AU2002213917A1 - Method for the dehydrogenation of hydrocarbons - Google Patents
Method for the dehydrogenation of hydrocarbonsInfo
- Publication number
- AU2002213917A1 AU2002213917A1 AU2002213917A AU1391702A AU2002213917A1 AU 2002213917 A1 AU2002213917 A1 AU 2002213917A1 AU 2002213917 A AU2002213917 A AU 2002213917A AU 1391702 A AU1391702 A AU 1391702A AU 2002213917 A1 AU2002213917 A1 AU 2002213917A1
- Authority
- AU
- Australia
- Prior art keywords
- hydrocarbons
- sub
- dehydrogenation
- gas mixture
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229930195733 hydrocarbon Natural products 0.000 title abstract 5
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 5
- 238000006356 dehydrogenation reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract 3
- 239000012495 reaction gas Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/324—Catalytic processes with metals
- C07C5/325—Catalytic processes with metals of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
- B01J38/14—Treating with free oxygen-containing gas with control of oxygen content in oxidation gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
In a process for the heterogeneously catalyzed dehydrogenation in one or more reaction zones of one or more dehydrogenatable C<SUB>2</SUB>-C<SUB>30</SUB>-hydrocarbons in a reaction gas mixture comprising them, with at least part of the heat of dehydrogenation required being generated directly in the reaction gas mixture in at least one reaction zone by combustion of hydrogen, the hydrocarbon or hydrocarbons and/or carbon in the presence of an oxygen-containing gas, the reaction gas mixture comprising the dehydrogenatable hydrocarbon or hydrocarbons is brought into contact with a Lewis-acid dehydrogenation catalyst which has essentially no Brönsted acidity.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10047642A DE10047642A1 (en) | 2000-09-26 | 2000-09-26 | Process for the dehydrogenation of hydrocarbons |
| DE10047642 | 2000-09-26 | ||
| PCT/EP2001/010673 WO2002026668A1 (en) | 2000-09-26 | 2001-09-14 | Method for the dehydrogenation of hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2002213917A1 true AU2002213917A1 (en) | 2002-04-08 |
Family
ID=7657671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2002213917A Abandoned AU2002213917A1 (en) | 2000-09-26 | 2001-09-14 | Method for the dehydrogenation of hydrocarbons |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US7087802B2 (en) |
| EP (1) | EP1322578B1 (en) |
| JP (1) | JP4846183B2 (en) |
| KR (1) | KR100770496B1 (en) |
| CN (1) | CN1220659C (en) |
| AT (1) | ATE319670T1 (en) |
| AU (1) | AU2002213917A1 (en) |
| BR (1) | BR0114116A (en) |
| CZ (1) | CZ2003875A3 (en) |
| DE (2) | DE10047642A1 (en) |
| DK (1) | DK1322578T3 (en) |
| EA (1) | EA004599B1 (en) |
| ES (1) | ES2257451T3 (en) |
| MY (1) | MY128587A (en) |
| NO (1) | NO20031351L (en) |
| SA (1) | SA01220388B1 (en) |
| TW (1) | TWI286131B (en) |
| WO (1) | WO2002026668A1 (en) |
| ZA (1) | ZA200302305B (en) |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10211275A1 (en) | 2002-03-13 | 2003-09-25 | Basf Ag | Process of continuous heterogeneously catalyzed partial dehydrogenation |
| DE10206845A1 (en) * | 2002-02-19 | 2003-08-28 | Basf Ag | Surfactant alcohols and their ethers are obtained by a modified process involving metathesis of an olefin mixture, followed by dimerization and derivatization |
| DE10333755A1 (en) * | 2003-07-24 | 2005-03-31 | Basf Ag | Process for the dehydrogenation of carbonyl compounds |
| US7767191B2 (en) * | 2003-12-11 | 2010-08-03 | The Ohio State University | Combustion looping using composite oxygen carriers |
| TWI314876B (en) * | 2004-11-18 | 2009-09-21 | Rohm And Haas Compan | Multi-staged catalyst systems and process for converting alkanes to alkenes and to their corresponding oxygenated products |
| DE102005053233A1 (en) * | 2005-11-06 | 2007-05-10 | Basf Ag | Process for aromatizing non-aromatic hydrocarbons with water vapor |
| WO2007082790A1 (en) * | 2006-01-13 | 2007-07-26 | Basf Aktiengesellschaft | Process for regenerating a dehydrogenation catalyst |
| DE102007006647A1 (en) | 2007-02-06 | 2008-08-07 | Basf Se | Process for the regeneration of a catalyst bed deactivated in the context of a heterogeneously catalyzed partial dehydrogenation of a hydrocarbon |
| EP2143701B1 (en) * | 2008-07-10 | 2011-03-02 | Rohm and Haas Company | Hybrid autothermal catalytic process for converting alkanes to alkenes and catalysts useful for same |
| CA2737946C (en) * | 2008-09-26 | 2016-11-15 | The Ohio State University | Conversion of carbonaceous fuels into carbon free energy carriers |
| US9091433B2 (en) | 2009-05-20 | 2015-07-28 | Basf Se | Monolith catalyst and use thereof |
| AU2010292310B2 (en) | 2009-09-08 | 2017-01-12 | The Ohio State University Research Foundation | Synthetic fuels and chemicals production with in-situ CO2 capture |
| US9371227B2 (en) | 2009-09-08 | 2016-06-21 | Ohio State Innovation Foundation | Integration of reforming/water splitting and electrochemical systems for power generation with integrated carbon capture |
| US8293670B2 (en) * | 2009-12-09 | 2012-10-23 | Uop Llc | Process for the production of propylene |
| CN102219632B (en) * | 2010-04-15 | 2013-12-25 | 中国石油化工股份有限公司 | Method for selective oxidation of hydrogen during propane dehydrogenation |
| CN102219631B (en) * | 2010-04-15 | 2013-12-25 | 中国石油化工股份有限公司 | Method for selectively oxidizing and catalyzing hydrogen in propane dehydrogenation process |
| CN103228354B (en) * | 2010-10-05 | 2015-08-12 | 太平洋工业发展公司 | The catalyst carrier material of sulfur resistive |
| EP2637777A1 (en) | 2010-11-08 | 2013-09-18 | The Ohio State University | Circulating fluidized bed with moving bed downcomers and gas sealing between reactors |
| EP2707350A4 (en) | 2011-05-11 | 2015-12-23 | Ohio State Innovation Foundation | SYSTEMS FOR CONVERTING A FUEL |
| EP2707583B1 (en) | 2011-05-11 | 2019-07-10 | Ohio State Innovation Foundation | Oxygen carrying materials |
| EP2739386B1 (en) * | 2011-08-02 | 2015-06-10 | Basf Se | Method for carrying out catalytic autothermal gas phase dehydrogenation in production and regeneration modes |
| CN102389810A (en) * | 2011-09-28 | 2012-03-28 | 海尔集团公司 | Formaldehyde oxidation catalyst |
| CN103030496B (en) * | 2011-09-29 | 2015-02-11 | 中国石油化工股份有限公司 | Method of selective oxidation of hydrogen in propane dehydrogenation process |
| CN103028400B (en) * | 2011-09-30 | 2015-06-10 | 中国石油化工股份有限公司 | Selective oxidation catalyst and preparation method thereof |
| US20130158327A1 (en) * | 2011-12-16 | 2013-06-20 | Uop Llc | Hydrocarbon dehydrogenation with inert diluent |
| US20130296585A1 (en) | 2012-03-30 | 2013-11-07 | Basf Corporation | Catalyst For Tetrahydrofuran Synthesis |
| CN103483123B (en) * | 2012-06-08 | 2015-05-13 | 中国石油化工股份有限公司 | Method of preparing butadiene from normal alkane |
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| US9616403B2 (en) | 2013-03-14 | 2017-04-11 | Ohio State Innovation Foundation | Systems and methods for converting carbonaceous fuels |
| US9963407B2 (en) | 2013-06-18 | 2018-05-08 | Uop Llc | Fluidized catalyst circulation reactor for paraffin oxydative dehydrogenation |
| CN103521209A (en) * | 2013-10-11 | 2014-01-22 | 中国海洋石油总公司 | Preparation method of catalyst for synthesis of pyridine |
| US9701913B2 (en) * | 2013-12-17 | 2017-07-11 | Uop Llc | Fluid catalytic cracking process including adsorption of hydrogen and a catalyst for the process |
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| IT1254988B (en) * | 1992-06-23 | 1995-10-11 | Eniricerche Spa | Process for the dehydrogenation of light paraffins in a fluidised bed reactor |
| NO179131C (en) | 1993-06-14 | 1996-08-14 | Statoil As | Catalyst, process for its preparation and process for dehydrogenation of light paraffins |
| US5530171A (en) | 1993-08-27 | 1996-06-25 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
| US5527979A (en) | 1993-08-27 | 1996-06-18 | Mobil Oil Corporation | Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen |
| IT1286045B1 (en) | 1996-10-25 | 1998-07-07 | Lucchini Centro Ricerche E Svi | IMPROVED RESOLFORATED FINE AUSTENITIC GRAIN STEEL AND RELATED PROCEDURE TO OBTAIN IT |
| DE19654391A1 (en) * | 1996-12-27 | 1998-07-02 | Basf Ag | Catalyst for the selective production of propylene from propane |
| DE19756292C2 (en) * | 1997-12-10 | 1999-10-28 | Mannesmann Ag | Catalyst for the conversion of paraffinic hydrocarbons into corresponding olefins |
| DE19937106A1 (en) * | 1999-08-06 | 2001-02-08 | Basf Ag | Multicomponent catalysts |
-
2000
- 2000-09-26 DE DE10047642A patent/DE10047642A1/en not_active Withdrawn
-
2001
- 2001-09-03 TW TW090121751A patent/TWI286131B/en active
- 2001-09-08 MY MYPI20014231A patent/MY128587A/en unknown
- 2001-09-14 DK DK01982292T patent/DK1322578T3/en active
- 2001-09-14 AU AU2002213917A patent/AU2002213917A1/en not_active Abandoned
- 2001-09-14 CZ CZ2003875A patent/CZ2003875A3/en unknown
- 2001-09-14 JP JP2002531057A patent/JP4846183B2/en not_active Expired - Fee Related
- 2001-09-14 BR BR0114116-3A patent/BR0114116A/en not_active Application Discontinuation
- 2001-09-14 EA EA200300404A patent/EA004599B1/en not_active IP Right Cessation
- 2001-09-14 EP EP01982292A patent/EP1322578B1/en not_active Expired - Lifetime
- 2001-09-14 ES ES01982292T patent/ES2257451T3/en not_active Expired - Lifetime
- 2001-09-14 US US10/380,552 patent/US7087802B2/en not_active Expired - Lifetime
- 2001-09-14 WO PCT/EP2001/010673 patent/WO2002026668A1/en not_active Ceased
- 2001-09-14 KR KR1020037004288A patent/KR100770496B1/en not_active Expired - Fee Related
- 2001-09-14 AT AT01982292T patent/ATE319670T1/en not_active IP Right Cessation
- 2001-09-14 CN CNB018163394A patent/CN1220659C/en not_active Expired - Fee Related
- 2001-09-14 DE DE50109177T patent/DE50109177D1/en not_active Expired - Lifetime
- 2001-09-25 SA SA01220388A patent/SA01220388B1/en unknown
-
2003
- 2003-03-25 ZA ZA200302305A patent/ZA200302305B/en unknown
- 2003-03-25 NO NO20031351A patent/NO20031351L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200302305B (en) | 2004-07-05 |
| CN1220659C (en) | 2005-09-28 |
| DE50109177D1 (en) | 2006-05-04 |
| JP2004509936A (en) | 2004-04-02 |
| JP4846183B2 (en) | 2011-12-28 |
| ES2257451T3 (en) | 2006-08-01 |
| KR20030036833A (en) | 2003-05-09 |
| WO2002026668A1 (en) | 2002-04-04 |
| ATE319670T1 (en) | 2006-03-15 |
| KR100770496B1 (en) | 2007-10-25 |
| SA01220388B1 (en) | 2006-11-14 |
| NO20031351D0 (en) | 2003-03-25 |
| TWI286131B (en) | 2007-09-01 |
| EP1322578A1 (en) | 2003-07-02 |
| CZ2003875A3 (en) | 2003-10-15 |
| BR0114116A (en) | 2003-07-29 |
| CN1466558A (en) | 2004-01-07 |
| US20040030214A1 (en) | 2004-02-12 |
| DK1322578T3 (en) | 2006-05-29 |
| DE10047642A1 (en) | 2002-04-11 |
| NO20031351L (en) | 2003-03-25 |
| US7087802B2 (en) | 2006-08-08 |
| EA004599B1 (en) | 2004-06-24 |
| MY128587A (en) | 2007-02-28 |
| EA200300404A1 (en) | 2003-10-30 |
| EP1322578B1 (en) | 2006-03-08 |
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