ATE175590T1 - Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen - Google Patents
Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffenInfo
- Publication number
- ATE175590T1 ATE175590T1 AT93917640T AT93917640T ATE175590T1 AT E175590 T1 ATE175590 T1 AT E175590T1 AT 93917640 T AT93917640 T AT 93917640T AT 93917640 T AT93917640 T AT 93917640T AT E175590 T1 ATE175590 T1 AT E175590T1
- Authority
- AT
- Austria
- Prior art keywords
- catalysts
- oxidation
- pct
- saturated hydrocarbons
- sec
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 230000003647 oxidation Effects 0.000 title abstract 4
- 238000007254 oxidation reaction Methods 0.000 title abstract 4
- 229930195734 saturated hydrocarbon Natural products 0.000 title 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 229910021536 Zeolite Inorganic materials 0.000 abstract 1
- 235000011037 adipic acid Nutrition 0.000 abstract 1
- 239000001361 adipic acid Substances 0.000 abstract 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 1
- 150000002432 hydroperoxides Chemical class 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 238000007142 ring opening reaction Methods 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 239000010457 zeolite Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/74—Noble metals
- B01J29/7415—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/005—Silicates, i.e. so-called metallosilicalites or metallozeosilites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/065—Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/285—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with peroxy-compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/36—Steaming
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Secondary Cells (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Primary Cells (AREA)
- Laminated Bodies (AREA)
- Moulding By Coating Moulds (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB929215822A GB9215822D0 (en) | 1992-07-24 | 1992-07-24 | Catalysts and their use in oxidation of saturated hydrocarbons |
| GB939307910A GB9307910D0 (en) | 1993-04-16 | 1993-04-16 | Catalysts and their use in oxidation of saturated hydrocarbons |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE175590T1 true ATE175590T1 (de) | 1999-01-15 |
Family
ID=26301322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT93917640T ATE175590T1 (de) | 1992-07-24 | 1993-07-23 | Katalysatoren und deren verwendung in oxidation von gesättigten kohlenwasserstoffen |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5739076A (de) |
| EP (1) | EP0651674B1 (de) |
| JP (1) | JPH07509650A (de) |
| KR (2) | KR100291875B1 (de) |
| AT (1) | ATE175590T1 (de) |
| AU (1) | AU678983B2 (de) |
| BR (1) | BR9306794A (de) |
| CA (1) | CA2140863C (de) |
| CZ (1) | CZ16095A3 (de) |
| DE (1) | DE69323083T2 (de) |
| PL (1) | PL307245A1 (de) |
| TW (1) | TW327165B (de) |
| WO (1) | WO1994002245A1 (de) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5374747A (en) * | 1993-12-23 | 1994-12-20 | Arco Chemical Technology, L.P. | Epoxidation process and catalyst therefore |
| US5453511A (en) * | 1993-12-23 | 1995-09-26 | Arco Chemical Technology, L.P. | Bis-piperidinium compounds |
| US5412122A (en) * | 1993-12-23 | 1995-05-02 | Arco Chemical Technology, L.P. | Epoxidation process |
| US5474754A (en) * | 1994-08-15 | 1995-12-12 | Arco Chemical Technology, L.P. | Preparation of an aluminosilicotitanate isomorphous with zeolite beta |
| ES2130540T3 (es) | 1994-09-28 | 1999-07-01 | Arco Chem Tech | Procedimiento de preparacion de peroxido de hidrogeno, procedimiento integral de epoxidacion y nuevas sales de alquilamonio de antrahidroquinona y antraquinona sustituidas con acido sulfonico. |
| FR2730722B1 (fr) * | 1995-02-17 | 1997-04-30 | Rhone Poulenc Chimie | Zeolithe ti-beta a haute teneur en silice, son procede de preparation et son utilisation comme catalyseur d'oxydation |
| WO1997029991A1 (es) * | 1996-02-16 | 1997-08-21 | Consejo Superior Investigaciones Cientificas | PROCEDIMIENTO DE PREPARACION DE ZEOLITA BETA CONTENIENDO Ti, Y SIN Al |
| US5663384A (en) * | 1996-03-06 | 1997-09-02 | Arco Chemical Technology, L.P. | Asymetric epoxidation using a titanium-containing zeolite and a chiral hydroperoxide |
| ES2133042B1 (es) * | 1996-03-14 | 2000-05-16 | Univ Valencia Politecnica | Sintesis de zeolita y zeotipos isomorfos a la zeolita beta. |
| US6191308B1 (en) | 1996-04-26 | 2001-02-20 | Exxon Chemical Patents Inc. | Process for the manufacture of oxygenates |
| US6074447A (en) * | 1997-02-21 | 2000-06-13 | University Of Hawaii | Hydrogen storage |
| ES2179753B1 (es) | 2000-10-11 | 2005-02-16 | Universidad Politecnica De Valencia | Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion gasolina. |
| ES2183710B1 (es) | 2001-04-12 | 2004-01-16 | Univ Valencia Politecnica | Proceso y catalizadores para la eliminacion de compuestos de azufre de la fraccion diesel. |
| DE10146590A1 (de) | 2001-09-21 | 2003-04-10 | Bayer Cropscience Ag | Selektive Herbizide auf Basis von substituierten Thien-3-yl-sulfonylamino(thio)carbonyl-triazolin(thi)onen und Safenern |
| US20040054199A1 (en) * | 2002-09-17 | 2004-03-18 | Basf Aktiengesellschaft | Process for epoxidation and catalyst to be used therein |
| DE10320634A1 (de) | 2003-05-08 | 2004-11-18 | Basf Ag | Verfahren zur Umsetzung einer organischen Verbindung mit einem Hydroperoxid |
| FR2869894B1 (fr) * | 2004-05-10 | 2007-02-23 | Inst Francais Du Petrole | Methode de synthese de metalloaluminosilicate cristallise par synthese directe |
| CN101098755B (zh) | 2005-01-14 | 2010-06-09 | 陶氏环球技术公司 | 钛硅酸盐的回收和活性氧化催化剂的再生 |
| DE102009008144A1 (de) * | 2009-02-09 | 2010-08-19 | Nano-X Gmbh | Verfahren zur Herstellung von Alkali- und Erdalkalilegierungen und Verwendung der Alkali- und Erdalkalilegierungen |
| CN102452917B (zh) * | 2010-10-27 | 2014-08-20 | 中国石油化工股份有限公司 | 一种催化氧化羟基酸的方法 |
| CN102452922B (zh) * | 2010-10-27 | 2014-08-20 | 中国石油化工股份有限公司 | 一种二元羧酸的生产方法 |
| CN105622385A (zh) * | 2014-10-27 | 2016-06-01 | 湖南师范大学 | 清洁催化氧化环己酮制己二酸工艺及催化剂和催化剂制备方法 |
| CN105622386A (zh) * | 2014-10-27 | 2016-06-01 | 湖南师范大学 | 一种环己酮合成己二酸的绿色工艺 |
| JP6621281B2 (ja) * | 2015-09-18 | 2019-12-18 | 国立大学法人横浜国立大学 | チタノシリケートの製造方法 |
| CN111484031B (zh) * | 2019-01-28 | 2023-03-10 | 中国石油化工股份有限公司 | 改性钛硅分子筛及其制备方法和应用以及硫醚氧化方法 |
| CN116120157A (zh) * | 2023-02-24 | 2023-05-16 | 山东京博石油化工有限公司 | 一种由环戊烷选择性氧化制备环戊酮的方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4490565A (en) * | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
| US4590322A (en) * | 1985-06-12 | 1986-05-20 | Mobil Oil Corporation | Use of hydrogen sulfide to improve benzene production over zeolites |
| US4798816A (en) * | 1986-12-19 | 1989-01-17 | Union Oil Company Of California | Process for increasing the selectivity of an alkylation catalyst for monoalkylation |
| US4927525A (en) * | 1988-08-30 | 1990-05-22 | Mobil Oil Corporation | Catalytic reforming with improved zeolite catalysts |
| US5412122A (en) * | 1993-12-23 | 1995-05-02 | Arco Chemical Technology, L.P. | Epoxidation process |
-
1993
- 1993-07-23 WO PCT/EP1993/001972 patent/WO1994002245A1/en not_active Ceased
- 1993-07-23 AU AU47023/93A patent/AU678983B2/en not_active Ceased
- 1993-07-23 BR BR9306794A patent/BR9306794A/pt not_active IP Right Cessation
- 1993-07-23 EP EP93917640A patent/EP0651674B1/de not_active Expired - Lifetime
- 1993-07-23 JP JP6503925A patent/JPH07509650A/ja active Pending
- 1993-07-23 DE DE69323083T patent/DE69323083T2/de not_active Expired - Fee Related
- 1993-07-23 US US08/374,588 patent/US5739076A/en not_active Expired - Lifetime
- 1993-07-23 CZ CZ95160A patent/CZ16095A3/cs unknown
- 1993-07-23 AT AT93917640T patent/ATE175590T1/de active
- 1993-07-23 CA CA002140863A patent/CA2140863C/en not_active Expired - Fee Related
- 1993-07-23 KR KR1019950700268A patent/KR100291875B1/ko not_active Expired - Fee Related
- 1993-07-23 PL PL93307245A patent/PL307245A1/xx unknown
-
1994
- 1994-07-23 KR KR1019960700313A patent/KR960703803A/ko not_active Withdrawn
- 1994-07-29 TW TW083106954A patent/TW327165B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2140863A1 (en) | 1994-02-03 |
| DE69323083D1 (de) | 1999-02-25 |
| BR9306794A (pt) | 1998-12-08 |
| KR950702451A (ko) | 1995-07-29 |
| AU678983B2 (en) | 1997-06-19 |
| JPH07509650A (ja) | 1995-10-26 |
| PL307245A1 (en) | 1995-05-15 |
| TW327165B (en) | 1998-02-21 |
| EP0651674A1 (de) | 1995-05-10 |
| EP0651674B1 (de) | 1999-01-13 |
| CZ16095A3 (en) | 1995-10-18 |
| KR960703803A (ko) | 1996-08-31 |
| CA2140863C (en) | 2004-04-20 |
| US5739076A (en) | 1998-04-14 |
| WO1994002245A1 (en) | 1994-02-03 |
| AU4702393A (en) | 1994-02-14 |
| DE69323083T2 (de) | 1999-07-15 |
| KR100291875B1 (ko) | 2001-11-05 |
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