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AR074975A1 - HERBICIDE COMPOSITIONS CONTAINING PIROXASULPHONE V - Google Patents

HERBICIDE COMPOSITIONS CONTAINING PIROXASULPHONE V

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Publication number
AR074975A1
AR074975A1 ARP090103438A ARP090103438A AR074975A1 AR 074975 A1 AR074975 A1 AR 074975A1 AR P090103438 A ARP090103438 A AR P090103438A AR P090103438 A ARP090103438 A AR P090103438A AR 074975 A1 AR074975 A1 AR 074975A1
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AR
Argentina
Prior art keywords
alkyl
radical
hydrogen
formula
herbicide
Prior art date
Application number
ARP090103438A
Other languages
Spanish (es)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/EP2009/053076 external-priority patent/WO2009115490A2/en
Application filed by Basf Se filed Critical Basf Se
Publication of AR074975A1 publication Critical patent/AR074975A1/en

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Abstract

Composiciones activas como herbicidas, que comprenden 3-[5-(difluorometoxi)-1-metil-3-(trifluorometil)pirazol-4-ilmetilsulfonil]-4,5-dihidro-5,5-dimetil-1,2oxazol [nombre comun piroxasulfona] y por lo menos un herbicida B que es seleccionado entre inhibidores de la protoporfirinogeno-IX-oxidasa. Además el uso de una composicion tal como se define en la presente para controlar vegetacion indeseable en los cultivos. Cuando se usan las composiciones para ese fin, el herbicida A y el herbicida B, que es por lo menos uno, pueden ser aplicados simultánea o sucesivamente en cultivos en los cuales pudiese surgir la vegetacion indeseable. Reivindicacion 2: La composicion de acuerdo con la reivindicacion 1, caracterizada porque el herbicida B contiene por lo menos un compuesto de la formula (1) en la que R1 es seleccionado entre el grupo compuesto por los radicales propargiloxi, aliloxi, isopropiloxi, C(=O)NHSO2NR1aR1b, C(=O)N-NR1aR1b, O-CR1aR1c-C(=O)-OR1e, C(=O)OR1aR1c-C(=O)-OR1e, C(=O)O-R1b, C(=O)O-CHR1c, C(=O)NHSO2NR1aR1b, NHSO2NR1aR1b, SO2NHc(=o)NR1aR1b, CH2-CH(Cl)CO2-R1d y el radical de la formula OC(CH3)2-C(=O)-OR1e en el que R1a representa hidrogeno o alquilo C1-4; R1b representa alquilo C1-4; R1c representa hidrogeno o alquilo C1-4; R1d representa hidrogeno o alquilo C1-4 o un cation aceptable en agricultura; y R1e representa alquilo C1-4, propargilo o alilo; R2 representa hidrogeno, fluor o cloro; R3 representa hidrogeno o bien forma, junto con R1 una fraccion -O-C(R3a)=N- o bien -N=C(R3b)-NH- en el que R3a y R3b son seleccionados, independientemente el uno del otro, entre hidrogeno, alquilo C1-6, haloalquilo C1-6, alquenilo C3-6, haloalquenilo C3-6, alquilinilo C3-6, haloalquilinilo C3-6, alcoxi C1-6, cicloalquilo C3-6 y alquilo C1-2 sustituido por un radical cicloalquilo C3-6; R4 representa halogeno o ciano; y Het representa un radical de las formulas (A) o (B), en las que R5 es seleccionado entre hidrogeno, amino, metilo o propargilo; R6 es seleccionado entre difluorometoxi, trifluorometilo y metilsulfonilo; R7 es seleccionado entre halogeno o metilo. Reivindicacion 11: La composicion de acuerdo con la reivindicacion 1 caracterizada porque el herbicida B contiene por lo menos un compuesto de la formula (2) en la que X representa O o NR11; R8 es seleccionado entre el grupo compuesto por propargiloxi, aliloxi, isopropiloxi, el radical de la formula CH2-CH(Cl)CO2-R12 y el radical de la formula NH-SO2-CH3; R9 representa fluor o cloro; R10 representa CH3, ter-butilo; R11 representa CHF2, o junto con R10 puede formar 1,4-butanodiilo; R12 representa hidrogeno, alquilo C1-6 o un cation aceptable en agricultura. Reivindicacion 13: La composicion de acuerdo con reivindicacion 1 caracterizada porque el herbicida B contiene por lo menos un compuesto de la formula (3) en la que R13 representa hidrogeno, fluor o cloro; R14 es seleccionado entre el grupo compuesto por propargiloxi, aliloxi, 1-metil-2-propiniloxi, O-CH2CO2-R16, CH=C(Cl)CO2R16 e isopropiloxi; R15 representa fluor o cloro; o R14 y R15 forman conjuntamente una fraccion O-CH2-C(=O)-NR17, en la que R17 representa un radical propargilo y en la que el átomo de oxígeno está en posicion meta respecto a la posicion de R13; R16 representa hidrogeno alquilo C1-6 o un cation aceptable en agricultura. Reivindicacion 15: La composicion de acuerdo con la reivindicacion 1, caracterizada porque el compuesto herbicida B contiene por lo menos un compuesto de la formula (4) en la que R18 representa cloro o trifluorometilo; R19 es seleccionado entre el grupo compuesto por hidrogeno, alcoxi C1-4, CO2-R21, C(=O)O-CH2CO2-R21, C(=O)O-CH(CH3)CO2-R21, C(=O)NH-SO2-R22; R20 representa hidrogeno, fluor o cloro; R21 representa hidrogeno, alquilo C1-6 o un cation aceptable en agricultura; y R22 representa alquilo C1-4. Reivindicacion 18: La composicion de acuerdo con la reivindicacion 1, caracterizada porque el herbicida B contiene por lo menos un compuesto de la formula (5) en la que R22 representa hidrogeno, fluor o cloro; R24 es seleccionado entre hidrogeno, alquilo C1-6, haloalquilo C1-6, alquenilo C3-6, haloalquenilo C3-6, alquinilo C3-6, haloalquinilo C3-6, alcoxi C1-6, cicloalquilo C3-6 y alquilo C1-2 sustituido por un radical cicloalquilo C3-6; R25 es seleccionado entre hidrogeno. amino, metilo y propargilo; R26 es seleccionado entre hidrogeno y metilo; e Y representa O o S. Reivindicacion 20: La composicion de acuerdo con la reivindicacion 1, caracterizada porque el herbicida B contiene por lo menos un compuesto de la formula (6) en la que m representa 0, 1, 2 o 3; n representa 0, 1, 2, 3 o 4; R27 es seleccionado entre alquilo C1-6, haloalquilo C1-6, alquenilo C3-6, haloalquenilo C3-6, alquilinilo C3-6, haloalquilinilo C3-6, cicloalquilo C3-6, alquilo C1-4 sustituido por un radical alcoxi C1-4, y alquilo C1-2 sustituido por un radical cicloalquilo C3-6; R28 es seleccionado entre halogeno, alquilo C1-3, haloalquilo C1-3, alcoxi C1-3 y alquilo C1-2 sustituido por un radical alcoxi C1-3, siendo posible, cuando m = 2 o 3, que los radicales R28 sean idénticos o diferentes unos de otros; R29 es seleccionado entre halogeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alquil C1-4-sulfonilo, alcoxi C1-4, alquilo C1-4 sustituido por un radical alcoxi C1-4, alquilo C1-2 sustituido por un radical cicloalquilo C3-6 y un radical CO2R30, siendo posible, cuando n = 2, 3 o 4, que los radicales R29 sean idénticos o diferentes unos de otros; R30 es seleccionado entre alquilo C1-6, haloalquilo C1-6, alquenilo C3-6, haloalquenilo C3-6, alquinilo C3-6, haloalquinilo C3-6, cicloalquilo C3-6, alquilo C1-4 sustituido por un radical alcoxi C1-4 y alquilo C1-2 sustituido por un radical cicloalquilo C3-6.Active compositions as herbicides, comprising 3- [5- (difluoromethoxy) -1-methyl-3- (trifluoromethyl) pyrazol-4-ylmethylsulfonyl] -4,5-dihydro-5,5-dimethyl-1,2oxazole [common name pyroxasulfone] and at least one herbicide B that is selected from protoporphyrinogen-IX-oxidase inhibitors. In addition the use of a composition as defined herein to control undesirable vegetation in crops. When the compositions are used for that purpose, herbicide A and herbicide B, which is at least one, can be applied simultaneously or successively in crops in which undesirable vegetation may arise. Claim 2: The composition according to claim 1, characterized in that the herbicide B contains at least one compound of the formula (1) in which R1 is selected from the group consisting of the propargiloxy, allyloxy, isopropyloxy radicals, C ( = O) NHSO2NR1aR1b, C (= O) N-NR1aR1b, O-CR1aR1c-C (= O) -OR1e, C (= O) OR1aR1c-C (= O) -OR1e, C (= O) O-R1b, C (= O) O-CHR1c, C (= O) NHSO2NR1aR1b, NHSO2NR1aR1b, SO2NHc (= o) NR1aR1b, CH2-CH (Cl) CO2-R1d and the radical of the formula OC (CH3) 2-C (= O ) -OR1e in which R1a represents hydrogen or C1-4 alkyl; R1b represents C1-4 alkyl; R1c represents hydrogen or C1-4 alkyl; R1d represents hydrogen or C1-4 alkyl or an acceptable cation in agriculture; and R1e represents C1-4 alkyl, propargyl or allyl; R2 represents hydrogen, fluorine or chlorine; R3 represents hydrogen or forms, together with R1 a fraction -OC (R3a) = N- or -N = C (R3b) -NH- in which R3a and R3b are independently selected from each other, from hydrogen, C 1-6 alkyl, C 1-6 haloalkyl, C 3-6 alkenyl, C 3-6 haloalkenyl, C 3-6 alkynyl, C 3-6 haloalkynyl, C 1-6 alkoxy, C 3-6 cycloalkyl and C 1-2 alkyl substituted by a C3 cycloalkyl radical -6; R4 represents halogen or cyano; and Het represents a radical of formulas (A) or (B), in which R5 is selected from hydrogen, amino, methyl or propargyl; R6 is selected from difluoromethoxy, trifluoromethyl and methylsulfonyl; R7 is selected from halogen or methyl. Claim 11: The composition according to claim 1 characterized in that the herbicide B contains at least one compound of the formula (2) in which X represents O or NR11; R8 is selected from the group consisting of propargiloxy, allyloxy, isopropyloxy, the radical of the formula CH2-CH (Cl) CO2-R12 and the radical of the formula NH-SO2-CH3; R9 represents fluorine or chlorine; R10 represents CH3, tert-butyl; R11 represents CHF2, or together with R10 can form 1,4-butanediyl; R12 represents hydrogen, C1-6 alkyl or an acceptable cation in agriculture. Claim 13: The composition according to claim 1 characterized in that the herbicide B contains at least one compound of the formula (3) in which R13 represents hydrogen, fluorine or chlorine; R14 is selected from the group consisting of propargiloxy, allyloxy, 1-methyl-2-propynyloxy, O-CH2CO2-R16, CH = C (Cl) CO2R16 and isopropyloxy; R15 represents fluorine or chlorine; or R14 and R15 together form a fraction O-CH2-C (= O) -NR17, in which R17 represents a propargyl radical and in which the oxygen atom is in a meta position relative to the position of R13; R16 represents C1-6 alkyl hydrogen or an acceptable cation in agriculture. Claim 15: The composition according to claim 1, characterized in that the herbicidal compound B contains at least one compound of the formula (4) in which R18 represents chlorine or trifluoromethyl; R19 is selected from the group consisting of hydrogen, C1-4 alkoxy, CO2-R21, C (= O) O-CH2CO2-R21, C (= O) O-CH (CH3) CO2-R21, C (= O) NH-SO2-R22; R20 represents hydrogen, fluorine or chlorine; R21 represents hydrogen, C1-6 alkyl or an acceptable cation in agriculture; and R22 represents C1-4 alkyl. Claim 18: The composition according to claim 1, characterized in that the herbicide B contains at least one compound of the formula (5) in which R22 represents hydrogen, fluorine or chlorine; R24 is selected from hydrogen, C1-6 alkyl, C1-6 haloalkyl, C3-6 alkenyl, C3-6 haloalkenyl, C3-6 alkynyl, C3-6 haloalkynyl, C1-6 alkoxy, C3-6 cycloalkyl and C1-2 alkyl substituted by a C3-6 cycloalkyl radical; R25 is selected from hydrogen. amino, methyl and propargyl; R26 is selected from hydrogen and methyl; and Y represents O or S. Claim 20: The composition according to claim 1, characterized in that the herbicide B contains at least one compound of the formula (6) in which m represents 0, 1, 2 or 3; n represents 0, 1, 2, 3 or 4; R27 is selected from C1-6 alkyl, C1-6 haloalkyl, C3-6 alkenyl, C3-6 haloalkenyl, C3-6 alkynyl, C3-6 haloalkynyl, C3-6 cycloalkyl, C1-4 alkyl substituted by a C1- alkoxy radical 4, and C1-2 alkyl substituted by a C3-6 cycloalkyl radical; R28 is selected from halogen, C1-3 alkyl, C1-3 haloalkyl, C1-3 alkoxy and C1-2 alkyl substituted by a C1-3 alkoxy radical, being possible, when m = 2 or 3, that the radicals R28 are identical or different from each other; R29 is selected from halogen, cyano, nitro, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkyl sulfonyl, C1-4 alkoxy, C1-4 alkyl substituted by a C1-4 alkoxy radical, substituted C1-2 alkyl by a C3-6 cycloalkyl radical and a CO2R30 radical, being possible, when n = 2, 3 or 4, that the radicals R29 are identical or different from each other; R30 is selected from C1-6 alkyl, C1-6 haloalkyl, C3-6 alkenyl, C3-6 haloalkenyl, C3-6 alkynyl, C3-6 haloalkynyl, C3-6 cycloalkyl, C1-4 alkyl substituted by a C1- alkoxy radical 4 and C1-2 alkyl substituted by a C3-6 cycloalkyl radical.

ARP090103438A 2008-12-01 2009-09-08 HERBICIDE COMPOSITIONS CONTAINING PIROXASULPHONE V AR074975A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11880308P 2008-12-01 2008-12-01
PCT/EP2009/053076 WO2009115490A2 (en) 2008-03-17 2009-03-16 Herbicidal compositions comprising pyroxasulfone v

Publications (1)

Publication Number Publication Date
AR074975A1 true AR074975A1 (en) 2011-03-02

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Family Applications (1)

Application Number Title Priority Date Filing Date
ARP090103438A AR074975A1 (en) 2008-12-01 2009-09-08 HERBICIDE COMPOSITIONS CONTAINING PIROXASULPHONE V

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AR (1) AR074975A1 (en)
TW (1) TW201021708A (en)

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Publication number Publication date
TW201021708A (en) 2010-06-16

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