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AU2001280028A1 - Catalytic hydrogenation processes - Google Patents

Catalytic hydrogenation processes

Info

Publication number
AU2001280028A1
AU2001280028A1 AU2001280028A AU8002801A AU2001280028A1 AU 2001280028 A1 AU2001280028 A1 AU 2001280028A1 AU 2001280028 A AU2001280028 A AU 2001280028A AU 8002801 A AU8002801 A AU 8002801A AU 2001280028 A1 AU2001280028 A1 AU 2001280028A1
Authority
AU
Australia
Prior art keywords
line
formulae
catalytic hydrogenation
phosphino
hydrogenation processes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001280028A
Inventor
Kamaluddin Abdur-Rashid
Eric Brazi
Rene Challand
Raphael Churlaud
Hubert Mimoun
Robert Harold Morris
Valentin Rautenstrauch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Firmenich SA
Original Assignee
Firmenich SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firmenich SA filed Critical Firmenich SA
Publication of AU2001280028A1 publication Critical patent/AU2001280028A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B43/00—Formation or introduction of functional groups containing nitrogen
    • C07B43/04—Formation or introduction of functional groups containing nitrogen of amino groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/52—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of imines or imino-ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B01J2231/643—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes of R2C=O or R2C=NR (R= C, H)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/08—Systems containing only non-condensed rings with a five-membered ring the ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Catalysts of formula <?in-line-formulae description="In-line Formulae" end="lead"?>[Ru(L)m(L')wXY] (II)<?in-line-formulae description="In-line Formulae" end="tail"?> wherein X and Y represent simultaneously or independently a hydrogen or halogen atom, a hydroxy group, or an alkoxy, carboxyl or other anionic radical, m is 1 or 2, w is 1 when m is 1 and w is 0 when m is 2, L is a phosphino-amine or phosphino-imine bidentate ligand and L' a diphosphine, are useful for the hydrogenation of substrates having a carbon-hetero atom double bond.
AU2001280028A 2000-09-13 2001-09-11 Catalytic hydrogenation processes Abandoned AU2001280028A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US23214400P 2000-09-13 2000-09-13
IBPCT/IB00/01303 2000-09-13
IB0001303 2000-09-13
US60/232,144 2000-09-13
PCT/IB2001/001657 WO2002022526A2 (en) 2000-09-13 2001-09-11 Catalytic hydrogenation processes

Publications (1)

Publication Number Publication Date
AU2001280028A1 true AU2001280028A1 (en) 2002-03-26

Family

ID=26318616

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001280028A Abandoned AU2001280028A1 (en) 2000-09-13 2001-09-11 Catalytic hydrogenation processes

Country Status (10)

Country Link
US (2) US7317131B2 (en)
EP (1) EP1366004B1 (en)
JP (2) JP5345270B2 (en)
AT (1) ATE395314T1 (en)
AU (1) AU2001280028A1 (en)
CA (1) CA2422029C (en)
DE (1) DE60134052D1 (en)
ES (1) ES2305095T3 (en)
IL (2) IL154822A0 (en)
WO (1) WO2002022526A2 (en)

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JP2005525426A (en) * 2002-05-15 2005-08-25 カマルディン アブドゥール−ラシッド Hydrogenation of inert imines using ruthenium complexes as catalysts
DE60313357T2 (en) * 2002-12-02 2008-01-03 Solvias Ag METHOD FOR THE CATALYTIC HYDROGENATION OF CARBON HETEROATOM DOUBLE BINDINGS
JP4704812B2 (en) * 2004-06-09 2011-06-22 エム． カレイラ エリック Monophosphine compound, transition metal complex thereof and method for producing optically active compound using the complex as asymmetric catalyst
US7989665B2 (en) 2005-04-05 2011-08-02 Firmenich Sa Hydrogenation of esters with Ru/tetradentate ligands complexes
CN101137601B (en) 2005-04-05 2011-08-10 弗门尼舍有限公司 Hydrogenation of esters with ru/bidentate ligands complexes
RU2007140871A (en) 2005-04-05 2009-05-20 Фирмениш Са (Ch) HYDROGENING ETHERS WITH COMPLEXES RU WITH BIDENTAL LIGANDS
WO2007082928A2 (en) * 2006-01-23 2007-07-26 Basf Se Method for production of a ruthenium catalyst
JP2007314433A (en) * 2006-05-23 2007-12-06 Univ Of Tokyo Optically active tertiary phosphine compound, metal complex having this as a ligand and use thereof
CN100465144C (en) * 2006-12-01 2009-03-04 华南理工大学 A method for preparing alcohol by catalytic hydrogenation reduction of carbonyl compound with supported amorphous ruthenium-containing boron catalyst
CA2591126A1 (en) 2007-06-08 2008-12-08 Kanata Chemical Technologies Inc. Process for the preparation of aminiphosphine ligands and their use in metal catalysts
US7772445B2 (en) 2007-07-06 2010-08-10 Kanata Chemical Technologies Inc. Ruthenium catalysts for catalytic hydrogenation
US8232430B2 (en) 2007-07-06 2012-07-31 Kanata Chemical Technologies Inc. Method for the preparation of cis-4-tert-butylcyclohexanol
JP5340297B2 (en) 2007-10-23 2013-11-13 フイルメニツヒ ソシエテ アノニム Method for producing tetranorlabdane derivative
AU2008318239B2 (en) * 2007-10-30 2014-06-05 Kanata Chemical Technologies Inc. Cationic transition metal catalysts
US7615671B2 (en) 2007-11-30 2009-11-10 Eastman Chemical Company Hydrogenation process for the preparation of 1,2-diols
JP5451209B2 (en) * 2008-07-08 2014-03-26 国立大学法人東京工業大学 Practical methods for reducing esters and lactones
CA2740500C (en) 2008-10-17 2018-06-12 Kanata Chemical Technologies Inc. Method for preparing a metal catalyst
CN102227261A (en) 2008-11-28 2011-10-26 弗门尼舍有限公司 Hydrogenation of ester, ketone or aldehyde groups with ruthenium complexes having di-amine and phosphorous-nitrogen bidentate ligand
EP2236487B1 (en) 2009-04-02 2015-09-02 International Flavors & Fragrances Inc. Processes for producing levosandal
US8038855B2 (en) 2009-04-29 2011-10-18 Freeport-Mcmoran Corporation Anode structure for copper electrowinning
JP6080774B2 (en) 2010-12-21 2017-02-15 フイルメニツヒ ソシエテ アノニムＦｉｒｍｅｎｉｃｈ Ｓａ Hydrogenation of ester or carbonyl groups with tetradentate amino / imino-thioether based ruthenium complexes
WO2013050297A1 (en) 2011-10-06 2013-04-11 Firmenich Sa Selective hydrogenation of aldehyde with ru/bidentate ligands complexes
US9714263B2 (en) 2013-03-15 2017-07-25 Firmenich Sa Selective hydrogenation of aldehydes with Ru/bidentate ligands complexes
GB201509664D0 (en) * 2015-06-03 2015-07-15 Johnson Matthey Plc And Universit Di Udine Process
US11008270B2 (en) 2018-04-06 2021-05-18 Kare Chemical Technologies Inc. Catalytic conversion of carbon dioxide to methanol using diformate esters as intermediates
CN109553509A (en) * 2018-12-17 2019-04-02 西安近代化学研究所 A kind of preparation method of five fluorine propyl alcohol of 2,2,3,3,3-

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JP2739254B2 (en) * 1990-10-01 1998-04-15 高砂香料工業株式会社 Iridium-optically active phosphine complex and method for producing optically active alcohol using the same
FR2693190B1 (en) * 1992-07-02 1994-09-23 Elf Aquitaine Enantioselective hydrogenation process for the C = O OXO double bond.
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JP4004123B2 (en) * 1997-12-26 2007-11-07 独立行政法人科学技術振興機構 Method for producing alcohol compound using ruthenium complex as catalyst
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Also Published As

Publication number Publication date
WO2002022526A3 (en) 2003-09-12
JP2004509087A (en) 2004-03-25
JP2012087138A (en) 2012-05-10
ES2305095T3 (en) 2008-11-01
JP5345270B2 (en) 2013-11-20
IL154822A0 (en) 2003-10-31
CA2422029C (en) 2008-11-18
EP1366004A2 (en) 2003-12-03
US7579295B2 (en) 2009-08-25
CA2422029A1 (en) 2002-03-21
EP1366004B1 (en) 2008-05-14
US7317131B2 (en) 2008-01-08
ATE395314T1 (en) 2008-05-15
IL154822A (en) 2009-11-18
DE60134052D1 (en) 2008-06-26
US20050245748A9 (en) 2005-11-03
US20040063966A1 (en) 2004-04-01
US20080015376A1 (en) 2008-01-17
WO2002022526A2 (en) 2002-03-21

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