AU2001288738A1 - Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors - Google Patents
Highly active metathesis catalysts generated in situ from inexpensive and air stable precursorsInfo
- Publication number
- AU2001288738A1 AU2001288738A1 AU2001288738A AU8873801A AU2001288738A1 AU 2001288738 A1 AU2001288738 A1 AU 2001288738A1 AU 2001288738 A AU2001288738 A AU 2001288738A AU 8873801 A AU8873801 A AU 8873801A AU 2001288738 A1 AU2001288738 A1 AU 2001288738A1
- Authority
- AU
- Australia
- Prior art keywords
- situ
- inexpensive
- highly active
- metathesis catalysts
- air stable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003054 catalyst Substances 0.000 title 1
- 238000011065 in-situ storage Methods 0.000 title 1
- 238000005649 metathesis reaction Methods 0.000 title 1
- 239000002243 precursor Substances 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2269—Heterocyclic carbenes
- B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
- C07C6/06—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/002—Osmium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/462—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/466—Osmium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US23054700P | 2000-09-05 | 2000-09-05 | |
| US60230547 | 2000-09-05 | ||
| US27831101P | 2001-03-23 | 2001-03-23 | |
| US60278311 | 2001-03-23 | ||
| US28104601P | 2001-04-02 | 2001-04-02 | |
| US60281046 | 2001-04-02 | ||
| US28868001P | 2001-05-03 | 2001-05-03 | |
| US60288680 | 2001-05-03 | ||
| US30980601P | 2001-08-01 | 2001-08-01 | |
| US60309806 | 2001-08-01 | ||
| PCT/US2001/027490 WO2002020535A1 (fr) | 2000-09-05 | 2001-09-05 | Production in situ de catalyseurs de metathese hautement actifs a partir de precurseurs bon marche et stables dans l'air |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2001288738A1 true AU2001288738A1 (en) | 2002-03-22 |
Family
ID=27539963
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2001288738A Abandoned AU2001288738A1 (en) | 2000-09-05 | 2001-09-05 | Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US6610626B2 (fr) |
| AU (1) | AU2001288738A1 (fr) |
| WO (1) | WO2002020535A1 (fr) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6393742B1 (en) * | 2000-03-02 | 2002-05-28 | Kathryn H. Dix | Minimum contact frame |
| US6921736B1 (en) * | 2000-07-17 | 2005-07-26 | University Of New Orleans Research And Technology Foundation, Inc. | Simply assembled and recyclable polymer-supported olefin metathesis catalysts |
| CA2441821A1 (fr) * | 2001-04-16 | 2002-10-24 | Yeda Research And Development Co. Ltd. | Nouveau procede de preparation de complexes metal-carbene |
| DE10137051A1 (de) * | 2001-07-31 | 2003-02-20 | Bayer Ag | Neue Übergangsmetall-Komplexe und deren Einsatz in Übergangsmetall-katalysierten Reaktionen |
| CA2455893C (fr) | 2001-08-01 | 2011-01-18 | California Institute Of Technology | Catalyseurs de metathese de carbene metallique de ruthenium ou d'osmium hexacoordonnes |
| AU2003258013A1 (en) * | 2002-08-01 | 2004-02-23 | California Institute Of Technology | Synthesis of macrocyclic polymers by ring insertion polymerization of cyclic olefin monomers |
| US7002049B2 (en) * | 2002-08-19 | 2006-02-21 | Eastman Chemical Company | Process for α,β-dihydroxyalkenes and derivatives |
| WO2004026454A2 (fr) * | 2002-09-19 | 2004-04-01 | Massachusetts Institute Of Technology | Formation d'enediynes par couplage reductif suivi de metathese d'alkyne |
| US6737531B1 (en) | 2002-12-17 | 2004-05-18 | Brookhaven Science Associates, Llc | Catalysts for hydrogenation and hydrosilylation, methods of making and using the same |
| BRPI0406756A (pt) * | 2003-01-13 | 2005-12-20 | Cargill Inc | Método para fabricação de agentes quìmicos industriais |
| JP4417261B2 (ja) * | 2003-02-28 | 2010-02-17 | 株式会社クラレ | 新規な重合体およびその製造方法 |
| US7094898B2 (en) * | 2003-05-29 | 2006-08-22 | University Of Ottawa | Ruthenium compounds, their production and use |
| US7205424B2 (en) * | 2003-06-19 | 2007-04-17 | University Of New Orleans Research And Technology Foundation, Inc. | Preparation of ruthenium-based olefin metathesis catalysts |
| US8461223B2 (en) | 2005-04-07 | 2013-06-11 | Aspen Aerogels, Inc. | Microporous polycyclopentadiene-based aerogels |
| JP5522941B2 (ja) * | 2005-12-16 | 2014-06-18 | マテリア, インコーポレイテッド | 有機金属ルテニウム錯体および関連する四置換および別の嵩高いオレフィンの製造方法 |
| WO2007081987A2 (fr) * | 2006-01-10 | 2007-07-19 | Elevance Renewable Sciences, Inc. | Procédé de fabrication de produits de métathèse hydrogénés |
| WO2008008440A2 (fr) * | 2006-07-12 | 2008-01-17 | Elevance Renewable Sciences, Inc. | Réaction de métathèse par ouverture de cycle d'oléfines cycliques avec des huiles végétales et similaires |
| US8067610B2 (en) | 2006-07-13 | 2011-11-29 | Yann Schrodi | Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis |
| EP2076484B1 (fr) | 2006-10-13 | 2020-01-08 | Elevance Renewable Sciences, Inc. | Synthèse d'alcènes terminaux à partir d'alcènes internes via la métathèse d'oléfines |
| EP3281931A1 (fr) | 2006-10-13 | 2018-02-14 | Elevance Renewable Sciences, Inc. | Procédés de production de composés organiques par métathèse |
| CN101627001A (zh) | 2006-10-13 | 2010-01-13 | 埃莱文斯可更新科学公司 | 通过复分解反应和氢氰化反应制备有机化合物的方法 |
| US20080306230A1 (en) * | 2007-06-07 | 2008-12-11 | General Electric Company | Composition and Associated Method |
| WO2009002427A2 (fr) | 2007-06-21 | 2008-12-31 | Amgen Inc. | Procédés de synthèse du cinacalcet et de ses sels |
| EP2028194B1 (fr) | 2007-08-21 | 2010-05-12 | Lanxess Deutschland GmbH | Métathèse de caoutchoucs de nitrile en présence de catalyseurs complexes de métal de transition |
| EP2027920B1 (fr) | 2007-08-21 | 2014-10-08 | LANXESS Deutschland GmbH | Catalyseurs pour les réactions de metathèses |
| DE102007039526A1 (de) * | 2007-08-21 | 2009-02-26 | Lanxess Deutschland Gmbh | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| DE102007039525A1 (de) * | 2007-08-21 | 2009-02-26 | Lanxess Deutschland Gmbh | Verfahren zum Metathese-Abbau von Nitrilkautschuk |
| JP5619724B2 (ja) * | 2008-04-09 | 2014-11-05 | マテリア, インコーポレイテッド | 置換された骨格を有するn−ヘテロ環状カルベンリガンドを有するルテニウムオレフィン複分解触媒 |
| WO2010083881A1 (fr) * | 2009-01-21 | 2010-07-29 | Henkel Ag & Co. Kgaa | Polymérisation par métathèse d'oléfines |
| DE102009040234A1 (de) * | 2009-09-07 | 2011-03-24 | Ernst-Moritz-Arndt-Universität Greifswald | Metallkomplexe und deren Verwendung als Katalysator in der Synthese organischer Verbindungen |
| FR2975310B1 (fr) | 2011-05-19 | 2014-03-14 | IFP Energies Nouvelles | Composition catalytique a base de ruthenium comprenant un compose de type silane ou siloxane et procede de metathese des olefines utilisant ladite composition |
| CN105308130B (zh) * | 2013-04-02 | 2017-09-29 | 巴斯夫欧洲公司 | 经涂覆的碳纤维增强塑料部件 |
| EP2933274A1 (fr) * | 2014-04-16 | 2015-10-21 | Evonik Degussa GmbH | Procédé de fabrication de polymères au moyen de la polymérisation par ouverture de cycle |
| US9932315B2 (en) | 2014-08-08 | 2018-04-03 | Massachusetts Institute Of Technology | Persistent carbene adducts and related methods |
| US11414587B2 (en) | 2020-05-22 | 2022-08-16 | Halliburton Energy Services, Inc. | Cycloalkene and transition metal compound catalyst resin for well sealing |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5710298A (en) | 1992-04-03 | 1998-01-20 | California Institute Of Technology | Method of preparing ruthenium and osmium carbene complexes |
| EP1251135A3 (fr) | 1992-04-03 | 2004-01-02 | California Institute Of Technology | Composé ruthénium et osmium métal-carbène avec haute activité de la méthathèse des oléfines , et leur préparation |
| US5312940A (en) | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
| DE4447066A1 (de) * | 1994-12-29 | 1996-07-04 | Hoechst Ag | Heterocyclische Carbene enthaltende Metallkomplexverbindungen |
| US5728785A (en) | 1995-07-07 | 1998-03-17 | California Institute Of Technology | Romp polymerization in the presence of peroxide crosslinking agents to form high-density crosslinked polymers |
| US5831108A (en) | 1995-08-03 | 1998-11-03 | California Institute Of Technology | High metathesis activity ruthenium and osmium metal carbene complexes |
| US5939504A (en) * | 1995-12-07 | 1999-08-17 | Advanced Polymer Technologies | Method for extending the pot life of an olefin metathesis polymerization reaction |
| DE19611629A1 (de) * | 1996-03-25 | 1997-10-02 | Hoechst Ag | Heterocyclische Carbene enthaltende Metallkomplexe als Katalysatoren für C-C-Verknüpfungen |
| US5917071A (en) * | 1996-11-15 | 1999-06-29 | California Institute Of Technology | Synthesis of ruthenium or osmium metathesis catalysts |
| EP0921129A1 (fr) * | 1997-12-03 | 1999-06-09 | Studiengesellschaft Kohle mbH | Complexes de ruthénium et d'osmium cationiques hautement actifs pour les réactions de métathèse des oléfines |
| US6175047B1 (en) * | 1997-12-26 | 2001-01-16 | Takasago International Corporation | Ruthenium metathesis catalyst and method for producing olefin reaction product by metathesis reaction using the same |
| US6107420A (en) * | 1998-07-31 | 2000-08-22 | California Institute Of Technology | Thermally initiated polymerization of olefins using Ruthenium or osmium vinylidene complexes |
| US6696597B2 (en) * | 1998-09-01 | 2004-02-24 | Tilliechem, Inc. | Metathesis syntheses of pheromones or their components |
| ATE438462T1 (de) | 1998-09-10 | 2009-08-15 | Univ New Orleans Foundation | Katalysatorkomplex mit phenylindenyliden-ligand |
| EP1180107B1 (fr) * | 1999-03-31 | 2008-06-11 | California Institute Of Technology | Nouveaux complexes d'alkylidene de ruthenium coordonnes avec des ligands de triazolylidene qui presentent une activite de metathese d'olefines elevee |
| US6225488B1 (en) * | 1999-04-02 | 2001-05-01 | Nippon Zeon Co., Ltd. | Ruthenium or osmium catalysts for olefin metathesis reactions |
| US6271315B1 (en) * | 1999-06-17 | 2001-08-07 | Wisconsin Alumni Research Foundation | Methods for making multivalent arrays |
| US6291616B1 (en) * | 1999-06-17 | 2001-09-18 | Wisconsin Alumni Research Foundation | Methods and reagents for capping ruthenium or osmium carbene-catalyzed ROMP products |
| DE19963125A1 (de) * | 1999-12-24 | 2001-06-28 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung von doppelbindungshaltigen Polymeren durch ringöffnende Polymerisation |
| FR2806644B1 (fr) * | 2000-03-23 | 2002-05-10 | Inst Francais Du Petrole | Composition catalytique et procede pour la catalyse de dimerisation, de codimerisation et d'oligomerisation des olefines |
| JP4131074B2 (ja) * | 2000-03-24 | 2008-08-13 | 日本ゼオン株式会社 | ルテニウム化合物の製造方法 |
| JP3943015B2 (ja) * | 2000-08-10 | 2007-07-11 | トラスティーズ オブ ボストン カレッジ | リサイクル可能メタセシス触媒 |
-
2001
- 2001-09-05 US US09/948,115 patent/US6610626B2/en not_active Expired - Lifetime
- 2001-09-05 WO PCT/US2001/027490 patent/WO2002020535A1/fr not_active Ceased
- 2001-09-05 AU AU2001288738A patent/AU2001288738A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002020535A1 (fr) | 2002-03-14 |
| US20020058812A1 (en) | 2002-05-16 |
| US6610626B2 (en) | 2003-08-26 |
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