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NZ775353B2 - Aerosolisable formulation - Google Patents

Aerosolisable formulation Download PDF

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Publication number
NZ775353B2
NZ775353B2 NZ775353A NZ77535319A NZ775353B2 NZ 775353 B2 NZ775353 B2 NZ 775353B2 NZ 775353 A NZ775353 A NZ 775353A NZ 77535319 A NZ77535319 A NZ 77535319A NZ 775353 B2 NZ775353 B2 NZ 775353B2
Authority
NZ
New Zealand
Prior art keywords
aerosolisable formulation
acid
flavours
water
encapsulated
Prior art date
Application number
NZ775353A
Other versions
NZ775353A (en
Inventor
Ross Cabot
Original Assignee
Nicoventures Trading Limited
Filing date
Publication date
Priority claimed from GBGB1817866.5A external-priority patent/GB201817866D0/en
Priority claimed from GBGB1906242.1A external-priority patent/GB201906242D0/en
Application filed by Nicoventures Trading Limited filed Critical Nicoventures Trading Limited
Priority claimed from PCT/GB2019/053096 external-priority patent/WO2020089641A1/en
Publication of NZ775353A publication Critical patent/NZ775353A/en
Publication of NZ775353B2 publication Critical patent/NZ775353B2/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/10Chemical features of tobacco products or tobacco substitutes
    • A24B15/16Chemical features of tobacco products or tobacco substitutes of tobacco substitutes
    • A24B15/167Chemical features of tobacco products or tobacco substitutes of tobacco substitutes in liquid or vaporisable form, e.g. liquid compositions for electronic cigarettes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • A24B15/283Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/281Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
    • A24B15/283Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
    • A24B15/284Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances the additive being bound to a host by chemical, electrical or like forces, e.g. use of precursors, inclusion complexes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/301Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by aromatic compounds
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/32Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by acyclic compounds
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/34Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a carbocyclic ring other than a six-membered aromatic ring
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24BMANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
    • A24B15/00Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
    • A24B15/18Treatment of tobacco products or tobacco substitutes
    • A24B15/28Treatment of tobacco products or tobacco substitutes by chemical substances
    • A24B15/30Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
    • A24B15/36Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring
    • A24B15/40Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms
    • A24B15/403Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a heterocyclic ring having only oxygen or sulfur as hetero atoms having only oxygen as hetero atoms
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/05Devices without heating means
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24FSMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
    • A24F40/00Electrically operated smoking devices; Component parts thereof; Manufacture thereof; Maintenance or testing thereof; Charging means specially adapted therefor
    • A24F40/10Devices using liquid inhalable precursors
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K31/00Medicinal preparations containing organic active ingredients
    • A61K31/33Heterocyclic compounds
    • A61K31/395Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
    • A61K31/435Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
    • A61K31/465Nicotine; Derivatives thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00Batteries for particular applications
    • H01M2220/30Batteries in portable systems, e.g. mobile phone, laptop
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

There is provided an aerosolisable formulation comprising (i) water; (ii) one or more flavours to be encapsulated; (iii) one or more encapsulating materials; wherein in the presence of water the energy of binding of the one or more encapsulating materials with the one or more flavours to be encapsulated is from -0.5 to -8 kcal/mol; (iv) nicotine; and (v) at least one acid.

Claims (32)

1. An aerosolisable formulation comprising (i) water present in an amount of at least 70 wt.% based on the aerosolisable formulation; 5 (ii) one or more flavours to be encapsulated; (iii) one or more encapsulating materials; (iv) nicotine; and (v) at least one acid; wherein in the presence of water the energy of binding of the one or more encapsulating 10 materials with the one or more flavours to be encapsulated is from -0.5 to -8 kcal/mol.
2. An aerosolisable formulation according to claim 1 comprising (i) water present in an amount of at least 70 wt.% based on the aerosolisable formulation (ii) one or more flavours to be encapsulated; and 15 (iii) one or more encapsulating materials having a solubility in water of at least 50% of the solubility in water of the one or more flavours to be encapsulated; and (iv) nicotine and (v) at least one acid. 20
3. An aerosolisable formulation according to any one of claims 1 or 2 wherein in the presence of water the energy of binding of the one or more encapsulating materials with the one or more flavours to be encapsulated is from -2 to -8 kcal/mol.
4. An aerosolisable formulation according to any one of claims 1 to 3 wherein in the 25 presence of water the energy of binding of the one or more encapsulating materials with the one or more flavours to be encapsulated is from -3 to -8 kcal/mol.
5. An aerosolisable formulation according to any one of claims 1 to 4 wherein in the presence of water the energy of binding of the one or more encapsulating materials with the 30 one or more flavours to be encapsulated is from -4 to -7 kcal/mol.
6. An aerosolisable formulation according to any one of claims 1 to 5 wherein water is present in an amount of at least 75 wt.% based on the aerosolisable formulation. 35
7. An aerosolisable formulation according to any one of claims 1 to 6 wherein water is present in an amount of at least 90 wt.% based on the aerosolisable formulation.
8. An aerosolisable formulation according to any one of claims 1 to 7 wherein the nicotine is present in an amount of no greater than 1wt.% based on the aerosolisable formulation. 5
9. An aerosolisable formulation according to claim 8 wherein nicotine is present in an amount of from 0.01 to 0.6 wt.% based on the aerosolisable formulation.
10. An aerosolisable formulation according to claim 1 wherein the acid is selected from the group consisting of acetic acid, lactic acid, formic acid, citric acid, benzoic acid, pyruvic 10 acid, levulinic acid, succinic acid, tartaric acid, sorbic acid, propionic acid, phenylacetic acid, and mixtures thereof.
11. An aerosolisable formulation according to claim 10 wherein the acid is selected from the group consisting of citric acid, benzoic acid, levulinic acid, sorbic acid, lactic acid, and 15 mixtures thereof.
12. An aerosolisable formulation according to any one of claims 10 to 11 wherein the acid is at least citric acid. 20
13. An aerosolisable formulation according to any one of claims 10 to 12 wherein the total content of acid present in the formulation is no greater than 1.0 mole equivalents based on the nicotine.
14. An aerosolisable formulation according to any one of claims 10 to 13 wherein the 25 total content of acid present in the solution is no less than 0.1 mole equivalents based on the nicotine.
15. An aerosolisable formulation according to any one of claims 1 to 14 wherein the one or more flavours are selected from (4-(para-)methoxyphenyl)butanone, vanillin, ?- 30 undecalactone, menthone, 5-propenyl guaethol, menthol, para-menthathiolone and mixtures thereof.
16. An aerosolisable formulation according to claim 15 wherein the flavour is at least menthol.
17. An aerosolisable formulation according to any one of claims 1 to 16 wherein the one or more flavours are present in a total amount of no greater than 2 wt.% based on the aerosolisable formulation.
18. An aerosolisable formulation according to any one of claims 1 to 17 wherein the one or more flavours are present in a total amount of from 0.01 to 1 wt.% based on the 5 aerosolisable formulation.
19. An aerosolisable formulation according to any one of claims 1 to 18 wherein the one or more encapsulating materials are selected from cyclodextrins and mixtures thereof. 10
20. An aerosolisable formulation according to claim 19 wherein the one more cyclodextrins are selected from the group consisting of substituted or unsubstituted (a)- cyclodextrin, substituted or unsubstituted (ß)-cyclodextrin, substituted or unsubstituted ( ?)- cyclodextrin, and mixtures thereof. 15
21. An aerosolisable formulation according to 19 or 20 wherein the one more cyclodextrins is at least a substituted (ß)-cyclodextrin.
22. An aerosolisable formulation according to any one of claims 1 to 21 wherein the one or more encapsulating materials are present in a total amount of no greater than 12 wt.% 20 based on the aerosolisable formulation.
23. An aerosolisable formulation according to any one of claims 1 to 22 wherein the one or more encapsulating materials have a solubility in water of at least 70 % of the solubility in water of the one or more flavours to be encapsulated.
24. An aerosolisable formulation according to any one of claims 1 to 23 wherein the one or more encapsulating materials have a solubility in water of at least 90 % of the solubility in water of the one or more flavours to be encapsulated. 30
25. A process for forming an aerosol, the process comprising aerosolising an aerosolisable formulation comprising (i) water present in an amount of at least 70 wt.% based on the aerosolisable formulation; (ii) one or more flavours to be encapsulated; 35 (iii) one or more encapsulating materials; and (v) at least one acid; wherein in the presence of water the energy of binding of the one or more encapsulating materials with the one or more flavours to be encapsulated is from -0.5 to -8 kcal/mol.
26. A process according to claim 25 wherein the aerosolisable formulation is a formulation as defined in any one of claims 2 to 24.
27. A process according to claim 25 or 26 wherein the aerosol is formed by a process performed at a temperature below 50°C.
28. A process according to claim 25, 26 or 27 wherein the aerosol is formed by applying 10 ultrasonic energy to the aerosolised formulation.
29. A contained aerosolisable formulation comprising (a) a container; and (b) an aerosolisable formulation comprising 15 (i) water present in an amount of at least 70 wt.% based on the aerosolisable formulation; (ii) one or more flavours to be encapsulated; (iii) one or more encapsulating materials; (iv) nicotine; and 20 (v) at least one acid; wherein in the presence of water the energy of binding of the one or more encapsulating materials with the one or more flavours to be encapsulated is from -0.5 to -8 kcal/mol.
30. A contained aerosolisable formulation according to claim 29 wherein the container is 25 configured for engagement with an electronic aerosol provision system.
31. An electronic aerosol provision system comprising: (a) an aerosoliser for aerosolising formulation for inhalation by a user of the electronic aerosol provision system; 30 (b) a power supply comprising a cell or battery for supplying power to the aerosoliser (c) an aerosolisable formulation comprising (i) water present in an amount of at least 70 wt.% based on the aerosolisable formulation; (ii) one or more flavours to be encapsulated; 35 (iii) one or more encapsulating materials; and (iv) at least one acid; wherein in the presence of water the energy of binding of the one or more encapsulating materials with the one or more flavours to be encapsulated is from -0.5 to -8 kcal/mol.
32. A process for improving the sensory properties of an aerosolised formulation, the process comprising the steps of aerosolising an aerosolisable formulation comprising 5 (i) water present in an amount of at least 70 wt.% based on the aerosolisable formulation; (ii) one or more flavours to be encapsulated; (iii) one or more encapsulating materials; and (iv) at least one acid; 10 wherein in the presence of water the energy of binding of the one or more encapsulating materials with the one or more flavours to be encapsulated is from -0.5 to -8 kcal/mol. Nicoventures Trading Limited 15 By the Attorneys for the Applicant SPRUSON & FERGUSON
NZ775353A 2019-10-31 Aerosolisable formulation NZ775353B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB1817866.5A GB201817866D0 (en) 2018-11-01 2018-11-01 Aerosolisable formulation
GBGB1906242.1A GB201906242D0 (en) 2019-05-03 2019-05-03 Aerosolisable formulation
PCT/GB2019/053096 WO2020089641A1 (en) 2018-11-01 2019-10-31 Aerosolisable formulation

Publications (2)

Publication Number Publication Date
NZ775353A NZ775353A (en) 2024-09-27
NZ775353B2 true NZ775353B2 (en) 2025-01-07

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