ATE169034T1 - Verwendung der veränderung des mg:ti verhältnisses in einem katalysator zur änderung oder kontrolle der verteilung der kurzen ketten in ethylencopolymeren - Google Patents
Verwendung der veränderung des mg:ti verhältnisses in einem katalysator zur änderung oder kontrolle der verteilung der kurzen ketten in ethylencopolymerenInfo
- Publication number
- ATE169034T1 ATE169034T1 AT93908549T AT93908549T ATE169034T1 AT E169034 T1 ATE169034 T1 AT E169034T1 AT 93908549 T AT93908549 T AT 93908549T AT 93908549 T AT93908549 T AT 93908549T AT E169034 T1 ATE169034 T1 AT E169034T1
- Authority
- AT
- Austria
- Prior art keywords
- support material
- mixing
- time sufficient
- temperature
- titanium compound
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 229920001038 ethylene copolymer Polymers 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 4
- 150000003609 titanium compounds Chemical class 0.000 abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 2
- 239000011369 resultant mixture Substances 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 239000002002 slurry Substances 0.000 abstract 2
- 238000003756 stirring Methods 0.000 abstract 2
- 150000003682 vanadium compounds Chemical class 0.000 abstract 2
- 239000004711 α-olefin Substances 0.000 abstract 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 150000001350 alkyl halides Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002734 organomagnesium group Chemical group 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/91—Product with molecular orientation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/854,175 US5231151A (en) | 1991-01-18 | 1992-03-20 | Silica supported transition metal catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE169034T1 true ATE169034T1 (de) | 1998-08-15 |
Family
ID=25317940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT93908549T ATE169034T1 (de) | 1992-03-20 | 1993-03-17 | Verwendung der veränderung des mg:ti verhältnisses in einem katalysator zur änderung oder kontrolle der verteilung der kurzen ketten in ethylencopolymeren |
Country Status (12)
| Country | Link |
|---|---|
| US (3) | US5231151A (de) |
| EP (1) | EP0705282B1 (de) |
| JP (3) | JP3306663B2 (de) |
| KR (1) | KR100256460B1 (de) |
| AT (1) | ATE169034T1 (de) |
| AU (2) | AU677184B2 (de) |
| CA (1) | CA2132447C (de) |
| DE (1) | DE69320070T2 (de) |
| ES (1) | ES2118952T3 (de) |
| FI (1) | FI111376B (de) |
| TW (1) | TW327177B (de) |
| WO (1) | WO1993019105A2 (de) |
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| US6747113B1 (en) | 1991-01-18 | 2004-06-08 | The Dow Chemical Company | Silica supported transition metal catalyst |
| US5231151A (en) * | 1991-01-18 | 1993-07-27 | The Dow Chemical Company | Silica supported transition metal catalyst |
| US5470812A (en) * | 1991-11-06 | 1995-11-28 | Mobil Oil Corporation | High activity polyethylene catalysts prepared with alkoxysilane reagents |
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| EP0729478B1 (de) * | 1993-11-18 | 1999-01-07 | Mobil Oil Corporation | Katalysatorzusammensetzung für die copolymerisation von ethylen |
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| AU2468897A (en) * | 1995-08-24 | 1997-08-28 | Quantum Chemical Corporation | Supported polymerization catalyst component and system |
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| US7569285B2 (en) * | 1996-10-17 | 2009-08-04 | The Trustees Of Princeton University | Enhanced bonding layers on titanium materials |
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-
1992
- 1992-03-20 US US07/854,175 patent/US5231151A/en not_active Expired - Lifetime
-
1993
- 1993-02-24 US US08/021,705 patent/US5420090A/en not_active Expired - Lifetime
- 1993-03-17 WO PCT/US1993/002751 patent/WO1993019105A2/en not_active Ceased
- 1993-03-17 DE DE69320070T patent/DE69320070T2/de not_active Expired - Lifetime
- 1993-03-17 AU AU39332/93A patent/AU677184B2/en not_active Ceased
- 1993-03-17 KR KR1019940703261A patent/KR100256460B1/ko not_active Expired - Lifetime
- 1993-03-17 JP JP51682393A patent/JP3306663B2/ja not_active Expired - Lifetime
- 1993-03-17 CA CA 2132447 patent/CA2132447C/en not_active Expired - Lifetime
- 1993-03-17 ES ES93908549T patent/ES2118952T3/es not_active Expired - Lifetime
- 1993-03-17 AT AT93908549T patent/ATE169034T1/de not_active IP Right Cessation
- 1993-03-17 EP EP19930908549 patent/EP0705282B1/de not_active Expired - Lifetime
- 1993-07-24 TW TW082105908A patent/TW327177B/zh active
-
1994
- 1994-09-19 FI FI944338A patent/FI111376B/fi active
- 1994-11-10 US US08336947 patent/US5487938B1/en not_active Expired - Lifetime
-
1997
- 1997-04-29 AU AU19940/97A patent/AU704251B2/en not_active Ceased
-
2002
- 2002-01-10 JP JP2002003385A patent/JP3626935B2/ja not_active Expired - Lifetime
- 2002-01-10 JP JP2002003386A patent/JP2002256027A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CA2132447C (en) | 2006-04-25 |
| FI111376B (fi) | 2003-07-15 |
| US5487938B1 (en) | 1997-11-18 |
| US5487938A (en) | 1996-01-30 |
| WO1993019105A2 (en) | 1993-09-30 |
| JP3626935B2 (ja) | 2005-03-09 |
| DE69320070D1 (de) | 1998-09-03 |
| EP0705282B1 (de) | 1998-07-29 |
| KR950700944A (ko) | 1995-02-20 |
| TW327177B (en) | 1998-02-21 |
| AU3933293A (en) | 1993-10-21 |
| FI944338A7 (fi) | 1994-11-18 |
| AU704251B2 (en) | 1999-04-15 |
| FI944338A0 (fi) | 1994-09-19 |
| US5231151A (en) | 1993-07-27 |
| WO1993019105A3 (en) | 1993-11-11 |
| JP2002256027A (ja) | 2002-09-11 |
| JP2002284904A (ja) | 2002-10-03 |
| AU1994097A (en) | 1997-08-21 |
| AU677184B2 (en) | 1997-04-17 |
| US5420090A (en) | 1995-05-30 |
| JPH07507819A (ja) | 1995-08-31 |
| ES2118952T3 (es) | 1998-10-01 |
| DE69320070T2 (de) | 1998-12-10 |
| KR100256460B1 (ko) | 2000-05-15 |
| EP0705282A1 (de) | 1996-04-10 |
| JP3306663B2 (ja) | 2002-07-24 |
| CA2132447A1 (en) | 1993-09-30 |
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| Date | Code | Title | Description |
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| UEP | Publication of translation of european patent specification | ||
| REN | Ceased due to non-payment of the annual fee |