AU2007219065B2

AU2007219065B2 - Low surface roughness cast strip and method and apparatus for making the same

Info

Publication number: AU2007219065B2
Application number: AU2007219065A
Authority: AU
Inventors: Walter Blejde; Jay Jon Ondrovic
Original assignee: Nucor Corp
Current assignee: Nucor Corp
Priority date: 2006-02-27
Filing date: 2007-02-27
Publication date: 2012-03-08
Anticipated expiration: 2027-02-27
Also published as: JP2014100741A; UA94089C2; BRPI0708328B1; EP1989009B1; US20090126896A1; JP5764282B2; KR20080096830A; MA30275B1; EP1989009A4; NZ571431A; JP2009528168A; KR101446937B1; MY157942A; KR20140077218A; PL1989009T3; US20070199627A1; CN101432083A; MX2008010670A; BRPI0708328A2; WO2007095695A1

Abstract

A thin cast strip is formed having at least one microstructure selected from the group consisting of polygonal ferrite, acicular ferrite, Widmanstatten, bainite and martinsite, a surface roughness of less than 1.5 microns Ra and a scale thickness of less than about 10 microns by applying a mixture of water and oil on the work rolls of the hot rolling mill, passing the thin cast strip at a temperature of less than 1100° C through the hot rolling mill while the mixture of oil and water is applied to the work rolls, and shrouding the thin cast strip from the casting rolls through the hot rolling mill in an atmosphere of less than 5 % oxygen to form the thin cast strip.

Description

WO 2007/095695 PCT/AU2007/000227 -1 LOW SURFACE ROUGHNESS CAST STRIP AND METHOD AND APPARATUS FOR MAKING THE SAME BACKGROUND AND SUMMARY OF THE INVENTION 5 This invention relates to cast strip made by a twin roll caster and a method and apparatus for making such cast strip. In a twin roll caster, molten metal is introduced between a pair of counter- 10 rotated horizontal casting rolls which are cooled so that metal shells solidify on the moving roll surfaces, and are brought together at the nip between them to produce a solidified strip product delivered downwardly from the nip between the casting rolls. The term "nip" is used herein to refer to the general region at which the 15 casting rolls are closest together. The molten metal may be poured from a ladle through a metal delivery system comprised of a tundish and a core nozzle located above the nip to form a casting pool of molten metal supported on the casting surfaces of the rolls above the nip and extending along the length of the nip. This casting pool is usually confined between refractory side plates or dams held in sliding engagement with 20 the end surfaces of the rolls so as to dam the two ends of the casting pool against outflow. When casting steel strip in a twin roll caster, the strip leaves the nip at very high temperatures on the order of 1400'C or higher. If exposed to normal atmosphere, it would suffer very rapid scaling due to oxidation at such high temperatures. 25 Therefore, a sealed enclosure is provided beneath the casting rolls to receive the hot strip and through which the strip passes on the way from the strip caster, the enclosure containing an atmosphere which inhibits oxidation of the strip. The oxidation inhibiting atmosphere may be created by injecting a non-oxidizing gas, for example, an inert gas such as argon or nitrogen, or combustion exhaust gases which may be reducing 30 gases. Alternatively, the enclosure may be sealed against ingress of oxygen containing atmosphere during operation of the strip caster. The oxygen content of the atmosphere within the enclosure is then reduced during an initial phase of casting by WO 2007/095695 PCT/AU2007/000227 -2 allowing oxidation of the strip to extract oxygen from the sealed enclosure as disclosed in United States Patents 5,762,126 and 5,960,855. It is known to hot roll cast strip produced by twin roll caster in a hot rolling 5 mill after the strip emerges from the caster to shape the thin strip. It is generally understood that a combination of a rolling mill and a twin roll caster is necessary to provide a desired cross-sectional profile to the strip. However, it has been found that strip that has been cast at a standard 10 casting speed of 80m/min and then hot rolled in a hot rolling mill with a 16% reduction of the strip by the hot rolling mill can have a relatively high surface roughnesses of 6 to 8 microns Ra with surface micro-cracking. Figure 1 is a micrograph showing typical surface roughness of such cast and hot rolled strip emerging from a hot rolling mill in-line with a twin roll caster. With the direction of 15 rolling from left to right, the micrograph shows pronounced lapping on the strip surface (20 to 30 gm deep). The reason or reasons for this surface roughness may be shearing at the strip surface caused by welding of the strip to the work roll surface, imprinting of the texture of the work roll surface onto the surface of the strip, and/or other factors. Moreover, micro-cracking on the surface of the cast strip has been 20 found to be a problem. It was possible to reduce microcracking by reducing the casting speed and the heat rate of the strip but it was uneconomical to reproduce these conditions during production. The microstructure of hot strip mill products is essentially 100% equiaxed 25 ferrite. However, in making a cast strip with a twin roll caster, previous experience was that microstructure was coarse grains of polygonal ferrite, acicular ferrite, and Widmanstatten. It was typical that the microstructure was 30-60% polygonal ferrite, 70-40 % Widmanstatten and acicular ferrite. With this microstructure, the typical surface roughness was 4-7 microns Ra. 30 A thin cast strip is provided having at least one microstructure selected from the group consisting of polygonal ferrite, acicular ferrite, Widmanstatten, bainite and WO 2007/095695 PCT/AU2007/000227 -3 martensite, a surface roughness of less than 1.5 microns Ra and a scale thickness of less than about 10 microns made by the steps comprising: a) assembling a twin roll caster having laterally positioned caster rolls 5 forming a nip between them and a hot rolling mill having work rolls and back-up rolls adjacent the twin roll caster, b) forming a thin cast strip from the nip between the casting rolls of the twin roll caster, 10 c) applying a mixture of water and oil on the work rolls of the hot rolling mill, d) passing the thin cast strip at a temperature of less than 1100* C through 15 the hot rolling mill while the mixture of oil and water is applied to the work rolls, and e) shrouding the thin cast strip from the casting rolls through the hot rolling mill in an atmosphere of less than 5 % oxygen forming a cast strip having 20 at least one microstructure selected from the group consisting of polygonal ferrite, acicular ferrite, Widmanstatten, bainite and martinsite, a surface roughness of less than 1.5 microns Ra, and a scale thickness of less than about 10 microns. 25 A thin cast steel strip is also provided with a reduced surface roughness below 1.5 microns Ra made by the steps comprising: a) assembling a strip caster having a pair of casting rolls having a nip there between; 30 WO 2007/095695 PCT/AU2007/000227 -4 b) assembling a metal delivery system capable of forming a casting pool between the cast rolls above the nip with side dams adjacent the ends of the nip to confine said casting pool; 5 c) assembling adjacent the strip caster a hot rolling mill having work rolls with work surfaces forming a gap between them through which hot strip is rolled; d) assembling spray nozzles positioned adjacent the work rolls capable of 10 providing a mixture of water and oil to the work rolls; e) introducing molten steel between the pair of casting rolls to form a casting pool supported on casting surfaces of the casting rolls confined by said first side dams; 15 f) counter-rotating the casting rolls to form solidified metal shells on the surfaces of the casting rolls and cast steel strip through the nip between the casting rolls from said solidified shells; 20 g) spraying the mixture of oil and water as the strip enters the hot rolling mill; and h) rolling the cast strip between the work rolls of the hot rolling mill to produce a cast strip having a surface roughness less than 1 microns Ra. 25 A thin cast steel strip is also provided with a reduced surface roughness below 1.5 microns Ra made by the steps comprising: a) assembling a strip caster having a pair of casting rolls having a nip there 3 0 between; WO 2007/095695 PCT/AU2007/000227 -5 b) assembling a metal delivery system capable of forming a casting pool between the cast rolls above the nip with side dams adjacent the ends of the nip to confine said casting pool; 5 c) assembling adjacent the strip caster a hot rolling mill having back-up rolls and work rolls with work surfaces forming a gap between the work rolls through which hot strip is rolled; d) assembling spray nozzles positioned upstream of the work rolls capable 10 of spraying a mixture of water and oil the back-up rolls; e) introducing molten steel between the pair of casting rolls to form a casting pool supported on casting surfaces of the casting rolls confined by said first side dams; 15 f) counter-rotating the casting rolls to form solidified metal shells on the surfaces of the casting rolls and cast steel strip through the nip between the casting rolls from the solidified shells; 20 g) spraying the mixture of oil and water as the cast strip enters the hot rolling mill; and h) rolling the cast strip between the work rolls of the hot rolling mill to produce a cast strip having a surface roughness less than 1.5 microns 25 Ra. The thin cast strip may have a surface roughness less than 1.0 microns Ra or less than 0.7 microns Ra or less than 0.5 microns Ra or less than 0.4 microns Ra. 30 The thin cast strip may have a scale thickness less than 7 microns or less than 4 microns.

WO 2007/095695 PCT/AU2007/000227 -6 The cast strip may be passed through the hot rolling mill at a temperature less than 10500 C while the mixture of oil and water is applied to the work rolls. The thin cast strip may have a scale thickness less than 7 microns or less 5 than 4 microns. The mixture of oil and water may be applied by spraying the work rolls. The mixture of oil and water may be applied to the back-up rolls. 10 The mixture of oil and water may be less than 5% oil to form the thin cast strip with a low surface roughness of less than 1.5 microns Ra. A method is provided for producing thin cast strip having at least one 15 microstructure selected from the group consisting of polygonal ferrite, acicular ferrite, Widmanstatten, bainite and martinsite, a surface roughness of less than 1.5 microns Ra and a scale thickness of less than about 10 microns, the method comprising the steps of: a) assembling a twin roll caster having laterally positioned caster rolls 20 forming a nip between them and a hot rolling mill having work rolls and back-up rolls adjacent the twin roll caster, b) forming a thin cast strip from the nip between the casting rolls of the twin roll caster, , 25 c) applying a mixture of water and oil on the work rolls of the hot rolling mill, d) passing the thin cast strip at a temperature of less than 11000 C through 30 the hot rolling mill while the mixture of oil and water is applied to the work rolls, and WO 2007/095695 PCT/AU2007/000227 -7 e) shrouding the thin cast strip from the casting rolls through the hot rolling mill in an atmosphere of less than 5 % oxygen forming a thin cast strip having: at least one microstructure selected from the group consisting of polygonal ferrite, acicular ferrite, Widmanstatten, bainite and martinsite, 5 a surface roughness of less than 1.5 microns Ra, and a scale thickness of less than 10 microns. A method is also provided for producing a thin cast steel strip with reduced surface roughness below 1.5 microns Ra, the method comprising the steps of: 10 a) assembling a strip caster having a pair of casting rolls having a nip there between; b) assembling a metal delivery system capable of forming a casting pool 15 between the cast rolls above the nip with side dams adjacent the ends of the nip to confine said casting pool; c) assembling adjacent the strip caster a hot rolling mill having work rolls with work surfaces forming a gap between them through which hot strip 20 is rolled; d) assembling spray nozzles positioned adjacent the work rolls capable of providing a mixture of water and oil to the work rolls; 25 e) introducing molten steel between the pair of casting rolls to form a casting pool supported on casting surfaces of the casting rolls confined by said first side dams; f) counter-rotating the casting rolls to form solidified metal shells on the 30 surfaces of the casting rolls and cast steel strip through the nip between the casting rolls from said solidified shells; WO 2007/095695 PCT/AU2007/000227 -8 g) spraying the mixture of oil and water as the strip enters the hot rolling mill; and h) rolling the cast strip between the work rolls of the hot rolling mill to 5 produce a cast strip having a surface roughness less than 1 microns Ra. A method is also provided for producing a thin cast steel strip with reduced surface roughness below 1.5 microns Ra, the method comprising the steps of: 10 a) assembling a strip caster having a pair of casting rolls having a nip there between; b) assembling a metal delivery system capable of forming a casting pool between the cast rolls above the nip with side dams adjacent the ends of 15 the nip to confine said casting pool; c) assembling adjacent the strip caster a hot rolling mill having back-up rolls and work rolls with work surfaces forming a gap between the work rolls through which hot strip is rolled; 20 d) assembling spray nozzles positioned upstream of the work rolls capable of spraying a mixture of water and oil the back-up rolls; e) introducing molten steel between the pair of casting rolls to form a 25 casting pool supported on casting surfaces of the casting rolls confined by said first side dams; f) counter-rotating the casting rolls to form solidified metal shells on the surfaces of the casting rolls and cast steel strip through the nip between 3 0 the casting rolls from the solidified shells; WO 2007/095695 PCT/AU2007/000227 -9 g) spraying the mixture of oil and water as the cast strip enters the hot rolling mill; and h) rolling the cast strip between the work rolls of the hot rolling mill to 5 produce a cast strip having a surface roughness less than 1.5 microns Ra. The method may comprise applying the mixture of oil and water by spraying the work rolls, for example with sparay nozzles. 10 The rate of spray by the nozzles may be between 10 and 30 gallons per minute. The mixture of oil and water may be applied to the work rolls by applying 15 the mixture of oil and water to the back-up rolls. The method may comprise producing the cast strip at a rate above 80 meters per minute. 20 The rolling temperature may below 11 OOC or below 1050* C or below 9000 C. BRIEF DESCRIPTION OF THE DRAWINGS 25 The operation of an illustrative twin roll casting plant in accordance with the present invention is described with reference to the accompanying drawings, in which: 3 0 Figure 1 is a micrograph showing typical surface roughness of a cast strip after hot rolling; WO 2007/095695 PCT/AU2007/000227 -10 Figure 2 is a schematic illustrating a thin strip casting plant having a hot rolling mill for controlling the shape of cast strip; Figure 3 is an enlarged cut-away side view of the caster of the thin strip 5 casting plant of Figure 2; Figure 4 is a schematic diagram showing a system for the application of an oil and water mixture to the rolls of a hot rolling mill; and 10 Figure 5 is a diagram showing the Average Surface Roughness for Thin Cast Steel Strip, Sequence 2613, made using o the present invention. DESCRIPTION OF THE PREFERRED EMBODIMENTS 15 The illustrated casting and rolling installation comprises a twin-roll caster denoted generally by 11 which produces thin cast steel strip 12 which passes into a transient path across a guide table 13 to a pinch roll stand 14. After exiting the pinch roll stand 14, thin cast strip 12 passes into and through hot rolling mill 15 comprised of back-up rolls 16 and upper and lower work rolls 16A and 16B, where the thickness 20 of the strip reduced. The strip 12, upon exiting the rolling mill 15, passes onto a run out table 17 where it may be forced cooled by water jets 18, and then through pinch roll stand 20 comprising a pair of pinch rolls 20A and to a coiler 19. Twin-roll caster 11 comprises a main machine frame which supports a pair 25 of laterally positioned casting rolls 22 having casting surfaces 22A and forming a nip between them. Molten metal is supplied during a casting campaign from a ladle (not shown) to a tundish 23, through a refractory shroud to a removable tundish 25 (also called distributor vessel or transition piece), and then through a metal delivery nozzle 28 (also called a core nozzle) between the casting rolls 22 above the nip. 30 Molten steel is introduced into removable tundish 25 from tundish 23 via an outlet of the refractory shroud. The tundish 23 is fitted with a stopper rod and a slide WO 2007/095695 PCT/AU2007/000227 - 11 gate valve (not shown) to selectively open and close the outlet of the shroud and effectively control the flow of molten metal from the tundish 23 to the caster. The molten metal flows from removable tundish 25 through an outlet and optionally to and through the delivery nozzle 28. 5 Molten metal thus delivered to the casting rolls 22 forms a casting pool above nip supported by casting roll surfaces 22A. This casting pool is confined at the ends of the rolls by a pair of side dams or plates, which are applied to the ends of the rolls by a pair of thrusters (not shown) comprising hydraulic cylinder units connected 10 to the side dams. The upper surface of the casting pool (generally referred to as the m eniscus" level) may rise above the lower end of the delivery nozzle 28 so that the lower end of the deliver nozzle is immersed within the casting pool. Casting rolls 22 are internally water cooled by coolant supply (not shown) 15 and driven in counter rotational direction by drives (not shown) so that shells solidify on the moving casting roll surfaces and are brought together at the nip to produce the thin cast strip 12, which is delivered downwardly from the nip between the casting rolls. 20 Below the twin roll caster 11, the cast steel strip 12 passes within a sealed enclosure 10 to the guide table 13, which guides the strip to a pinch roll stand 14 through which it exits sealed enclosure 10. The seal of the enclosure 10 may not be complete, but is appropriate to allow control of the atmosphere within the enclosure and access of oxygen to the cast strip within the enclosure as hereinafter described. After 25 exiting the sealed enclosure 10, the strip may pass through further sealed enclosures after the pinch roll stand 14, including the hot rolling mill 15. Enclosure 10 is formed by a number of separate wall sections that fit together at various seal connections to form a continuous enclosure wall. These sections 30 comprise a first wall section 41 at the twin roll caster to enclose the casting rolls 22, and a wall enclosure 42 extending downwardly beneath first wall section 41 to form an opening that is in sealing engagement with the upper edges of a scrap box receptacle 40.

WO 2007/095695 PCT/AU2007/000227 -12 A seal 43 between the scrap box receptacle 40 and the enclosure wall 42 may be formed by a knife and sand seal around the opening in enclosure wall 42, which can be established and broken by vertical movement of the scrap box receptacle 40 relative to enclosure wall 42. Seal 43 is formed by raising the scrap box receptacle 40 to cause 5 the knife flange to penetrate the sand in the channel to establish the seal. This seal 43 can be broken by lowering the scrap box receptacle 40 from its operative position, preparatory to movement away from the caster to a scrap discharge position (not shown). Scrap box receptacle 40 is mounted on a carriage 45 fitted with 10 wheels 46 which run on rails 47, whereby the scrap box receptacle can be moved to the scrap discharge position. Carriage 45 is fitted with a set of powered screw jacks 51 operable to lift the scrap box receptacle 40 from a lowered position, where it is spaced from the enclosure wall 42, to a raised position where the knife flange penetrates the sand to form seal 43 between the two. 15 Sealed enclosure 10 further may have a third wall section disposed 61 about the guide table 13and connected to the frame of pinch roll stand 14, which includes a pair of pinch rolls 50. The third wall section disposed 61 of enclosure 10 is sealed by sliding seals. 20 Most of the enclosure wall sections 41, 42 and 61 may be lined with fire brick. Also, scrap box receptacle 40 may be lined either with fire brick or with a castable refractory lining. In this way, the complete enclosure 10 is sealed prior to a casting operation, thereby limiting access of oxygen to thin cast strip 12, as it passes 25 from the casting rolls 22 through the pinch roll stand 14 and the hot rolling mill 15. Initially the strip can take up all of the oxygen from enclosure 10 space by forming heavy scale on an initial section of the strip. However, the sealing enclosure 10 limits ingress of oxygen into the enclosure from the surrounding atmosphere to below the amount of oxygen that could be taken up by the strip. Thus, after an initial start-up 30 period, the oxygen content in the enclosure 10 will remain depleted so limiting the availability of oxygen for oxidation of the strip 12. In this way, the formation of scale is controlled to a thickness less than 10 microns without the need to continuously WO 2007/095695 PCT/AU2007/000227 - 13 feed a reducing or non-oxidizing gas into the enclosure. Of course, a reducing or non oxidizing gas may be fed through the enclosure walls. However, in order to avoid the heavy scaling during the start-up period, the enclosure 10 can be purged immediately prior to the commencement of casting so as to reduce the initial oxygen level within 5 enclosure 10, thereby reducing the time period for the oxygen level to stabilize in the enclosure as a result of the interaction of the oxygen in oxidizing the strip passing through it. Thus, illustratively, the enclosure may conveniently be purged with, for example, nitrogen gas. It has been found that reduction of the initial oxygen content to levels of between 5% will limit the scaling of the strip at the exit from the enclosure 10 10 to about 10 microns to 17 microns even during the initial start-up phase. In an embodiment of the present invention, the thin cast steel strip has a scale thickness less than about 10 microns, or the scale thickness may be less than 7 or 4 microns, during continuous casting. 15 At the start of a casting campaign, a short length of imperfect strip is produced as the casting conditions stabilize. After continuous casting is established, the casting rolls 22 are moved apart slightly and then brought together again to cause this lead end of the strip to break away in the manner described in Australian Patent 646,981 and United States Patent No. 5,287,912, to form a clean head end of the following 20 thin cast strip 12. The imperfect material drops into scrap box receptacle 40 located beneath caster 11, and at this time swinging apron 38, which normally hangs downwardly from a pivot 39 to one side of the caster as shown in Figure 3, is swung across the caster outlet to guide the clean end of thin cast strip 12 onto the guide table 13 where the strip is fed to the pinch roll stand 14. Apron 38 is then retracted back to 25 its hanging position as shown in Figure 3 to allow the strip 12 to hang in a loop 36 beneath the caster as shown in Figures 2 and 3 before the strip passes onto the guide table 13. The guide table 13 comprises a series of strip support rolls 37 to support the strip before it passes to the pinch roll stand 14. The rolls 37 are disposed in an array extending from the pinch roll stand 14 backwardly beneath the caster and curve 30 downwardly to smoothly receive and guide the strip from the loop 36.

WO 2007/095695 PCT/AU2007/000227 -14 The twin-roll caster may be of a kind which is illustrated and described in detail in United States Patent No. 5,184,668 and 5,277,243, or United States Patent No. 5,488,988. Reference may be made to these patents for construction details, which are no part of the present invention. 5 Pinch roll stand 14 comprises a pair of pinch rolls 50 reactive to tension applied by the hot rolling mill 15. Accordingly, the strip is able to hang in the loop 36 as it passes from the casting rolls 22 to the guide table 13 and into the pinch roll stand 14. The pinch rolls 50 thus provides a tension barrier between the freely hanging loop 10 and tension on the strip downstream of the processing line. The pinch rolls 50 also stabilize the position of the strip on the feed table 13, feeding the strip into hot rolling mill 15. From the pinch roll stand 14, the thin cast strip 12 is delivered to the hot 15 rolling mill 15 comprised of upper work roll 16A and lower roll 16B. As shown in Figure 4, a preferred embodiment of the present invention comprises spraying a mixture of water and oil on the downstream surfaces of back-up rolls 16. An oil reservoir 100 is provided with a heater 101 to maintain the oil at approximately 500 C, but heating is not necessary. The heated oil is transferred through oil transfer 20 lines 103 by fixed displacement pumps 102 to static mixers 104 where the heated oil is mixed with water. Water is supplied from a source 110 to water strip chilling headers 111 and to mill rolls supply lines 112. A first portion of the water is supplied to spray 25 headers 18 to supply cooling water to cool the hot strip 12 after exiting the hot rolling mill 15. Typically, the water pressure is reduced through pressure regulator 113 to about 40 psi. Between about 10 and 30 gpm of water is supplied to each static mixer 104 where the water is mixed with about 4 gph of heated oil. 30 The mixed oil and water is then applied to the downstream surfaces (the direction of travel of the thin cast steel strip 12 is shown by arrow 120) of back-up rolls 16 through oil-water nozzles 71. Alternately, the oil-water mixture may be WO 2007/095695 PCT/AU2007/000227 - 15 applied to cast strip 12 in the roll bite area, may be applied to the upstream surfaces of the back-up rolls 16 or to the work rolls 16A, 16B. Preferably, the temperature of the thin cast steel strip 12 in the hot rolling 5 mill 15 is less than 11000 C, and more preferably less than 1050* C, and most preferably less than 900* C. Also, preferably, the temperature of the thin cast steel strip in the hot rolling mill 15 is above 4000 C The static mixers 104 are standard conventionally available devices. 10 Other forms of mixers may be used provided they are capable of good mixing of the oil and water. In one embodiment, the oil-water mixture is delivered at between 5 and 30 gpm at 40 psi to the back-up rolls 16. Typically the oil-water mixture is delivered to 15 the back up rolls in this embodiment at about 10 to 20 gpm, with 15 gpm a reasonable setting. The oil-water mixture may comprise less than 5% oil, and in one embodiment comprises 4 parts oil and between 600 parts to 1800 parts water by volume. The oil may be less than 2% or 1% of the mixture. The oil is provided to be mixed with the water generally at less than 15 gph. 20 Figure 5 shows the Average Surface Roughness (Ra) in microns for thin cast strip steel strip 12 produced using the present invention. As can be seen in Figure 5, the Average Surface Roughness is noticeably lower, about 0.66 to about 1.5 microns with the addition of an oil-water mixture as described above. 25 In one embodiment, the present invention comprises producing thin cast steel strip using the oil-water application described above to produce thin cast steel strip at a rate above 80 meters per minute. 30 While the invention has been described with reference to certain embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted without departing from the scope of the WO 2007/095695 PCT/AU2007/000227 - 16 invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from its scope. Therefore, it is intended that the invention not be limited to the particular embodiments disclosed, but that the invention will include all embodiments falling within the scope 5 of the appended claims.

Claims

1. A thin cast strip having at least one microstructure selected from the group 5 consisting of polygonal ferrite, acicular ferrite, Widmanstatten, bainite and martinsite, a surface roughness of less than 1.5 microns Ra and a scale thickness of less than 10 microns made by the steps comprising: a) assembling a twin roll caster having laterally positioned caster rolls 10 forming a nip between them and a hot rolling mill having work rolls and back-up rolls adjacent the twin roll caster, b) forming a thin cast strip from the nip between the casting rolls of the twin roll caster, , 15 c) applying a mixture of water and oil on the work rolls of the hot rolling mill, d) passing the thin cast strip at a temperature of less than 11000 C through 20 the hot rolling mill while the mixture of oil and water is applied to the work rolls, and e) shrouding the thin cast strip from the casting rolls through the hot rolling mill in an atmosphere of less than 5 % oxygen forming a thin cast strip 25 having: at least one microstructure selected from the group consisting of polygonal ferrite, acicular ferrite, Widmanstatten, bainite and martinsite, a surface roughness of less than 1.5 microns Ra, and a scale thickness of less than 10 microns. 30

2. A thin cast strip as claimed in claim 1 wherein the thin cast strip is passed through the hot rolling mill at a temperature less than 10500 C while the mixture of oil and water is applied to the work rolls. WO 2007/095695 PCT/AU2007/000227 -18

3. A thin cast strip as claimed in claim 1 or claim 2 wherein the surface roughness is less than 1.0 microns Ra. 5

4. A thin cast strip as claimed in claim 3 wherein the surface roughness is less than 0.7 microns Ra.

5. A thin cast strip as claimed in claim 4 wherein the surface roughness is less than 0.5 microns Ra. 10

6. A thin cast strip as claimed in any one of the preceding claims wherein the scale thickness is less than 7 microns.

7. A thin cast strip as claimed in claim 6 wherein the scale thickness is less 15 than 4 microns.

8. A thin cast strip as claimed in any one of the preceding claims wherein the mixture of oil and water is applied by spraying the work rolls. 20

9. A thin cast strip as claimed in any one of the preceding claims wherein the mixture of oil and water is applied to the work rolls by applying the mixture of oil and water to the back-up rolls.

10. A thin cast strip as claimed in any one of the preceding claims wherein the 25 mixture of oil and water is less than 5% oil and the low surface roughness is less than 1.5 microns Ra.

11. A thin cast steel strip with reduced surface roughness below 1.5 microns Ra, produced by the steps comprising: 30 a) assembling a strip caster having a pair of casting rolls having a nip there between; WO 2007/095695 PCT/AU2007/000227 -19 b) assembling a metal delivery system capable of forming a casting pool between the cast rolls above the nip with side dams adjacent the ends of the nip to confine said casting pool; 5 c) assembling adjacent the strip caster a hot rolling mill having work rolls with work surfaces forming a gap between them through which hot strip is rolled; 10 d) assembling spray nozzles positioned adjacent the work rolls capable of providing a mixture of water and oil to the work rolls; e) introducing molten steel between the pair of casting rolls to form a casting pool supported on casting surfaces of the casting rolls confined 15 by said first side dams; f) counter-rotating the casting rolls to form solidified metal shells on the surfaces of the casting rolls and cast steel strip through the nip between the casting rolls from said solidified shells; 20 g) spraying the mixture of oil and water as the strip enters the hot rolling mill; and h) rolling the cast strip between the work rolls of the hot rolling mill to 25 produce a cast strip having a surface roughness less than 1.5 microns Ra.

12. The thin cast steel strip with reduced surface roughness as claimed in claim 11 where the rate of production of the cast strip is above 80 meters per minute. 30

13. The thin cast steel strip with reduced surface roughness as claimed in claim 11 or Claim 12 where the rolling temperature is below 900 'C. WO 2007/095695 PCT/AU2007/000227 - 20

14. The thin cast steel strip with reduced surface roughness as claimed in any one of claims 11 to 13 where the rate of spray by the nozzles is between 10 and 30 gallons per minute. 5

15. The thin cast steel strip with reduced surface roughness as claimed in any one of claim 11 to 14 where the surface roughness below 0.7 microns Ra.

16. The thin cast steel strip with reduced surface roughness as claimed in 10 claim 15 where the surface roughness below 0.4 microns Ra.

17. A thin cast steel strip with reduced surface roughness below 1.5 microns Ra, produced by the steps comprising: 15 a) assembling a strip caster having a pair of casting rolls having a nip there between; b) assembling a metal delivery system capable of forming a casting pool between the cast rolls above the nip with side dams adjacent the ends of 20 the nip to confine said casting pool; c) assembling adjacent the strip caster a hot rolling mill having back-up rolls and work rolls with work surfaces forming a gap between the work rolls through which hot strip is rolled; 25 d) assembling spray nozzles positioned upstream of the work rolls capable of spraying a mixture of water and oil the back-up rolls; e) introducing molten steel between the pair of casting rolls to form a 30 casting pool supported on casting surfaces of the casting rolls confined by said first side dams; WO 2007/095695 PCT/AU2007/000227 -21 f) counter-rotating the casting rolls to form solidified metal shells on the surfaces of the casting rolls and cast steel strip through the nip between the casting rolls from the solidified shells; 5 g) spraying the mixture of oil and water as the cast strip enters the hot rolling mill; and h) rolling the cast strip between the work rolls of the hot rolling mill to produce a cast strip having a surface roughness less than 1.5 microns 10 Ra.

18. The thin cast steel strip with reduced surface roughness below 1.5 microns Ra as claimed in claim 17 where the rate of production of the cast strip in above 80 meters per minute. 15

19 The thin cast steel strip with reduced surface roughness below 1.5 microns Ra as claimed in claim 17 or claim 18 where the rolling temperature is below 1100C.

20 20. The thin cast steel strip with reduced surface roughness as claimed in any one of claims 17 to 19 where the rolling temperature is below 10500 C.

21. The thin cast steel strip with reduced surface roughness as claimed in claim 20 where the rolling temperature is below 9000 C. 25

22. The thin cast steel strip with reduced surface roughness as claimed in any one of claims 17 to 21 where the rate of spray by the nozzles is between 10 and 30 gallons per minute. 30

23. The thin cast steel strip with reduced surface roughness as claimed in any one of claims 17 to 22 where the surface roughness below 0.7 microns Ra. WO 2007/095695 PCT/AU2007/000227 -22

24. The thin cast steel strip with reduced surface roughness as claimed in any one of claims 17 to 23 where the mixture of oil and water is less than 5% oil.

25. The thin cast steel strip with reduced surface roughness below 1.5 5 microns Ra as claimed in any one of claims 17 to 24 where the thin cast steel strip has a surface scale thickness of less than about 7 microns.

26. A method of producing thin cast strip having at least one microstructure selected from the group consisting of polygonal ferrite, acicular ferrite, Widmanstatten, 10 bainite and martinsite, a surface roughness of less than 1.5 microns Ra and a scale thickness of less than about 10 microns, the method comprising the steps of: a) assembling a twin roll caster having laterally positioned caster rolls forming a nip between them and a hot rolling mill having work rolls and 15 back-up rolls adjacent the twin roll caster, b) forming a thin cast strip from the nip between the casting rolls of the twin roll caster, , 20 c) applying a mixture of water and oil on the work rolls of the hot rolling mill, d) passing the thin cast strip at a temperature of less than 11000 C through the hot rolling mill while the mixture of oil and water is applied to the 25 work rolls, and e) shrouding the thin cast strip from the casting rolls through the hot rolling mill in an atmosphere of less than 5 % oxygen forming a thin cast strip having: at least one microstructure. selected from the group consisting of 30 polygonal ferrite, acicular ferrite, Widmanstatten, bainite and martinsite, a surface roughness of less than 1.5 microns Ra, and a scale thickness of less than 10 microns. WO 2007/095695 PCT/AU2007/000227 -23

27. A method of producing a thin cast steel strip with reduced surface roughness below 1.5 microns Ra, the method comprising the steps of: 5 a) assembling a strip caster having a pair of casting rolls having a nip there between; b) assembling a metal delivery system capable of forming a casting pool between the cast rolls above the nip with side dams adjacent the ends of 10 the nip to confine said casting pool; c) assembling adjacent the strip caster a hot rolling mill having work rolls with work surfaces forming a gap between them through which hot strip is rolled; 15 d) assembling spray nozzles positioned adjacent the work rolls capable of providing a mixture of water and oil to the work rolls; e) introducing molten steel between the pair of casting rolls to form a 20 casting pool supported on casting surfaces of the casting rolls confined by said first side dams; f) counter-rotating the casting rolls to form solidified metal shells on the surfaces of the casting rolls and cast steel strip through the nip between 25 the casting rolls from said solidified shells; g) spraying the mixture of oil and water as the strip enters the hot rolling mill; and 30 h) rolling the cast strip between the work rolls of the hot rolling mill to produce a cast strip having a surface roughness less than 1 microns Ra. WO 2007/095695 PCT/AU2007/000227 -24

28. A method of producing a thin cast steel strip with reduced surface roughness below 1.5 microns Ra, the method comprising the steps of: a) assembling a strip caster having a pair of casting rolls having a nip there 5 between; b) assembling a metal delivery system capable of forming a casting pool between the cast rolls above the nip with side dams adjacent the ends of the nip to confine said casting pool; 10 c) assembling adjacent the strip caster a hot rolling mill having back-up rolls and work rolls with work surfaces forming a gap between the work rolls through which hot strip is rolled; 15 d) assembling spray nozzles positioned upstream of the work rolls capable of spraying a mixture of water and oil the back-up rolls; e) introducing molten steel between the pair of casting rolls to form a casting pool supported on casting surfaces of the casting rolls confined 20 by said first side dams; f) counter-rotating the casting rolls to form solidified metal shells on the surfaces of the casting rolls and cast steel strip through the nip between the casting rolls from the solidified shells; 25 g) spraying the mixture of oil and water as the cast strip enters the hot rolling mill; and h) rolling the cast strip between the work rolls of the hot rolling mill to 30 produce a cast strip having a surface roughness less than 1.5 microns Ra.