AR077834A1 - Heterociclos microbiocidas - Google Patents
Heterociclos microbiocidasInfo
- Publication number
- AR077834A1 AR077834A1 ARP100102923A ARP100102923A AR077834A1 AR 077834 A1 AR077834 A1 AR 077834A1 AR P100102923 A ARP100102923 A AR P100102923A AR P100102923 A ARP100102923 A AR P100102923A AR 077834 A1 AR077834 A1 AR 077834A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- haloalkyl
- cyano
- halogen
- phenylsulfinyl
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing three or more hetero rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
- C07D263/30—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D263/34—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D263/48—Nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D277/22—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
- C07D277/28—Radicals substituted by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
- C07D285/08—1,2,4-Thiadiazoles; Hydrogenated 1,2,4-thiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
La presente refiere a compuestos heterocíclicos de formula 1 que tienen actividad microbiocida, en particular, actividad fungicida, así como también a métodos de uso de los compuestos de formula 1 para controlar los microbios (1) donde: A es x-C(=O)-, x-C(=S)-, x-C(R10R11)-C(=O), x-C(R12R13)-C(=S)-, x-O-C(=O)-, x-O-C(=S)-, x-N(R14)-C(=O)-, x-N(R15)-C(=S)-, x-C(R16R17)-SO2- o x-N=C(R26)-, en cada caso x indica el enlace que está conectado con R1; T es CR18 o N; G es O o S; Y1 y Y2 son independientemente CR19 o N; Q es -C(=O)-z, -C(=S)-z, -C(=O)-O-z, -C(=S)-O-z, -C(=O)-N(R20)-z, -C(=S)-N(R21)-z o -SO2-z-, en cada caso z indica el enlace que está conectado con R9; n es 1 o 2; p es 1 o 2, con la condicion de que cuando n es 2, p es 1; R1 es fenilo, piridilo, imidazolilo, o pirazolilo; donde el fenilo, piridilo, imidazolilo y pirazolilo están cada uno opcionalmente sustituido con 1 a 3 sustituyentes independientemente seleccionados de alquilo C1-4, haloalquilo C1-4, halogeno, ciano, hidroxi y amino; R2, R3, R4, R5, R6, R7, R10, R11, R12, R13, R16, R17, R18, R19 y R26 son cada uno independientemente hidrogeno, halogeno, ciano, alquilo C1-4 o haloalquilo C1-4; R8, R14, R15, R20 y R21 son cada uno independientemente hidrogeno, alquilo C1-4 o alcoxi C1-4; y R9 es fenilo, bencilo o un grupo (2): donde el fenilo, bencilo y el grupo (2) están cada uno opcionalmente sustituido con 1 a 3 sustituyentes independientemente seleccionados de alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, halogeno, ciano, hidroxilo, N(R27)2, SH, alquiltio C1-4, nitro, fenilsulfonilo y fenilsulfinilo, donde el fenilsulfonilo y fenilsulfinilo están opcionalmente sustituidos con 1 a 3 sustituyentes independientemente seleccionados de alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, halogeno y ciano; cada R27 es independientemente hidrogeno, alquilo C1-4, fenilsulfonilo o fenilsulfinilo, donde el fenilsulfonilo y fenilsulfinilo están opcionalmente sustituidos con 1 a 3 sustituyentes independientemente seleccionados de alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, halogeno y ciano; o una sal o un N-oxido del mismo.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09167736 | 2009-08-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR077834A1 true AR077834A1 (es) | 2011-09-28 |
Family
ID=43016641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP100102923A AR077834A1 (es) | 2009-08-12 | 2010-08-10 | Heterociclos microbiocidas |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US8557821B2 (es) |
| EP (1) | EP2464643A1 (es) |
| JP (1) | JP2013501744A (es) |
| KR (1) | KR20120089644A (es) |
| CN (1) | CN102596943A (es) |
| AP (1) | AP2012006153A0 (es) |
| AR (1) | AR077834A1 (es) |
| AU (1) | AU2010283832A1 (es) |
| BR (1) | BR112012002369A2 (es) |
| CA (1) | CA2769110A1 (es) |
| CL (1) | CL2012000338A1 (es) |
| CO (1) | CO6420414A2 (es) |
| CR (1) | CR20120063A (es) |
| EA (1) | EA021058B1 (es) |
| GE (1) | GEP20146079B (es) |
| IL (1) | IL217289A0 (es) |
| MA (1) | MA33519B1 (es) |
| MX (1) | MX2012001690A (es) |
| NI (1) | NI201200024A (es) |
| NZ (1) | NZ597562A (es) |
| TW (1) | TW201114764A (es) |
| UA (1) | UA104203C2 (es) |
| UY (1) | UY32841A (es) |
| WO (1) | WO2011018401A1 (es) |
| ZA (1) | ZA201109515B (es) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112012027762B1 (pt) | 2010-04-28 | 2018-06-05 | Bayer Intellectual Property Gmbh | Derivados de cetoheteroarilpiperidina e - piperazina como fungicidas |
| BR112012030184A2 (pt) | 2010-05-27 | 2015-12-29 | Bayer Cropscience Ag | derivados de ácido piridinilcarboxílico como fungicidas |
| US20120122928A1 (en) | 2010-08-11 | 2012-05-17 | Bayer Cropscience Ag | Heteroarylpiperidine and -Piperazine Derivatives as Fungicides |
| US8759527B2 (en) | 2010-08-25 | 2014-06-24 | Bayer Cropscience Ag | Heteroarylpiperidine and -piperazine derivatives as fungicides |
| WO2012031383A1 (zh) * | 2010-09-06 | 2012-03-15 | 中国科学院广州生物医药与健康研究院 | 酰胺类化合物 |
| BR112013010497B1 (pt) | 2010-10-27 | 2018-07-17 | Bayer Intellectual Property Gmbh | derivados de heteroaril - piperidina e - piperazina enquanto fungicidas, composição os compreendendo, bem como processo para a produção de composições para controle de fungos fitopatogênicos nocivos e método para controle de fungos fitopatogênicos nocivos |
| US20130317064A1 (en) * | 2011-02-10 | 2013-11-28 | Syngenta Participations Ag | Microbiocidal pyrazole derivatives |
| WO2013000941A1 (en) | 2011-06-30 | 2013-01-03 | Syngenta Participations Ag | Microbiocidal heterocycles |
| US9301530B2 (en) | 2011-06-30 | 2016-04-05 | Syngenta Participations Ag | Microbiocidal heterocycles |
| US20140228372A1 (en) * | 2011-10-18 | 2014-08-14 | Syngenta Participations Ag | Microbiocidal pyrazole derivatives |
| US20140243371A1 (en) * | 2011-10-18 | 2014-08-28 | Syngenta Participations Ag | Microbiocidal pyrazole derivatives |
| DK2921492T3 (en) | 2011-12-27 | 2017-12-11 | Bayer Ip Gmbh | HETEROARYLPIPERIDINE AND ¿PIPERAZINE DERIVATIVES |
| CA2861020C (en) | 2012-02-02 | 2018-07-17 | Actelion Pharmaceuticals Ltd | 4-(benzoimidazol-2-yl)-thiazole compounds and related aza derivatives and their use as cxcr3 receptor modulators |
| WO2014060176A1 (en) | 2012-10-16 | 2014-04-24 | Syngenta Participations Ag | Microbiocidal pyrazole derivatives |
| WO2014179144A1 (en) * | 2013-04-29 | 2014-11-06 | E. I. Du Pont De Nemours And Company | Fungicidal heterocyclic compounds |
| EP2801575A1 (en) | 2013-05-07 | 2014-11-12 | Bayer CropScience AG | Heteroaryldihydropyridine derivatives as fungicides |
| CN105473585B (zh) | 2013-06-24 | 2018-04-13 | 拜耳作物科学股份公司 | 作为杀真菌剂的哌啶羧酸衍生物 |
| US10259807B2 (en) | 2013-07-22 | 2019-04-16 | Idorsia Pharmaceuticals Ltd. | 1-(piperazin-1-yl)-2-([1,2,4]triazol-1-yl)-ethanone derivatives |
| CN105705503B (zh) | 2013-08-28 | 2019-07-09 | 拜耳作物科学股份公司 | 作为杀真菌剂的杂芳基哌啶和杂芳基哌嗪的丙二酸酯衍生物 |
| CN106459028A (zh) | 2014-03-24 | 2017-02-22 | 拜耳作物科学股份公司 | 作为杀真菌剂的苯基哌啶羧酰胺衍生物 |
| AR099789A1 (es) | 2014-03-24 | 2016-08-17 | Actelion Pharmaceuticals Ltd | Derivados de 8-(piperazin-1-il)-1,2,3,4-tetrahidro-isoquinolina |
| WO2016024350A1 (ja) | 2014-08-13 | 2016-02-18 | 株式会社エス・ディー・エス バイオテック | 縮合１１員環化合物及びそれらを含有する農園芸用殺菌剤 |
| AR103399A1 (es) | 2015-01-15 | 2017-05-10 | Actelion Pharmaceuticals Ltd | Derivados de (r)-2-metil-piperazina como moduladores del receptor cxcr3 |
| CA2972952C (en) | 2015-01-15 | 2021-01-05 | Idorsia Pharmaceuticals Ltd | Hydroxyalkyl-piperazine derivatives as cxcr3 receptor modulators |
| CN108601353B (zh) | 2016-02-08 | 2024-04-05 | 高文作物保护公司 | 杀菌性组合物 |
| US11274076B2 (en) | 2016-02-08 | 2022-03-15 | Gowan Company, L.L.C. | Process for preparing 1, 2-benzenedimethanol compound |
| JP2024500558A (ja) * | 2020-12-04 | 2024-01-09 | エウブルス バイオセラピューティクス インク． | ヘテロアリール－アセチレン、その医薬組成物、及びその治療的応用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1340685C (en) | 1988-07-29 | 1999-07-27 | Frederick Meins | Dna sequences encoding polypeptides having beta-1,3-glucanase activity |
| DK0392225T3 (da) | 1989-03-24 | 2003-09-22 | Syngenta Participations Ag | Sygdomsresistente transgene planter |
| US5639949A (en) | 1990-08-20 | 1997-06-17 | Ciba-Geigy Corporation | Genes for the synthesis of antipathogenic substances |
| WO1997033890A1 (en) | 1996-03-11 | 1997-09-18 | Novartis Ag | Pyrimidin-4-one derivatives as pesticide |
| FR2856685B1 (fr) * | 2003-06-25 | 2005-09-23 | Merck Sante Sas | Derives de thiazolylpiperidine, leurs procedes de preparation et les compositions pharmaceutiques qui les contiennent |
| TW200738701A (en) | 2005-07-26 | 2007-10-16 | Du Pont | Fungicidal carboxamides |
| WO2008013622A2 (en) | 2006-07-27 | 2008-01-31 | E. I. Du Pont De Nemours And Company | Fungicidal azocyclic amides |
| WO2008091594A2 (en) | 2007-01-24 | 2008-07-31 | E. I. Du Pont De Nemours And Company | Fungicidal mixtures |
| EP2121660B1 (en) | 2007-01-25 | 2014-12-31 | E. I. Du Pont de Nemours and Company | Fungicidal amides |
| TWI428091B (zh) | 2007-10-23 | 2014-03-01 | Du Pont | 殺真菌劑混合物 |
| CN103965187A (zh) | 2008-01-25 | 2014-08-06 | 杜邦公司 | 杀真菌杂环化合物 |
-
2010
- 2010-08-05 UA UAA201202484A patent/UA104203C2/ru unknown
- 2010-08-05 CN CN201080035227XA patent/CN102596943A/zh active Pending
- 2010-08-05 GE GEAP201012623A patent/GEP20146079B/en unknown
- 2010-08-05 MX MX2012001690A patent/MX2012001690A/es active IP Right Grant
- 2010-08-05 BR BR112012002369A patent/BR112012002369A2/pt not_active IP Right Cessation
- 2010-08-05 EA EA201200262A patent/EA021058B1/ru not_active IP Right Cessation
- 2010-08-05 US US13/390,036 patent/US8557821B2/en not_active Expired - Fee Related
- 2010-08-05 WO PCT/EP2010/061381 patent/WO2011018401A1/en not_active Ceased
- 2010-08-05 AP AP2012006153A patent/AP2012006153A0/xx unknown
- 2010-08-05 CA CA2769110A patent/CA2769110A1/en not_active Abandoned
- 2010-08-05 JP JP2012524203A patent/JP2013501744A/ja active Pending
- 2010-08-05 EP EP10739935A patent/EP2464643A1/en not_active Withdrawn
- 2010-08-05 KR KR1020127006305A patent/KR20120089644A/ko not_active Withdrawn
- 2010-08-05 NZ NZ597562A patent/NZ597562A/xx not_active IP Right Cessation
- 2010-08-05 AU AU2010283832A patent/AU2010283832A1/en not_active Abandoned
- 2010-08-10 AR ARP100102923A patent/AR077834A1/es not_active Application Discontinuation
- 2010-08-10 TW TW099126587A patent/TW201114764A/zh unknown
- 2010-08-12 UY UY0001032841A patent/UY32841A/es not_active Application Discontinuation
-
2011
- 2011-12-22 ZA ZA2011/09515A patent/ZA201109515B/en unknown
- 2011-12-29 IL IL217289A patent/IL217289A0/en unknown
-
2012
- 2012-02-08 NI NI201200024A patent/NI201200024A/es unknown
- 2012-02-08 CR CR20120063A patent/CR20120063A/es unknown
- 2012-02-08 CO CO12022024A patent/CO6420414A2/es active IP Right Grant
- 2012-02-09 CL CL2012000338A patent/CL2012000338A1/es unknown
- 2012-02-10 MA MA34618A patent/MA33519B1/fr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EA021058B1 (ru) | 2015-03-31 |
| US8557821B2 (en) | 2013-10-15 |
| TW201114764A (en) | 2011-05-01 |
| CA2769110A1 (en) | 2011-02-17 |
| MA33519B1 (fr) | 2012-08-01 |
| AU2010283832A1 (en) | 2012-02-23 |
| CN102596943A (zh) | 2012-07-18 |
| EP2464643A1 (en) | 2012-06-20 |
| IL217289A0 (en) | 2012-02-29 |
| ZA201109515B (en) | 2013-01-30 |
| CR20120063A (es) | 2012-03-22 |
| CL2012000338A1 (es) | 2012-10-12 |
| UA104203C2 (en) | 2014-01-10 |
| AP2012006153A0 (en) | 2012-04-30 |
| US20120142700A1 (en) | 2012-06-07 |
| MX2012001690A (es) | 2012-02-22 |
| UY32841A (es) | 2011-03-31 |
| WO2011018401A1 (en) | 2011-02-17 |
| CO6420414A2 (es) | 2012-04-16 |
| GEP20146079B (en) | 2014-04-25 |
| JP2013501744A (ja) | 2013-01-17 |
| NI201200024A (es) | 2012-08-15 |
| BR112012002369A2 (pt) | 2019-09-24 |
| EA201200262A1 (ru) | 2012-09-28 |
| NZ597562A (en) | 2013-10-25 |
| KR20120089644A (ko) | 2012-08-13 |
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