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AR009613A1 - A METALLOCENE, A LINKAGE USEFUL AS AN INTERMEDIATE IN THE PREPARATION OF SUCH METALLOCENE, AND A CATALYTIC SYSTEM AND A PROCEDURE FOR THE POLYMERIZATION OF ADDITIONAL MONOMERES. - Google Patents

A METALLOCENE, A LINKAGE USEFUL AS AN INTERMEDIATE IN THE PREPARATION OF SUCH METALLOCENE, AND A CATALYTIC SYSTEM AND A PROCEDURE FOR THE POLYMERIZATION OF ADDITIONAL MONOMERES.

Info

Publication number
AR009613A1
AR009613A1 ARP970105366A ARP970105366A AR009613A1 AR 009613 A1 AR009613 A1 AR 009613A1 AR P970105366 A ARP970105366 A AR P970105366A AR P970105366 A ARP970105366 A AR P970105366A AR 009613 A1 AR009613 A1 AR 009613A1
Authority
AR
Argentina
Prior art keywords
metallocene
monomeres
polymerization
procedure
preparation
Prior art date
Application number
ARP970105366A
Other languages
Spanish (es)
Original Assignee
Montell Technology Company Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Montell Technology Company Bv filed Critical Montell Technology Company Bv
Publication of AR009613A1 publication Critical patent/AR009613A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/50—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
    • C07D333/52—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes
    • C07D333/62—Benzo[b]thiophenes; Hydrogenated benzo[b]thiophenes with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to carbon atoms of the hetero ring
    • C07D333/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • C07D333/70—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D495/00—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms
    • C07D495/02—Heterocyclic compounds containing in the condensed system at least one hetero ring having sulfur atoms as the only ring hetero atoms in which the condensed system contains two hetero rings
    • C07D495/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/05—Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Indole Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Se revelan una nueva clase de metalocenos heterocíclicos, un sistema catalítico que los contiene y un procedimiento para polimerizar monomerosde adicion polimerizables usando dicho sistema catalítico; los metalocenos heterocíclicoscorres ponden a la formula (I): Yj RiZjj-MeQkP1 (I) en donde:Y es un grupo coordinador que contiene un radical central de seis electrones que coordina directamente Me, al cual están asociados uno o más radicales quecontienen por lo menos un átomono carb ono seleccionado entre B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb y Te; R es un puente divalente entre losgrupos Y y Z; Z es un grupo coordinador, siendo opcionalmente igual a Y; Me es un metal de transicion; Q es un sustituyentehalogeno o hidrocarburo; P esun contraion; i es 0 o 1; j es 1-4, jj es 0-2; k es 1-3; y 1 es 0-2.A new class of heterocyclic metallocenes, a catalyst system containing them, and a process for polymerizing polymerizable addition monomers using such a catalyst system are disclosed; the corresponding heterocyclic metallocenes put the formula (I): Yj RiZjj-MeQkP1 (I) where: Y is a coordinating group that contains a central radical of six electrons that directly coordinates Me, to which one or more radicals are associated, which contain minus one carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R is a divalent bridge between the Y and Z groups; Z is a coordinating group, being optionally equal to Y; It is a transition metal to me; Q is a halogen or hydrocarbon substituent; P is a counterion; i is 0 or 1; j is 1-4, jj is 0-2; k is 1-3; and 1 is 0-2.

ARP970105366A 1996-11-15 1997-11-17 A METALLOCENE, A LINKAGE USEFUL AS AN INTERMEDIATE IN THE PREPARATION OF SUCH METALLOCENE, AND A CATALYTIC SYSTEM AND A PROCEDURE FOR THE POLYMERIZATION OF ADDITIONAL MONOMERES. AR009613A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96118369 1996-11-15

Publications (1)

Publication Number Publication Date
AR009613A1 true AR009613A1 (en) 2000-04-26

Family

ID=8223400

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP970105366A AR009613A1 (en) 1996-11-15 1997-11-17 A METALLOCENE, A LINKAGE USEFUL AS AN INTERMEDIATE IN THE PREPARATION OF SUCH METALLOCENE, AND A CATALYTIC SYSTEM AND A PROCEDURE FOR THE POLYMERIZATION OF ADDITIONAL MONOMERES.

Country Status (21)

Country Link
US (2) US7238818B2 (en)
EP (2) EP1327636B1 (en)
KR (1) KR100536794B1 (en)
CN (1) CN1113890C (en)
AR (1) AR009613A1 (en)
AU (1) AU733813B2 (en)
BR (1) BR9715006B1 (en)
CA (1) CA2271861C (en)
DE (2) DE69721807T2 (en)
ES (2) ES2197377T3 (en)
HU (1) HUP9904527A2 (en)
ID (1) ID22443A (en)
IL (1) IL129600A0 (en)
NO (1) NO992352L (en)
PE (1) PE52899A1 (en)
PL (1) PL188107B1 (en)
RU (1) RU2194708C2 (en)
TR (1) TR199901635T2 (en)
TW (1) TW394779B (en)
WO (1) WO1998022486A1 (en)
ZA (1) ZA9710211B (en)

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