AR042329A1 - Un compuesto de relleno-fibra, metodo para producirlo y los articulos de papel que contienen dicho compuesto - Google Patents
Un compuesto de relleno-fibra, metodo para producirlo y los articulos de papel que contienen dicho compuestoInfo
- Publication number
- AR042329A1 AR042329A1 ARP030104510A ARP030104510A AR042329A1 AR 042329 A1 AR042329 A1 AR 042329A1 AR P030104510 A ARP030104510 A AR P030104510A AR P030104510 A ARP030104510 A AR P030104510A AR 042329 A1 AR042329 A1 AR 042329A1
- Authority
- AR
- Argentina
- Prior art keywords
- compound
- produce
- fiber
- stage reactor
- slake
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 7
- 239000000835 fiber Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 6
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract 2
- 239000001569 carbon dioxide Substances 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 239000000123 paper Substances 0.000 abstract 2
- 239000002002 slurry Substances 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- MJUDLWQWPKWWPB-UHFFFAOYSA-K [OH-].[Ca+2].[Ca+2].[O-]C([O-])=O Chemical compound [OH-].[Ca+2].[Ca+2].[O-]C([O-])=O MJUDLWQWPKWWPB-UHFFFAOYSA-K 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- VMLAJPONBZSGBD-UHFFFAOYSA-L calcium;hydrogen carbonate;hydroxide Chemical compound [OH-].[Ca+2].OC([O-])=O VMLAJPONBZSGBD-UHFFFAOYSA-L 0.000 abstract 1
- 239000004917 carbon fiber Substances 0.000 abstract 1
- 239000011111 cardboard Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000012764 mineral filler Substances 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000011087 paperboard Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H3/00—Paper or cardboard prepared by adding substances to the pulp or to the formed web on the paper-making machine and by applying substances to finished paper or cardboard (on the paper-making machine), also when the intention is to impregnate at least a part of the paper body
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
- D21C9/005—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
- C01F11/181—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by control of the carbonation conditions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
- C01F11/182—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds
- C01F11/183—Preparation of calcium carbonate by carbonation of aqueous solutions and characterised by an additive other than CaCO3-seeds the additive being an organic compound
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/002—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives
- D21C9/004—Modification of pulp properties by chemical means; preparation of dewatered pulp, e.g. in sheet or bulk form, containing special additives inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/70—Inorganic compounds forming new compounds in situ, e.g. within the pulp or paper, by chemical reaction with other substances added separately
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
- D21H21/52—Additives of definite length or shape
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Paper (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Un compuesto de relleno-fibra, un proceso para su producción, la utilización del mismo en la elaboración de productos de papel o cartón y a papel reducido de eso. Más particularmente, se revela a un compuesto de relleno-fibra en el cual la morfología y el tamano de las partículas del relleno mineral se establecen antes de desarrollar el vínculo a la fibra. Aún más particularmente, se revela un compuesto de relleno-fibra de PCC es el cual se realizan las propiedades ópticas y físicas deseadas del papel producto de eso. Reivindicación 1: Un compuesto de relleno-fibra caracterizado porque comprende: (a) alimentar "slake" que contiene ácido cítrico a un reactor de primera etapa, (b) reaccionar el "slake" que contiene ácido cítrico en el reactor de primera etapa en presencia de dióxido de carbono para producir un talón de CaCO3; (c). agregar el "slake" que contiene bicarbonato de sodio al material del talón del reactor de primer etapa en presencia de CO2 para producir una lechada parcialmente convertida de hidróxido de calcio carbonato de calcio y (d) reaccionar la lechada parcialmente convertida de hidróxido de calcio carbonato de calcio en un reactor de segunda etapa en presencia de dióxido de carbono y fibras para producir un compuesto de relleno-fibra.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/314,730 US20040108082A1 (en) | 2002-12-09 | 2002-12-09 | Filler-fiber composite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR042329A1 true AR042329A1 (es) | 2005-06-15 |
Family
ID=32468550
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP030104510A AR042329A1 (es) | 2002-12-09 | 2003-12-05 | Un compuesto de relleno-fibra, metodo para producirlo y los articulos de papel que contienen dicho compuesto |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US20040108082A1 (es) |
| EP (1) | EP1579068A2 (es) |
| JP (1) | JP2006509120A (es) |
| KR (1) | KR20040050052A (es) |
| CN (1) | CN1723316A (es) |
| AR (1) | AR042329A1 (es) |
| AU (1) | AU2003294561A1 (es) |
| BR (1) | BR0317093A (es) |
| CA (1) | CA2538371A1 (es) |
| CL (1) | CL2003002530A1 (es) |
| NO (1) | NO20053287L (es) |
| RU (1) | RU2005121563A (es) |
| TW (1) | TW200508457A (es) |
| WO (1) | WO2004053228A2 (es) |
| ZA (1) | ZA200504337B (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040168781A1 (en) * | 2002-08-05 | 2004-09-02 | Petri Silenius | Noil for use in paper manufacture, method for its production, and paper pulp and paper containing such noil |
| DE102007029688A1 (de) * | 2007-06-27 | 2009-01-02 | Voith Patent Gmbh | Verfahren zum Bilden von Füllstoffen, insbesondere Calciumcarbonat in einer Suspension |
| EP2287398A1 (de) | 2009-07-20 | 2011-02-23 | Voith Patent GmbH | Verfahren zur Herstellung eines Calciumcarbonatpartikel und Faserfibrillen enhaltenden Verbundstoffes |
| FI20105128A7 (fi) * | 2010-02-10 | 2011-08-11 | Kemira Oyj | Menetelmä pigmentti-kuitukomposiitin valmistamiseksi |
| FI122304B (fi) * | 2010-04-22 | 2011-11-30 | Nordkalk Oy Ab | Happaman veden käyttö paperinvalmistuksessa |
| FI124634B (fi) | 2010-06-11 | 2014-11-14 | Upm Kymmene Oyj | Menetelmä ja laitteisto kalkkimaidon in-line valmistamiseksi kuiturainakoneen yhteyteen järjestettyyn PCC:n in-line valmistusprosessiin |
| FI20116326A7 (fi) * | 2011-12-28 | 2013-06-29 | Nordkalk Oy Ab | Saostetun karbonaatin käyttö kuitutuotteen valmistuksessa |
| FI20125569A7 (fi) * | 2012-05-28 | 2013-11-29 | Nordkalk Oy Ab | Saostettua karbonaattia sisältävän komposiittirakenteen valmistus ja käyttö |
| WO2014176579A2 (en) | 2013-04-26 | 2014-10-30 | G.R. Technologies, Llc | Fibrous structured amorphous silica including precipitated calcium carbonate, compositions of matter made therewith, and methods of use thereof |
| WO2015152269A1 (ja) | 2014-03-31 | 2015-10-08 | 日本製紙株式会社 | 炭酸カルシウム微粒子およびその製造方法 |
| SE538770C2 (sv) * | 2014-05-08 | 2016-11-15 | Stora Enso Oyj | Förfarande för framställning av ett termoplastiskt fiberkompositmaterial och en väv |
| JP6530145B2 (ja) | 2017-03-31 | 2019-06-12 | 日本製紙株式会社 | 無機粒子複合繊維シートの製造方法 |
| CN108101091B (zh) * | 2017-12-30 | 2020-05-12 | 石家庄市红星钙业有限公司 | 一种动态碳化法生产碳酸钙的方法和装置 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1447566A (en) * | 1974-02-14 | 1976-08-25 | Ici Ltd | Production of calcium carbonate |
| US4157379A (en) * | 1976-04-16 | 1979-06-05 | Toyo Soda Manufacturing Co., Ltd. | Process for producing chain structured corpuscular calcium carbonate |
| US5096539A (en) * | 1989-07-24 | 1992-03-17 | The Board Of Regents Of The University Of Washington | Cell wall loading of never-dried pulp fibers |
| EP0643166B1 (en) * | 1990-05-14 | 1999-04-07 | Oji Paper Co., Ltd. | Process for modifying hydrophilic fibers with substantially water-insoluble inorganic substance |
| ES2099150T3 (es) * | 1990-10-30 | 1997-05-16 | Ciba Geigy Ag | Mezclas de oligomeros de compuestos de trifenodioxazina, procedimiento para su obtencion y uso de las mismas. |
| FR2689530B1 (fr) * | 1992-04-07 | 1996-12-13 | Aussedat Rey | Nouveau produit complexe a base de fibres et de charges, et procede de fabrication d'un tel nouveau produit. |
| US5275699A (en) * | 1992-10-07 | 1994-01-04 | University Of Washington | Compositions and methods for filling dried cellulosic fibers with an inorganic filler |
| DK0604095T3 (da) * | 1992-12-23 | 2001-08-27 | Imerys Minerals Ltd | Fremgangsmåde til behandling af affaldsstofopslæmninger |
| US5679220A (en) * | 1995-01-19 | 1997-10-21 | International Paper Company | Process for enhanced deposition and retention of particulate filler on papermaking fibers |
| US5665205A (en) * | 1995-01-19 | 1997-09-09 | International Paper Company | Method for improving brightness and cleanliness of secondary fibers for paper and paperboard manufacture |
| FI100729B (fi) * | 1995-06-29 | 1998-02-13 | Metsae Serla Oy | Paperinvalmistuksessa käytettävä täyteaine ja menetelmä täyteaineen va lmistamiseksi |
| FI100670B (fi) * | 1996-02-20 | 1998-01-30 | Metsae Serla Oy | Menetelmä täyteaineen lisäämiseksi selluloosakuituperäiseen massaan |
| US5928470A (en) * | 1997-11-07 | 1999-07-27 | Kimberly-Clark Worldwide, Inc. | Method for filling and coating cellulose fibers |
| FI106140B (fi) * | 1997-11-21 | 2000-11-30 | Metsae Serla Oyj | Paperinvalmistuksessa käytettävä täyteaine ja menetelmä sen valmistamiseksi |
| DK1114219T3 (da) * | 1998-02-20 | 2004-02-16 | Air Liquide | Fremgangsmåde til syntese af calciumcarbonat og det opnåede produkt |
| BR9909003A (pt) * | 1998-03-23 | 2000-11-28 | Pulp Paper Res Inst | Processo para a produção de fibras de polpa carregadas em um lúmen com um enchedor particulado de carbonato de cálcio, lúmen de fibras de polpa, e, fibras de polpa |
| US6355138B1 (en) * | 2000-02-24 | 2002-03-12 | Voith Sulzer Paper Technology North America, Inc. | Method of chemically loading fibers in a fiber suspension |
| DE10033979A1 (de) * | 2000-07-13 | 2002-01-24 | Voith Paper Patent Gmbh | Verfahren zum Beladen von Fasern mit Calciumcarbonat |
| US6413365B1 (en) * | 2001-07-11 | 2002-07-02 | Voith Paper Patent Gmbh | Method of loading a fiber suspension with calcium carbonate |
-
2002
- 2002-12-09 US US10/314,730 patent/US20040108082A1/en not_active Abandoned
-
2003
- 2003-12-03 CA CA002538371A patent/CA2538371A1/en not_active Abandoned
- 2003-12-03 CN CNA2003801055251A patent/CN1723316A/zh active Pending
- 2003-12-03 EP EP03787248A patent/EP1579068A2/en not_active Withdrawn
- 2003-12-03 JP JP2004559235A patent/JP2006509120A/ja not_active Withdrawn
- 2003-12-03 AU AU2003294561A patent/AU2003294561A1/en not_active Abandoned
- 2003-12-03 WO PCT/US2003/038360 patent/WO2004053228A2/en not_active Ceased
- 2003-12-03 RU RU2005121563/04A patent/RU2005121563A/ru not_active Application Discontinuation
- 2003-12-03 BR BR0317093-4A patent/BR0317093A/pt not_active IP Right Cessation
- 2003-12-04 CL CL200302530A patent/CL2003002530A1/es unknown
- 2003-12-05 AR ARP030104510A patent/AR042329A1/es not_active Application Discontinuation
- 2003-12-06 KR KR1020030088375A patent/KR20040050052A/ko not_active Withdrawn
- 2003-12-09 TW TW092134703A patent/TW200508457A/zh unknown
-
2005
- 2005-05-27 ZA ZA200504337A patent/ZA200504337B/en unknown
- 2005-07-05 NO NO20053287A patent/NO20053287L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| JP2006509120A (ja) | 2006-03-16 |
| CA2538371A1 (en) | 2004-06-24 |
| RU2005121563A (ru) | 2006-01-27 |
| KR20040050052A (ko) | 2004-06-14 |
| US20040108082A1 (en) | 2004-06-10 |
| WO2004053228A3 (en) | 2005-02-24 |
| TW200508457A (en) | 2005-03-01 |
| BR0317093A (pt) | 2005-10-25 |
| CN1723316A (zh) | 2006-01-18 |
| AU2003294561A1 (en) | 2004-06-30 |
| NO20053287L (no) | 2005-07-05 |
| CL2003002530A1 (es) | 2005-01-28 |
| ZA200504337B (en) | 2006-02-22 |
| EP1579068A2 (en) | 2005-09-28 |
| WO2004053228A2 (en) | 2004-06-24 |
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