AR032887A1 - AN AMONIACAL WATER ABSORPTION DEVICE - Google Patents
AN AMONIACAL WATER ABSORPTION DEVICEInfo
- Publication number
- AR032887A1 AR032887A1 ARP010103688A ARP010103688A AR032887A1 AR 032887 A1 AR032887 A1 AR 032887A1 AR P010103688 A ARP010103688 A AR P010103688A AR P010103688 A ARP010103688 A AR P010103688A AR 032887 A1 AR032887 A1 AR 032887A1
- Authority
- AR
- Argentina
- Prior art keywords
- generator
- section
- water absorption
- desorbent
- amoniacal
- Prior art date
Links
- 238000010521 absorption reaction Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 239000006096 absorbing agent Substances 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
- F25B15/02—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas
- F25B15/04—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas the refrigerant being ammonia evaporated from aqueous solution
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/007—Energy recuperation; Heat pumps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B33/00—Boilers; Analysers; Rectifiers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
- B01D2257/406—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40088—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
- B01D2259/40092—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot liquid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/32—Details relating to packing elements in the form of grids or built-up elements for forming a unit of module inside the apparatus for mass or heat transfer
- B01J2219/322—Basic shape of the elements
- B01J2219/32279—Tubes or cylinders
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2315/00—Sorption refrigeration cycles or details thereof
- F25B2315/002—Generator absorber heat exchanger [GAX]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2333/00—Details of boilers; Analysers; Rectifiers
- F25B2333/001—Details of boilers; Analysers; Rectifiers the generator or boiler having an analyser
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2333/00—Details of boilers; Analysers; Rectifiers
- F25B2333/003—Details of boilers; Analysers; Rectifiers the generator or boiler is heated by combustion gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2333/00—Details of boilers; Analysers; Rectifiers
- F25B2333/006—Details of boilers; Analysers; Rectifiers the generator or boiler having a rectifier
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2500/00—Problems to be solved
- F25B2500/05—Cost reduction
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2500/00—Problems to be solved
- F25B2500/17—Size reduction
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2500/00—Problems to be solved
- F25B2500/26—Problems to be solved characterised by the startup of the refrigeration cycle
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/52—Heat recovery pumps, i.e. heat pump based systems or units able to transfer the thermal energy from one area of the premises or part of the facilities to a different one, improving the overall efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Power Engineering (AREA)
- Sorption Type Refrigeration Machines (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Un aparato de absorcion de agua amoniacal que comprende un absorbedor, un generador, un condensador y un evaporador, generador (10) que comprende una seccion de caldera (12), una seccion desorbedora calentado por solucion (14), una seccion desorbedora adiabática (16) o desorbedora de GAX (36), y una seccion rectificadora (18), donde el espacio interno de al menos una de dichas secciones de dicho generador está sustancialmente llena de material de relleno estructurado inerte en una solucion acuosa de amoníaco a temperaturas operativas del generador.An ammonia water absorption apparatus comprising an absorber, a generator, a condenser and an evaporator, generator (10) comprising a boiler section (12), a desorbent section heated by solution (14), an adiabatic desorbent section ( 16) or GAX desorbent (36), and a grinding section (18), where the internal space of at least one of said sections of said generator is substantially filled with inert structured filler material in an aqueous solution of ammonia at operating temperatures of the generator.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/632,037 US6487875B1 (en) | 2000-08-03 | 2000-08-03 | Aqua-ammonia absorption system generator utilizing structured packing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR032887A1 true AR032887A1 (en) | 2003-12-03 |
Family
ID=24533808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP010103688A AR032887A1 (en) | 2000-08-03 | 2001-08-02 | AN AMONIACAL WATER ABSORPTION DEVICE |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6487875B1 (en) |
| EP (1) | EP1305558B1 (en) |
| JP (1) | JP4740520B2 (en) |
| KR (1) | KR100780428B1 (en) |
| CN (1) | CN1227493C (en) |
| AR (1) | AR032887A1 (en) |
| AT (1) | ATE371839T1 (en) |
| AU (1) | AU2001285382A1 (en) |
| CA (1) | CA2417256C (en) |
| DE (1) | DE60130221T2 (en) |
| ES (1) | ES2291344T3 (en) |
| IL (1) | IL153950A0 (en) |
| MX (1) | MXPA03000921A (en) |
| TW (1) | TW544505B (en) |
| WO (1) | WO2002012803A1 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6718792B1 (en) * | 2000-01-05 | 2004-04-13 | Rocky Research | Integrated aqua-ammonia chiller/heater |
| KR100473566B1 (en) * | 2002-10-10 | 2005-03-08 | 엘지전선 주식회사 | Combustive region improved slim desorber |
| EP1733773A1 (en) * | 2005-06-17 | 2006-12-20 | Methanol Casale S.A. | Process for carrying out mass transfer between a liquid phase and a gaseous phase |
| JP2008032311A (en) * | 2006-07-28 | 2008-02-14 | Daikin Ind Ltd | Ammonia absorption refrigerator and its corrosion inhibitor |
| US8056360B2 (en) * | 2006-11-22 | 2011-11-15 | Paul Neilson Unmack | Absorption refrigeration protective controller |
| CN102557167A (en) * | 2011-11-18 | 2012-07-11 | 上海金炼化工科技有限公司 | Atmospheric analytical recovery tower for high-ammonia-content wastewater |
| WO2015048858A1 (en) * | 2013-10-06 | 2015-04-09 | Tranquility Group Pty Ltd | System and apparatus for electronic control of an absorption refrigeration system |
| EP2939722A1 (en) * | 2014-05-01 | 2015-11-04 | Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO | Gas desorption |
| WO2015187667A1 (en) * | 2014-06-05 | 2015-12-10 | University Of Florida Research Foundation, Inc. | Architecture for absorption based heaters |
| CN108097001A (en) * | 2018-01-11 | 2018-06-01 | 中石化南京工程有限公司 | A kind of system and method for ammonia in absorbing ammonia nitrogen mixed gas |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4558383A (en) * | 1983-06-30 | 1985-12-10 | International Business Machines Corporation | Information storage disk transducer position control system using a prerecorded servo pattern requiring no alignment with the storage disk |
| US4646541A (en) * | 1984-11-13 | 1987-03-03 | Columbia Gas System Service Corporation | Absorption refrigeration and heat pump system |
| US4724679A (en) * | 1986-07-02 | 1988-02-16 | Reinhard Radermacher | Advanced vapor compression heat pump cycle utilizing non-azeotropic working fluid mixtures |
| US4902207A (en) * | 1987-06-12 | 1990-02-20 | Recovery Engineering, Inc. | Energy recovery apparatus |
| US4972679A (en) * | 1990-02-09 | 1990-11-27 | Columbia Gas Service Corporation | Absorption refrigeration and heat pump system with defrost |
| US5024063A (en) * | 1990-05-11 | 1991-06-18 | Erickson Donald C | Branched gax absorption vapor compressor |
| US5097676A (en) * | 1990-10-24 | 1992-03-24 | Erickson Donald C | Vapor exchange duplex GAX absorption cycle |
| US5367884B1 (en) | 1991-03-12 | 1996-12-31 | Phillips Eng Co | Generator-absorber-heat exchange heat transfer apparatus and method and use thereof in a heat pump |
| US5255534A (en) * | 1992-06-25 | 1993-10-26 | Gas Research Institute | System and process for operating and absorption cycle around a crystallization curve of the solution |
| DE4242602A1 (en) | 1992-12-17 | 1994-07-14 | Keller Juergen U Univ Prof Dr | Working material systems for absorption machines |
| US5490393A (en) | 1994-03-31 | 1996-02-13 | Robur Corporation | Generator absorber heat exchanger for an ammonia/water absorption refrigeration system |
| JPH07318191A (en) | 1994-05-20 | 1995-12-08 | Matsushita Electric Ind Co Ltd | Absorption heat pump device |
| US5548971A (en) | 1995-06-14 | 1996-08-27 | Rocky Research | Method for use of liquid/vapor ammonia absorption systems in unitary HVAC systems |
| JP3442974B2 (en) * | 1997-07-30 | 2003-09-02 | 本田技研工業株式会社 | Rectification unit for absorption refrigerator |
| JP4015735B2 (en) | 1998-01-27 | 2007-11-28 | 本田技研工業株式会社 | Filler element |
| JP2000055498A (en) | 1998-08-04 | 2000-02-25 | Sanyo Electric Co Ltd | Absorption type heat pump |
-
2000
- 2000-08-03 US US09/632,037 patent/US6487875B1/en not_active Expired - Lifetime
-
2001
- 2001-07-30 AT AT01964541T patent/ATE371839T1/en not_active IP Right Cessation
- 2001-07-30 EP EP01964541A patent/EP1305558B1/en not_active Expired - Lifetime
- 2001-07-30 AU AU2001285382A patent/AU2001285382A1/en not_active Abandoned
- 2001-07-30 KR KR1020037001504A patent/KR100780428B1/en not_active Expired - Fee Related
- 2001-07-30 IL IL15395001A patent/IL153950A0/en unknown
- 2001-07-30 CN CNB018137571A patent/CN1227493C/en not_active Expired - Fee Related
- 2001-07-30 DE DE60130221T patent/DE60130221T2/en not_active Expired - Lifetime
- 2001-07-30 WO PCT/US2001/041483 patent/WO2002012803A1/en not_active Ceased
- 2001-07-30 JP JP2002518047A patent/JP4740520B2/en not_active Expired - Lifetime
- 2001-07-30 MX MXPA03000921A patent/MXPA03000921A/en active IP Right Grant
- 2001-07-30 CA CA002417256A patent/CA2417256C/en not_active Expired - Fee Related
- 2001-07-30 ES ES01964541T patent/ES2291344T3/en not_active Expired - Lifetime
- 2001-08-02 AR ARP010103688A patent/AR032887A1/en active IP Right Grant
- 2001-08-02 TW TW090118865A patent/TW544505B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| KR100780428B1 (en) | 2007-11-28 |
| KR20030023730A (en) | 2003-03-19 |
| WO2002012803A8 (en) | 2003-10-30 |
| CA2417256C (en) | 2009-12-08 |
| EP1305558A1 (en) | 2003-05-02 |
| WO2002012803A1 (en) | 2002-02-14 |
| CN1227493C (en) | 2005-11-16 |
| HK1053164A1 (en) | 2003-10-10 |
| TW544505B (en) | 2003-08-01 |
| CA2417256A1 (en) | 2002-02-14 |
| ATE371839T1 (en) | 2007-09-15 |
| DE60130221T2 (en) | 2008-06-05 |
| JP4740520B2 (en) | 2011-08-03 |
| JP2004506171A (en) | 2004-02-26 |
| EP1305558B1 (en) | 2007-08-29 |
| AU2001285382A1 (en) | 2002-02-18 |
| IL153950A0 (en) | 2003-07-31 |
| WO2002012803B1 (en) | 2002-07-25 |
| MXPA03000921A (en) | 2004-04-02 |
| US6487875B1 (en) | 2002-12-03 |
| DE60130221D1 (en) | 2007-10-11 |
| ES2291344T3 (en) | 2008-03-01 |
| CN1446305A (en) | 2003-10-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |