AR111257A1 - Piridil-formamidinas que tienen actividad fungicida, composiciones agronómicas y usos de las mismas - Google Patents
Piridil-formamidinas que tienen actividad fungicida, composiciones agronómicas y usos de las mismasInfo
- Publication number
- AR111257A1 AR111257A1 ARP180100718A ARP180100718A AR111257A1 AR 111257 A1 AR111257 A1 AR 111257A1 AR P180100718 A ARP180100718 A AR P180100718A AR P180100718 A ARP180100718 A AR P180100718A AR 111257 A1 AR111257 A1 AR 111257A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- groups
- haloalkyl
- cycloalkyl
- cyano group
- Prior art date
Links
- 230000009418 agronomic effect Effects 0.000 title abstract 3
- 239000000417 fungicide Substances 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- 230000000694 effects Effects 0.000 title 1
- 230000000855 fungicidal effect Effects 0.000 title 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 12
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 abstract 8
- 125000005843 halogen group Chemical group 0.000 abstract 7
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 6
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 5
- 125000004641 (C1-C12) haloalkyl group Chemical group 0.000 abstract 4
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 4
- 125000004737 (C1-C6) haloalkoxy group Chemical group 0.000 abstract 3
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 3
- 125000001188 haloalkyl group Chemical group 0.000 abstract 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 3
- -1 Pyridyl formamidines Chemical class 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000004122 cyclic group Chemical group 0.000 abstract 2
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 abstract 1
- 241000233866 Fungi Species 0.000 abstract 1
- 101100495923 Schizosaccharomyces pombe (strain 972 / ATCC 24843) chr2 gene Proteins 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000004480 active ingredient Substances 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000005090 alkenylcarbonyl group Chemical group 0.000 abstract 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 1
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 1
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 abstract 1
- 125000006254 cycloalkyl carbonyl group Chemical group 0.000 abstract 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 abstract 1
- 239000012634 fragment Substances 0.000 abstract 1
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 1
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 1
- 125000004692 haloalkylcarbonyl group Chemical group 0.000 abstract 1
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 1
- 125000005347 halocycloalkyl group Chemical group 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Chemical group 0.000 abstract 1
- 230000003032 phytopathogenic effect Effects 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/74—Amino or imino radicals substituted by hydrocarbon or substituted hydrocarbon radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Piridil-formamidinas de la fórmula general (1) junto con composiciones agronómicas que comprenden dichos compuestos de la fórmula (1) y por lo menos un ingrediente activo adicional compatible los mismos, seleccionados entre fungicidas diferente de aquellos de la fórmula general (1), y su uso con relación al control de hongos fitopatógenos de cultivos agronómicos. Reivindicación 1: Piridil-formamidinas, caracterizadas porque son de la fórmula general (1), en donde: R representa un hidrógeno; un C₁₋₁₂ alquilo; un C₁₋₁₂ haloalquilo; un C₂₋₁₂ alquenilo; un C₂₋₁₂ haloalquenilo; un C₂₋₁₂ alquinilo; un C₂₋₁₂ haloalquinilo; un C₃₋₁₄ cicloalquilo; un C₄₋₁₈ cicloalquilalquilo; un C₃₋₁₄ cicloalquenilo; un C₃₋₁₄ halocicloalquilo; un C₄₋₁₈ cicloalquenilalquilo; un formilo; un C₂₋₁₂ alquilcarbonilo; un C₂₋₁₂ haloalquilcarbonilo; un C₃₋₁₂ alquenilcarbonilo; un C₄₋₁₄ cicloalquilcarbonilo; o R representa un C₁₋₆-alquil-B-C₁₋₁₂-alquilo; C₁₋₆-haloalquil-B-C₁₋₁₂-alquilo; C₁₋₆-alquil-B-C₁₋₁₂-haloalquilo; C₁₋₆-haloalquil-B-C₁₋₁₂-haloalquilo; C₃₋₈-C₃₋₁₄-cicloalquil-B-C₁₋₁₂-alquilo; C₃₋₁₄-cicloalquil-B-C₁₋₁₂-haloalquilo; C₁₋₆-alquil-B-C₃₋₁₄-cicloalquilo; C₁₋₆-alquil-B-C₃₋₁₄-halocicloalquilo; C₃₋₁₄-cicloalquil-B-C₃₋₁₄-cicloalquilo; C₄₋₁₈-cicloalquilalquil-B-C₃₋₁₄-cicloalquilo; C₁₋₆-alquil-B-C₂₋₁₂-alquenilo; o R representa A-; A-(C₁₋₆ alquil)-; A-(C₁₋₆ haloalquil)-; A-(C₃₋₁₄ cicloalquil)-; A-(C=O)-; A-(C₁₋₆ alquil)-(C=O)-; A-B-(C₁₋₁₂ alquil)-; A-B-(C₁₋₁₂ haloalquil); A-B-(C₃₋₁₄ cicloalquil)-; A-(C₁₋₁₂ alquil)-B-(C₁₋₁₂ alquilo); A-(C₁₋₁₂ alquil)-B-(C₁₋₁₂-haloalquilo); A-B-A-; (C₁₋₆ alquil)-B-A-; (C₁₋₆ haloalquil)-B-A-; (C₃₋₁₄ cicloalquil)-B-A-; A-B-A-(C₁₋₆ alquil)-; A-B-A-(C₃₋₁₄ cicloalquil)-; (C₁₋₆ alquil)-B-A-(C₁₋₆ alquil)-; (C₃₋₁₄ cicloalquil)-B-A-(C₁₋₆ alquil)-; (C₁₋₆ haloalquil)-B-A-(C₁₋₆ alquil)-; A representa un grupo carbocíclico aromático mono o bicíclico sustituido posiblemente por uno o más grupos, iguales o diferentes, que preferiblemente se seleccionan entre átomos de halógeno, grupos C₁₋₁₂ alquilo, grupos C₁₋₁₂ haloalquilo, grupos C₁₋₆ alcoxilo, grupos C₄₋₁₅ cicloalcoxilo, grupos C₁₋₆ haloalcoxilo, un grupo ciano, un hidroxilo; o un monociclo o biciclo condensado con los terminales 3 - 12, posiblemente aromático, parcial o completamente saturado y que contiene entre 1 y 4 heteroátomos seleccionados entre nitrógeno, oxígeno y azufre, siempre que estos sistemas cíclicos con 3 - 12 terminales no contengan fragmentos -O-O-, -S-S-, -O-S-, donde dichos sistemas cíclicos con 3 - 12 terminales pueden estar sustituidas por uno o más grupos, iguales o diferentes, seleccionados preferiblemente entre átomos de halógeno, grupos C₁₋₁₂ alquilo, grupos C₁₋₁₂ haloalquilo, grupos C₁₋₆ alcoxilo, grupos C₄₋₁₅ cicloalcoxilo, grupos C₁₋₆ haloalcoxilo, un grupo ciano, un hidroxilo; B representa -(C=O)-; -C(=NOR⁵)-; O-(C=O)-; -C(=O)-O-; -O-; -S-; -N(R⁶)-(C=O)-; o -(C=O)-N(R⁶)-; R¹ representa un C₁₋₆ alquilo; R² representa un C₂₋₆ alquilo; o R¹ y R², junto con el átomo de N al cual están unidos, forman un anillo heterocíclico que contiene entre 4 y 7 átomos, posiblemente sustituidas por átomos de halógeno; R³ y R⁴, iguales o diferentes, representan un átomo de hidrógeno; un átomo de halógeno; un C₁₋₆ alquilo; un C₁₋₆ alcoxilo; un C₁₋₆ haloalcoxilo, un grupo CF₃; un grupo CF₂H; un grupo CFH₂; un grupo ciano; R⁵ y R⁶ representan un átomo de hidrógeno; un C₁₋₆ alquilo; un C₁₋₆ haloalquilo; un C₃₋₆ cicloalquilo; un grupo bencilo o arilo posiblemente sustituido por uno o más grupos, iguales o diferentes, que preferiblemente se seleccionan entre átomos de halógeno, grupos C₁₋₁₂ alquilo, grupos C₁₋₁₂ haloalquilo, grupos C₁₋₆ alcoxilo, grupos C₄₋₁₅ cicloalcoxilo, grupos C₁₋₆ haloalcoxilo, un grupo ciano, un hidroxilo; siempre que cuando R³ es un átomo de hidrógeno, un átomo de halógeno, un grupo ciano, un C₁₋₆ alquilo o un C₁₋₆ alcoxilo, entonces R⁴ es diferente de un átomo de hidrógeno, un átomo de halógeno o un grupo ciano.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT102017000033543A IT201700033543A1 (it) | 2017-03-27 | 2017-03-27 | Piridil-formammidine ad attività fungicida, loro composizioni agronomiche e relativo uso |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR111257A1 true AR111257A1 (es) | 2019-06-19 |
Family
ID=59683719
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP180100718A AR111257A1 (es) | 2017-03-27 | 2018-03-26 | Piridil-formamidinas que tienen actividad fungicida, composiciones agronómicas y usos de las mismas |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20210100246A1 (es) |
| AR (1) | AR111257A1 (es) |
| IT (1) | IT201700033543A1 (es) |
| UY (1) | UY37655A (es) |
| WO (1) | WO2018178848A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT201900021216A1 (it) | 2019-11-14 | 2021-05-14 | Isagro Spa | Processo per la preparazione di derivati piridinici e corrispondenti piridil-formammidine |
| TW202237561A (zh) * | 2020-11-23 | 2022-10-01 | 美商科迪華農業科技有限責任公司 | 殺真菌芳基脒 |
| JPWO2023189781A1 (es) * | 2022-03-28 | 2023-10-05 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010519267A (ja) * | 2007-02-22 | 2010-06-03 | シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト | 新規殺微生物剤 |
| EP2264011A1 (de) * | 2009-06-03 | 2010-12-22 | Bayer CropScience AG | Heteroarylamidine und deren Verwendung als Fungizide |
| ITMI20101564A1 (it) * | 2010-08-23 | 2012-02-24 | Isagro Ricerca Srl | Fenilammidine ad elevata attivita' fungicida e relativo uso |
| BR112015004968B1 (pt) * | 2012-09-07 | 2020-09-15 | Bayer Cropscience Ag | Combinações fungicidas sinérgicas compreendendo um composto amidina e um inibidor da biossíntese do ergosterol, suas utilizações e métodos para o controle de fungos fitopatogênicos |
-
2017
- 2017-03-27 IT IT102017000033543A patent/IT201700033543A1/it unknown
-
2018
- 2018-03-26 US US16/496,802 patent/US20210100246A1/en not_active Abandoned
- 2018-03-26 WO PCT/IB2018/052051 patent/WO2018178848A1/en not_active Ceased
- 2018-03-26 AR ARP180100718A patent/AR111257A1/es not_active Application Discontinuation
- 2018-04-02 UY UY0001037655A patent/UY37655A/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| IT201700033543A1 (it) | 2018-09-27 |
| BR112019019096A2 (pt) | 2020-04-22 |
| WO2018178848A1 (en) | 2018-10-04 |
| UY37655A (es) | 2018-10-31 |
| US20210100246A1 (en) | 2021-04-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |