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AR072317A1 - DIXID OXO AZINIL ISOXAZOLINAS HERBICIDES OF SIX MEMBERS - Google Patents

DIXID OXO AZINIL ISOXAZOLINAS HERBICIDES OF SIX MEMBERS

Info

Publication number
AR072317A1
AR072317A1 ARP090102358A AR072317A1 AR 072317 A1 AR072317 A1 AR 072317A1 AR P090102358 A ARP090102358 A AR P090102358A AR 072317 A1 AR072317 A1 AR 072317A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
7alkyl
halogen
independently
Prior art date
Application number
Other languages
Spanish (es)
Inventor
Brenton Todd Smith
Thomas Paul Selby
Thomas Martin Stevenson
Andrew Edmund Taggi
David Alan Clark
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont filed Critical Du Pont
Publication of AR072317A1 publication Critical patent/AR072317A1/en

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D413/00Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/12Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

Composiciones que contienen los compuestos de formula 1 y métodos para controlar la vegetacion indeseable que comprenden poner en contacto la vegetacion indeseable o su ambiente con una cantidad eficaz de un compuesto o una composicion de la solicitud. Reivindicacion 1: Un compuesto caracterizado porque se selecciona entre formula 1, N-oxidos y sales del mismo donde J es como en formulas (2), (3) (4) o (5); Q1 es N o CR9a; Q2 es N o CR9b; Q3 es N o CR9c; Q4 es N o CR9d; W1 es N o CR10a; W2 es N o CR10b; con la condicion de que cuando Q2 es N, luego W2 es CR10b; W3 es N o CR10c; W4 es N o CR10d; Y1 es N o CR11a; con la condicion de que cuando W1 es N, luego Y1 es CR11a; Y2 es N o CR11b; con la condicion de que cuando W2 es N, luego Y2 es CR11b; Y3 es N o CR11c, con la condicion de que cuando W3 es N, luego Y3 es CR11c; Y4 es N o CR11d; m es 0, 1 o 2; n es o 1; con la condicion de que la suma de n y m es no más que 2; R1 y R2 son independientemente H, alquilo C1-6, alquenilo C2-C6, alquinilo C2-6, cicloalquilo C3-6, haloalquilo C1-6, haloalquenilo C2-6, alquilcicloalquilo C4-6 o cicloalquilalquilo C4-6; o R1 y R2 se toman juntos con el carbono al cual se encuentran unidos para formar un anillo carbocíclico saturado C3-6 opcionalmente sustituido con alquilo C1-3, halogeno o haloalquilo C1-3; R3 es H, alquilo C1-6, alquenilo C2-C6, alquinilo C2-6, cicloalquilo C3-6, haloalquilo C1-6, haloalquenilo C2-6, alquilcicloalquilo C4-6 o cicloalquilalquilo C4-6; alcoxi C1-6, haloalcoxi C1-6, alquiltio C1-6, haloalquiltio C1-6, -SCN, halogeno, ciano, nitro, azido, -CO2H o alcoxicarbonilo C2-5; R4 es H, alquilo C1-6, haloalquilo C1-6 o halogeno; o R3 y R4 se toman juntos con el carbono al cual se encuentran unidos para formar un anillo carbocíclico saturado C3-6 opcionalmente sustituido con alquilo C1-3, halogeno o haloalquilo C1-3; o R1 y R4 se toman juntos con los carbonos a los cuales se encuentran unidos para formar un anillo carbocíclico saturado C3-7 opcionalmente sustituido con alquilo C1-3, halogeno o haloalquilo C1-3; R5 es H, alquilo C1-2, halogeno, ciano o alcoxicarbonilo C2-5; R6 es H, alquilo C1-2 o halogeno; o R5 y R6 se toman juntos con el carbono al cual se encuentran unidos para formar un anillo carbocíclico saturado C3-6; R7 es H, -CN, alcoxicarbonilo C2-4, alquilsulfonilo C1-4, alquilcarbonilo C2-4 o haloalquilcarbonilo C2-4; cada R8a, R8b, R8c y R8d es independientemente alquilo C1-7, alquenilo C2-7, alquinilo C2-7, cicloalquilo C3-7, haloalquilo C1-7, haloalquenilo C2-7, alcoxialquilo C2-7, cicloalquilalquilo C4-7, haloalquinilo C3-7, alquilcarbonilalquilo C3-7, alcoxicarbonilalquilo C3-7, halocicloalquilalquilo C4-7, haloalcoxialquilo C2-7, alquiltioalquilo C2-7, alquilsulfonilalquilo C2-7, alquilsulfinilalquilo C2-7, cianoalquilo C2-7, haloalquiltioalquilo C2-7, haloalquilsulfonilalquilo C2-7, haloalquilsulfinilalquilo C2-7, haloalcoxicarbonilalquilo C3-7, haloalquilcarbonilalquilo C3-7, alquilsulfonilo C1-6, haloalquilsulfonilo C1-6 o cicloalquilsulfonilo C3-6; y cada R9a, R9b, R9c, R9d, R10a, R10b, R10c, R10d, R11a, R11b, R11c y R11d es independientemente H, halogeno, ciano, alquilo C1-7, alquenilo C2-7, alquinilo C2-7, cicloalquilo C3-7, cicloalquilalquilo C4-7, alquilcicloalquilo C4-7, haloalquilo C1-7, haloalquenilo C2-7, haloalquinilo C3-7, halocicloalquilo C3-7, alcoxi C1-7, haloalcoxi C1-7, alqueniloxi C2-7, haloalqueniloxi C2-7, cicloalcoxi C3-7, halocicloalcoxi C3-7, alquiniloxi C2-7, cicloalquilalcoxi C4-7, halocicloalquilalcoxi C4-7, alquiltio C1-7, haloalquiltio C1-7, haloalquilsulfinilo C1-7, haloalquilsulfonilo C1-7, alquilamino C1-6, dialquilamino C2-7, haloalquilamino C1-7, alquilcarbonilo C2-7, alcoxicarbonilo C2-7, haloalquilcarbonilo C2-7, haloalcoxicarbonilo C2-7, alquilcarbonilalquilo C3-7, alcoxicarbonilalquilo C3-7, aminocarbonilo, alquilaminocarbonilo C2-8, haloalquilaminocarbonilo C2-8, dialquilaminocarbonilo C3-8, haloalquil(alquil)aminocarbonilo C3-8, cicloalquilaminocarbonilo C4-7, cicloalquil(alquil)aminocarbonilo C5-8, halocicloalquilalquilo C4-7, alcoxialquilo C2-7, haloalcoxialquilo C2-7, alquiltioalquilo C2-7, alquilsulfonilalquilo C2-7, alquilsulfinilalquilo C2-7, cianoalquilo C2-7, haloalquiltioalquilo C2-7, haloalquilsulfonilalquilo C2-7, haloalquilsulfinilalquilo C2-7, haloalcoxicarbonilalquilo C3-7, haloalquilcarbonilalquilo C3-7, alcoxialcoxi C2-7, haloalcoxialcoxi C2-7, alquiltioalcoxi C2-7, haloalquiltioalcoxi C2-7, haloalquilsulfonilalcoxi C2-7, haloalquilsulfinilalcoxi C2-7, nitro, trialquilsililo C3-10, aminosulfonilo, alquilaminosulfonilo C1-7, haloalquilaminosulfonilo C1-7, dialquilaminosulfonilo C2-8, haloalquil(alquil)aminosulfonilo C3-8, cicloalquilaminosulfonilo C3-6 o cicloalquil(alquil)aminosulfonilo C4-7 o Z; cada Z es independientemente -ON=CR12R13, -C(=NOR14)R15, cianoalcoxi C2-6, alcoxihaloalquilo C2-6 o alcoxicarbonilalcoxi C3-7; o fenilo opcionalmente sustituidos con hasta dos sustituyentes seleccionados entre R16; o anillo heterocíclico de 5 o 6 miembros opcionalmente sustituidos con hasta dos sustituyentes seleccionados entre R17 sobre carbonos miembros del anillo y R18 sobre nitrogenos miembros del anillo; cada R12 es independientemente H o alquilo C1-6; cada R13 es independientemente H, alquilo C1-6 o alcoxi C1-4; o un par de R12 y R13 en una instancia de -ON=CR12R13 se toman juntos como -(CH2)2-, -(CH2)3-, -(CH2)4- o -(CH2)5-; cada R14 y R15 es independientemente H o alquilo C1-4; o un par de R14 y R15 en una instancia de -C(=NOR14)R15 se toman juntos como -(CH2)2-, -(CH2)3- o -(CH2)4-; cada R16 es independientemente alquilo C1-6, halogeno, alcoxi C1-4, haloalquilo C1-4 o haloalcoxi C1-4; cada R17 es independientemente alquilo C1-6, halogeno, alcoxi C1-4, haloalquilo C1-4 o haloalcoxi C1-4; y cada R18 es independientemente alquilo C1-6.Compositions containing the compounds of formula 1 and methods for controlling undesirable vegetation comprising contacting undesirable vegetation or its environment with an effective amount of a compound or a composition of the application. Claim 1: A compound characterized in that it is selected from formula 1, N-oxides and salts thereof wherein J is as in formulas (2), (3) (4) or (5); Q1 is N or CR9a; Q2 is N or CR9b; Q3 is N or CR9c; Q4 is N or CR9d; W1 is N or CR10a; W2 is N or CR10b; with the proviso that when Q2 is N, then W2 is CR10b; W3 is N or CR10c; W4 is N or CR10d; Y1 is N or CR11a; with the proviso that when W1 is N, then Y1 is CR11a; Y2 is N or CR11b; with the proviso that when W2 is N, then Y2 is CR11b; Y3 is N or CR11c, with the proviso that when W3 is N, then Y3 is CR11c; Y4 is N or CR11d; m is 0, 1 or 2; n is or 1; with the proviso that the sum of n and m is no more than 2; R1 and R2 are independently H, C1-6 alkyl, C2-C6 alkenyl, C2-6 alkynyl, C3-6 cycloalkyl, C1-6 haloalkyl, C2-6 haloalkenyl, C4-6 alkylcycloalkyl or C4-6 cycloalkylalkyl; or R1 and R2 are taken together with the carbon to which they are attached to form a C3-6 saturated carbocyclic ring optionally substituted with C1-3 alkyl, halogen or C1-3 haloalkyl; R3 is H, C1-6 alkyl, C2-C6 alkenyl, C2-6 alkynyl, C3-6 cycloalkyl, C1-6 haloalkyl, C2-6 haloalkenyl, C4-6 alkylcycloalkyl or C4-6 cycloalkylalkyl; C1-6 alkoxy, C1-6 haloalkoxy, C1-6 alkylthio, C1-6 haloalkylthio, -SCN, halogen, cyano, nitro, azido, -CO2H or C2-5 alkoxycarbonyl; R4 is H, C1-6 alkyl, C1-6 haloalkyl or halogen; or R3 and R4 are taken together with the carbon to which they are attached to form a C3-6 saturated carbocyclic ring optionally substituted with C1-3 alkyl, halogen or C1-3 haloalkyl; or R1 and R4 are taken together with the carbons to which they are attached to form a C3-7 saturated carbocyclic ring optionally substituted with C1-3 alkyl, halogen or C1-3 haloalkyl; R5 is H, C1-2 alkyl, halogen, cyano or C2-5 alkoxycarbonyl; R6 is H, C1-2 alkyl or halogen; or R5 and R6 are taken together with the carbon to which they are attached to form a C3-6 saturated carbocyclic ring; R7 is H, -CN, C2-4 alkoxycarbonyl, C1-4 alkylsulfonyl, C2-4 alkylcarbonyl or C2-4 haloalkylcarbonyl; each R8a, R8b, R8c and R8d is independently C1-7 alkyl, C2-7 alkenyl, C2-7 alkynyl, C3-7 cycloalkyl, C1-7 haloalkyl, C2-7 haloalkenyl, C2-7 alkoxyalkyl, C4-7 cycloalkylalkyl, C3-7 haloalkynyl, C3-7 alkylcarbonylalkyl C3-7 alkoxycarbonylalkyl C4-7 alkyl, C2-7 haloalkoxyalkyl, C2-7 alkylthioalkyl, C2-7 alkylsulfonylalkylC2-7alkyl, C2-7alkyl, C2-7alkyl, C2-7alkyl, C2-7alkyl, C2-7alkyl, C2-7alkyl, C2-7alkyl, C2-7alkyl, C2-7alkyl C2-7 haloalkylsulfonylalkyl, C2-7 haloalkylsulfinylalkyl, C3-7 haloalkoxycarbonylalkyl C3-7 alkyl, C1-6 alkylsulfonyl, C1-6 haloalkylsulfonyl or C3-6 cycloalkylsulfonyl; and each R9a, R9b, R9c, R9d, R10a, R10b, R10c, R10d, R11a, R11b, R11c and R11d is independently H, halogen, cyano, C1-7 alkyl, C2-7 alkenyl, C2-7 alkynyl, C3 cycloalkyl -7, C4-7 cycloalkylalkyl, C4-7 alkylcycloalkyl, C1-7 haloalkyl, C2-7 haloalkenyl, C3-7 haloalkenyl, C3-7 halocycloalkyl, C1-7 alkoxy, C1-7 haloalkoxy, C2-7 alkenyloxy -7, C3-7 cycloalkoxy, C3-7 halocycloalkoxy, C2-7 alkynyloxy, C4-7 cycloalkylalkoxy, C4-7 halocycloalkylalkoxy, C1-7 alkylthio, C1-7 haloalkylthio, C1-7 haloalkylsulfinyl, C1-7 haloalkylsulfonyl, -6, C2-7 dialkylamino, C1-7 haloalkylamino, C2-7 alkylcarbonyl, C2-7 alkoxycarbonyl, C2-7 haloalkylcarbonyl, C2-7 haloalkoxycarbonyl, C3-7 alkylcarbonylalkyl, C3-7 alkoxycarbonyl, C2- alkylaminocarbonyl C2-8 haloalkylaminocarbonyl, C3-8 dialkylaminocarbonyl, C3-8 haloalkyl (alkyl) aminocarbonyl, C4-7 cycloalkylaminocarbonyl, cycloalkyl (alkyl) aminocarbonyl C5-8, C4-7 I halocycloalkylalkyl, C2-7 alkoxyalkyl, haloalkoxyalkyl C2-7, C2-7 alkylthioalkyl, C2-7 alkylsulfonylalkyl, alkylsulfinylalkyl C2-7, C2-7 cyanoalkyl, haloalquiltioalquilo C2-7, C2-7 haloalquilsulfonilalquilo, haloalquilsulfinilalquilo C2-7, haloalkoxycarbonylalkyl C3-7, haloalkylcarbonylalkyl C3-7, alkoxyalkoxy C2-7, haloalkoxyalkoxy C2-7, alkylthioalkoxy C2-7, haloalkylthioalkoxy C2-7, haloalkylsulfonylalkyl alkoxy C2-7yl, alkylalkyl-C3-7 alkylalkyl-C3-7-alkyl , aminosulfonyl, C1-7 alkylaminosulfonyl, C1-7 haloalkylaminosulfonyl, C2-8 dialkylaminosulfonyl, C3-8 haloalkyl (alkyl) aminosulfonyl, C3-6 cycloalkylaminosulfonyl or C4-7 or cycloalkyl (alkyl) aminosulfonyl; each Z is independently -ON = CR12R13, -C (= NOR14) R15, C2-6 cyanoalkoxy, C2-6 alkoxyhaloalkyl or C3-7 alkoxycarbonylalkoxy; or phenyl optionally substituted with up to two substituents selected from R16; or 5- or 6-membered heterocyclic ring optionally substituted with up to two substituents selected from R17 on ring member carbons and R18 on ring member nitrogen; each R12 is independently H or C1-6 alkyl; each R13 is independently H, C1-6 alkyl or C1-4 alkoxy; or a pair of R12 and R13 in an instance of -ON = CR12R13 are taken together as - (CH2) 2-, - (CH2) 3-, - (CH2) 4- or - (CH2) 5-; each R14 and R15 is independently H or C1-4 alkyl; or a pair of R14 and R15 in an instance of -C (= NOR14) R15 are taken together as - (CH2) 2-, - (CH2) 3- or - (CH2) 4-; each R16 is independently C1-6 alkyl, halogen, C1-4 alkoxy, C1-4 haloalkyl or C1-4 haloalkoxy; each R17 is independently C1-6 alkyl, halogen, C1-4 alkoxy, C1-4 haloalkyl or C1-4 haloalkoxy; and each R18 is independently C1-6 alkyl.

ARP090102358 2008-06-25 2009-06-25 DIXID OXO AZINIL ISOXAZOLINAS HERBICIDES OF SIX MEMBERS AR072317A1 (en)

Applications Claiming Priority (2)

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US7549508P 2008-06-25 2008-06-25
US8660408P 2008-08-06 2008-08-06

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