first polymer, with a second polymer such that the resin (masterbatch) comprising the white pigment comprises between about 0.5 and about 50% by weight of the total mixture.
16. A ground cover sheet material as claimed in claim 15 wherein the material incorporates a compound or compounds added to cause or increase the extent to which the material reflects and/or absorption of radiation from the earth (terrestrial (long wave or infrared) radiation).
17. A ground cover sheet material as claimed in claim 15 wherein the material incorporates a compound or compounds added to cause or increase the extent to which the material allows transmission and/or absorption of radiation from die earth (terrestrial (long wave or infrared) radiation).
18. A ground cover sheet material as claimed in claim 15 wherein the material incorporates a compound or compounds added to cause or increase the extent to which the material reflects and/or absorbs solar radiation.
19. A ground cover sheet material as claimed in claim 15 wherein the material incorporates a compound or compounds added to cause or increase the extent to w7hich the material allows transmission and/or absorption of solar radiation.
20. A ground cover sheet material as claimed in claim 12 wherein the warp and weft tapes are formed from polyolefin, or an ethylene alpha-olefin, or polyester, or a biopolymer, or a blend of any of the foregoing.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NZ59959112 | 2012-04-26 | ||
| NZ599591 | 2012-04-26 | ||
| PCT/NZ2013/000074 WO2013162385A1 (en) | 2012-04-26 | 2013-04-24 | Ground cover material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2013253096A1 AU2013253096A1 (en) | 2014-12-18 |
| AU2013253096B2 true AU2013253096B2 (en) | 2017-06-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2013253096A Ceased AU2013253096B2 (en) | 2012-04-26 | 2013-04-24 | Ground cover material |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20150083267A1 (en) |
| EP (1) | EP2840885A1 (en) |
| AU (1) | AU2013253096B2 (en) |
| CA (1) | CA2871583A1 (en) |
| WO (1) | WO2013162385A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2013316703B2 (en) | 2012-09-12 | 2017-09-21 | Nine Ip Limited | Netting, crop cover, and ground cover materials |
| US20160174473A1 (en) * | 2013-08-08 | 2016-06-23 | Nine Ip Limited | Ground cover materials |
| JP7424847B2 (en) * | 2020-01-31 | 2024-01-30 | セーレン株式会社 | Weed control sheet and method for manufacturing the weed control sheet |
| US20210259166A1 (en) * | 2020-02-24 | 2021-08-26 | Ayyappan K. Rajasekaran | Weed growth control and water and nutrient conservation technology |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006009479A1 (en) * | 2004-07-22 | 2006-01-26 | Extenday Ip Limited | Plant treatment material |
| WO2011008109A1 (en) * | 2009-07-15 | 2011-01-20 | Jonathan Dallas Toye | Woven ground cover materials |
-
2013
- 2013-04-24 WO PCT/NZ2013/000074 patent/WO2013162385A1/en not_active Ceased
- 2013-04-24 EP EP13780645.1A patent/EP2840885A1/en not_active Withdrawn
- 2013-04-24 US US14/397,451 patent/US20150083267A1/en not_active Abandoned
- 2013-04-24 AU AU2013253096A patent/AU2013253096B2/en not_active Ceased
- 2013-04-24 CA CA2871583A patent/CA2871583A1/en not_active Abandoned
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006009479A1 (en) * | 2004-07-22 | 2006-01-26 | Extenday Ip Limited | Plant treatment material |
| WO2011008109A1 (en) * | 2009-07-15 | 2011-01-20 | Jonathan Dallas Toye | Woven ground cover materials |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2013162385A1 (en) | 2013-10-31 |
| US20150083267A1 (en) | 2015-03-26 |
| CA2871583A1 (en) | 2013-10-31 |
| EP2840885A1 (en) | 2015-03-04 |
| AU2013253096A1 (en) | 2014-12-18 |
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