AR086819A1 - 3-alcoxi, tioalquil y amino-4-amino-6-picolinatos (sustituidos) y su uso como herbicidas - Google Patents
3-alcoxi, tioalquil y amino-4-amino-6-picolinatos (sustituidos) y su uso como herbicidasInfo
- Publication number
- AR086819A1 AR086819A1 ARP120102360A ARP120102360A AR086819A1 AR 086819 A1 AR086819 A1 AR 086819A1 AR P120102360 A ARP120102360 A AR P120102360A AR P120102360 A ARP120102360 A AR P120102360A AR 086819 A1 AR086819 A1 AR 086819A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- amino
- haloalkyl
- substituted
- nr4c
- Prior art date
Links
- 239000004009 herbicide Substances 0.000 title abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 3
- -1 amino-4-amino-6-picolinic acids Chemical class 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical group 0.000 abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 2
- 125000006272 (C3-C7) cycloalkyl group Chemical group 0.000 abstract 2
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- 125000005133 alkynyloxy group Chemical group 0.000 abstract 2
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 2
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 2
- 125000005347 halocycloalkyl group Chemical group 0.000 abstract 2
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 1
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- 125000004738 (C1-C6) alkyl sulfinyl group Chemical group 0.000 abstract 1
- 125000004739 (C1-C6) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000006700 (C1-C6) alkylthio group Chemical group 0.000 abstract 1
- 125000000171 (C1-C6) haloalkyl group Chemical group 0.000 abstract 1
- MZAGXDHQGXUDDX-JSRXJHBZSA-N (e,2z)-4-ethyl-2-hydroxyimino-5-nitrohex-3-enamide Chemical compound [O-][N+](=O)C(C)C(/CC)=C/C(=N/O)/C(N)=O MZAGXDHQGXUDDX-JSRXJHBZSA-N 0.000 abstract 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 1
- 241000196324 Embryophyta Species 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 125000005108 alkenylthio group Chemical group 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000005109 alkynylthio group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000002843 carboxylic acid group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004994 halo alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000005291 haloalkenyloxy group Chemical group 0.000 abstract 1
- 125000004692 haloalkylcarbonyl group Chemical group 0.000 abstract 1
- 125000004441 haloalkylsulfonyl group Chemical group 0.000 abstract 1
- 125000000232 haloalkynyl group Chemical group 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Chemical group COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000004001 thioalkyl group Chemical group 0.000 abstract 1
- 125000004665 trialkylsilyl group Chemical group 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/65—One oxygen atom attached in position 3 or 5
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/73—Unsubstituted amino or imino radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
- C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pyridine Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Los ácidos 3-alcoxi, tioalquilo y amino-4-amino-6-picolínicos (sustituidos) que poseen un sustituyente halógeno, alquilo o arilo mono-, di- tri- y tetra-sustituido en la posición 6, y sus derivados ácidos, son herbicidas que muestran un amplio espectro de control de malezas. Reivindicación 1: Un compuesto de la fórmula (1) en donde Q representa alcoxi C₁₋₄, haloalcoxi C₁₋₄, SR³, o NR¹R²; X representa H o halógeno; Y representa F, Cl, alquilo C₁₋₆, haloalquilo C₁₋₆, alquenilo C₂₋₆, haloalquenilo C₂₋₆, cicloalquilo C₃₋₇, halocicloalquilo C₃₋₇ o Ar; Ar representa un grupo fenilo o una piridina sustituida con uno a cuatro sustituyentes seleccionados de manera independiente de halógeno, nitro, ciano, formilo, alquilo C₁₋₆, cicloalquilo C₃₋₇, alquenilo C₂₋₆, alquinilo C₂₋₆, alcoxi C₁₋₆, alcoxialquilo C₂₋₄, alquilcarbonilo C₂₋₆, alquiltio C₁₋₆, alquilsulfinilo C₁₋₆, alquilsulfonilo C₁₋₆, alqueniloxi C₂₋₄, alquiniloxi C₂₋₄, alqueniltio C₂₋₄, alquiniltio C₂₋₄, haloalquilo C₁₋₆, halocicloalquilo C₃₋₇, haloalquenilo C₂₋₆, haloalquinilo C₁₋₆, haloalcoxi C₁₋₆, haloalcoxialquilo C₂₋₄, haloalquilcarbonilo C₂₋₆, haloalquiltio haloalquilsulfinilo C₁₋₆, haloalquilsulfonilo C₁₋₆, trialquilsililo C₃₋₆, haloalqueniloxi C₂₋₄, haloalquiniloxi C₂₋₄, haloalqueniltio C₂₋₄, haloalquiniltio C₂₋₄, -OCH₂CH₂-, -OCH₂CH₂CH₂-, -OCH₂O-, -OCH₂CH₂O-, -C(O)OR³, -C(O)NR³R⁴, -CR⁴NOR³, -NH₂, -NR³R⁴, -NR⁴OR³, -NR⁴SO₂R³, -NR⁴C(O)R³, -NR⁴C(O)OR³, -NR⁴C(O)NR³R⁴ o -NCR⁴NR³R⁴; R¹ y R² representan de manera independiente H, alquilo C₁₋₆, o acilo C₁₋₆; R³ representa alquilo C₁₋₄ o haloalquilo C₁₋₄; y R⁴ representa H, alquilo C₁₋₄ o haloalquilo C₁₋₄; o, con respecto al grupo de ácido carboxílico de fórmula (1), un derivado aceptable desde el punto de vista agrícola del mismo.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161502888P | 2011-06-30 | 2011-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR086819A1 true AR086819A1 (es) | 2014-01-22 |
Family
ID=47391234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP120102360A AR086819A1 (es) | 2011-06-30 | 2012-06-29 | 3-alcoxi, tioalquil y amino-4-amino-6-picolinatos (sustituidos) y su uso como herbicidas |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US8754229B2 (es) |
| EP (1) | EP2725903B1 (es) |
| JP (2) | JP6147252B2 (es) |
| KR (1) | KR102108222B1 (es) |
| CN (1) | CN103763923B (es) |
| AR (1) | AR086819A1 (es) |
| AU (1) | AU2012275201B2 (es) |
| BR (1) | BR102012016297A8 (es) |
| CA (1) | CA2839627C (es) |
| CL (1) | CL2013003714A1 (es) |
| CO (1) | CO6852094A2 (es) |
| EA (1) | EA028844B1 (es) |
| ES (1) | ES2795438T3 (es) |
| MX (1) | MX374482B (es) |
| PT (1) | PT2725903T (es) |
| UA (1) | UA113412C2 (es) |
| WO (1) | WO2013003740A1 (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2626975C2 (ru) * | 2011-12-30 | 2017-08-02 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Способы выделения (4-хлор-2-фтор-3-замещенный-фенил)боронатов и способы их применения |
| US9637505B2 (en) | 2013-03-15 | 2017-05-02 | Dow Agrosciences Llc | 4-amino-6-(heterocyclic)picolinates and 6-amino-2-(heterocyclic)pyrimidine-4-carboxylates and their use as herbicides |
| CN105208859A (zh) * | 2013-03-15 | 2015-12-30 | 美国陶氏益农公司 | 作为除草剂的新型的4-氨基吡啶和6-氨基嘧啶羧酸酯 |
| US9113629B2 (en) * | 2013-03-15 | 2015-08-25 | Dow Agrosciences Llc | 4-amino-6-(4-substituted-phenyl)-picolinates and 6-amino-2-(4-substituted-phenyl)-pyrimidine-4-carboxylates and their use as herbicides |
| CN109134440A (zh) * | 2013-03-15 | 2019-01-04 | 美国陶氏益农公司 | 除草化合物及其作为除草剂的用途 |
| US9993289B2 (en) * | 2013-03-18 | 2018-06-12 | Olympus Corporation | Treatment device |
| CN105899521A (zh) | 2013-09-05 | 2016-08-24 | 陶氏益农公司 | 制备硼基化芳烃的方法 |
| TW201625354A (zh) | 2014-06-16 | 2016-07-16 | 陶氏農業科學公司 | 用於製備氧硼基化芳烴之方法 |
| AR101858A1 (es) | 2014-09-15 | 2017-01-18 | Dow Agrosciences Llc | Composiciones herbicidas protegidas que comprenden un herbicida de ácido piridincarboxílico |
| TWI689252B (zh) | 2014-09-15 | 2020-04-01 | 美商陶氏農業科學公司 | 源自於施用吡啶羧酸除草劑與乙醯乳酸合成酶（ａｌｓ）抑制劑的協同性雜草控制 |
| TWI685302B (zh) | 2014-09-15 | 2020-02-21 | 美商陶氏農業科學公司 | 包含吡啶羧酸除草劑之安全的除草組成物 |
| WO2016044276A1 (en) | 2014-09-15 | 2016-03-24 | Dow Agrosciences Llc | Synergistic weed control from applications of pyridine carboxylic acid herbicides and photosystem ii inhibitors |
| TWI689251B (zh) | 2014-09-15 | 2020-04-01 | 美商陶氏農業科學公司 | 源自於施用吡啶羧酸除草劑與合成生長素除草劑及/或生長素轉運抑制劑的協同性雜草控制 |
| GB201604969D0 (en) * | 2016-03-23 | 2016-05-04 | Syngenta Participations Ag | Improvements in or relating to organic compounds |
| GB201604970D0 (en) * | 2016-03-23 | 2016-05-04 | Syngenta Participations Ag | Improvements in or relating to organic compounds |
| ES2899104T3 (es) * | 2016-03-23 | 2022-03-10 | Syngenta Participations Ag | Herbicidas |
| BR112018076990B1 (pt) | 2016-06-27 | 2022-08-23 | Moghu Research Center Ltd. | Composto baseado em piridina incluindo anel de isoxazolina, herbicida, composição herbicida e método de preparação do dito composto |
| CN115057845B (zh) * | 2022-06-14 | 2024-05-03 | 山东罗欣药业集团恒欣药业有限公司 | 一种阿贝西利的制备方法 |
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| NZ192948A (en) * | 1979-03-09 | 1982-02-23 | Ishihara Sangyo Kaisha | Preparation of beta-trifuloromethyl-pyridine derivatives directly from beta-picoline |
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| AU2007204887B2 (en) | 2006-01-13 | 2011-06-23 | Corteva Agriscience Llc | 2-(poly-substituted aryl)-6-amino-5-halo-4-pyrimidinecarboxylic acids and their use as herbicides |
| JP2007204458A (ja) | 2006-02-06 | 2007-08-16 | Dai Ichi Seiyaku Co Ltd | 抗真菌作用三環性複素環化合物 |
| ATE500230T1 (de) | 2007-08-30 | 2011-03-15 | Dow Agrosciences Llc | 2-(substituierte phenyl)-6-amino-5-alkoxy-, thioalkoxy- und aminoalkyl-4-pyrimidincarboxylate und ihre verwendung als herbizide |
| CN102786480B (zh) * | 2007-10-02 | 2016-02-10 | 陶氏益农公司 | 2-取代的-6-氨基-5-烷基、烯基或炔基-嘧啶-4-羧酸及其作为除草剂的用途 |
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2012
- 2012-06-29 CA CA2839627A patent/CA2839627C/en active Active
- 2012-06-29 CN CN201280041458.0A patent/CN103763923B/zh active Active
- 2012-06-29 AR ARP120102360A patent/AR086819A1/es active IP Right Grant
- 2012-06-29 EP EP12804735.4A patent/EP2725903B1/en active Active
- 2012-06-29 MX MX2013015322A patent/MX374482B/es active IP Right Grant
- 2012-06-29 JP JP2014519149A patent/JP6147252B2/ja not_active Expired - Fee Related
- 2012-06-29 KR KR1020147002031A patent/KR102108222B1/ko active Active
- 2012-06-29 BR BR102012016297A patent/BR102012016297A8/pt not_active Application Discontinuation
- 2012-06-29 ES ES12804735T patent/ES2795438T3/es active Active
- 2012-06-29 US US13/538,399 patent/US8754229B2/en active Active
- 2012-06-29 AU AU2012275201A patent/AU2012275201B2/en active Active
- 2012-06-29 EA EA201490134A patent/EA028844B1/ru not_active IP Right Cessation
- 2012-06-29 WO PCT/US2012/044970 patent/WO2013003740A1/en not_active Ceased
- 2012-06-29 PT PT128047354T patent/PT2725903T/pt unknown
- 2012-06-29 UA UAA201400680A patent/UA113412C2/uk unknown
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2013
- 2013-12-24 CL CL2013003714A patent/CL2013003714A1/es unknown
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2014
- 2014-01-10 CO CO14004190A patent/CO6852094A2/es not_active Application Discontinuation
- 2014-04-29 US US14/264,142 patent/US9518018B2/en active Active
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2017
- 2017-03-15 JP JP2017050599A patent/JP6334025B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| ES2795438T3 (es) | 2020-11-23 |
| US9518018B2 (en) | 2016-12-13 |
| AU2012275201A1 (en) | 2014-02-20 |
| PT2725903T (pt) | 2020-06-30 |
| CL2013003714A1 (es) | 2014-10-10 |
| JP2014523432A (ja) | 2014-09-11 |
| CN103763923A (zh) | 2014-04-30 |
| EA201490134A1 (ru) | 2014-11-28 |
| AU2012275201B2 (en) | 2016-05-12 |
| CA2839627A1 (en) | 2013-01-03 |
| KR102108222B1 (ko) | 2020-05-08 |
| JP2017141252A (ja) | 2017-08-17 |
| MX374482B (es) | 2025-03-06 |
| BR102012016297A8 (pt) | 2018-07-31 |
| CN103763923B (zh) | 2016-08-17 |
| BR102012016297A2 (pt) | 2013-07-02 |
| CA2839627C (en) | 2021-01-19 |
| EP2725903A1 (en) | 2014-05-07 |
| CO6852094A2 (es) | 2014-01-30 |
| MX2013015322A (es) | 2014-01-31 |
| US20150133301A1 (en) | 2015-05-14 |
| JP6147252B2 (ja) | 2017-06-14 |
| US8754229B2 (en) | 2014-06-17 |
| JP6334025B2 (ja) | 2018-05-30 |
| US20130005574A1 (en) | 2013-01-03 |
| UA113412C2 (xx) | 2017-01-25 |
| EP2725903B1 (en) | 2020-04-15 |
| EA028844B1 (ru) | 2018-01-31 |
| EP2725903A4 (en) | 2015-06-24 |
| WO2013003740A1 (en) | 2013-01-03 |
| KR20140040251A (ko) | 2014-04-02 |
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