AU2002216953A1 - Method for electroless nickel plating - Google Patents
Method for electroless nickel platingInfo
- Publication number
- AU2002216953A1 AU2002216953A1 AU2002216953A AU1695302A AU2002216953A1 AU 2002216953 A1 AU2002216953 A1 AU 2002216953A1 AU 2002216953 A AU2002216953 A AU 2002216953A AU 1695302 A AU1695302 A AU 1695302A AU 2002216953 A1 AU2002216953 A1 AU 2002216953A1
- Authority
- AU
- Australia
- Prior art keywords
- substrates
- nickel plating
- electroless nickel
- treated
- electroless
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title abstract 8
- 229910052759 nickel Inorganic materials 0.000 title abstract 4
- 238000007747 plating Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 239000000758 substrate Substances 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- 230000003213 activating effect Effects 0.000 abstract 1
- UORVGPXVDQYIDP-BJUDXGSMSA-N borane Chemical class [10BH3] UORVGPXVDQYIDP-BJUDXGSMSA-N 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000084 colloidal system Substances 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000005554 pickling Methods 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 239000004332 silver Substances 0.000 abstract 1
- 150000003606 tin compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1803—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces
- C23C18/1824—Pretreatment of the material to be coated of metallic material surfaces or of a non-specific material surfaces by chemical pretreatment
- C23C18/1837—Multistep pretreatment
- C23C18/1844—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1851—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
- C23C18/1872—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment
- C23C18/1886—Multistep pretreatment
- C23C18/1893—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/2006—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30
- C23C18/2046—Pretreatment of the material to be coated of organic surfaces, e.g. resins by other methods than those of C23C18/22 - C23C18/30 by chemical pretreatment
- C23C18/2073—Multistep pretreatment
- C23C18/2086—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/28—Sensitising or activating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/48—Coating with alloys
- C23C18/50—Coating with alloys with alloys based on iron, cobalt or nickel
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemically Coating (AREA)
- Catalysts (AREA)
Abstract
A method for electroless metal plating of substrates, more specifically with electrically non-conductive surfaces, by which the substrates may be reliably metal plated at low cost under manufacturing conditions as well and by means of which it is possible to selectively coat the substrates to be treated only, and not the surfaces of the racks. The method involves the following steps: a. pickling the surfaces with a solution containing chromate ions; b. activating the pickled surfaces with a silver colloid containing stannous ions; c. treating the activated surfaces with an accelerating solution in order to remove tin compounds from the surfaces; and d. depositing, by means of an electroless nickel plating bath, a layer that substantially consists of nickel to the surfaces treated with the accelerating solution, the electroless nickel plating bath containing at least one reducing agent selected from the group comprising borane compounds.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10054544A DE10054544A1 (en) | 2000-11-01 | 2000-11-01 | Process for the chemical metallization of surfaces |
| DE10054544 | 2000-11-01 | ||
| PCT/EP2001/011468 WO2002036853A1 (en) | 2000-11-01 | 2001-10-04 | Method for electroless nickel plating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2002216953A1 true AU2002216953A1 (en) | 2002-05-15 |
Family
ID=7662047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002216953A Abandoned AU2002216953A1 (en) | 2000-11-01 | 2001-10-04 | Method for electroless nickel plating |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US6902765B2 (en) |
| EP (1) | EP1343921B1 (en) |
| JP (1) | JP3929399B2 (en) |
| CN (1) | CN1314835C (en) |
| AT (1) | ATE291106T1 (en) |
| AU (1) | AU2002216953A1 (en) |
| CA (1) | CA2425575A1 (en) |
| DE (2) | DE10054544A1 (en) |
| ES (1) | ES2237615T3 (en) |
| TW (1) | TWI253481B (en) |
| WO (1) | WO2002036853A1 (en) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4143385B2 (en) * | 2002-03-05 | 2008-09-03 | 株式会社大和化成研究所 | Pretreatment liquid for imparting catalyst for electroless plating, pretreatment method using the liquid, electroless plating film and / or plating coating produced using the method |
| JP3881614B2 (en) * | 2002-05-20 | 2007-02-14 | 株式会社大和化成研究所 | Circuit pattern forming method |
| US7166152B2 (en) * | 2002-08-23 | 2007-01-23 | Daiwa Fine Chemicals Co., Ltd. | Pretreatment solution for providing catalyst for electroless plating, pretreatment method using the solution, and electroless plated film and/or plated object produced by use of the method |
| US7407689B2 (en) | 2003-06-26 | 2008-08-05 | Atotech Deutschland Gmbh | Aqueous acidic immersion plating solutions and methods for plating on aluminum and aluminum alloys |
| US20050274445A1 (en) * | 2004-06-01 | 2005-12-15 | Paul Chang | Method for manufacturing decoration of imitation metal |
| US7410899B2 (en) * | 2005-09-20 | 2008-08-12 | Enthone, Inc. | Defectivity and process control of electroless deposition in microelectronics applications |
| DE102005051632B4 (en) | 2005-10-28 | 2009-02-19 | Enthone Inc., West Haven | Process for pickling non-conductive substrate surfaces and for metallizing plastic surfaces |
| US7297373B2 (en) * | 2005-11-18 | 2007-11-20 | Noble Fiber Technologies, Llc | Conductive composites |
| KR100717909B1 (en) * | 2006-02-24 | 2007-05-14 | 삼성전기주식회사 | A substrate comprising a nickel layer and a method of manufacturing the same |
| US20070235876A1 (en) * | 2006-03-30 | 2007-10-11 | Michael Goldstein | Method of forming an atomic layer thin film out of the liquid phase |
| US8193087B2 (en) * | 2006-05-18 | 2012-06-05 | Taiwan Semiconductor Manufacturing Co., Ltd. | Process for improving copper line cap formation |
| US20080003366A1 (en) * | 2006-06-30 | 2008-01-03 | Dubin Valery M | Method of forming a conducting layer on a conducting and non-conducting substrate |
| US20080175986A1 (en) * | 2007-01-24 | 2008-07-24 | Kenneth Crouse | Second surface metallization |
| KR101058635B1 (en) * | 2008-12-23 | 2011-08-22 | 와이엠티 주식회사 | Electroless Nickel Plating Solution Composition, Flexible Printed Circuit Board and Manufacturing Method Thereof |
| WO2011003116A2 (en) * | 2009-07-03 | 2011-01-06 | Enthone Inc. | Beta-amino acid comprising electrolyte and method for the deposition of a metal layer |
| EP2270255A1 (en) * | 2009-07-03 | 2011-01-05 | Enthone, Inc. | Beta-amino acid comprising electrolyte and method for the deposition of a metal layer |
| FR2958944B1 (en) | 2010-04-19 | 2014-11-28 | Pegastech | METHOD FOR COATING A SURFACE OF A SUBSTRATE OF NON-METALLIC MATERIAL WITH A METAL LAYER |
| SG188351A1 (en) * | 2010-09-03 | 2013-04-30 | Omg Electronic Chemicals Llc | Electroless nickel alloy plating bath and process for depositing thereof |
| US20120126181A1 (en) * | 2010-11-22 | 2012-05-24 | Whitcomb David R | Nanowire preparation methods, compositions, and articles |
| US9327348B2 (en) | 2010-11-22 | 2016-05-03 | Junping Zhang | Nanowire preparation methods, compositions, and articles |
| US8613888B2 (en) | 2010-11-23 | 2013-12-24 | Carestream Health, Inc. | Nanowire preparation methods, compositions, and articles |
| DE102011000138A1 (en) | 2011-01-14 | 2012-07-19 | Lpkf Laser & Electronics Ag | Method for the selective metallization of a substrate and a circuit carrier produced by this method |
| US20130084395A1 (en) * | 2011-09-29 | 2013-04-04 | Roshan V. Chapaneri | Treatment of Plastic Surfaces After Etching in Nitric Acid Containing Media |
| EP2610365B1 (en) * | 2011-12-31 | 2020-02-26 | Rohm and Haas Electronic Materials LLC | Electroless plating method |
| US20130209689A1 (en) * | 2012-02-15 | 2013-08-15 | Mark Wojtaszek | Sulfonation of Plastic and Composite Materials |
| EP2657367B1 (en) | 2012-04-24 | 2015-11-25 | Enthone Inc. | Pre-etching composition and etching process for plastic substrates |
| LT6070B (en) * | 2012-12-07 | 2014-09-25 | Atotech Deutschland Gmbh | Preparation of plastic surface for chemical metallization process |
| DE102012112550A1 (en) | 2012-12-18 | 2014-06-18 | Lpkf Laser & Electronics Ag | Method for metallizing a workpiece and a layer structure of a workpiece and a metal layer |
| CN107923043A (en) | 2015-07-30 | 2018-04-17 | 巴斯夫欧洲公司 | By the method for metallization of plastic surface |
| JP6865734B2 (en) | 2015-07-30 | 2021-04-28 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | Pretreatment method for plastic surface for plating |
| US10772218B2 (en) * | 2017-10-03 | 2020-09-08 | The University Of Western Ontario | React-on-demand (ROD) fabrication method for high performance printed electronics |
| CZ308348B6 (en) | 2018-11-06 | 2020-06-10 | Bochemie A.S. | Process for continuously metallizing a textile material, the apparatus for carrying out the process, metallized textile material and its use |
| JP7360155B2 (en) * | 2019-11-18 | 2023-10-12 | 奥野製薬工業株式会社 | Electroless nickel plating film and pretreatment method for forming the electroless nickel plating film |
| CN118085377A (en) * | 2024-01-31 | 2024-05-28 | 中山美力特环保科技有限公司 | Nylon surface regulator and surface regulating method and application thereof |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE292869C (en) | ||||
| US3011920A (en) | 1959-06-08 | 1961-12-05 | Shipley Co | Method of electroless deposition on a substrate and catalyst solution therefor |
| US4035227A (en) * | 1973-09-21 | 1977-07-12 | Oxy Metal Industries Corporation | Method for treating plastic substrates prior to plating |
| US4355083A (en) * | 1977-06-06 | 1982-10-19 | Nathan Feldstein | Electrolessly metallized silver coated article |
| IT1107840B (en) * | 1978-07-25 | 1985-12-02 | Alfachimici Spa | CATALYTIC SOLUTION FOR ANELECTRIC METAL DEPOSITION |
| US4204013A (en) * | 1978-10-20 | 1980-05-20 | Oxy Metal Industries Corporation | Method for treating polymeric substrates prior to plating employing accelerating composition containing an alkyl amine |
| US4582729A (en) * | 1983-06-30 | 1986-04-15 | Learonal, Inc. | Process for electro-magnetic interference shielding |
| DE3523957A1 (en) * | 1985-07-04 | 1987-01-08 | Licentia Gmbh | METHOD OF METALIZING CERAMICS |
| JPS62205284A (en) * | 1986-03-06 | 1987-09-09 | Nippon Mining Co Ltd | Catalytic solution for electroless plating |
| NO304746B1 (en) * | 1989-05-04 | 1999-02-08 | Ad Tech Holdings Ltd | Object that resists microbiological growth consisting of a non-conductive substrate coated with a funnel coated with a method of depositing |
| CA2119050C (en) | 1993-03-18 | 1999-11-23 | Nayan H. Joshi | Self accelerating and replenishing non-formaldehyde immersion coating method and composition |
| JP2737599B2 (en) * | 1993-04-27 | 1998-04-08 | 上村工業株式会社 | Electroless plating method on copper circuit pattern of printed wiring board |
| US5935706A (en) * | 1996-05-30 | 1999-08-10 | E. I. Dupont De Nemours & Comp | Thermally stable metal coated polymeric monofilament or yarn |
| JP3826544B2 (en) * | 1998-02-27 | 2006-09-27 | 奥野製薬工業株式会社 | Catalyst composition for electroless plating |
| JPH11335858A (en) * | 1998-05-27 | 1999-12-07 | Yuji Shikamata | Formation of silver plating surface and solution used therefor |
-
2000
- 2000-11-01 DE DE10054544A patent/DE10054544A1/en not_active Ceased
-
2001
- 2001-10-04 EP EP01992803A patent/EP1343921B1/en not_active Expired - Lifetime
- 2001-10-04 DE DE60109486T patent/DE60109486T2/en not_active Expired - Lifetime
- 2001-10-04 AT AT01992803T patent/ATE291106T1/en active
- 2001-10-04 WO PCT/EP2001/011468 patent/WO2002036853A1/en not_active Ceased
- 2001-10-04 CA CA002425575A patent/CA2425575A1/en not_active Abandoned
- 2001-10-04 US US10/415,585 patent/US6902765B2/en not_active Expired - Fee Related
- 2001-10-04 JP JP2002539589A patent/JP3929399B2/en not_active Expired - Fee Related
- 2001-10-04 ES ES01992803T patent/ES2237615T3/en not_active Expired - Lifetime
- 2001-10-04 CN CNB018183484A patent/CN1314835C/en not_active Expired - Fee Related
- 2001-10-04 AU AU2002216953A patent/AU2002216953A1/en not_active Abandoned
- 2001-10-11 TW TW090125100A patent/TWI253481B/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1343921B1 (en) | 2005-03-16 |
| US6902765B2 (en) | 2005-06-07 |
| DE60109486T2 (en) | 2006-04-06 |
| ES2237615T3 (en) | 2005-08-01 |
| ATE291106T1 (en) | 2005-04-15 |
| CN1314835C (en) | 2007-05-09 |
| JP3929399B2 (en) | 2007-06-13 |
| CN1473207A (en) | 2004-02-04 |
| US20040086646A1 (en) | 2004-05-06 |
| TWI253481B (en) | 2006-04-21 |
| DE10054544A1 (en) | 2002-05-08 |
| WO2002036853A1 (en) | 2002-05-10 |
| JP2004513229A (en) | 2004-04-30 |
| DE60109486D1 (en) | 2005-04-21 |
| EP1343921A1 (en) | 2003-09-17 |
| CA2425575A1 (en) | 2002-05-10 |
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