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NZ335515A - Process for the preparation of hydrocarbons by reacting carbon monoxide and hydrogen in the presence of a cobalt/magnesium catalyst - Google Patents

Process for the preparation of hydrocarbons by reacting carbon monoxide and hydrogen in the presence of a cobalt/magnesium catalyst

Info

Publication number
NZ335515A
NZ335515A NZ335515A NZ33551597A NZ335515A NZ 335515 A NZ335515 A NZ 335515A NZ 335515 A NZ335515 A NZ 335515A NZ 33551597 A NZ33551597 A NZ 33551597A NZ 335515 A NZ335515 A NZ 335515A
Authority
NZ
New Zealand
Prior art keywords
cobalt
hydrogen
carbon monoxide
hydrocarbons
preparation
Prior art date
Application number
NZ335515A
Inventor
Jacobus Johannes Cor Geerlings
Arend Hoek
Hans Michiel Huisman
Peter William Lednor
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of NZ335515A publication Critical patent/NZ335515A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/889—Manganese, technetium or rhenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The present disclosure relates to a process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen in which reaction a feed comprising hydrogen and carbon monoxide is contacted at elevated temperature and pressure with a catalyst comprising cobalt and manganese in which catalyst the cobalt/manganese molar ratio is between 14:1 and 7:1 and the GHSV is at least 1600 N1/1/h. Preferably the cobalt/manganese molar ratio is between 13:1 and 9:1 and the GHSV is between 2700 and 25,000 N1/1/h. The reaction is especially carried out in a slurry phase regime.
NZ335515A 1996-12-13 1997-12-11 Process for the preparation of hydrocarbons by reacting carbon monoxide and hydrogen in the presence of a cobalt/magnesium catalyst NZ335515A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96203538 1996-12-13

Publications (1)

Publication Number Publication Date
NZ335515A true NZ335515A (en) 2000-04-28

Family

ID=8224699

Family Applications (1)

Application Number Title Priority Date Filing Date
NZ335515A NZ335515A (en) 1996-12-13 1997-12-11 Process for the preparation of hydrocarbons by reacting carbon monoxide and hydrogen in the presence of a cobalt/magnesium catalyst

Country Status (15)

Country Link
US (1) US5958985A (en)
EP (1) EP0966415B1 (en)
AU (1) AU718101B2 (en)
CA (1) CA2274688C (en)
DE (1) DE69711714T2 (en)
DZ (1) DZ2370A1 (en)
ES (1) ES2175521T3 (en)
ID (1) ID21757A (en)
MY (1) MY118696A (en)
NO (1) NO329313B1 (en)
NZ (1) NZ335515A (en)
RU (1) RU2187486C2 (en)
SA (1) SA97180722B1 (en)
WO (1) WO1998025870A1 (en)
ZA (1) ZA9711090B (en)

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US6475943B1 (en) * 1995-11-08 2002-11-05 Shell Oil Company Catalyst activation process
ES2221235T3 (en) * 1997-12-30 2004-12-16 Shell Internationale Research Maatschappij B.V. COBALT FISCHER-TROSCH CATALYST.
US6191066B1 (en) * 1998-05-27 2001-02-20 Energy International Corporation Fischer-Tropsch activity for non-promoted cobalt-on-alumina catalysts
RU2259988C2 (en) * 2000-07-03 2005-09-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Catalyst and method for preparing hydrocarbons
AU2001285823B2 (en) * 2000-07-14 2004-09-23 Shell Internationale Research Maatschappij B.V. A catalyst support, a supported group VIII metal catalyst and a precursor thereof, processes for their preparation, and a use of the supported group VIII metal catalyst
WO2003018481A1 (en) * 2001-08-22 2003-03-06 Shell Internationale Research Maatschappij B.V. Purification of titania
FR2830858B1 (en) * 2001-10-11 2003-12-12 Inst Francais Du Petrole PROCESS FOR THE SYNTHESIS OF HYDROCARBONS IN A THREE-PHASE REACTOR IN THE PRESENCE OF A CATALYST COMPRISING A GROUP VIII METAL SUPPORTED ON ZIRCONIA OR ON MIXED ZIRCONIUM-ALUMINA OXIDE
US6956063B2 (en) * 2001-12-28 2005-10-18 Conocophillips Company Method for reducing water concentration in a multi-phase column reactor
US7001927B2 (en) * 2001-12-28 2006-02-21 Conocophillips Company Water removal in Fischer-Tropsch processes
US6809122B2 (en) 2001-12-28 2004-10-26 Conocophillips Company Method for reducing the maximum water concentration in a multi-phase column reactor
RU2212376C1 (en) * 2002-04-10 2003-09-20 Общество с ограниченной ответственностью "Научно-исследовательский институт природных газов и газовых технологий-ВНИИГАЗ" Method of producing distillate fractions from furnace black production emission gases
MY134279A (en) * 2002-06-05 2007-11-30 Shell Int Research Process for the production of hydrocarbons from gaseous hydrocarbonaceous feed
EP1632289A4 (en) * 2003-04-07 2012-03-07 Nippon Steel Corp CATALYST FOR PRODUCING HYDROCARBON FROM SYNTHESIS GAS AND PROCESS FOR MANUFACTURING THE CATALYST
FR2864532B1 (en) * 2003-12-31 2007-04-13 Total France PROCESS FOR TRANSFORMING A SYNTHETIC GAS TO HYDROCARBONS IN THE PRESENCE OF SIC BETA AND EFFLUTING THE SAME
FR2887545B1 (en) * 2005-06-27 2007-08-10 Total Sa PROCESS FOR PROCESSING HYDROCARBON SYNTHESIS GAS IN THE PRESENCE OF SIC FOAM
BRPI0615192A2 (en) * 2005-08-22 2011-05-10 Shell Int Research diesel fuel, and, Methods for operating a diesel engine and reducing the emission of nitrogen oxides
WO2008090105A2 (en) * 2007-01-23 2008-07-31 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
CA2748216C (en) * 2008-12-22 2016-06-07 Wm Gtl, Inc. Low-pressure fischer-tropsch process
US8148295B2 (en) * 2009-02-16 2012-04-03 Millennium Inorganic Chemicals, Inc. Catalyst promoters in vanadium-free mobile catalyst
TWI399241B (en) * 2009-10-30 2013-06-21 Univ Nat Defense A modified catalyst for reforming ethanol to produce hydrogen and the manufacturing method thereof
JP5730495B2 (en) * 2010-03-30 2015-06-10 独立行政法人石油天然ガス・金属鉱物資源機構 Method for producing activated catalyst for Fischer-Tropsch synthesis reaction, method for producing catalyst slurry, and method for supplying catalyst slurry to Fischer-Tropsch synthesis reactor
JP5827343B2 (en) * 2010-12-22 2015-12-02 サウディ ベーシック インダストリーズ コーポレイション Useful catalysts for Fischer-Tropsch synthesis
EP2679568A1 (en) 2012-06-25 2014-01-01 Saudi Basic Industries Corporation Process for production ethylene and propylene from syngas
WO2014001354A1 (en) 2012-06-27 2014-01-03 Saudi Basic Industries Corporation Catalyst and process for the selective production of lower hydrocarbons c1-c5 from syngass with low methane and co2 production
GB201214122D0 (en) * 2012-08-07 2012-09-19 Oxford Catalysts Ltd Treating of catalyst support
WO2015015316A2 (en) 2013-07-31 2015-02-05 Saudi Basic Industies Corporation Catalyst for conversion of synthesis gas
CA2977175C (en) 2015-02-25 2022-11-15 Sasol Technology (Pty) Limited A hydrocarbon synthesis process
WO2018029548A1 (en) 2016-08-11 2018-02-15 Sasol South Africa (Pty) Limited A cobalt-containing catalyst composition
GB201614363D0 (en) * 2016-08-23 2016-10-05 Bp Plc Fischer-tropsch catalyst performance enhancement process
US20190308876A1 (en) * 2016-11-30 2019-10-10 Sabic Global Technologies B.V. Apparatus and method related to carbon dioxide removal
EP3749736A1 (en) 2018-02-09 2020-12-16 Bp P.L.C. Fischer-tropsch process, supported fischer-tropsch synthesis catalyst and uses thereof
EP3628400A1 (en) 2018-09-26 2020-04-01 Bp P.L.C. Fischer-tropsch process, supported fischer-tropsch synthesis catalyst and uses thereof
EP3549996A1 (en) * 2018-04-03 2019-10-09 Evonik Degussa GmbH Olefins based on fischer-tropsch synthesis
WO2020064929A1 (en) 2018-09-28 2020-04-02 Bp P.L.C. Fischer-tropsch process
RU2732328C1 (en) * 2020-03-02 2020-09-15 Роман Евгеньевич Яковенко Method for obtaining hydrocarbons c5-c18 of carbon monoxide and hydrogen

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US4463101A (en) * 1980-12-29 1984-07-31 Mobil Oil Corporation Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha
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Also Published As

Publication number Publication date
ZA9711090B (en) 1998-06-15
DE69711714D1 (en) 2002-05-08
EP0966415B1 (en) 2002-04-03
MY118696A (en) 2005-01-31
EP0966415A1 (en) 1999-12-29
US5958985A (en) 1999-09-28
DZ2370A1 (en) 2002-12-28
CA2274688A1 (en) 1998-06-18
ID21757A (en) 1999-07-22
WO1998025870A1 (en) 1998-06-18
NO329313B1 (en) 2010-09-27
DE69711714T2 (en) 2002-07-18
SA97180722B1 (en) 2005-06-08
AU718101B2 (en) 2000-04-06
NO992860L (en) 1999-06-11
CA2274688C (en) 2006-10-24
NO992860D0 (en) 1999-06-11
AU5858298A (en) 1998-07-03
ES2175521T3 (en) 2002-11-16
RU2187486C2 (en) 2002-08-20

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