AU2001252059A1 - Process for hydrogenating carboxylated nitrile rubber, the hydrogenated rubber and its uses - Google Patents
Process for hydrogenating carboxylated nitrile rubber, the hydrogenated rubber and its usesInfo
- Publication number
- AU2001252059A1 AU2001252059A1 AU2001252059A AU5205901A AU2001252059A1 AU 2001252059 A1 AU2001252059 A1 AU 2001252059A1 AU 2001252059 A AU2001252059 A AU 2001252059A AU 5205901 A AU5205901 A AU 5205901A AU 2001252059 A1 AU2001252059 A1 AU 2001252059A1
- Authority
- AU
- Australia
- Prior art keywords
- rubber
- hydrogenated
- hydrogenating
- carboxylated nitrile
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920000459 Nitrile rubber Polymers 0.000 title 1
- 229920001971 elastomer Polymers 0.000 title 1
- 229920000642 polymer Polymers 0.000 abstract 2
- 238000005299 abrasion Methods 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 abstract 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 125000002560 nitrile group Chemical group 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L13/00—Compositions of rubbers containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
- C08L15/005—Hydrogenated nitrile rubber
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Laminated Bodies (AREA)
- Sealing Material Composition (AREA)
Abstract
Polymers of a conjugated diene, an unsaturated nitrile and an alpha,beta-unsaturated carboxylic acid are selectively hydrogenated to reduce carbon-carbon double bonds, without also reducing carboxyl groups and nitrile groups, using a rhodium-containing compound as catalyst. The hydrogenated polymers are novel and display excellent adhesive properties at both room temperature and high temperature, excellent hot tear strength, and excellent abrasion resistance.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA002304501A CA2304501A1 (en) | 2000-04-10 | 2000-04-10 | Process for hydrogenating carboxylated nitrile rubber, the hydrogenated rubber and its uses |
| CA2304501 | 2000-04-10 | ||
| PCT/CA2001/000485 WO2001077185A1 (en) | 2000-04-10 | 2001-04-09 | Process for hydrogenating carboxylated nitrile rubber, the hydrogenated rubber and its uses |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU2001252059A1 true AU2001252059A1 (en) | 2001-10-23 |
Family
ID=4165825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2001252059A Abandoned AU2001252059A1 (en) | 2000-04-10 | 2001-04-09 | Process for hydrogenating carboxylated nitrile rubber, the hydrogenated rubber and its uses |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US7265185B2 (en) |
| EP (1) | EP1276773B1 (en) |
| JP (1) | JP4694082B2 (en) |
| KR (1) | KR20030007512A (en) |
| CN (1) | CN100523013C (en) |
| AT (1) | ATE454406T1 (en) |
| AU (1) | AU2001252059A1 (en) |
| BR (1) | BR0109933B1 (en) |
| CA (1) | CA2304501A1 (en) |
| DE (1) | DE60141007D1 (en) |
| HU (1) | HUP0300336A3 (en) |
| MX (1) | MXPA02009754A (en) |
| PL (1) | PL358059A1 (en) |
| RU (1) | RU2002129931A (en) |
| SK (1) | SK14482002A3 (en) |
| WO (1) | WO2001077185A1 (en) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10102047A1 (en) | 2001-01-17 | 2002-07-18 | Bayer Ag | Rubber mixture, useful for the production of coatings for rollers, contains a carboxylated nitrile rubber, a metal acrylate salt, a liquid acrylate and a silane |
| CA2355578A1 (en) | 2001-07-31 | 2003-01-31 | Bayer Inc. | Covulcanisation of polymers |
| US6905319B2 (en) * | 2002-01-29 | 2005-06-14 | Halliburton Energy Services, Inc. | Stator for down hole drilling motor |
| CA2413636A1 (en) * | 2002-12-05 | 2004-06-05 | Bayer Inc. | Adhesive compositions |
| CA2413607A1 (en) * | 2002-12-05 | 2004-06-05 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
| US20040132886A1 (en) * | 2003-01-06 | 2004-07-08 | Jian Tao | Accelerator free nitrile gloves |
| CA2428222A1 (en) * | 2003-05-08 | 2004-11-08 | Bayer Inc. | Rubber compound comprising nitrile rubbers |
| DE10321875A1 (en) * | 2003-05-15 | 2004-12-02 | Bayer Ag | HXNBR rubber as crosslinking agent |
| DE10327452A1 (en) * | 2003-06-18 | 2005-01-05 | Bayer Materialscience Ag | adhesives |
| CA2437406A1 (en) * | 2003-08-14 | 2005-02-14 | Bayer Inc. | Butyl compositions comprising nitrile polymers |
| CA2438111A1 (en) * | 2003-08-25 | 2005-02-25 | Bayer Inc. | Nitrile polymer compounds for magntic seal applications |
| CA2452910A1 (en) * | 2003-12-12 | 2005-06-12 | Bayer Inc. | Butyl rubber composition for tire treads |
| CA2452863A1 (en) * | 2003-12-12 | 2005-06-12 | Bayer Inc. | Rubber composition for tire treads |
| CA2478431A1 (en) * | 2004-06-23 | 2005-12-23 | Richard Pazur | Elastomeric compositions having improved mechanical properties and scorch resistance |
| US20060110559A1 (en) * | 2004-10-05 | 2006-05-25 | Victor Nasreddine | Crosslinking of carboxylated nitrile polymers with organo functional silanes: a curable plasticizer composition |
| CA2487744A1 (en) | 2004-11-18 | 2006-05-18 | Lanxess Inc. | Peroxide curable rubber composition comprising hnbr |
| JP4791725B2 (en) * | 2004-11-19 | 2011-10-12 | 日本板硝子株式会社 | Reinforcing sheet for reinforcing toothed belt, toothed belt and method for manufacturing the same |
| CA2490046A1 (en) * | 2004-12-10 | 2006-06-10 | Lanxess Inc. | Multistage process for the manufacture of peroxide-cured hxnbr-polyamide thermoplastic vulcanizates |
| CA2501203A1 (en) * | 2005-03-18 | 2006-09-18 | Lanxess Inc. | Hydrogenation of diene-based polymer latex |
| CA2501199A1 (en) * | 2005-03-18 | 2006-09-18 | Lanxess Inc. | Organic solvent-free hydrogenation of diene-based polymers |
| CN100376611C (en) * | 2005-05-20 | 2008-03-26 | 中国石油天然气股份有限公司 | Hydrogenation method of nitrile butadiene rubber |
| DE102005042265A1 (en) | 2005-09-06 | 2007-03-08 | Lanxess Deutschland Gmbh | Crosslinkable compositions, thermoplastic elastomers obtainable therefrom and their use |
| DE102005047115A1 (en) | 2005-09-30 | 2007-04-05 | Lanxess Deutschland Gmbh | Crosslinkable compositions, processes for their preparation and their use |
| US7741392B2 (en) * | 2006-02-23 | 2010-06-22 | Lanxess Inc. | Rubber compositions having improved physical and low temperature properties |
| US7666950B2 (en) * | 2006-06-01 | 2010-02-23 | Lanxess Deutschland Gmbh | Process for preparing hydrogenated nitrile rubbers |
| JP4669443B2 (en) * | 2006-06-12 | 2011-04-13 | 三菱電線工業株式会社 | Rubber composition for sealing material and sealing material using the same |
| US7765720B2 (en) | 2007-01-12 | 2010-08-03 | Nike, Inc, | Outsole for an article of footwear |
| FR2919613B1 (en) | 2007-07-30 | 2009-10-09 | Inergy Automotive Systems Res | OBJECT BASED ON A COMPOSITION CONTAINING A RETICLE MIXTURE OF ELASTOMERS |
| US7858540B2 (en) * | 2007-12-21 | 2010-12-28 | Honeywell International Inc. | Environmentally resistant ballistic composite based on a nitrile rubber binder |
| JP4792053B2 (en) * | 2008-03-19 | 2011-10-12 | 日本板硝子株式会社 | Aqueous treatment agent applied to reinforcing fibers |
| BRPI0806233A2 (en) | 2008-06-23 | 2011-09-06 | Lanxess Deutschland Gmbh | vulcanizable composition, process for preparing the vulcanizable composition, method for preparing vulcanized polymer and vulcanized polymer |
| PL2368916T3 (en) * | 2010-03-25 | 2013-03-29 | Lanxess Int Sa | Process for the production of water and solvent-free nitrile rubbers |
| CN101870744A (en) * | 2010-06-11 | 2010-10-27 | 北京化工大学 | A kind of hydrogenation method of nitrile ester rubber |
| US8091855B1 (en) * | 2010-06-30 | 2012-01-10 | Hydril Usa Manufacturing Llc | Fluorinated elastomeric blowout preventer packers and method |
| CN101987874A (en) * | 2010-09-15 | 2011-03-23 | 郴州高鑫铂业有限公司 | Method for synthesizing hydrogenated nitrile-butadiene rubber by using nanometer Pd/C catalyst |
| BR112013024969A2 (en) | 2011-03-31 | 2016-12-20 | Zeon Corp | nitrile rubber composition, and, production method of nitrile rubber composition |
| US9484123B2 (en) | 2011-09-16 | 2016-11-01 | Prc-Desoto International, Inc. | Conductive sealant compositions |
| CN102875861A (en) * | 2012-10-17 | 2013-01-16 | 浙江固特气动机械有限公司 | Modified hydrogenated nitrile material for thermal power plant ash valve sealing ring and preparation process of modified hydrogenated nitrile material |
| EP2868676A1 (en) | 2013-10-30 | 2015-05-06 | LANXESS Deutschland GmbH | Functionalised copolymer rubber containing nitrile groups |
| EP2918612B1 (en) | 2014-03-10 | 2016-09-07 | ARLANXEO Deutschland GmbH | Hydrogenated nitrile rubber containing aminomethyl groups, method for producing the same, vulcanizable compositions containing hydrogenated nitrile rubber containing aminomethyl groups, method for their vulcanization and vulcanizates obtainable by this method |
| EP3196239A1 (en) | 2016-01-25 | 2017-07-26 | ARLANXEO Deutschland GmbH | Vulcanisable compounds on the basis of hydrogenated nitrile rubber, method for their preparation and their use |
| EP3248989B1 (en) * | 2016-05-23 | 2020-12-02 | University Of Waterloo | Hydrogenation of nitrile groups in hydrogenated nitrile butadiene rubber and tandem hydrogenation of nitrile groups and olefinic groups in nitrile butadiene rubber using a ruthenium or rhodium complex and a basic reagent |
| EP3248988B1 (en) * | 2016-05-23 | 2020-12-02 | University Of Waterloo | Hydrogenation of nitrile groups in hydrogenated nitrile butadiene rubber and tandem hydrogenation of nitrile groups and olefinic groups in nitrile butadiene rubber using an unsupported rhodium containing catalyst |
| EP3255088B1 (en) | 2016-06-07 | 2020-04-29 | ARLANXEO Deutschland GmbH | Use of vulcanizable compositions and vulcanizates in contact with silane-coated wollastonite containing coolant |
| EP3668922B1 (en) | 2017-08-16 | 2022-03-16 | ARLANXEO Deutschland GmbH | Vulcanisable compositions containing hydrogenated nitrile rubber, vulcanizates prepared from same and their use |
| JP7252212B2 (en) | 2017-09-20 | 2023-04-04 | アランセオ・ドイチュランド・ゲーエムベーハー | Vulcanizable HNBR composition with high thermal conductivity |
| US11370849B2 (en) * | 2018-01-26 | 2022-06-28 | Zeon Corporation | Method for producing carboxy group-containing hydrogenated nitrile rubber |
| EP3770309B1 (en) * | 2018-03-19 | 2023-08-09 | Nippon Sheet Glass Company, Limited | Cord for rubber reinforcement, method for producing same, and rubber product |
| CN108993608B (en) * | 2018-07-27 | 2020-11-06 | 北京化工大学 | Multifunctional catalyst and method for synthesizing hydrogenated nitrile rubber by hydrogen production hydrogenation |
| CN112940185B (en) * | 2021-03-29 | 2022-04-22 | 黄河三角洲京博化工研究院有限公司 | A kind of selective hydrogenation method of copolymer latex |
| WO2025219242A1 (en) | 2024-04-18 | 2025-10-23 | ARLANXEO High Performance Elastomers (Changzhou) Co., Ltd. | Binder composition for an electrochemical energy storage device and method of preparing the same |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2539132C2 (en) * | 1975-09-03 | 1987-04-09 | Bayer Ag, 5090 Leverkusen | Use of hydrogenated diene copolymers as temperature-resistant materials in the sealing sector |
| CA1220300A (en) * | 1982-12-08 | 1987-04-07 | Polysar Limited | Polymer hydrogenation process |
| DE3329974A1 (en) | 1983-08-19 | 1985-02-28 | Bayer Ag, 5090 Leverkusen | MANUFACTURE OF HYDRATED NITRILE RUBBER |
| DE3433392A1 (en) | 1984-09-12 | 1986-03-20 | Bayer Ag, 5090 Leverkusen | HYDROGENATION OF UNSATURATED POLYMER WITH NITRILE GROUPS |
| DE3618907A1 (en) * | 1986-06-05 | 1987-12-10 | Bayer Ag | COMPOSITIONS FROM PRE-TREATED FIBER MATERIAL AND VOLCANISES FROM HNBR |
| JPH0796629B2 (en) | 1987-06-29 | 1995-10-18 | 日本ゼオン株式会社 | Rubber composition |
| US4843114A (en) * | 1988-01-29 | 1989-06-27 | The United States Of America As Represented By The Secretary Of The Army | Rubber compound for tracked vehicle track pads |
| US4914160A (en) * | 1988-06-23 | 1990-04-03 | Hormoz Azizian | Deuteration of unsaturated polymers and copolymers |
| JPH03220206A (en) * | 1989-10-26 | 1991-09-27 | Asahi Chem Ind Co Ltd | Liquid hydrogenated telechelic nitrile rubber and its production |
| CN1058218C (en) * | 1993-06-09 | 2000-11-08 | 机械工厂股份有限公司 | Method and apparatus for heating preform blanks composed of partly crystalline synthetic resins produced by injection molding |
| US5852093A (en) * | 1994-11-30 | 1998-12-22 | Nippon Zeon Co., Ltd. | Vulcanizable rubber composition, seal used in dynamic state, and sealing material |
| US5561197A (en) * | 1995-06-27 | 1996-10-01 | University Of Waterloo | Hydrogenation of diene copolymers |
| CN1058725C (en) * | 1997-05-08 | 2000-11-22 | 南帝化学工业股份有限公司 | A kind of method for the hydrogenation of unsaturated copolymer and its used bimetallic catalyst system |
| DE19753302A1 (en) * | 1997-12-01 | 1999-06-02 | Basf Ag | Process for the selective hydrogenation of ethylenically unsaturated double bonds in polymers |
-
2000
- 2000-04-10 CA CA002304501A patent/CA2304501A1/en not_active Withdrawn
-
2001
- 2001-04-09 PL PL01358059A patent/PL358059A1/en not_active Application Discontinuation
- 2001-04-09 AU AU2001252059A patent/AU2001252059A1/en not_active Abandoned
- 2001-04-09 MX MXPA02009754A patent/MXPA02009754A/en active IP Right Grant
- 2001-04-09 WO PCT/CA2001/000485 patent/WO2001077185A1/en not_active Ceased
- 2001-04-09 US US10/258,245 patent/US7265185B2/en not_active Expired - Lifetime
- 2001-04-09 BR BRPI0109933-7A patent/BR0109933B1/en not_active IP Right Cessation
- 2001-04-09 DE DE60141007T patent/DE60141007D1/en not_active Expired - Lifetime
- 2001-04-09 SK SK1448-2002A patent/SK14482002A3/en not_active Application Discontinuation
- 2001-04-09 EP EP01925236A patent/EP1276773B1/en not_active Expired - Lifetime
- 2001-04-09 KR KR1020027013519A patent/KR20030007512A/en not_active Abandoned
- 2001-04-09 CN CNB018078958A patent/CN100523013C/en not_active Expired - Lifetime
- 2001-04-09 JP JP2001575655A patent/JP4694082B2/en not_active Expired - Lifetime
- 2001-04-09 HU HU0300336A patent/HUP0300336A3/en unknown
- 2001-04-09 RU RU2002129931/04A patent/RU2002129931A/en not_active Application Discontinuation
- 2001-04-09 AT AT01925236T patent/ATE454406T1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR0109933A (en) | 2003-05-27 |
| JP4694082B2 (en) | 2011-06-01 |
| HUP0300336A2 (en) | 2003-06-28 |
| SK14482002A3 (en) | 2003-04-01 |
| US7265185B2 (en) | 2007-09-04 |
| DE60141007D1 (en) | 2010-02-25 |
| MXPA02009754A (en) | 2003-03-27 |
| WO2001077185A1 (en) | 2001-10-18 |
| HK1054558A1 (en) | 2003-12-05 |
| CA2304501A1 (en) | 2001-10-10 |
| BR0109933B1 (en) | 2011-05-03 |
| HUP0300336A3 (en) | 2005-06-28 |
| EP1276773B1 (en) | 2010-01-06 |
| RU2002129931A (en) | 2004-03-27 |
| KR20030007512A (en) | 2003-01-23 |
| ATE454406T1 (en) | 2010-01-15 |
| US20030171500A1 (en) | 2003-09-11 |
| CN100523013C (en) | 2009-08-05 |
| CN1422284A (en) | 2003-06-04 |
| PL358059A1 (en) | 2004-08-09 |
| EP1276773A1 (en) | 2003-01-22 |
| JP2003530467A (en) | 2003-10-14 |
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