AR017065A1 - PROCESO PARA LA PREPARACIoN DE UNA COMPOSICIoN MICROENCAPSULADA DE LIBERACIoN CONTROLADA, COMPOSICIoN HERBICIDA MICROENCAPSULADA, MÉTODO HERBICIDA, Y MÉTODO PARA CONTROL MALEZAS - Google Patents
PROCESO PARA LA PREPARACIoN DE UNA COMPOSICIoN MICROENCAPSULADA DE LIBERACIoN CONTROLADA, COMPOSICIoN HERBICIDA MICROENCAPSULADA, MÉTODO HERBICIDA, Y MÉTODO PARA CONTROL MALEZASInfo
- Publication number
- AR017065A1 AR017065A1 ARP980104436A ARP980104436A AR017065A1 AR 017065 A1 AR017065 A1 AR 017065A1 AR P980104436 A ARP980104436 A AR P980104436A AR P980104436 A ARP980104436 A AR P980104436A AR 017065 A1 AR017065 A1 AR 017065A1
- Authority
- AR
- Argentina
- Prior art keywords
- composition
- microencapsulated
- microcapsules
- herbicide
- nucleus
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 239000004009 herbicide Substances 0.000 title abstract 3
- 230000002363 herbicidal effect Effects 0.000 title 2
- 239000003094 microcapsule Substances 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 3
- 239000000126 substance Substances 0.000 abstract 3
- 239000002775 capsule Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229920000768 polyamine Polymers 0.000 abstract 2
- 239000003905 agrochemical Substances 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 230000001012 protector Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002569 water oil cream Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
- C08G18/7831—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3228—Polyamines acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
- C08G18/765—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group alpha, alpha, alpha', alpha', -tetraalkylxylylene diisocyanate or homologues substituted on the aromatic ring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Manufacturing Of Micro-Capsules (AREA)
Abstract
Un proceso para la preparacion de una composicion microencapsulada que comprende los siguientes pasos: (a) combinar(I) un triisocianato que es un aducto deisocanatos alifáticos linealesm que poseen la formula O=C=N-(CH2)n-N=C=O, donde el valor de ne s de 4-18; (II) un diisocianato alifático que contiene un grupoque es un anillo aromático o cicloalifático, donde el diisocianato alifático posee de 6-32 átomos de carbono, con mayor preferencia de 8-18 átomos de carbono;y (III) una composicioninmiscible en agua que comprende la sustancia química del nucleo; (b) agregar un líquido acuoso y formar una emulsion aceite-agua; (c)agregar una poliamina a la emulsion; y (d) hacer reaccionar al triisocianato, al diisocianato y a la poliamina, conlo cua l se produce una pluralidad demicrocápsulas que poseen una pared capsular, con por lo menos una gran porcion de la sustancia química del nucleo encapsulada dentro de dicha pared capsular delas microcápsulas. Las sustancias químicas del nucleoadecuad as incluyen sustancias químicas agrícolas, tales como herbicidas y protectores. El ajuste de lacomposicion de las paredes de la cápsula y los contenidos en el nucleo de la cápsula permite ajustar la velocidad de liberacion de los materialesdel nucle o delas microcápsulas. Cuando el nucleo contiene dos o más materiales a liberar, las microcápsulas pueden proporcionar una mayor velocidad de liberacion de uno dedichos materiales que del otro.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/924,671 US5925595A (en) | 1997-09-05 | 1997-09-05 | Microcapsules with readily adjustable release rates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR017065A1 true AR017065A1 (es) | 2001-08-22 |
Family
ID=25450522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP980104436A AR017065A1 (es) | 1997-09-05 | 1998-09-04 | PROCESO PARA LA PREPARACIoN DE UNA COMPOSICIoN MICROENCAPSULADA DE LIBERACIoN CONTROLADA, COMPOSICIoN HERBICIDA MICROENCAPSULADA, MÉTODO HERBICIDA, Y MÉTODO PARA CONTROL MALEZAS |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5925595A (es) |
| EP (1) | EP1037527B1 (es) |
| KR (1) | KR20010015572A (es) |
| CN (1) | CN1291074A (es) |
| AR (1) | AR017065A1 (es) |
| AT (1) | ATE256389T1 (es) |
| AU (1) | AU734072B2 (es) |
| BR (1) | BR9814262B1 (es) |
| CA (1) | CA2302235C (es) |
| DE (1) | DE69820677T2 (es) |
| HU (1) | HUP0100193A3 (es) |
| ID (1) | ID20837A (es) |
| MY (1) | MY120760A (es) |
| PL (1) | PL343867A1 (es) |
| WO (1) | WO1999011122A1 (es) |
| YU (1) | YU13100A (es) |
| ZA (1) | ZA988125B (es) |
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| DE19840583A1 (de) | 1998-09-05 | 2000-03-09 | Bayer Ag | Mikrokapsel-Formulierungen |
| US6653256B1 (en) | 1999-08-24 | 2003-11-25 | Bayer Aktiengesellschaft | Microcapsule formulations |
| US6231895B1 (en) * | 2000-03-01 | 2001-05-15 | Agway, Inc | Feedstock for ruminants with controlled-release non-protein nitrogen |
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| US7702995B2 (en) * | 2000-04-24 | 2010-04-20 | TVWorks, LLC. | Method and system for transforming content for execution on multiple platforms |
| US9788058B2 (en) | 2000-04-24 | 2017-10-10 | Comcast Cable Communications Management, Llc | Method and system for automatic insertion of interactive TV triggers into a broadcast data stream |
| US8296792B2 (en) | 2000-04-24 | 2012-10-23 | Tvworks, Llc | Method and system to provide interactivity using an interactive channel bug |
| KR100854530B1 (ko) * | 2000-06-05 | 2008-08-26 | 신젠타 리미티드 | 신규한 마이크로캡슐 |
| US6992047B2 (en) * | 2001-04-11 | 2006-01-31 | Monsanto Technology Llc | Method of microencapsulating an agricultural active having a high melting point and uses for such materials |
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| MXPA05006365A (es) * | 2002-12-13 | 2005-08-29 | Monsanto Technology Llc | Microcapsulas con velocidad de liberacion ajustada con aminas. |
| BRPI0512102A (pt) * | 2004-06-14 | 2008-02-06 | Monsanto Technology Llc | microcápsulas tendo liberação ativada de material de núcleo dentro delas |
| WO2007009023A2 (en) * | 2005-07-13 | 2007-01-18 | Engineered Release Systems, Inc. | Chemically cross-linked elastomeric microcapsules |
| HUE038015T2 (hu) | 2006-03-30 | 2018-09-28 | Fmc Corp | Acetilén karbamid származék-polikarbamid polimerek, és ezek mikrokapszulái és kiszerelései szabályozott kibocsátáshoz |
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| CA2754931C (en) * | 2009-02-13 | 2018-12-18 | Monsanto Technology Llc | Encapsulation of herbicides to reduce crop injury |
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| US10085925B2 (en) | 2009-09-18 | 2018-10-02 | International Flavors & Fragrances Inc. | Polyurea capsule compositions |
| US11311467B2 (en) * | 2009-09-18 | 2022-04-26 | International Flavors & Fragrances Inc. | Polyurea capsules prepared with a polyisocyanate and cross-linking agent |
| ES2628087T3 (es) * | 2010-06-25 | 2017-08-01 | Cognis Ip Management Gmbh | Procedimiento para producir microcápsulas |
| EP2605646B1 (en) | 2010-08-18 | 2016-07-20 | Monsanto Technology LLC | Early applications of encapsulated acetamides for reduced injury in crops |
| RU2592851C2 (ru) * | 2010-11-23 | 2016-07-27 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Гербицидные суспензии капсул ацетохлора, содержащие пониженные количества антидота |
| US9333454B2 (en) | 2011-01-21 | 2016-05-10 | International Business Machines Corporation | Silicone-based chemical filter and silicone-based chemical bath for removing sulfur contaminants |
| US8900491B2 (en) | 2011-05-06 | 2014-12-02 | International Business Machines Corporation | Flame retardant filler |
| US9186641B2 (en) | 2011-08-05 | 2015-11-17 | International Business Machines Corporation | Microcapsules adapted to rupture in a magnetic field to enable easy removal of one substrate from another for enhanced reworkability |
| US8935719B2 (en) | 2011-08-25 | 2015-01-13 | Comcast Cable Communications, Llc | Application triggering |
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| US8741804B2 (en) | 2011-10-28 | 2014-06-03 | International Business Machines Corporation | Microcapsules adapted to rupture in a magnetic field |
| BR102012027933A2 (pt) * | 2011-11-01 | 2015-11-17 | Dow Agrosciences Llc | composições pesticidas estáveis |
| US9716055B2 (en) | 2012-06-13 | 2017-07-25 | International Business Machines Corporation | Thermal interface material (TIM) with thermally conductive integrated release layer |
| US9724542B2 (en) | 2012-10-12 | 2017-08-08 | Premier Dental Products Company | Remineralizing and desensitizing compositions, treatments and methods of manufacture |
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| GB2496330B (en) * | 2013-01-21 | 2016-06-29 | Rotam Agrochem Int Co Ltd | Preparation of an agrochemical active composition encapsulated in cross linked polyurea |
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| EP3310166B1 (en) * | 2015-06-19 | 2020-03-25 | Basf Se | Pendimethalin microcapsules with a shell made of tetramethylxylylene diisocyanate and a polyamine with at least three amine groups |
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| JP6911014B2 (ja) | 2015-10-27 | 2021-07-28 | エンカプシス エルエルシー | カプセル化 |
| EP3550968A1 (en) * | 2016-12-07 | 2019-10-16 | BASF Agro B.V. | Cinmethylin microcapsules with a shell made of tetramethylxylylene diisocyanate and a polyam-ine with at least three amine groups |
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| DE102017113883A1 (de) | 2017-06-22 | 2018-12-27 | Technische Universität Darmstadt | Verfahren zur Bekämpfung von Misteln |
| AU2018403208B2 (en) | 2018-01-17 | 2024-10-17 | Monsanto Technology Llc | Herbicidal compositions |
| WO2020160223A1 (en) | 2019-01-30 | 2020-08-06 | Monsanto Technology Llc | Microencapsulated acetamide herbicides |
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| CN117511277B (zh) * | 2023-11-08 | 2025-08-19 | 浙江升华云峰新材股份有限公司 | 一种香味微胶囊及其制备方法以及抗菌释香uv漆、饰面人造板 |
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| DE4130743A1 (de) * | 1991-09-16 | 1993-03-18 | Bayer Ag | Mikrokapseln aus isocyanaten mit polyethylenoxidhaltigen gruppen |
| US5411802A (en) * | 1993-10-29 | 1995-05-02 | Minnesota Mining And Manufacturing Company | Colorant compositions and processes |
| DE4409265A1 (de) * | 1994-03-18 | 1995-09-21 | Bayer Ag | Druckempfindliches Aufzeichnungsmaterial, das natürliche Öle und/oder Derivate davon enthält |
| US5597780A (en) * | 1994-11-16 | 1997-01-28 | Fmc Corporation | Low volatility formulations of microencapsulated clomazone |
| US5583090A (en) * | 1995-06-26 | 1996-12-10 | Monsanto Company | Herbicidal microencapsulated clomazone compositions with reduced vapor transfer |
-
1997
- 1997-09-05 US US08/924,671 patent/US5925595A/en not_active Expired - Lifetime
-
1998
- 1998-09-03 AU AU93763/98A patent/AU734072B2/en not_active Ceased
- 1998-09-03 CA CA002302235A patent/CA2302235C/en not_active Expired - Lifetime
- 1998-09-03 KR KR1020007002349A patent/KR20010015572A/ko not_active Ceased
- 1998-09-03 PL PL98343867A patent/PL343867A1/xx unknown
- 1998-09-03 YU YU13100A patent/YU13100A/sh unknown
- 1998-09-03 HU HU0100193A patent/HUP0100193A3/hu unknown
- 1998-09-03 BR BRPI9814262-3A patent/BR9814262B1/pt not_active IP Right Cessation
- 1998-09-03 CN CN98810827A patent/CN1291074A/zh active Pending
- 1998-09-03 EP EP98946830A patent/EP1037527B1/en not_active Expired - Lifetime
- 1998-09-03 DE DE69820677T patent/DE69820677T2/de not_active Expired - Lifetime
- 1998-09-03 AT AT98946830T patent/ATE256389T1/de not_active IP Right Cessation
- 1998-09-03 WO PCT/US1998/018373 patent/WO1999011122A1/en not_active Ceased
- 1998-09-04 MY MYPI98004043A patent/MY120760A/en unknown
- 1998-09-04 AR ARP980104436A patent/AR017065A1/es active IP Right Grant
- 1998-09-04 ZA ZA988125A patent/ZA988125B/xx unknown
- 1998-09-07 ID IDP981203A patent/ID20837A/id unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU9376398A (en) | 1999-03-22 |
| ATE256389T1 (de) | 2004-01-15 |
| US5925595A (en) | 1999-07-20 |
| EP1037527B1 (en) | 2003-12-17 |
| CA2302235C (en) | 2009-11-24 |
| MY120760A (en) | 2005-11-30 |
| DE69820677T2 (de) | 2004-09-30 |
| WO1999011122A1 (en) | 1999-03-11 |
| BR9814262A (pt) | 2004-02-25 |
| HUP0100193A3 (en) | 2002-10-28 |
| CN1291074A (zh) | 2001-04-11 |
| EP1037527A1 (en) | 2000-09-27 |
| HUP0100193A2 (hu) | 2001-06-28 |
| ZA988125B (en) | 1999-03-05 |
| BR9814262B1 (pt) | 2010-06-01 |
| DE69820677D1 (de) | 2004-01-29 |
| ID20837A (id) | 1999-03-11 |
| CA2302235A1 (en) | 1999-03-11 |
| PL343867A1 (en) | 2001-09-10 |
| AU734072B2 (en) | 2001-05-31 |
| YU13100A (sh) | 2002-08-12 |
| KR20010015572A (ko) | 2001-02-26 |
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