AU2001260264A1 - Process for catalytic hydroxylation of benzene - Google Patents
Process for catalytic hydroxylation of benzeneInfo
- Publication number
- AU2001260264A1 AU2001260264A1 AU2001260264A AU6026401A AU2001260264A1 AU 2001260264 A1 AU2001260264 A1 AU 2001260264A1 AU 2001260264 A AU2001260264 A AU 2001260264A AU 6026401 A AU6026401 A AU 6026401A AU 2001260264 A1 AU2001260264 A1 AU 2001260264A1
- Authority
- AU
- Australia
- Prior art keywords
- benzene
- catalytic hydroxylation
- hydroxylation
- catalyst
- oxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 230000033444 hydroxylation Effects 0.000 title abstract 2
- 238000005805 hydroxylation reaction Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000000571 coke Substances 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 230000000640 hydroxylating effect Effects 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
A process for hydroxylating benzene under catalytic distillation conditions to produce hydroxylated products such as phenol is provided. The process provides for direct hydroxylation of liquid phase benzene with an oxidant and a zeolite catalyst under conditions effective to prevent coke formation on the catalyst.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/559,925 US6437197B1 (en) | 2000-04-27 | 2000-04-27 | Process for catalytic hydroxylation of aromatic hydrocarbons |
| US09559925 | 2000-04-27 | ||
| PCT/EP2001/004851 WO2001083415A2 (en) | 2000-04-27 | 2001-04-27 | Process for catalytic hydroxylation of benzene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2001260264A1 true AU2001260264A1 (en) | 2001-11-12 |
Family
ID=24235633
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2001268985A Abandoned AU2001268985A1 (en) | 2000-04-27 | 2001-04-26 | Process for catalytic hydroxylation of aromatic compounds |
| AU2001260264A Abandoned AU2001260264A1 (en) | 2000-04-27 | 2001-04-27 | Process for catalytic hydroxylation of benzene |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2001268985A Abandoned AU2001268985A1 (en) | 2000-04-27 | 2001-04-26 | Process for catalytic hydroxylation of aromatic compounds |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US6437197B1 (en) |
| EP (2) | EP1276706B1 (en) |
| CN (2) | CN1213967C (en) |
| AT (2) | ATE258153T1 (en) |
| AU (2) | AU2001268985A1 (en) |
| DE (2) | DE60101844T2 (en) |
| WO (2) | WO2001081275A2 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7148386B2 (en) | 2004-07-30 | 2006-12-12 | General Electric Company | Processes for preparing benzoquinones and hydroquinones |
| ITMI20050062A1 (en) * | 2005-01-20 | 2006-07-21 | Polimeri Europa Spa | PROCESS FOR THE PREPARATION OF PHENOL |
| US20060266288A1 (en) * | 2005-05-27 | 2006-11-30 | Applied Materials, Inc. | High plasma utilization for remote plasma clean |
| CN101733098B (en) * | 2008-11-07 | 2012-08-08 | 中国石油天然气股份有限公司 | A kind of benzene hydroxylation preparation phenol catalyst and its preparation method and application |
| CN101747155B (en) * | 2008-12-08 | 2013-04-24 | 中国石油天然气股份有限公司 | A kind of N2O is the method for the one-step oxidation synthesis phenol of oxidant benzene |
| EP3201164B1 (en) | 2014-10-02 | 2020-11-25 | Monsanto Technology LLC | Processes for preparing 2,5-dichlorophenol |
| US9630899B1 (en) | 2015-10-26 | 2017-04-25 | Chang Chun Plastics Co. Ltd. | Process for producing hydroquinone and derivates |
| CN106045820B (en) * | 2016-07-04 | 2019-03-12 | 中石化炼化工程(集团)股份有限公司 | A kind of method that catalytic distillation produces phenol and/or benzenediol |
| CN106187704B (en) * | 2016-07-04 | 2019-03-12 | 中石化炼化工程(集团)股份有限公司 | A kind of method that catalytic distillation produces phenol and/or benzenediol |
| CN106083531B (en) * | 2016-07-04 | 2019-05-24 | 中石化炼化工程(集团)股份有限公司 | A kind of phenol, the production method of benzenediol and the destilling tower that uses |
| RU2630473C1 (en) * | 2016-10-27 | 2017-09-11 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Method for producing and regenerating hydroxylation catalyst for aromatic compounds with nitrogen oxide and aromatic compound hydroxylating method |
| WO2018128960A1 (en) | 2017-01-04 | 2018-07-12 | Shell Oil Company | A process for the preparation of adipic acid |
| WO2018128959A1 (en) | 2017-01-04 | 2018-07-12 | Shell Oil Company | A process for the preparation of adipic acid |
Family Cites Families (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1184772B (en) * | 1961-08-08 | 1965-01-07 | Karl Ziegler Dr | Process for the preparation of phenol or its homologues |
| US4016245A (en) | 1973-09-04 | 1977-04-05 | Mobil Oil Corporation | Crystalline zeolite and method of preparing same |
| NL7812162A (en) | 1978-12-14 | 1980-06-17 | Shell Int Research | PROCESS FOR THE PREPARATION OF FERRIERITE. |
| US4310440A (en) | 1980-07-07 | 1982-01-12 | Union Carbide Corporation | Crystalline metallophosphate compositions |
| DE3117135A1 (en) | 1981-04-30 | 1982-11-18 | Bayer Ag, 5090 Leverkusen | CRYSTALLINE ALUMOSILICATE, METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF FOR CATALYTICALLY CONVERTING METHANOL AND / OR DIMETHYL ETHER IN HYDROCARBONS |
| IT1150699B (en) | 1982-03-19 | 1986-12-17 | Anic Spa | PROCEDURE FOR THE OXIDRILATION OF AROMATIC HYDROCARBONS |
| US4683217A (en) | 1984-04-13 | 1987-07-28 | Union Carbide Corporation | Iron-aluminum-phosphorus-silicon-oxide molecular sieves |
| CA1241628A (en) | 1984-04-13 | 1988-09-06 | Brent M.T. Lok | Molecular sieve compositions |
| US4758419A (en) | 1984-04-13 | 1988-07-19 | Union Carbide Corporation | Magnesium-aluminum-phosphorus-silicon-oxide molecular sieve compositions |
| US5176883A (en) | 1985-01-07 | 1993-01-05 | Chemical Research & Licensing Company | Alkylation of organic aromatic compounds |
| US5321181A (en) | 1985-01-07 | 1994-06-14 | Chemical Research & Licensing Company | Alkylation of organic aromatic compounds |
| US4795623A (en) | 1986-08-05 | 1989-01-03 | Shell Oil Company | Time effective method for preparing ferrierite |
| US4826667A (en) | 1986-01-29 | 1989-05-02 | Chevron Research Company | Zeolite SSZ-25 |
| US5243115A (en) | 1986-03-31 | 1993-09-07 | Chemical Research & Licensing Company | Alkylation of organic aromatic compounds |
| US4954325A (en) | 1986-07-29 | 1990-09-04 | Mobil Oil Corp. | Composition of synthetic porous crystalline material, its synthesis and use |
| US4942027A (en) | 1986-08-05 | 1990-07-17 | Shell Oil Company | Method for preparing ferrierite |
| FR2630733B1 (en) | 1988-05-02 | 1990-07-20 | Rhone Poulenc Chimie | PROCESS FOR THE PREPARATION OF PHENOL |
| US5120403A (en) | 1989-03-23 | 1992-06-09 | Chemical Research & Licensing Company | Method for operating a catalytic distillation process |
| US5262576A (en) | 1989-03-23 | 1993-11-16 | Chemical Research & Licensing Company | Method for the alkylation of organic aromatic compounds |
| FR2648810B1 (en) | 1989-06-22 | 1992-02-28 | Rhone Poulenc Chimie | PROCESS FOR THE PREPARATION OF PHENOLS |
| US5476978A (en) | 1989-09-05 | 1995-12-19 | Chemical Research & Licensing Company | Process for the preparation of ethyl benzene |
| US5215725A (en) | 1990-11-09 | 1993-06-01 | Chemical Research & Licensing Company | Aromatic alkylation process |
| US5190904A (en) | 1990-12-24 | 1993-03-02 | Chemical Research & Licensing Company | Paraffin alkylation catalyst |
| US5110995A (en) * | 1991-03-12 | 1992-05-05 | Institute Of Catalysis | Preparation of phenol or phenol derivatives |
| US5236575A (en) | 1991-06-19 | 1993-08-17 | Mobil Oil Corp. | Synthetic porous crystalline mcm-49, its synthesis and use |
| US5324702A (en) * | 1991-11-22 | 1994-06-28 | Amoco Corporation | Catalytic oxidation and oxidative dehydrogenation using metal-compound-loaded, deboronated hams-1b crystalline borosilicate molecular sieve compositions |
| US5827491A (en) | 1993-04-26 | 1998-10-27 | Mobil Oil Corporation | Process for preparing the synthetic porous crystalline material MCM-56 |
| US5362697A (en) | 1993-04-26 | 1994-11-08 | Mobil Oil Corp. | Synthetic layered MCM-56, its synthesis and use |
| RU2074164C1 (en) | 1994-04-12 | 1997-02-27 | Институт катализа им.Г.К.Борескова СО РАН | Method of producing phenol and derivatives thereof |
| RU2058286C1 (en) | 1994-04-12 | 1996-04-20 | Институт катализа им.Г.К.Борескова СО РАН | Method for production of phenol or its derivatives |
| US5446223A (en) | 1994-05-23 | 1995-08-29 | Chemical Research & Licensing Company | Alkylation of organic aromatic compounds |
| US5770782A (en) | 1996-02-08 | 1998-06-23 | Huntsman Petrochemical Corporation | Process and system for alkylation of aromatic compounds |
| US5762777A (en) | 1996-05-02 | 1998-06-09 | Persee Chemical Co. Ltd. | Process of directly electroplating onto a nonconductive substrate |
| US5874646A (en) | 1996-08-07 | 1999-02-23 | Solutia Inc. | Preparation of phenol or phenol derivatives |
| US5808167A (en) | 1996-08-20 | 1998-09-15 | Solutia Inc. | Selective introduction of active sites for hydroxylation of benzene |
| DE19634406C2 (en) | 1996-08-26 | 1998-11-26 | Hoechst Ag | Process for the preparation of hydroxyaromatics by reacting aromatics with N¶2¶O |
| US5912391A (en) | 1997-11-17 | 1999-06-15 | General Electric Company | Method for hydroxylating aromatic compounds |
| US5958370A (en) | 1997-12-11 | 1999-09-28 | Chevron U.S.A. Inc. | Zeolite SSZ-39 |
| US5961951A (en) | 1998-01-12 | 1999-10-05 | Mobil Oil Corporation | Synthesis ZSM-48 |
-
2000
- 2000-04-27 US US09/559,925 patent/US6437197B1/en not_active Expired - Lifetime
-
2001
- 2001-04-24 US US09/841,654 patent/US6900358B2/en not_active Expired - Lifetime
- 2001-04-26 EP EP01947249A patent/EP1276706B1/en not_active Expired - Lifetime
- 2001-04-26 CN CNB018094929A patent/CN1213967C/en not_active Expired - Lifetime
- 2001-04-26 DE DE2001601844 patent/DE60101844T2/en not_active Expired - Lifetime
- 2001-04-26 AT AT01947249T patent/ATE258153T1/en not_active IP Right Cessation
- 2001-04-26 WO PCT/EP2001/004853 patent/WO2001081275A2/en not_active Ceased
- 2001-04-26 AU AU2001268985A patent/AU2001268985A1/en not_active Abandoned
- 2001-04-27 DE DE60101679T patent/DE60101679T2/en not_active Expired - Lifetime
- 2001-04-27 WO PCT/EP2001/004851 patent/WO2001083415A2/en not_active Ceased
- 2001-04-27 EP EP01933907A patent/EP1276708B1/en not_active Expired - Lifetime
- 2001-04-27 AU AU2001260264A patent/AU2001260264A1/en not_active Abandoned
- 2001-04-27 CN CNB018097057A patent/CN1178886C/en not_active Expired - Lifetime
- 2001-04-27 AT AT01933907T patent/ATE257140T1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001081275A2 (en) | 2001-11-01 |
| EP1276708A2 (en) | 2003-01-22 |
| CN1213967C (en) | 2005-08-10 |
| DE60101844T2 (en) | 2004-11-18 |
| ATE257140T1 (en) | 2004-01-15 |
| EP1276706B1 (en) | 2004-01-21 |
| WO2001083415A2 (en) | 2001-11-08 |
| EP1276706A2 (en) | 2003-01-22 |
| CN1178886C (en) | 2004-12-08 |
| CN1429191A (en) | 2003-07-09 |
| ATE258153T1 (en) | 2004-02-15 |
| WO2001083415A3 (en) | 2002-03-14 |
| US6900358B2 (en) | 2005-05-31 |
| EP1276708B1 (en) | 2004-01-02 |
| DE60101679T2 (en) | 2004-12-09 |
| WO2001081275A3 (en) | 2002-03-14 |
| AU2001268985A1 (en) | 2001-11-07 |
| US20010044559A1 (en) | 2001-11-22 |
| DE60101844D1 (en) | 2004-02-26 |
| CN1429186A (en) | 2003-07-09 |
| DE60101679D1 (en) | 2004-02-05 |
| US6437197B1 (en) | 2002-08-20 |
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