AR052262A1 - PHENYLPIRAZOL-PIPERAZINAS AND IMPORTANT PESTICID COMPOSITIONS OF THE SAME - Google Patents

Abstract

A process for its preparation, its compositions and its use for pest control, including arthropods and helminths. 5-Diazacycloalkylpyrazole derivatives of formula (1), wherein: R1 is CN, CH3, CF3, C (= N-Z) p-C1-4alkyl and CSNH2; where Z is H, C1-6 alkyl, C1-6 haloalkyl, C3-6 alkenyl, C3-6 alkynyl, - (CH2) qR8, COR9, CO2-C1-6 alkyl or S (O) pR9; R2 is halogen, CH3 or NR11R12; R3 is C1-3 haloalkyl, C1-3 haloalkoxy or SF5; R4 is hydrogen, C2-6 alkenyl, C2-6 haloalkenyl, C2-6 alkynyl, C2-6 haloalkynyl, C3-7 cycloalkyl, C3-7 cycloalkylC1-6, CO2-C1-6 alkyl, CO2-C3-6 alkenyl, CO -C3.6 alkynyl, CO2. (CH2) qR10, CO2- (CH2) qR10, CONR6R7 and SO2R9; formyl, CO-CO2-C 1-6 alkyl or CO-C 1-6 alkyl unsubstituted or substituted with one or more radicals selected from the group including halogen, C 1-6 alkoxy, C 1-6 haloalkoxy, C 3-6 alkenyloxy, C 3-6 haloalkenyloxy , C3-6 alkynyloxy, C3-6 haloalkyloxy, C3-4 cycloalkyl, S (O) pR9, CN, NO2, OH, R8, R10, COR9, NR6R76, OR9 and CO2R9; or CO- (CH2) mR8; or CO- (CH2) mR10; or C1-6 alkyl unsubstituted or substituted with one or more radicals selected from the group including halogen, C1-6 alkoxy, C1-6 haloalkoxy, C3-6 alkenyloxy, C3-6 haloalkyloxy, C3-6 alkynyloxy, C3-6 haloalkyloxy , C3-7 cycloalkyl, S (O) or R9, CN, NO2, O, R8, R10, COR9, NR6R7, OR9, COOH and CO2R9; or R8 and R10; R 5 is C 1-6 alkyl, C 1-6 haloalkyl, C 2-6 alkenyl, C 2-6 haloalkenyl, C 2-6 alkynyl or C 2-6 haloalkynyl; A is C1-6 alkylene or C2-6 alkenylene whose groups are not substituted or substituted with one or more C1-6 alkyl, C1-6 haloalkyl, C2-6 alkenyl, C2-6 haloalkenyl, C2-6 alkynyl, C2 haloalkynyl -6, C3-7 cycloalkyl, C3-7 cycloalkyl-C1-4alkyl, (CH2) qR8 or (CH2) qR10; E is C2-6 alkylene or C2-6 alkenylene whose groups are not substituted or substituted with one or more C1-6 alkyl, C1-6 haloalkyl, C2-6 alkenyl, C2-6 haloalkenyl, C2-6 alkynyl, C2 haloalkynyl -6, C3-7 cycloalkyl, C3-7 cycloalkyl-C1-4alkyl, (CH2) qR8 or (CH2) qR10; and where A and E may be linked to form a bicyclic system; R 6 and R 7 are each independently H, C 1-6 alkyl, C 1-6 haloalkyl, C 2-6 alkenyl, C 2-6 haloalkenyl, C 2-6 alkynyl, C 2-6 haloalkynyl, C 3-7 cycloalkyl, C 3-7 cycloalkyl C1-4alkyl, (CH2) qR8 or (CH2) qR10; R6 and R7 can form together with the attached N atom a saturated ring of four to seven members and an unsaturated ring of five to seven members, whose ring optionally contains one and more additional heteroatoms in the ring that are selected from O, S and N , the ring being unsubstituted or substituted with one and more radicals selected from the group including halogen, C1-6 alkyl, C1-6 haloalkyl and oxo, and when there is any additional cyclic N atom it is not substituted and is substituted with a C1 alkyl -6, CO-C1-6 alkyl or a CH2R11 radical; R8 is unsubstituted phenyl or is substituted by one and more radicals selected from the group including halogen, C1-6 alkyl, C1-6 haloalkyl, C1-6 alkoxy, haloalkoxy, CN, NO2, S (O) pR9 and NR6R7; R9 is C1-6 alkyl, C1-6 haloalkyl, C3-7 cycloalkyl, -C14 alkyl-C3-7 cycloalkyl, - (CH2) qR8 or - (CH2) qR10; R10 is unsubstituted heterocyclyl or is substituted with one and more radicals selected from the group including halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy, S (O) pR9, OH and oxo; R11 and R12 are each independently H, C1-6 alkyl, C2-6 alkenyl or C2-6 alkynyl, whose last three groups mentioned are unsubstituted or substituted with one and more radicals selected from the group including halogen, cycloalkyl C3-7, R8, R10, C1-6 alkoxy, C1-5 haloalkoxy; n, p and q are each independently zero one or two; m is zero, one, two or three; and each heterocyclyl in the radicals mentioned above is independently a heterocyclic radical having 3 to 7 cyclic atoms and 1, 2 and 3 heteroatoms in the ring selected from the group that includes N, O and S; or a salt thereof acceptable for use as a pesticide.