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AU2001288738A1 - Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors - Google Patents

Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors

Info

Publication number
AU2001288738A1
AU2001288738A1 AU2001288738A AU8873801A AU2001288738A1 AU 2001288738 A1 AU2001288738 A1 AU 2001288738A1 AU 2001288738 A AU2001288738 A AU 2001288738A AU 8873801 A AU8873801 A AU 8873801A AU 2001288738 A1 AU2001288738 A1 AU 2001288738A1
Authority
AU
Australia
Prior art keywords
situ
inexpensive
highly active
metathesis catalysts
air stable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001288738A
Other languages
English (en)
Inventor
Robert H. Grubbs
Janis Louie
Jason L. Moore
John P Morgan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
California Institute of Technology
Cymetech LLC
Original Assignee
California Institute of Technology
Cymetech LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by California Institute of Technology, Cymetech LLC filed Critical California Institute of Technology
Publication of AU2001288738A1 publication Critical patent/AU2001288738A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2282Unsaturated compounds used as ligands
    • B01J31/2295Cyclic compounds, e.g. cyclopentadienyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • B01J31/2269Heterocyclic carbenes
    • B01J31/2273Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C07C6/06Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond at a cyclic carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/002Osmium compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046Ruthenium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14Other (co) polymerisation, e.g. of lactides or epoxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/462Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46Ruthenium, rhodium, osmium or iridium
    • B01J23/466Osmium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/825Osmium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
AU2001288738A 2000-09-05 2001-09-05 Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors Abandoned AU2001288738A1 (en)

Applications Claiming Priority (11)

Application Number Priority Date Filing Date Title
US23054700P 2000-09-05 2000-09-05
US60230547 2000-09-05
US27831101P 2001-03-23 2001-03-23
US60278311 2001-03-23
US28104601P 2001-04-02 2001-04-02
US60281046 2001-04-02
US28868001P 2001-05-03 2001-05-03
US60288680 2001-05-03
US30980601P 2001-08-01 2001-08-01
US60309806 2001-08-01
PCT/US2001/027490 WO2002020535A1 (fr) 2000-09-05 2001-09-05 Production in situ de catalyseurs de metathese hautement actifs a partir de precurseurs bon marche et stables dans l'air

Publications (1)

Publication Number Publication Date
AU2001288738A1 true AU2001288738A1 (en) 2002-03-22

Family

ID=27539963

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001288738A Abandoned AU2001288738A1 (en) 2000-09-05 2001-09-05 Highly active metathesis catalysts generated in situ from inexpensive and air stable precursors

Country Status (3)

Country Link
US (1) US6610626B2 (fr)
AU (1) AU2001288738A1 (fr)
WO (1) WO2002020535A1 (fr)

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CA2441821A1 (fr) * 2001-04-16 2002-10-24 Yeda Research And Development Co. Ltd. Nouveau procede de preparation de complexes metal-carbene
DE10137051A1 (de) * 2001-07-31 2003-02-20 Bayer Ag Neue Übergangsmetall-Komplexe und deren Einsatz in Übergangsmetall-katalysierten Reaktionen
CA2455893C (fr) 2001-08-01 2011-01-18 California Institute Of Technology Catalyseurs de metathese de carbene metallique de ruthenium ou d'osmium hexacoordonnes
AU2003258013A1 (en) * 2002-08-01 2004-02-23 California Institute Of Technology Synthesis of macrocyclic polymers by ring insertion polymerization of cyclic olefin monomers
US7002049B2 (en) * 2002-08-19 2006-02-21 Eastman Chemical Company Process for α,β-dihydroxyalkenes and derivatives
WO2004026454A2 (fr) * 2002-09-19 2004-04-01 Massachusetts Institute Of Technology Formation d'enediynes par couplage reductif suivi de metathese d'alkyne
US6737531B1 (en) 2002-12-17 2004-05-18 Brookhaven Science Associates, Llc Catalysts for hydrogenation and hydrosilylation, methods of making and using the same
BRPI0406756A (pt) * 2003-01-13 2005-12-20 Cargill Inc Método para fabricação de agentes quìmicos industriais
JP4417261B2 (ja) * 2003-02-28 2010-02-17 株式会社クラレ 新規な重合体およびその製造方法
US7094898B2 (en) * 2003-05-29 2006-08-22 University Of Ottawa Ruthenium compounds, their production and use
US7205424B2 (en) * 2003-06-19 2007-04-17 University Of New Orleans Research And Technology Foundation, Inc. Preparation of ruthenium-based olefin metathesis catalysts
US8461223B2 (en) 2005-04-07 2013-06-11 Aspen Aerogels, Inc. Microporous polycyclopentadiene-based aerogels
JP5522941B2 (ja) * 2005-12-16 2014-06-18 マテリア, インコーポレイテッド 有機金属ルテニウム錯体および関連する四置換および別の嵩高いオレフィンの製造方法
WO2007081987A2 (fr) * 2006-01-10 2007-07-19 Elevance Renewable Sciences, Inc. Procédé de fabrication de produits de métathèse hydrogénés
WO2008008440A2 (fr) * 2006-07-12 2008-01-17 Elevance Renewable Sciences, Inc. Réaction de métathèse par ouverture de cycle d'oléfines cycliques avec des huiles végétales et similaires
US8067610B2 (en) 2006-07-13 2011-11-29 Yann Schrodi Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
EP2076484B1 (fr) 2006-10-13 2020-01-08 Elevance Renewable Sciences, Inc. Synthèse d'alcènes terminaux à partir d'alcènes internes via la métathèse d'oléfines
EP3281931A1 (fr) 2006-10-13 2018-02-14 Elevance Renewable Sciences, Inc. Procédés de production de composés organiques par métathèse
CN101627001A (zh) 2006-10-13 2010-01-13 埃莱文斯可更新科学公司 通过复分解反应和氢氰化反应制备有机化合物的方法
US20080306230A1 (en) * 2007-06-07 2008-12-11 General Electric Company Composition and Associated Method
WO2009002427A2 (fr) 2007-06-21 2008-12-31 Amgen Inc. Procédés de synthèse du cinacalcet et de ses sels
EP2028194B1 (fr) 2007-08-21 2010-05-12 Lanxess Deutschland GmbH Métathèse de caoutchoucs de nitrile en présence de catalyseurs complexes de métal de transition
EP2027920B1 (fr) 2007-08-21 2014-10-08 LANXESS Deutschland GmbH Catalyseurs pour les réactions de metathèses
DE102007039526A1 (de) * 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
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JP5619724B2 (ja) * 2008-04-09 2014-11-05 マテリア, インコーポレイテッド 置換された骨格を有するn−ヘテロ環状カルベンリガンドを有するルテニウムオレフィン複分解触媒
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Also Published As

Publication number Publication date
WO2002020535A1 (fr) 2002-03-14
US20020058812A1 (en) 2002-05-16
US6610626B2 (en) 2003-08-26

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