AU2003280394B2 - Gas flushing device for metallurgical melting pots - Google Patents
Gas flushing device for metallurgical melting pots Download PDFInfo
- Publication number
- AU2003280394B2 AU2003280394B2 AU2003280394A AU2003280394A AU2003280394B2 AU 2003280394 B2 AU2003280394 B2 AU 2003280394B2 AU 2003280394 A AU2003280394 A AU 2003280394A AU 2003280394 A AU2003280394 A AU 2003280394A AU 2003280394 B2 AU2003280394 B2 AU 2003280394B2
- Authority
- AU
- Australia
- Prior art keywords
- gas purging
- receptacle
- gas
- purging device
- brick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 238000002844 melting Methods 0.000 title claims abstract description 12
- 230000008018 melting Effects 0.000 title claims abstract description 12
- 238000011010 flushing procedure Methods 0.000 title abstract description 18
- 239000011214 refractory ceramic Substances 0.000 claims abstract description 4
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 3
- 238000010926 purge Methods 0.000 claims description 68
- 239000011449 brick Substances 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 6
- 238000009434 installation Methods 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 2
- 101100366937 Caenorhabditis elegans sto-4 gene Proteins 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 51
- 238000000034 method Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D1/00—Treatment of fused masses in the ladle or the supply runners before casting
- B22D1/002—Treatment with gases
- B22D1/005—Injection assemblies therefor
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/42—Constructional features of converters
- C21C5/46—Details or accessories
- C21C5/48—Bottoms or tuyéres of converters
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/52—Manufacture of steel in electric furnaces
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
- C22B9/05—Refining by treating with gases, e.g. gas flushing also refining by means of a material generating gas in situ
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B3/00—Hearth-type furnaces, e.g. of reverberatory type; Electric arc furnaces ; Tank furnaces
- F27B3/10—Details, accessories or equipment, e.g. dust-collectors, specially adapted for hearth-type furnaces
- F27B3/22—Arrangements of air or gas supply devices
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/16—Introducing a fluid jet or current into the charge
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/16—Introducing a fluid jet or current into the charge
- F27D2003/161—Introducing a fluid jet or current into the charge through a porous element
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/16—Introducing a fluid jet or current into the charge
- F27D2003/162—Introducing a fluid jet or current into the charge the fluid being an oxidant or a fuel
- F27D2003/163—Introducing a fluid jet or current into the charge the fluid being an oxidant or a fuel the fluid being an oxidant
- F27D2003/164—Oxygen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D3/00—Charging; Discharging; Manipulation of charge
- F27D3/16—Introducing a fluid jet or current into the charge
- F27D2003/167—Introducing a fluid jet or current into the charge the fluid being a neutral gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- General Engineering & Computer Science (AREA)
- Furnace Charging Or Discharging (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Furnace Details (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
Abstract
The invention relates to a gas flushing device for metallurgical melting pots, having the following construction: a porous plug is arranged in an upper cylindrical housing at the gas outlet end thereof and in a lower cylindrical housing on the adjacent section thereof, an annular chamber is provided at least between the lower housing and the porous plug which is filled with a mass, whereby the porous plug, housings and mass are made from a refractory ceramic material.
Description
Verification of Translation Applicant: Refractory Intellectual Property GmbH Co. KG Application No: PCT/EP2003/011575 Lodgement Date: October 18,2003 I, Patent Attorney Dr. Thomas U. Becker, Turmstra8e 22, 40878 Ratingen, Germany declare that the attached English language translation of the specification of International Patent Application PCT/EP2003/011575 is a true and correct translation of the attached copy of that Application in the German language.
Dated: this 17 th day ofay 2005 Signature of Translator: Gas Purging Device for Metallurgical Melting Pots
DESCRIPTION
The invention pertains to a gas purging device for metallurgical melting vessels. Numerous variations of gas purging devices as well as corresponding gas purging elements, particularly gas purging plugs, have been known and used for many years.
Discrete gas purging plugs can be realized with so-called directional or non-directional porosity. "Directional porosity" is achieved, for example, with channels that extend in the flushing element. "Non-directional porosity" can be achieved with a porous refractory material that has corresponding gas permeability.
Gas flushing devices can be installed into a refractory lining of a metallurgical melting vessel that forms a wall or the bottom of the vessel. However, they may also be realized in the bottom or a wall in-situ, for example, as described in EP 0 560 834 BI.
Gas flushing elements primarily serve for conducting gas.
However, a gas flushing device of this type may also conduct gas/solid mixtures in certain instances.
The gases used may be inert gases, for example, when flushing ladles. However, it is also known to flush with oxygen, for example, in electric furnaces.
2 All gas flushing/purging devices are subjected to significant wear, particularly a chemical/corrosive attack. This is the reason why these gas purging devices need to be replaced regularly.
The left part of Figure 1 shows a conventional gas purging device. A so-called gas purging lance L is guided into the bottom region H of an electric furnace from outside, wherein said lance is held on the outer casing A of the vessel with the aid of washers B and mounted by means of a flange.
Subsequently, a well nozzle S is placed over the lance L and a mass is filled between the well nozzle and the lance. The well nozzle S is subsequently walled in with bricks M and the bottom H is then lined with a furnace mass.
Once the gas purging device is worn out (indicated with a broken line in Figure the entire purging device needs to be cleared. This leads to the situation illustrated in the left part of Figure 2. A new gas flushing device is subsequently installed as described above.
This method is very time-consuming and nearly the entire hearth mass of the bottom needs to be cleared, particularly up to the outer casing A.
Consequently, it is an object of the invention to develop a gas purging device that can be replaced faster and cheaper when it is worn out.
3 The invention proposes to separate the parts of the gas purging device that are subject to particular wear, the parts of the gas flushing device that are situated adjacent to the molten metal or the parts situated at the gas outlet end, from the parts arranged upstream thereof, in the direction of the gas inlet end.
When an exchange is required, individual parts of the gas purging device may remain and only the actually worn zones or worn parts are replaced.
According to another aspect, the actual flushing element is realized in a monolithic mass in the section that is situated adjacent to the wall of the melting vessel. This mass simplifies the alignment of the flushing element during the installation of the flusher. This mass can also be cleared and replaced more easily when the flushing device is torn down. The mass may be arranged, in turn, in a permanent receptacle that is not exchanged when the flusher (purging element) is replaced.
According to its most general embodiment, the invention pertains to a gas purging device for metallurgical melting vessels with the following characteristics: -a gas purging brick is arranged in an upper cylindrical receptacle with its end on the gas outlet side and in a lower cylindrical receptacle with its adjacent section, and 4 -an annular space provided at least between the lower receptacle and the gas purging brick is filled with a mass, wherein -the gas purging brick, the receptacles and the mass are made of a refractory ceramic material.
In this context, the term "cylindrical" merely refers to a body that is open on opposite sections and serves for accommodating another body, wherein this term does not imply any other geometric restrictions.
The lower receptacle is not subjected to wear in the normal operating state and can be enclosed with refractory bricks or a refractory mass (hearth mass) that also remains as a permanent lining when a replacement is required. Its serves for receiving a refractory ceramic mass, for example, a ramming mass, which simultaneously serves for adjusting the purging element (gas purging brick) when it is aligned in the lower receptacle and embedded in the mass. The upper cylindrical receptacle is situated adjacent to and practically forms an extension of the lower receptacle (referred to the flow direction of a gas or the direction toward the molten metal). This upper receptacle may have, for example, a circular inside cross section and encloses the purging device in a more or less direct fashion such that it forms a mechanical guide as well as a protection against chemical attacks.
The gas purging element may be arranged in the upper receptacle on the "hot side") flush or with slight clearance. It 5 may be fixed in the upper receptacle by means of an adhesive or mortar.
The gas purging brick usually extends over the entire length (height) of the upper and the lower receptacle. It may also protrude the upper receptacle by a short distance (when mounted). The gas connection and, if applicable, a gas distribution chamber for distributing gas to individual channels or pores are situated on the other end.
The flusher (gas purging element) may have a circular cross section. However, gas flushing elements in the shape of truncated cones or cuboid geometries may also be utilized.
When using a cuboid purging element, the upper receptacle accordingly has a rectangular cross section.
In this context, the term "cylindrical receptacle" should be understood in the form of an enclosure for a certain length of the gas purging element regardless of its inside cross section. The outside cross section may have an arbitrary shape.
At least one receptacle may be realized in the form of a pressed part. Pressed enclosure parts for the flushing element are particularly tight and consequently wearresistant.
The purging element itself can be realized with directed or non-directed porosity. Purging elements with directed porosity are used, in particular, when purging electric furnaces with oxygen. This can be achieved by realizing the purging element with 6 several tubular channels that extend in the axial direction and consist, for example, of small metal or ceramic tubes.
The purging element may be equipped with an additional lance (separate gas supply for purging element and lance) or consist merely of a lance lined with refractory material.
The length of the upper receptacle is determined in dependence on the respective application and the expected wear, namely because only the upper receptacle should be subsequently replaced.
According to one embodiment, the upper receptacle is at least as long as the lower receptacle. However, the upper receptacle may be up to four-times as long as the lower receptacle referred to the axial direction of the flushing element, in the flow direction of the gas. For example, the upper receptacle is two-times to three-times as long as the lower receptacle.
The upper receptacle may have a cross-sectional shape that makes it possible to directly place the upper receptacle on the lower receptacle. However, the upper receptacle may also have a wall thickness that corresponds to the wall thickness of the refractory mass introduced between the flushing element and the lower receptacle as discussed below in the description of the figures.
It usually suffices to realize the upper receptacle with an outside cross section that is smaller than the outside cross section of the lower receptacle. This means that the gas 7 purging device has a stepped cross section as shown in the right part of Figures 1, 2. However, it would also be conceivable to realize embodiments, in which the upper receptacle ends at a certain distance in front of the lower receptacle or protrudes into the lower receptacle.
The described gas purging device can be installed into the bottom or a wall of a metallurgical melting vessel. The term "metallurgical melting vessel" includes all crucibles for melting metal and for treating molten metal, respectively.
The gas purging device consequently is also suitable for installation into the hearth bottom of an electric furnace, for example, an electric arc furnace.
Other characteristics of the invention are disclosed in the dependent claims as well as the remaining application documents. This includes the multi-part design of one or both receptacles.
One embodiment of the invention is described below with reference to the figures that respectively show a schematic section through the embodiment in the right part of Figures 1, 2.
The gas purging device comprises a total of four parts. A lower receptacle 10 is initially inserted during the lining process. This receptacle is a pressed, refractory enclosure of annular shape. Subsequently, a purging brick 12 with directed porosity (channels 20) is inserted via the outer wall A through an opening 14 from below (from outside), 8 and its section 12u is centered in the lower receptacle 10 as well as the region situated thereunder with the aid of a ramming mass. The gas outlet end 12o of the purging element 12 protrudes the lower receptacle 10 and the mass 16, respectively. An upper receptacle 18 that is also realized cylindrically analogous to the lower receptacle 10 is then placed over the upper section 12o of the gas purging element, wherein the upper receptacle has an inside cross section that corresponds to the outside cross section of the gas purging element 12. The upper receptacle 18 is aligned with the annular channel, filled with the mass 16, between the lower receptacle 10 and the purging element 12. The upper receptacle 18 is twice as long as the lower receptacle The hearth mass H is ultimately introduced and the hearth bottom is formed.
In an alternative variation of the embodiment shown, the region underneath the lower receptacle 10 may also be equipped with mounting elements B analogous to the state of the art, for example, washers (as illustrated in the left part of Figures 1, 2) in order to fix the purging elements 12 on the outer wall A of the melting vessel.
The time required for lining the gas purging device shown in Figures 1, 2 is approximately one hour.
The time required for a lining process in accordance with the state of the art that is illustrated in the left part of Figures 1, 2 is approximately 2.5 hours. Another advantage of the gas flushing device according to the invention can be seen in the fact that the lower receptacle 10 can remain when 9
IND
(0 a replacement is required (Figure In addition, the zones of the hearth mass H that are situated adjacent to the 0 Z outer wall A can be largely preserved such that the required h quantity of new hearth mass is reduced.
With reference to the use of the word(s) "comprise" or "comprises" or "comprising" in the foregoing description and/or in the following claims, unless the context requires 0O otherwise, those words are used on the basis and clear understanding that they are to be interpreted inclusively, CI rather than exclusively, and that each of those words is to be so interpreted in construing the foregoing description and/or the following claims.
Claims (10)
1.1 a gas purging brick (12) is arranged in an upper cylindrical receptacle (18) with its end (12o) on Sthe gas outlet side and in a lower cylindrical 00 receptacle (10) with its adjacent section (12u), (1 1.2 the upper receptacle (18) has an outside cross section that is larger than the inside cross section of the lower receptacle 1.3 an annular space provided at least between the lower receptacle (10) and the gas purging brick (12) is filled with a mass wherein 1.4 the gas purging brick the receptacles 18) and the mass (16) are made of a refractory ceramic material, the gas purging brick (12) is arranged in the upper receptacle (18) flush or with slight clearance.
2. The gas purging device according to Claim 1, wherein the gas purging brick (12) extends over the entire height of the lower and the upper receptacle (10, 18).
3. The gas purging device according to Claim 1 or 2, wherein the gas purging brick (12) has a circular cross section. 11 \O IND
4. The gas purging device according to any one of Claims 1 to 3, wherein at least one receptacle (10, 18) is 0 Z realized in the form of a pressed part. The gas purging device according to any one of Claims 1 to 4, wherein the gas purging brick (12) has a directed porosity. 00 (N 6. The gas purging device according to any one of Claims 1 Sto 4, wherein the gas purging brick (12) comprises (N several small metal or ceramic tubes (20) that extend in the axial direction and serve for achieving a directed porosity.
7. The gas purging device according to any one of Claims 1 to 6, wherein the upper receptacle (18) is at least as long as the lower receptacle
8. The gas purging device according to any one of Claims 1 to 6, wherein the upper receptacle (18) is l.l-times to as long as the lower receptacle
9. The gas purging device according to any one of Claims 1 to 6, wherein the upper receptacle (18) is 2-times to 3-times as long as the lower receptacle The gas purging device according to any one of Claims 1 to 9, wherein the upper receptacle (18) lies on the lower receptacle
11. The gas purging device according to any one of Claims 1 to 9, wherein the upper receptacle (18) protrudes into the lower receptacle 12 \O IND C-i 12. The gas purging device according to any one of Claims 1 to 11, wherein the upper receptacle (18) has an outside 0 Z cross section that is smaller than the outside cross section of the lower receptacle
13. The gas purging device according to any one of Claims 1 to 12, wherein the mass (16) is a ramming mass. 00 C- 14. The gas purging device according to any one of Claims 1 O to 13, wherein at least one of the receptacles (10, 18) C-i comprises more than one part. Use of a gas purging device according to any one of Claims 1-14 for installation in the bottom of a metallurgical melting vessel.
16. Use of a gas purging device according to any one of Claims 1-14 for installation in the hearth bottom (H) of an electric furnace. BA. 5801
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10259434A DE10259434B3 (en) | 2002-12-19 | 2002-12-19 | Gas purging device for metallurgical melting vessels |
| DE10259434.1 | 2002-12-19 | ||
| PCT/EP2003/011575 WO2004056505A1 (en) | 2002-12-19 | 2003-10-18 | Gas flushing device for metallurgical melting pots |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2003280394A1 AU2003280394A1 (en) | 2004-07-14 |
| AU2003280394B2 true AU2003280394B2 (en) | 2006-12-14 |
Family
ID=32667510
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2003280394A Ceased AU2003280394B2 (en) | 2002-12-19 | 2003-10-18 | Gas flushing device for metallurgical melting pots |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20060119019A1 (en) |
| EP (1) | EP1572398B1 (en) |
| KR (1) | KR20050084405A (en) |
| CN (1) | CN1315596C (en) |
| AT (1) | ATE338599T1 (en) |
| AU (1) | AU2003280394B2 (en) |
| CA (1) | CA2509137A1 (en) |
| DE (2) | DE10259434B3 (en) |
| EG (1) | EG23558A (en) |
| MX (1) | MXPA05006706A (en) |
| PL (1) | PL377817A1 (en) |
| WO (1) | WO2004056505A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1656464B1 (en) * | 2003-08-23 | 2007-01-03 | Refractory Intellectual Property GmbH & Co. KG | Method for the pyrometallurgical production of copper in a converter |
| EP2845667B1 (en) * | 2013-09-10 | 2015-09-02 | Refractory Intellectual Property GmbH & Co. KG | Ladle bottom and ladle |
| ES2572686T3 (en) * | 2014-05-05 | 2016-06-01 | Refractory Intellectual Property Gmbh & Co. Kg | Refractory ceramic element with gas scanning |
| EP3023173B9 (en) * | 2014-09-29 | 2018-12-12 | Refractory Intellectual Property GmbH & Co. KG | Attachment device for a cylindrical ceramic hollow body and fireproof ceramic gas purging plug with such an attachment device |
| WO2023028283A1 (en) * | 2021-08-27 | 2023-03-02 | J.H. Fletcher & Co. | System and method for porous plug removal and installation |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6033163B2 (en) * | 1980-10-30 | 1985-08-01 | 新日本製鐵株式会社 | Converter bottom blowing tuyere hot exchange method |
| AU541441B2 (en) * | 1981-07-15 | 1985-01-10 | Nippon Steel Corporation | Bottom blowing nozzle embedded in a refractory block |
| IN168760B (en) * | 1987-04-10 | 1991-06-01 | Injectall Ltd | |
| DE3727938C1 (en) * | 1987-08-21 | 1988-09-08 | Didier Werke Ag | Dish stone |
| DE3833502A1 (en) * | 1988-10-01 | 1990-04-05 | Didier Werke Ag | GASSPUELSTEIN |
| FR2644566B1 (en) * | 1989-03-15 | 1991-06-21 | Air Liquide | ELECTRIC ARC FURNACE AND SCRAP MELTING METHOD |
| SK55393A3 (en) * | 1990-12-07 | 1993-09-08 | Veitsch Radex Ag | Creation of a bottom or a wall of ametallurgical tank |
-
2002
- 2002-12-19 DE DE10259434A patent/DE10259434B3/en not_active Expired - Fee Related
-
2003
- 2003-10-18 EP EP03772236A patent/EP1572398B1/en not_active Expired - Lifetime
- 2003-10-18 DE DE50304988T patent/DE50304988D1/en not_active Expired - Lifetime
- 2003-10-18 MX MXPA05006706A patent/MXPA05006706A/en not_active Application Discontinuation
- 2003-10-18 CN CNB2003801069038A patent/CN1315596C/en not_active Expired - Fee Related
- 2003-10-18 AT AT03772236T patent/ATE338599T1/en not_active IP Right Cessation
- 2003-10-18 AU AU2003280394A patent/AU2003280394B2/en not_active Ceased
- 2003-10-18 US US10/540,164 patent/US20060119019A1/en not_active Abandoned
- 2003-10-18 CA CA002509137A patent/CA2509137A1/en not_active Abandoned
- 2003-10-18 WO PCT/EP2003/011575 patent/WO2004056505A1/en not_active Ceased
- 2003-10-18 KR KR1020057011302A patent/KR20050084405A/en not_active Ceased
- 2003-10-18 PL PL377817A patent/PL377817A1/en not_active Application Discontinuation
- 2003-12-17 EG EG2003121091A patent/EG23558A/en active
Also Published As
| Publication number | Publication date |
|---|---|
| EG23558A (en) | 2006-06-05 |
| KR20050084405A (en) | 2005-08-26 |
| CN1729067A (en) | 2006-02-01 |
| CA2509137A1 (en) | 2005-06-08 |
| PL377817A1 (en) | 2006-02-20 |
| DE10259434B3 (en) | 2004-08-26 |
| MXPA05006706A (en) | 2005-09-08 |
| EP1572398B1 (en) | 2006-09-06 |
| WO2004056505A1 (en) | 2004-07-08 |
| EP1572398A1 (en) | 2005-09-14 |
| US20060119019A1 (en) | 2006-06-08 |
| DE50304988D1 (en) | 2006-10-19 |
| CN1315596C (en) | 2007-05-16 |
| ATE338599T1 (en) | 2006-09-15 |
| AU2003280394A1 (en) | 2004-07-14 |
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